Thermal Management Properties Research Articles

Multifunctional Smart Fabrics with Integration of Self-Cleaning, Energy Harvesting, and Thermal Management Properties.

Due to their good wearability, smart fabrics have gradually developed into one of the important components of multifunctional flexible electronics. Nevertheless, function integration is typically accomplished through the intricate stacking of diverse modules, which inevitably compromises comfort and elevates processing complexities. The integration of these discrete functional modules into a unified design for smart fabrics represents a superior solution. Here, we put forward a rational approach to functional integration for the typical challenges of thermal management, energy supply, and surface contamination in smart fabrics. This sandwich-structured multilayer fabric (MLF) is obtained by continuous electrospinning of two layer P(VDF-HFP) fabric and one layer P(VDF-HFP) fabric functionalized with core-shell SiO2/ZnO/ZIF-8 (SZZ) nanoparticles. Specifically, MLFs achieve effective and stable energy harvesting in triboelectric nanogenerators (TENGs) with hydrophobicity and antibacterial properties. Meanwhile, MLFs also have high mid-infrared emissivity and sunlight reflectivity, successfully realizing radiative cooling under different climates, and have been applied in wearing clothing, roof shading, and car covers. This work may contribute to the design and manufacturing of next-generation thermal comfort smart fabrics and wearable electronics, particularly in terms of the rational design of multifunctional devices.

Exfoliation of boron nitride nanosheets by liquid phase method based on deep eutectic solvents and their thermal management application

AbstractBoron nitride had emerged as an innovative thermally conductive filler, garnering increasing attention from researchers. However, there was a need to create new methods for efficiently producing functionalized boron nitride nanosheets with enhanced thermal conductivity and dispersion. In this study, a novel approach was introduced to utilize deep eutectic solvents as additives to facilitate the exfoliation of boron nitride nanosheets. This method offered significant advantages in terms of cost‐effectiveness (low additives level) and high yield (about 60%). Furthermore, the resulting epoxy resin composite material exhibited outstanding thermal conductivity and thermal management properties. The thermal conductivity of EP/d‐BNNS composites reached 1.02 W/mK at 20 wt% d‐BNNS loading. Additionally, the composite material demonstrated good thermal stability and low dielectric properties. This work demonstrated that this proposed approach represents an effective means for the scalable production of boron nitride nanosheets.Highlights The boron nitride nanosheets were obtained by deep eutectic solvents (DES) ball milling method. The exfoliated boron nitride exhibits superior dispersion stability. The thermal conductivity of EP composites is significantly improved.

Multifunctional 3D-Printed Thermoplastic Polyurethane (TPU)/Multiwalled Carbon Nanotube (MWCNT) Nanocomposites for Thermal Management Applications

In this work, multiwalled carbon nanotubes (MWCNTs) were melt-compounded into a novel thermal energy storage system consisting of a microencapsulated paraffin, with a melting temperature of 6 °C (M6D), dispersed within a flexible thermoplastic polyurethane (TPU) matrix. The resulting materials were then processed via Fused Filament Fabrication (FFF), and their thermo-mechanical properties were comprehensively evaluated. After an optimization of the processing parameters, good adhesion between the polymeric layers was obtained. Field-Emission Scanning Electron Microscopy (FESEM) images of the 3D-printed samples highlighted a uniform distribution of the microcapsules within the polymer matrix, without an evident MWCNT agglomeration. The thermal energy storage/release capability provided by the paraffin microcapsules, evaluated through Differential Scanning Calorimetry (DSC), was slightly lowered by the FFF process but remained at an acceptable level (i.e., >80% with respect to the neat M6D capsules). The novelty of this work lies in the successful integration of MWCNTs and PCMs into a TPU matrix, followed by 3D printing via FFF technology. This approach combines the high thermal conductivity of MWCNTs with the thermal energy storage capabilities of PCMs, creating a multifunctional nanocomposite material with unique thermal management properties.

Bacterial cellulose-based Janus energy storage phase change composite aerogel for efficient interfacial solar vapor generation

Interfacial solar evaporation systems based on Janus structures exhibit potential application prospects in terms of salt tolerance. However, intermittent and unstable light conditions limited the evaporation rate and water production performance of the evaporators. The introduction of energy storage phase change (ESPC) composite materials into the interface solar evaporators can effectively solve this problem. In this work, bacterial cellulose (BC) is selected as the matrix material, sodium alginate (SA) and multi-walled carbon nanotubes (MWCNTs) are added as functional fillers, and porous composite aerogels are prepared using direct freeze-drying. On this basis, Janus porous composite aerogel (J-BCS/CNT) with ESPC function is further constructed by depositing paraffin onto the upper layer of the aerogel through a unilateral vacuum impregnation method. The aerogel exhibits strong photothermal conversion capabilities and excellent thermal management properties. The addition of appropriate amount of MWCNTs enables it to obtain high latent heat storage and release functions, providing energy for operation in dark conditions. Under the solar irradiation of 1.5 kW m−2, J-BCS/CNT40% aerogel exhibits a high evaporation rate of 1.95 kg m−2h−1 in pure water and 0.67 kg m−2h−1 under dark conditions. The salt evaporation resistance test shows that the aerogel has excellent purification capabilities in high-concentration salt water (20 wt%) solutions. More importantly, the long-term energy storage-release tests of J-BCS/CNT in 3.5 wt% saline water indicate that the aerogel reveals excellent sustainability and latent heat release functions.

Yarn-Based Degradable Janus PPDO Fabric for Multifunctional Applications.

The growing high standard of people's wear has put forward requirements for fabrics, and multifunctional fabrics have been developed precisely in response to the requirements of the times. However, the incineration of waste fabrics produces a large amount of pollutants, resulting in a massive waste of resources and environmental pollution. Herein, the degradable nanofiber yarns (NYs) with self-cleaning properties were fabricated by in situ growth of SiO2 nanoparticles on the surface of the electrospun poly(p-dioxanone) (PPDO) NYs using the Stöber method. Then, the PPDO NYs were blended with carbon fibers and the PPDO/SiO2 NYs with themselves to form the Janus PPDO fabrics, respectively. The Janus PPDO fabric offered asymmetric wettability and dual personal thermal management properties. The PPDO/C side of the Janus PPDO fabric provided 65.8 °C at 1.5 V or 58.5 °C under one sunlight intensity for radiative heating. The PPDO/SiO2 side exhibited high solar reflectivity (81.8%) and mid-infrared (MIR) emissivity (99.1%), which reduced the skin temperature by 4.6 °C, resulting in radiative cooling. Moreover, the Janus PPDO fabrics display an excellent electromagnetic interference (EMI) shielding performance (53.3 dB). Therefore, yarn-based degradable Janus fabric has a promising future in multifunctional wearable products.

Reactive extrusion for efficient preparation of high temperature resistant PA6T/66/BN composites with great thermal management and mechanical properties

High temperature resistant polymer-based composite with high thermal conductivity and great mechanical properties are highly demanded in the field of electronic devices for simultaneously meeting surface mounting process and high-power operation. The key to achieving this goal is to balance the contradiction between the high melt viscosity of high-temperature resistant polymers and the dispersibility of fillers. In this work, the high-performance polyamide 6T/66/hexagonal boron nitride (PA6T/66/BN) composites were fabricated successfully via the method combining prepolymerization and reactive extrusion. Results demonstrated that this method not only significantly improves the preparation efficiency of high temperature resistant polyamide and its composites, but also enables the prepared composites to reach 3.6 W/(m⋅K), over 299 °C and 67.8 MPa in thermal conductivity, melting point and tensile strength respectively. Furthermore, the prepared composite exhibits excellent thermal management effects on LED and CPU. Therefore, the results of this work are of great significance for the efficient preparation and wide application of high-temperature resistant polymer based thermally conductive composites.

Unlocking epoxy thermal management capability via hierarchical Ce-MOF@MoS2 hybrid constructed by in-situ growth method

This study demonstrates the preparation of needle-like Ce-MOF crystals on molybdenum disulfide (MoS2) nanosheets using in-situ growth technology. This hybrid structure significantly enhances the thermal management and mechanical properties of thermosetting epoxy resin (EP). Specifically, EP/Ce-MOF@MoS2-3 exhibits a notable increase in tensile strength (TS) to 50.87 MPa and elongation at break (EB) to 10.84 %. Moreover, Ce-MOF@MoS2 provides synergistic flame retardant benefits, reducing the peak heat release rate (pHRR) and total heat release (THR) of EP/Ce-MOF@MoS2-3 by 38 % and 12.64 %, respectively, compared to EP-0. Additionally, Ce-MOF@MoS2 suppresses smoke and reduces toxic emissions; at a 3 % loading, it decreases CO and CO2 production in EP nanocomposites by 48.8 % and 38.7 %, respectively. Thus, this Ce-MOF@MoS2 hybrid, synthesized via in-situ growth, offers a novel approach for developing EP nanocomposites with superior thermal management and mechanical properties, along with effective flame retardancy and reduced hazardous emissions during thermal events.

Construction of tree-ring mimetic 3D networks in polyvinyl alcohol/boron nitride composites for enhanced thermal management and mechanical properties

Constructing a three-dimensional (3D) filler network in polymer thermal interface materials (TIMs) is crucial for enhancing thermal conductivity and mechanical properties. However, the discontinuous and loose network of fillers are one of the main reasons hindering the joint improvement of thermal conductivity and mechanical properties. The construction of a regular and dense 3D continuous filler network remains a significant challenge. In this study, an innovative bidirectional freezing technique was designed to create a polyvinyl alcohol (PVA)/boron nitride (BN) composite with a tree-ring-like 3D network. This technique promotes the formation of 3D network consisting of long-range lamellar BN layers with a tree-ring-like structure by controlling the nucleation and growth of ice crystals along the bidirectional temperature gradient induced by a polytetrafluoroethylene (PTFE) cone. The resulting PVA/BN composite exhibits high thermal conductivity (6.25 W/m·K) due to the lower interfacial thermal resistance between fillers (1.271 × 10−7 K m2/W), and an enhanced tensile strength of 41.71 MPa, which is attributed to the regular and dense BN network. This study presents a feasible strategy for constructing a 3D continuous network structure in polymer-based TIMs, paving the way for advancements in thermal management solutions.

Mechanical–thermal coupling in micro-nanocavity graphene/paraffin phase change energy storage materials for heat management

Combining the superior thermal conductivity of graphene and the outstanding heat storage of paraffin, micro-nanocavity graphene/paraffin nanocomposites (MNGPNs) have recently served as promising thermal management materials in high-power microelectronic devices. However, current evaluations of the thermal management performances of MNGPNs are restricted in the lab condition, deviating from the complex mechanical–thermal coupling environment in practical scenarios. Here, we have investigated the structural and thermal management properties of MNGPNs with varying mechanical loads by in situ electron microscopy and in situ thermal characterizations. Our results reveal distinct mechanical–thermal coupling effects along in-plane and out-of-plane directions of MNGPNs. Specifically, mechanical loading reduces the porosity and enhances the heat transfer capacity of MNGPNs in the out-of-plane direction, while mechanical loading along the in-plane direction causes local damage to the graphene structure and weakens the heat transfer capacity of MNGPNs. Since the heat management performance of MNGPNs is dominated by the in-plane thermal transport, MNGPNs with mechanical loading show a delayed phase transition response time and unchanged phase transition enthalpy. This work provides in situ mechanical guidance for the practical application of MNGPNs for heat management.

Thermomechanical analysis of tungsten-copper joints for fusion applications using digital image correlation

The European DEMOnstration Fusion Power Plant DEMO represents a significant milestone in the progression towards sustainable fusion energy and a critical phase between ITER and commercial fusion reactors, aiming to demonstrate sustained net positive electricity production. Thanks to its properties, tungsten is a promising material for divertor armor. Coupled with copper alloys as heatsinks, they offer robust thermal management properties to deal with intense thermomechanical loads and irradiation damage. Understanding the thermomechanical behaviour of tungsten-copper joints during their application is then necessary for divertor design.This study presents experimental analysis on tungsten-copper brazed materials subjected to thermomechanical solicitations to simulate mono-block conditions with heat fluxes expected to reach 20 MW/m2 and so to face potential creep-fatigue failure. The experimental tests were coupled with Digital Image Correlation up to 400 °C to analyse the thermomechanical behaviour of these joints, providing insights into their thermal behaviour, structural integrity, damage accumulation, joint failure and identification of strains required for creep-fatigue assessment using design codes.

A regenerated cellulose fiber with high mechanical properties for temperature-adaptive thermal management

The escalating global population has led to a surge in waste textiles, posing a significant challenge in landfill management worldwide. In this work, ionic liquid 1-butyl-3-methylimidazole acetate ([Bmim]OAc) and DMF (N, n-dimethylformamide) were used as solvents to dissolve waste denim fabric, then vanadium dioxide (VO2) nanoparticles were introduced into the spinning solution, and cellulose fibers were regenerated by dry-wet spinning process, to promote the recycling of waste cotton fabric. Finally, regenerated cellulose fibers with high added value were prepared by dry-wet spinning. Through this innovative strategy, on the one hand, because VO2 can form a large number of hydrogen bonds between the regenerated cellulose molecules, and realize the cross-networking structure of the molecular chains inside the fiber, the mechanical properties of the regenerated cellulose fibers are enhanced. On the other hand, due to the thermal phase transformation characteristics of VO2, it also endows the regenerated cellulose fiber unique intelligent temperature control function. Compared with the pristine regenerated fiber, the tensile stress of the regenerated fiber after adding VO2 nanoparticles (F-VO2) increased by 25.6 %, reaching 158.68 MPa. In addition, the F-VO2 fibric provides excellent intelligent temperature control, reducing temperatures by up to 6.7 °C.

Cellulose–derived carbon scaffolds with bidirectional gradient Fe3O4 distribution: Integration of green EMI shielding and thermal management

Cellulose papers (CPs) possess a pore structure, rendering them ideal precursors for carbon scaffolds because of their renewability. However, achieving a tradeoff between high electromagnetic shielding effectiveness and low reflection coefficient poses a tremendous challenge for CP-based carbon scaffolds. To meet the challenge, leveraging the synergistic effect of gravity and evaporation dynamics, laminar CP-based carbon scaffolds with a bidirectional gradient distribution of Fe3O4 nanoparticles were fabricated via immersion, drying, and carbonization processes. The resulting carbon scaffold, owing to the bidirectional gradient structure of magnetic nanoparticles and unique laminar arrangement, exhibited excellent in-plane electrical conductivity (96.3 S/m), superior electromagnetic shielding efficiency (1805.9 dB/cm2 g), low reflection coefficients (0.23), and a high green index (gs, 3.38), suggesting its green shielding capabilities. Furthermore, the laminar structure conferred upon the resultant carbon scaffold a surprisingly anisotropic thermal conductivity, with an in-plane thermal conductivity of 1.73 W/m K compared to a through-plane value of only 0.07 W/m K, confirming the integration of thermal insulation and thermal management functionalities. These green electromagnetic interference shielding materials, coupled with thermal insulation and thermal management properties, hold promising prospects for applications in sensitive devices.

Self-healing, adaptive and shape memory polymer-based thermal interface phase change materials via boron ester cross-linking

Addressing the thermal resistance between rough interfaces without applying pressure to the interfacial sandwich has been a challenge. Herein, a thermal interface phase change material (TIPCM) is designed to realize a 3D support skeleton with a dynamic crosslinking network by introducing a boron ester crosslinking backbone into paraffin wax (PW) and ethylene-octene copolymer (EOC), thus enabling the TIPCM to ensure mechanical integrity without leakage even above the melting temperature of EOC. The chemical cross-linking between the organic solid–liquid phase change material (PCM) and the polymer realizes thermally triggered self-healing and adaptive shape memory properties. The phase transition of PW leads to a decrease in the modulus of TIPCM and activates the ester exchange of the dynamic covalent bonding of boron esters, which allows TIPCM to self-heal and self-adapt to a variety of object surfaces. These enabled the TIPCM to fill the interface gaps through small stress deformations, forming an interlocking structure that reduces contact thermal resistance and promotes heat transfer. The obtained TIPCM achieves excellent chip thermal management performance, cooling the analog CPU temperature by 67 °C at 5 V. In conclusion, this study provides a potential strategy for redesigning TIPCMs with high latent heat and special physical properties for thermal management.

Lightweight, robust and conductive MXene/SiO2 nanofiber aerogels for excellent sensing and thermal management properties

Flexible pressure sensors embody outstanding mechanical and sensing performance, particularly in the fields of personal health monitoring and artificial intelligence, while catering to multifunctional applications resilient against harsh weather conditions. Among these, Ti3C2Tx MXene-based aerogel materials with high surface area and excellent conductivity have attracted a lot of attention. However, there are big challenges in improving the mechanical properties at low densities and designing multi-level pore structures. Herein, the prepared silane monomers (MP) are firstly synthesized by 3-(Trimethoxysilyl) propyl methacrylate (MPTES) and polyethylene glycol diacrylate (PEGDA), then polydopamine-modified silicon dioxide (PDA-SiO2) nanofibers employed with MXene nanosheets form covalent cross-linking nanofiber aerogels. The multi-level stable structure improves both mechanical strength and elasticity. The assembled MXene/MP/PDA-SiO2 pressure sensors exhibit a high sensitivity of −0.83 kPa−1, a rapid response time of 48 ms, a minimum 1 % strain detection limit, and reliable stability over 10,000 cycles. Furthermore, these sensors can be used for human motion detection and health diagnostics, and show good personal thermal management performance. This work holds a promising candidate for the next generation of multifunctional flexible electronic devices.

Multifunctional PPy/MXene decorated polylactic acid film for thermal management and electromagnetic interference shielding

Composite films composed of biodegradable materials possessing flexibility, thermal regulation capabilities, and electromagnetic interference shielding attributes represent optimal selections for wearable items and the packaging of devices. Here, we employ a simple alternating immersion and spray-coating process to fabricate flexible multifunctional films by combining hydrophobic PLA electrospun film with PPy and MXene, and investigate the thermal management and electromagnetic interference shielding properties of the films. Through alternating immersion, PPy can be rapidly in-situ polymerized on the PLA film, enhancing the surface roughness of the fibers, enabling firm integration of MXene with the film. Benefiting from the broad wavelength absorption characteristics of PPy, the solar absorption capacity of the film is significantly enhanced (97.16 %), endowing it with excellent photothermal conversion capability. Meanwhile, the high conductivity of MXene imparts the composite film with controllable and stable active heating ability, meeting heating demands under complex weather conditions. Finally, inspired by origami techniques the electromagnetic interference shielding performance of films with different folding frequencies was compared. It was found that attributed to the increased reflection paths, the film exhibited a significant improvement in electromagnetic interference shielding performance (32.58 dB to 51.96 dB) after folding. In brief, this biodegradable multifunctional composite film is an attractive candidate for future wearable products or devices packaging.

Multi-heterointerface integration in nitrogen-doped Ti3C2Tx@Fe3O4 nanocomposites for superior microwave absorption

Engineering a lightweight and thin microwave absorber through the design of multiple heterogeneous interfaces represents a significant challenge. Here, we synthesized a nitrogen (N)-doped Ti3C2Tx@Fe3O4 (N–Ti3C2Tx@Fe3O4) nanocomposite with a sandwich-like structure through a solvothermal approach using hydrazine hydrate as the N donor. The numerous Ti3C2Tx electron transfer pathways of Ti3C2Tx enable the realization of a hierarchical conduction network within N–Ti3C2Tx@Fe3O4. The introduction of defects through N doping and the integration of Fe3O4 with Ti3C2Tx are pivotal for enhancing the dipole polarization. The heterogeneous interfaces in N–Ti3C2Tx@Fe3O4, coupled with Fe3O4 components, substantially boost the electromagnetic wave (EMW) absorption performance of the composite. An optimal N integration and the loading of Fe3O4 in Ti3C2Tx result in an improved impedance matching of N–Ti3C2Tx@Fe3O4. The synergistic effect of the improved impedance matching and the strong EMW attenuation capability endow N–Ti3C2Tx@Fe3O4 with enhanced microwave absorption (MA) properties. Specifically, at a thickness of 1.04 mm, the composite exhibits the effective absorption bandwidth (3.92 GHz; 14.08–18.00 GHz), surpassing that of Ti3C2Tx. At a thickness of 0.98 mm, it exhibits a maximum reflection loss of −40.28 dB at 17.25 GHz, which substantially exceeds that of Ti3C2Tx. Furthermore, it shows a maximum Radar Cross Section reduction of 21.32 dB cm2. A cotton fabric was coated with N–Ti3C2Tx@Fe3O4, and it was found to exhibit enhanced heat conduction and dissipation, at rates 3.83 and 4.64 times greater than those of uncoated cotton, respectively. These results highlight the considerable potential of N–Ti3C2Tx@Fe3O4 nanocomposites for use in far-field applications. It is envisaged that the exceptional MA and thermal management properties of N–Ti3C2Tx@Fe3O4 nanocomposites will provide a novel avenue for crafting lightweight and thin EMW absorbing materials.

Low-temperature strain-free encapsulation for perovskite solar cells and modules passing multifaceted accelerated ageing tests

Perovskite solar cells promise to be part of the future portfolio of photovoltaic technologies, but their instability is slow down their commercialization. Major stability assessments have been recently achieved but reliable accelerated ageing tests on beyond small-area cells are still poor. Here, we report an industrial encapsulation process based on the lamination of highly viscoelastic semi-solid/highly viscous liquid adhesive atop the perovskite solar cells and modules. Our encapsulant reduces the thermomechanical stresses at the encapsulant/rear electrode interface. The addition of thermally conductive two-dimensional hexagonal boron nitride into the polymeric matrix improves the barrier and thermal management properties of the encapsulant. Without any edge sealant, encapsulated devices withstood multifaceted accelerated ageing tests, retaining >80% of their initial efficiency. Our encapsulation is applicable to the most established cell configurations (direct/inverted, mesoscopic/planar), even with temperature-sensitive materials, and extended to semi-transparent cells for building-integrated photovoltaics and Internet of Things systems.

Bioinspired composite fiber aerogel pressure sensor for machine-learning-assisted human activity and gesture recognition

Machine-learning-assisted human activity and gesture recognition are valuable for human-computer interaction, and data acquisition often necessitates high-performance sensors. Here, inspired by spider web and bat wing airflow sensing system, polyimide fiber (PIF)/carbon black (CB) composite fiber aerogel (CFA) pressure sensor with biomimetic hair-Merkel cell sensitive unit was developed, exhibiting ultralow detection limit (2 Pa), high pressure sensitivity (S=23.1 kPa-1), wide linear detection capacity up to 67.61 kPa, and fast response/recovery time (140/100 ms). Thanks to the excellent mechanical property and environmental tolerance of CFA, it also possesses excellent low fatigue over >4000 cycles and good durability even at extreme high-temperature (200 °C) and underwater conditions. The superior signal data of the sensor, combined with the Convolutional Neural Network machine learning algorithm, achieves ultra-high prediction accuracies of 96.73% and 98.26% for human activity and gesture recognition, respectively. Additionally, CFA also has amazing thermal management properties, making it to be an ideal candidate for wearable electronics with excellent wearing comfort and safety.

Construction of 3D BN network with high-density thermal conductive paths

Efficient heat dissipation is essential to further improve the integration of high-power electronic packaging devices. Three-dimensional BN networks with high-density thermal conductive paths were designed as the heat transfer skeleton of thermal interface materials. 3D networks with high-density thermal conductive paths inlaid between oriented BN paths were constructed using precursor self-assembly and freeze-drying to improve the thermal conductivity of polymeric materials. The results show that high-density thermally conductive paths have stronger polymer-enhanced thermal conductivity than directional thermal paths and compared with pure TPU, the thermal conductivity of TPU/BN-2 under low BN filling content (10%wt) is increased by 250 % and 286.5 % in the through surface and flat surface respectively. This work provides new ideas for the preparation of polymer composites for thermal interface materials in electronic packaging and integrated circuits with excellent thermal management properties.

Multiple birds with one stone: A new type of PPy/Fe3O4/rGO multifunctional composite fabric for wave absorption, UV resistance, anti-static and thermal insulation

To solve the problem of electromagnetic radiation pollution, it is especially important to develop electromagnetic wave-absorbing materials with excellent performance. The preparation of composite multifunctional textile materials with excellent wave-absorbing properties is one of the research hotspots for practical personal protection applications. In this work, PPy/Fe3O4/rGO polyester/cotton composite fabrics were prepared by impregnation, chemical reduction, chemical co-precipitation and in situ polymerization. When the thickness is 0.97 mm, the minimum reflection loss (RLmin) of PPy/Fe3O4/rGO polyester/cotton composite fabric is −12.12 dB, and the effective absorption bandwidth (EAB) is 4.7 GHz, which is excellent in wave absorption. Meanwhile, the PPy/Fe3O4/rGO polyester/cotton composite fabrics have excellent UV resistance (UV transmittance ratio of UVA and UVB bands as low as 0.02 %, UPF value of 100+), antistatic properties (static voltage half-life of 0.2 s), and excellent thermal management properties (thermal conductivity as low as 0.05796 W/(m·K)), and so on. The PPy/Fe3O4/rGO polyester/cotton composite fabrics prepared in this study are suitable for a variety of application scenarios, such as individual electromagnetic protection, individual protection in extremely cold environments, and individual heating physiotherapy, which is of great reference significance for the research of wearable individual protective textile materials.