Thermal Quench Research Articles

Cr3+-Doped LiAlO2 NIR-I Emitting Phosphors with Superior Resistance to Thermal Quenching for Night Vision Monitoring and Bioimaging.

Near-infrared phosphor-converted light-emitting diodes (NIR pc-LEDs) as a new NIR light source has outstanding application potential in the fields of NIR spectroscopy analysis, sensing, imaging, and pattern recognition. Therefore, the development of NIR phosphors with good NIR luminescence thermal stability has attracted much attention. To this end, we developed LiAlO2:Cr3+ garnet-type NIR phosphors by a high-temperature solid-state reaction method. Under 405 nm excitation, the Cr3+ ions located in tetrahedrons of LiAlO2 emit NIR emission in a broadband NIR emission that covers 650-900 nm mixed with several sharp narrowband R-line emissions, which showed excellent luminescence thermal stability with integrated intensity of emission measured at 573 K is ∼90.86% of that measured at 303 K caused by good structural rigidity and low thermal expansion coefficient of the matrix material. An NIR pc-LED device assembled with the optimized LiAlO2:Cr3+ and a commercially available purple LED chip emitted NIR output power of ∼98.172 mW at a driving current of 300 mA and demonstrated an electro-optical conversion efficiency of ∼9.09%, while demonstrated it has excellent application potential in the fields of night vision monitoring and biomedical imaging.

Thermal Quenching Mechanism of Mn4+ in Na2SiF6, NaKSiF6, and K2SiF6 Phosphors: Insights from the First-Principles Analysis.

This study aims to identify the key factors governing the thermal quenching of Mn4+ ion luminescence in fluoride-based phosphor materials used as red emitters in modern-day phosphor-converted LED devices. Here, we employ first-principles calculations for Mn4+-doped Na2SiF6, NaKSiF6, and K2SiF6 hosts to explore how host properties and local coordination environments influence thermal quenching behavior. The ΔSCF method was used to model the geometric structures of the Mn4+4A2 (ground) and 2E, 4T2 (excited) states and the energies of the optical transitions between these states. Our results reveal that thermal quenching in Na2SiF6 and K2SiF6 phosphors occurs through thermally activated 2E → 4T2 → 4A2 crossover. In contrast, thermal quenching in NaKSiF6 is due to other nonradiative decay pathways. Investigations of the mechanical stability of these fluorides show that NaKSiF6 is mechanically unstable. We suggest that this property of the host limits the luminescence efficiency of the embedded Mn4+ ions. We also determined the reason for the difference in the intensity of the 2E → 4A2 emission transition (ZPL) in the systems. These findings advance our fundamental understanding of the thermal quenching mechanism of Mn4+ ion luminescence in fluorides, and the results can aid future discoveries of technologically useful phosphors through high-throughput design methodologies.

Thermal quench modeling of REBCO racetrack coils under either alternating current or short-circuit voltage

Abstract Racetrack coils in REBCO High-Temperature Superconductor (HTS) motors help to increase the power-over-weight ratio by raising the magnetic flux density and output power. Nevertheless, HTS motors face thermal quench due to self-heating effects when subjected to alternating or short-circuit onset DC voltage. Additionally, thermal events have been observed due to screening currents when motors operate at high frequencies. Therefore, for the safe operation of HTS motors, quench research is crucial. To accurately simulate and analyze quench events in different scenarios, it is imperative to employ fast and precise software to numerically model the electrothermal behavior in racetrack coils. Our contribution involves the development of a novel and efficient model implemented in C++ that takes screening currents into account. This model is designed to conduct coupled electromagnetic and electrothermal analyses, utilizing variational methods. Specifically, the model incorporates both Minimum Electro-Magnetic Entropy Production and the Finite Difference Method. In this article, we explore the phenomenon of temperature rise within a racetrack coil subjected to either alternating or DC voltages of magnitudes ranging from 0.1 V to 1000 V. The study encompasses conditions of adiabatic operation and heat exchange with liquid nitrogen (LN2). Among other results, we found that in moderate DC voltages like 10 V, non-uniformity in the AC loss causes highly localized quench at the central turns. Then, screening currents play a key role also for DC voltages. The developed model exhibits the potential to comprehensively and swiftly analyze the electromagnetic and electrothermal characteristics of real-world superconducting applications, including high-field rotating machines, such as motors for aviation.

Interrelation of macroscopic mechanical properties and molecular scale thermal relaxation of biodegradable and non-biodegradable polymers

Comparative analysis of macroscopic mechanical properties of a biodegradable polymer polypropylene carbonate (PPC) is carried out concerning two most commonly used, non-biodegradable synthetic polymers-high-density polyethylene (HDPE) and linear-low density polyethylene (LLDPE). Responses of the films of these polymers when subjected to mechanical and thermal stresses are analyzed. Response to tensile stress reveals the highest elongation at break (EB) in PPC films (396 ± 104 mm), compared to HDPE (26 ± 0.5 mm) and LLDPE (301 ± 143 mm), although the elastic modulus (YM) of PPC is around 50 ± 6 MPa, 3-fold lesser than LLDPE (YM = 153 ± 7 MPa) and 6-fold lesser than HDPE (YM = 305 ± 32 MPa). The plastic deformation response of PPC is intermediate to that of HDPE and LLDPE; initial strain softening is followed by strain hardening in LLDPE, a plateau region in PPC, and prolonged strain softening in HDPE. Crystalline domains in HDPE produce restriction on molecular motion. Crystallinity abruptly decreases by 70% in HDPE following a thermal quench, showing the possibility of free chain molecular mobility during plastic deformation. High correlation among Raman modes for all polymers reveals cooperative relaxation processes after thermal quench; C-C stretching modes and C-H bending, CH2wagging modes have Pearson's correlation coefficient 0.9. The integrated peak intensity and width of the C-C stretching Raman mode is 3-fold higher in PPC than HDPE after a thermal quench, showing enhanced molecular mobility and contributing modes in PPC. The peak width of this mode shows a strong negative correlation of -0.7 with the YM and a strong positive correlation of 0.6 with EB, showing that higher amorphicity leads to enhanced molecular mobility and EB at the cost of YM. This study reveals importance of molecular-scale response in governing the macroscopic properties of polymers.

Simulation of DIII-D disruption with argon pellet injection and runaway electron beam

Abstract The next generation of large tokamaks, including ITER, will be equipped with a disruption mitigation system (DMS) that can be activated if a disruption is deemed to be imminent. Introducing impurities by pellet (large or shattered) or massive gas injection has been shown to be an effective mitigation mechanism on many tokamaks. The goal of the mitigation is to lessen the thermal and electromagnetic loads from the disruption without generating enough high-energy (runaway) electrons to damage the device. Variations of this mitigation process with impurity injection are presently being tested on many experiments. We have modeled one such impurity injection experiment on DIII-D using the M3D-C1 nonlinear 3D extended MHD code (Jardin et al 2012 Comput. Sci. Discovery 6 014002), The model includes an argon large pellet injection and ablation model, impurity ionization, recombination, and radiation, and runaway electron formation and subsequent evolution, including both Dreicer and avalanche sources. We obtain reasonable agreement with the experimental results for the timescale of the thermal and current quench and for the magnitude of the runaway electron plateau formed during the mitigation. This is the first 3D full MHD simulation with pellets and REs to simulate the disruption process and it also provides a partial validation of the M3D-C1 DMS model.

Collisionless cooling of perpendicular electron temperature in the thermal quench of a magnetized plasma

Thermal quench of a nearly collisionless plasma against an isolated cooling boundary or region is an undesirable off-normal event in magnetic fusion experiments, but an ubiquitous process of cosmological importance in astrophysical plasmas. Parallel transport theory of ambipolar-constrained tail electron loss is known to predict rapid cooling of the parallel electron temperature \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$T_{e\\parallel },$$\\end{document} although \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$T_{e\\parallel }$$\\end{document} is difficult to diagnose in actual experiments. Instead direct experimental measurements can readily track the perpendicular electron temperature \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$T_{e\\perp }$$\\end{document} via electron cyclotron emission. The physics underlying the observed fast drop in \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$T_{e\\perp }$$\\end{document} requires a resolution. Here two collisionless mechanisms, dilutional cooling by infalling cold electrons and wave-particle interaction by two families of whistler instabilities, are shown to enable fast \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$T_{e\\perp }$$\\end{document} cooling that closely tracks the mostly collisionless crash of \\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$T_{e\\parallel }.$$\\end{document} These findings motivate both experimental validation and reexamination of a broad class of plasma cooling problems in laboratory, space, and astrophysical settings.

Optimizing the thermal stability of Tb3+-based phosphor through intervalence charge transfer compensation and charge transfer band edge red-shift

Thermal quenching (TQ) limits the large-scale practical application of most luminescent materials, so the investigation on thermal quenching phenomenon of phosphors has emerged as a prominent research area, garnering significant attention in academic circles. The thermal quenching performance is closely related to the charge transfer band (CTB) and intervalence charge transfer (IVCT) band. Herein, we study the correlation between CTB edge red-shift, IVCT band position and the thermal stability of Tb3+-based lithium tantalate phosphors, aiming to regulate the thermal quenching performance. The results show that totally anomalous thermal quenching (TATQ) was found to exist in LiTaO3:xTb3+ phosphors during the process of temperature rising, and the whole CTB edge absorption showed a red-shift and enhance with increasing temperature. Based on this characteristic phenomenon, under the excitation of CTB edge (270 nm), the phosphor exhibits obvious antithermal quenching. In addition, the existence of the Tb3+-Ta5+ IVCT band can be used as a compensation channel for Tb3+ 5D3 → 5D4 transition, which makes the phosphor produce stronger antithermal quenching performance. Accordingly, the co-regulation of the CTB edge red-shift and IVCT compensation effect was proposed. Modulation of Tb3+ concentration revealed that during thermal activation (λem = 547 nm), LiTaO3:0.005Tb3+ luminescence integral intensity (423 K) reaches 255.6% of the initial intensity, phosphor achieves the most excellent performance. The maximum absolute sensitivity (Sa) and relative sensitivity (Sr) for temperature sensing scheme based on the intensity ratio of excitation spectrum CTB and CTB-IVCT reaches 0.996%@523 K and 0.927%@523 K, respectively. The co-regulation strategy of thermal activation-induced CTB edge red-shift and IVCT compensation channel provides a promising research idea for developing Tb3+-based antithermal quenching luminescent materials.

Efficient and Near-Zero Thermal Quenching Cr3+-Doped Garnet-Type Phosphor for High-Performance Near-Infrared Light-Emitting Diode Applications.

In recent years, near-infrared (NIR) phosphors have attracted great research interest due to their unique physical properties and broad application prospects. However, obtaining NIR phosphors with both high quantum efficiency and excellent thermal stability remains a great challenge. In this study, novel NIR Ca3Mg2ZrGe3O12:Cr3+ phosphors were successfully prepared using a high-temperature solid-phase method, and the structure and luminescent properties of the material were systematically investigated. Ca3Mg2ZrGe3O12:0.01Cr3+ emits NIR light in the range of 600 to 900 nm with a peak at 758 nm and a half-height width of 89 nm under the excitation of 457 nm blue light. NIR luminescence shows considerable quantum efficiency, and the internal quantum efficiency of the optimized sample is up to 68.7%. Remarkably, the Ca3Mg2ZrGe3O12:0.01Cr3+ phosphor exhibits a near-zero thermal quenching behavior, and the luminescence intensity of the sample at 250 °C maintains 92% of its intensity at room temperature. The mechanism of high thermal stability has been elucidated by calculating the Huang Kun factor and activation energy. Finally, NIR pc-LED devices prepared from Ca3Mg2ZrGe3O12:0.01Cr3+ phosphor with commercial blue LED chips have good performance, proving that this Ca3Mg2ZrGe3O12:0.01Cr3+ NIR phosphor has potential applications in night vision and biomedical imaging.

Wide Range Near-Zero Thermal Quenching of Orange-Yellow Phosphor via Impeding Self-Oxidation of Eu2+ for Versatile Optoelectronic Applications.

Li2SrSiO4:Eu2+ is a promising substitute for traditional Y3Al5O12:Ce3+ (YAG:Ce3+) owing to its strong orange-yellow emission of 4f-5d transition originating from Eu2+ dopant, covering the more red-light region. However, its inevitable luminescence thermal quenching at high temperatures and the self-oxidation of Eu2+ strongly impede their applications. Their remediation remains highly challenging. Herein, an anti-self-oxidation(ASO) concept of Eu2+ in Li2SrSiO4 substrate by adding trivalent rare-earth ions (A3+: A = La, Gd, Y, Lu) for highly efficient and stable orange-yellow light emission have been proposed. A significantly increased orange-yellow emission (202% improvement) from Li2Sr0.95A0.05SiO4:Eu2+ with a wide range near-zero thermal quenching is obtained, superior to other Eu2+ activated phosphors. The presence of A3+ ions with various radii modifies the ASO degree of Eu2+ ions, achieving the tunable chemical state, composition, electronic configuration, crystal-field strength, and luminescent characteristics of the developed phosphors. For the proof of the concept, a W-LED device and a PDMS (Polydimethylsiloxane) luminescent film are fabricated, endowing excellent luminescence performance and thermal stability and the huge application prospects of Li2SrSiO4:Eu2+ in lighting and display fields.

Killing Three Birds with One Stone: Energy Transfer Inducing Efficient, Zero Thermal Quenching, and Emission‐Color Tunable Phosphors

AbstractRed emission phosphors with high efficiency and excellent thermal stability are essential for phosphor‐converted light‐emitting diodes (pc‐LEDs). Na2MgPO4F: Mn2+ shows a very weak red emission peak at 615 nm due to 3d–3d forbidden transition. And it exhibits a normal thermal quenching behavior. Blue‐emitting Eu2+ with anti‐thermal quenching (ATQ) is introduced to tune the emission color, emission efficiency, and thermal stability of Mn2+ in Na2MgPO4F. The emission color of Na2MgPO4F: Eu2+, Mn2+ phosphors can be tuned by increasing the Mn2+ content. The internal and external quantum efficiencies of Na2MgPO4F:0.03Eu2+, 0.05Mn2+ are 89.3% and 41.1%, respectively, which are much higher than those of the Mn2+‐doped ones. Furthermore, the ATQ effect of Eu2+ is also transferred to Mn2+ via energy transfer, which results in Na2MgPO4F: Eu2+, Mn2+ phosphors with zero thermal quenching (ZTQ). The cooperation of energy transfer, enhanced absorption, and increased defects amount promotes the achievement of ZTQ in the co‐doped samples. Two white pc‐LEDs with a color rendering index of more than 90 are manufactured by using the as‐synthesized Na2MgPO4F: Eu2+, Mn2+ phosphors combined with near‐UV chips. This study not only provides high‐performance Eu2+, Mn2+ co‐doped phosphors suitable for high‐quality solid‐state lighting, but also exhibits a killing‐three‐birds‐with‐one‐stone strategy to obtain efficient, thermally stable, and color‐tunable phosphors.

Disruption runaway electron generation and mitigation in the Spherical Tokamak for Energy Production (STEP)

Abstract Generation of Runaway Electrons (REs) during plasma disruptions is of great concern for ITER and future reactors based on the tokamak concept. The current STEP (Spherical Tokamak for Energy Production) concept design features a plasma current higher than 20 MA, thus expected to be in a regime of very high avalanche multiplication. This is confirmed by modelling runaway electron generation in unmitigated disruptions using the code DREAM, with hot-tail generation found to be the dominant primary generation mechanism and avalanche confirmed to be extremely high. Varying assumptions for the prescribed thermal quench phase (duration, final electron temperature) as well as the wall time, the plasma-wall distance, and shaping effects, all STEP unmitigated disruptions are found to generate large runaway electron beams (from 10 MA up to full conversion). The possibility of RE avoidance is first studied by idealized, i.e. radially uniform, impurity injection of a mixture of argon and deuterium, with ad-hoc particle transport arising from the stochasticity of the magnetic field during the thermal quench (TQ). Unfortunately, no such injection scenario allows runaways to be avoided while respecting the other constraints of disruption mitigation. STEP disruption mitigation system (DMS) has then been tested with DREAM, by modelling 2-stage Shattered Pellet Injections consisting of pure D2 followed by Ar+D2. Such a scheme is found to reduce the generation of REs by the hot-tail mechanism, reducing the final RE current to about 13 MA, but isn't sufficient by itself. Options for mitigating such a RE beam (benign termination scheme), as well as estimations of required RE losses during the current quench (from a potential passive RE mitigation coil) will also be briefly discussed.

Modeling of Soot Emission in Turbulent Diffusion Flames Impinging on a Cold Surface

ABSTRACT A hydrocarbon flame impinging on a cold surface produces an enhanced soot emission compared to the identical free flame. Cooking with biomass fuels is one practical process where soot emissions due to flame impingement has important environmental and health consequences. This problem was examined in a simplified system in which a turbulent non-premixed ethylene flame impinged on a cold surface. Previous experiment on this configuration examined the influence of a number of parameters on soot emission. The present paper uses numerical modeling to investigate the mechanism of soot emission enhancement in this configuration. Variations in the height of the surface above the fuel jet inlet showed going through a maximum, replicating the data. Since soot behavior can be affected by both thermal quench and flow field disruption, we decoupled the processes by replacing the cold surface with an adiabatic surface. These results indicated that most of the emission enhancement was due to the flow field disruption and not due to thermal quench. The modeling suggests that the presence of the surface changes the scalar dissipation rate, which influences C2H2 concentration, a key species in the soot surface growth process. Specifically, the surface causes a spike in the scalar dissipation rate adjacent to the surface, which significantly influences C2H2 concentration and results in increased soot production. The surface also forces the flame to spread radially, allowing more O2 to penetrate the flame immediately, enhancing the soot oxidation process. The combination of the enhanced soot production and oxidation produces the observed behavior.

Simulation of Rotating Asymmetric Sideways Forces during Vertical Displacement Events in CFETR

Abstract Tokamak plasmas with elongated cross sections are susceptible to vertical displacement events (VDEs), which can damage the first wall via heat flux or electromagnetic (EM) forces. We present a 3D nonlinear reduced magnetohydrodynamic (MHD) simulation of CFETR plasma during a cold VDE following the thermal quench, focusing on the relationship among the EM force, plasma displacement, and the n = 1 mode. The dominant mode, identified as m/n = 2/1, becomes destabilized when most of the current is contracted within the q = 2 surface. The displacement of the plasma current centroid is less than that of the magnetic axis due to the presence of SOL current in the open field line region. Hence, the symmetric component of the induced vacuum vessel current is significantly mitigated. The direction of the sideways force keeps a constant phase approximately compared to the asymmetric component of the vacuum vessel current and the SOL current, which in turn keep in-phase with the dominant 2/1 mode. Their amplitudes are also closely associated with the growth of the dominant mode. These findings provide insights into potential methods for controlling the phase and amplitude of sideways forces during VDEs in the future.

Cryogenic system of the high performance 1.3 GHz 9-cell superconducting radio frequency prototype cryomodule

High quality factor 1.3 GHz 9-cell superconducting radio frequency (SRF) cavity cryomodule is the core technology of the international advanced accelerator. China’s first high-quality factor 1.3 GHz 9-cell SRF cavity cryomodule was developed, assembled and tested at the Institute of High Energy Physics (IHEP), Chinese Academy of Sciences for the Dalian Advanced Light Source (DALS) and Circular Electron Positron Collider (CEPC) R&D. The 9-cell cavities in the cryomodule achieved a high average intrinsic quality factor (Q0) of 3.8 × 1010 at 16 MV/m and 3.6 × 1010 at 21 MV/m in the horizontal test. With such high specifications, the SRF cavity system has corresponding requirements for the cryogenic system. Key criteria for stable and reliable operation include a dependable cryogenic refrigeration system and process design, good thermal insulation, pressure control, temperature uniformity, and quench protection, etc. IHEP has successfully completed cryogenic testing development of the first 1.3 GHz 9-cell SRF prototype cryomodule. The whole cooldown period was 74 h, and the automatic cooldown was completed. The successful development and implementation of the 1.3 GHz superconducting cryomodule cryogenic system will provide a stable and reliable test environment for advanced superconducting cavity cryogenic testing, which will be critical in promoting the further development of the Free Electron Laser (FEL) and CEPC projects.

Transport characteristic evaluation of runaway electrons in an ITER disruption simulation

In previous studies, it has been observed that the transport of energetic electrons decreases with increasing energy. This observation is a global and long-time-scale result, attributed to the space-averaged perturbations. In this work, we focus on the local and instantaneous transport characteristics of runaway electrons (REs) during the phase of tokamak disruption, with REs speeds close to the speed of light. To simulate the dynamics of REs, we utilize a particle tracing code called PTC. By coupling PTC with the MHD code JOREK, we are able to study the energy and spatial dependence of RE transport. Our investigations reveal that the finite orbit width (FOW) effect plays an important role in RE transport. This effect is influenced by the relative direction of the electron drift and the magnetic field line. Specifically, the FOW effect strengthens the transport when the drift direction aligns with the deflecting direction of the field line. And we compare the transport profiles among three time slices: at the beginning of the thermal quench, during the thermal quench, and at the beginning of the current quench. In this ITER disruption simulation, the perturbation scale is strong and δB/B is up to 0.05 at developed thermal quench stage. It is reasonable that the influence of FOW effect on transport is less than that of magnetic perturbation even if the energy of REs is about hundreds MeV and the orbit width is equal to or greater than the perturbation length. These analyses provide insights into the mechanisms of RE transport based on magnetic perturbations.

Radiation asymmetry in JET disruption mitigation experiments with shattered pellet injection

In ITER, to mitigate the deleterious effects of plasma disruptions, massive quantities of radiating impurities will be injected into the disrupting plasma by shattered pellet injectors (SPI) to pre-emptively radiate away the stored thermal and magnetic energy (Lehnen et al Proc. 27th IAEA Fusion Energy Conf. (FEC 2018) (Gandhinagar, India) EX/P7-12). However, asymmetries in the radiation pattern could result in intense photon flashes during the thermal quench that could locally damage or erode the stainless steel plasma-facing surface of the diagnostic port plugs (Pitts et al 2015 J. Nucl. Mater. 463 748–75). Experiments have been undertaken at JET to assess the potential dependence of the radiated power asymmetry on plasma energy during SPI mitigated disruptions. Calculations of the toroidal asymmetry in the radiated power indicate that the toroidal peaking factor is largest near the SPI position and decreases with the plasma stored energy, which is a promising result in view of radiation heat loads during mitigated disruptions in ITER.

Luminescence thermometry based on negative thermal expansion host matrices

In practical applications involving high temperatures in oxides and oxide-based structures, challenges such as flames and aggressive environments are common. Turbine engines, where oxide coatings are crucial, face difficulties in temperature measurement due to rapid part motion. The emergence of luminescence thermometry offers advantages in such scenarios and has been studied extensively. However, thermal quenching (TQ) of luminescence happening at such conditions limits the use of phosphor materials as luminescence thermometers for high-temperature sensing, thereby restricting the achievement of sufficient sensitivities and temperature resolutions. Thus, thermally stable phosphors, or more favorably phosphors with anti-TQ of luminescence, have been explored to address TQ issues of luminescence thermometry in recent years. Particularly, phosphors based on negative thermal expansion (NTE) as host matrices have shown feasibility in luminescence thermometry at temperatures exceeding 600 °C. This review focuses on NTE-based phosphors, addressing their luminescent properties and analytical techniques for extending the temperature measurement range. The aim of this review is for better understanding of the structural changes with temperature of NTE-based phosphors, assessing their potential for temperature sensing in harsh conditions, and ultimately encouraging researchers to explore new NTE-based phosphors.

Runaway electron dynamics in ITER disruptions with shattered pellet injections

This study systematically explores the parameter space of disruption mitigation through shattered pellet injection in ITER with a focus on runaway electron (RE) dynamics, using the disruption modeling tool Dream. The physics fidelity is considerably increased compared to previous studies, by e.g. using realistic magnetic geometry, resistive wall configuration, thermal quench onset criteria, as well as including additional effects, such as ion transport and enhanced RE transport during the thermal quench. The work aims to provide a fairly comprehensive coverage of experimentally feasible scenarios, considering plasmas representative of both non-activated and high-performance DT operation, different thermal quench onset criteria and transport levels, a wide range of hydrogen and neon quantities injected in one or two stages, and pellets with various characteristic shard sizes. Using a staggered injection scheme, with a pure hydrogen injection preceding a mixed hydrogen-neon injection, we find injection parameters leading to acceptable RE currents in all investigated discharges without activated runaway sources. Dividing the injection into two stages is found to significantly enhance the assimilation and minimize RE generation due to the hot-tail mechanism. However, while a staggered injection outperforms a single stage injection also in cases with radioactive RE sources, no cases with acceptable RE currents are found for a DT-plasma with a 15MA plasma current.

Influence of the preparation method (thermal quench, ball-milling, dehydration and freeze-drying) on the dynamical properties of glassy trehalose

Dielectric relaxation measurements have been performed on the glassy states of trehalose reached using different routes of amorphisation: thermal quench of the liquid state, milling of the anhydrous crystalline form, freeze-drying and dehydration of the dihydrate crystalline form. This study has revealed that all the glassy states are characterized by two relaxation processes respectively attributed to the slow Johari-Goldstein mode and to fast secondary intramolecular relaxations. These sub-Tg secondary relaxations are however strikingly different in the four glassy states revealing different energy landscape topologies.

Plasmoid drift and first wall heat deposition during ITER H-mode dual-SPIs in JOREK simulations

The heat flux mitigation during the thermal quench (TQ) by the shattered pellet injection (SPI) is one of the major elements of disruption mitigation strategy for ITER. It’s efficiency greatly depends on the SPI and the target plasma parameters, and is ultimately characterised by the heat deposition on to the plasma facing components. To investigate such heat deposition, JOREK simulations of neon-mixed dual-SPIs into ITER baseline H-mode and a ‘degraded H-mode’ with and without good injector synchronization are performed with focus on the first wall heat flux and its energy impact. It is found that low neon fraction SPIs into the baseline H-mode plasmas exhibit strong major radial plasmoid drift as the fragments arrive at the pedestal, accompanied by edge stochasticity. Significant density expulsion and outgoing heat flux occurs as a result, reducing the mitigation efficiency. Such drift motion could be mitigated by injecting higher neon fraction pellets, or by considering the pre-disruption confinement degradation, thus improving the radiation fraction. The radiation heat flux is found to peak in the vicinity of the fragment injection location in the early injection phase, while it relaxes later on due to parallel impurity transport. The overall radiation asymmetry could be significantly mitigated by good synchronization. Time integration of the local heat flux is carried out to provide its energy impact for wall heat damage assessment. For the baseline H-mode case with full pellet injection, melting of the stainless steel armour of the diagnostic port could occur near the injection port, which is acceptable, without any melting of the first wall tungsten tiles. For the degraded H-mode cases with quarter-pellet SPIs, which have 1/4 total volume of a full pellet, the maximum energy impact approaches the tolerable limit of the stainless steel with un-synchronized SPIs, and stays well below such limit for the perfectly synchronized ones.