ABSTRACTThe thermo‐physical response of timber structures in fire is complex. For this reason, debate still exists today as to the best approaches for simulating thermal response in fire using tools such as finite element analysis (FEA) modelling. Much of the debate is concerned with the thermal properties of timber, for example, conductivity, specific heat and density, at elevated temperature and how such properties should be implemented or interpreted in numerical calculations. For practitioners intending to use modelling as a fire design tool for timber buildings, guidance exists on the thermal properties of softwood in Annex B of EN 1995‐1‐2. These properties are limited for use under standard fire exposure conditions because of the way in which they were derived from calibration against focussed test data. As a result, they cannot be applied to non‐standard fires, which are more representative of real fires due to a combination of varying heating rates and the decay phase of fire development.The limitations of the standard fire test (and associated curve) are widely understood. As a result, much recent structures in fire research has focussed on the ‘performance based design’ of buildings subject to increasingly realistic fire conditions. Such an approach allows engineers to quantify the level of safety that can be achieved in a building should a fire occur. In addition, the design of buildings to withstand fires proportionate to the risks foreseen and also the geometry present results in better value buildings that are inherently more robust. For the same approaches and associated benefits to be realised for timber buildings, then a number of barriers must be overcome. The most obvious of these is engineers' ability to determine timber structure temperatures as a result of fires other than the standard fire curve. This however presents a number of challenges.Upon heating, the moisture bound within begins to evaporate, volatiles begin to flow from the heated surface and char forms. The rate of which these behaviours occur and the nature of the char that forms depends on a number of factors, but most notably the rate of heating. Upon cooling, the timber member continues to generate heat energy as the surface oxidises. As a result, any models intended to simulate temperature development must consider the relationship not only between temperature and thermo‐physical characteristics but also between heating rate and the process of heat generation. Many models have been developed for this purpose; however, they are extremely complex and are some way from being ready for implementation as design tools. This paper proposes implementing ‘heat of hydration’ routines, intended for the curing of concrete structures, to simulate the heating and cooling process in timber structures. Such routines are available in many commercial FEA software packages. The adoption of the hydration routines allows the heat generation process, as a result of oxidation, to be considered in parallel with solid phase heat transfer using apparent thermal properties.The approach is shown to be very effective in simulating temperature development in timber members subject to parametric design fires. The models developed are benchmarked against experiments conducted in the 1990s by SP Trätek. Predictably, a number of the heat generation parameters adopted are shown to depend on the fire dynamics considered. However, recommended parameters are given that provide an acceptable level of accuracy for most design purposes. Copyright © 2012 John Wiley & Sons, Ltd.