Thermal Lens Research Articles

Studies of third order nonlinearity and thermal diffusivity of C3OC dye using thermal lens technique

An FT-IR spectrometer and a UV–Visible spectrometer were utilised in order to characterise the Cyanidin-3-O-glucoside chloride (C3OC) dye. The dye’s thermally induced optical nonlinearity was measured in a dimethylformamide solvent using an adjustable diode-pumped solid-state (DPSS) laser at 473 nm. The optical response was measured using the Z-scan technique. The dye showed negative and large nonlinear refractive index) NRX) values, with high nonlinear absorption coefficients (NBO). Because of its ability to change with concentration, the NRX is a viable candidate for applications in the field of nonlinear optics. Thermal lens (THS) technique was used to investigate thermo-optical properties and the NRX. The optical limiter capabilities of the C3OC dye are being investigated as a potential use.

Performance evaluation of ∼2.1 μm microchip laser operation in Ho3+ doped germanate glass

An in-band pumped continuous wave (CW) ∼2.1 μm microchip laser is presented for the first time based on a short cavity Ho3+ doped germanate glass (GeO2-PbO-Ga2O3–Na2O: GPGN). A 1.94 μm, 5 W Tm3+ fiber laser was employed for the excitation of the Ho3+ ions. A 19% laser slope efficiency was achieved in a simple, unoptimized plane parallel Fabry-Perot cavity configuration. A positive thermal lens was estimated in the laser cavity with a sensitivity factor of S ∼31 m−1W−1 and an optical path distortion value exceeding 6 μm. The laser results along with the analysis of the thermal lens indicate that with improved thermal management and an optimized cavity configuration GPGN is a promising gain medium for microchip laser operation around 2.1 μm.

Seed-Assisted Hydrothermal Synthesis of Monodispersed Au@C Core–Shell Nanostructures for Enhancing Thermal Diffusivity of Water-Based Nanofluids

Au@C core–shell nanostructures (Au@C-NS) were synthesized through a low-temperature seed-assisted hydrothermal approach using glucose as carbon source. The material characterization and chemical analysis confirm that the synthesis method allows to obtain uniform core–shell nanostructures constituted by a crystalline metal core and an amorphous carbon shell. Depending on the synthesis conditions, their average size ranges from 146 nm to 342 nm with relative standard deviation as low as 7 %. It is proposed that the characteristic monodispersity results due to a high nucleation rate of the carbon phase at the liquid–solid interface. The obtained monodisperse Au@C-NS were used to prepare water-based nanofluids with superior heat transport properties. The thermal lens analysis shows that the thermal diffusivity of Au@C nanofluids is 9.5 % and 31.3 % higher than their Au nanofluids counterparts and pure water, respectively, at particle concentration of 285 × 1011 ml−1. Phonon-related interactions at the metal cores and carbon shells interfaces are proposed as the heat transport mechanism behind the thermal diffusivity enhancement of the Au@C water-based nanofluids.

Optical Characterization of Fluorescent Chitosan-Based Carbon Dots Embedded in Aqueous Natural Dye

(1) Background: This work evaluated the optical characterization of aqueous fluorescent chitosan-based carbon dots (or carbon nanoparticles CNPs) embedded in natural dye for potential functional packaging applications. Chitosan-based materials are nontoxic, biodegradable, biocompatible, bactericidal, and produced from renewable polymer sources. Anthocyanins are pigments of different colors with a large range of potential applications, such as in bioindicators and biomonitoring; (2) Methods: The CNPs were synthetized in aqueous solutions using chitosan as a carbon source. The natural dye was extracted from the leaves of Tradescantia pallida Purpurea in aqueous solutions. The fluorescence quantum efficiency (η) and fluorescence lifetime (τ) were determined using the mode-mismatched pump–probe thermal lens (TL) technique and time-resolved fluorescence lifetimes (TRFL) measurements, respectively; (3) Results: The η and τ were measured for CNPs embedded in natural dye solution at different concentrations (5.2, 12.09, and 21.57 mass percentage composition). The η and τ photophysical parameters obtained for CNPs embedded in natural dye were compared with those of other CNPs synthesized using different carbon sources, such as leaves, seeds, and protein; (4) Conclusions: Fluorescence spectra and time-resolved fluorescence measurements corroborate the TL results, and relatively high values of η were obtained for the CNP synthesized and embedded in natural dye.

Astigmatic thermal lensing due to surface bulging in Yb:KYW laser crystals

One of the sources of thermal lensing in crystals is surface bulging that results from an inhomogeneous temperature distribution. We investigate a thermal lens caused by surface bulging in an end-pumped Yb:KYW crystal, which serves as a gain medium in lasers and optical amplifiers. The surface profile of the pumped crystal is measured using a Fizeau-type interferometer and compared with a numerical simulation using a finite element method. The study reveals that due to anisotropic thermal expansion, the surface shape of the Yb:KYW crystal is anisotropic and the profile of the expansion is transversely displaced with respect to the pump beam profile which generates the temperature distribution. The observed surface bulging gives rise to aberrations and deflection of the transmitted beam. It was found that the surface bulging introduces astigmatism that is significantly larger than previously estimated [Appl. Opt. 56, 3857 (2017)10.1364/AO.56.003857]. Our results allow the evaluation of the bulging contribution with improved accuracy. We show that these effects can be significant in certain designs of amplifiers and lasers.

Investigating intermolecular interactions of surfactant solutions using femtosecond thermal lens spectroscopy

In this study, we examined the impact of various surfactants (oleic acid, butyric acid, Span-20, and CTAB) on the thermophysical properties of methanol (MeOH) using a femtosecond laser-induced thermal lens (TL) spectroscopic technique. Methanol was chosen for its unique convective properties under intense localized heating, making it a promising candidate for studying photothermal responses. We discovered that the TL characteristics of both pure methanol and methanol-surfactant mixtures are significantly influenced by the molecular interactions and physical properties of the components. Our experimental results indicate that the addition of surfactants notably alters the heat transfer dynamics of the solvent by restricting natural molecular movement and modifying thermal properties, which in turn affect the TL signatures. Beyond the surfactant concentration, we observed that the extent of variation in steady-state TL signals, inflection points, and heat transfer mechanisms depends on the molecular properties of the surfactants, such as chain length, the number of active (hydrophilic) groups per molecule, thermal conductivity, viscosity, and intermolecular interactions. Our TL findings provide a detailed investigation into the effect of surfactants on the photothermal response and heat transfer process of a solvent for the first time.

Gas flows generated by pulse-periodic optical breakdown and quiet optical discharge

Quiet optical discharge in high-pressure xenon is visually stable pre-breakdown stage of optical discharge supported by pulse-periodic short-wavelength infrared laser radiation with intensity of the order of 109 W/cm2. Increasing the laser intensity leads to the transition of the quiet discharge into a pulse-periodic optical breakdown. In this study, quasi-stationary directional flows generated by both the quiet discharge and the optical breakdown are observed. The flows and their initial stages under limited number of discharge pulses are visualized by shadow imaging method using a point-like laser-plasma radiation source. It is shown that the gas streams outflow points in a quiet discharge correspond to the positions of the laser radiation intensity local maxima in the focal beam waist with astigmatism complicated by defocusing effect of thermal lens arising in the discharge zone. The pulse-periodic optical breakdown emits a turbulent gas flow toward the laser beam. The beam refraction on density gradients in the turbulent flow causes the breakdown instability from pulse to pulse. It was found that time-average absorption of laser radiation in a quiet discharge is about 3% (also in a pulse), while that in optical breakdown is 15% and higher (from 70% to 100% in a pulse). Laser beam intensity for quiet discharge at pulse repetition rate νp = 20 kHz ranges from 1.3 × 109 to 1.5 × 109 W/cm2. At intensities above 4 × 109 W/cm2 and repetition rates νp > 50–55 kHz, laser breakdowns are observed in each laser pulse with the focal ratio f/d ≤ 7. At f/d = 10.6 and νp > 28 kHz, the quiet discharge does not transit to laser breakdown due to defocusing by the thermal lens induced.

Features of High-Precision Photothermal Analysis of Liquid Systems by Dual-Beam Thermal Lens Spectrometry.

Thermal lens spectrometry is a high-sensitivity method for measuring the optical and thermal parameters of samples of different nature. To obtain both thermal diffusivity and absorbance-based signal measurements with high accuracy and precision, it is necessary to pay attention to the factors that influence the trueness of photothermal measurements. In this study, the features of liquid objects are studied, and the influence of optical and thermal effects accompanying photothermal phenomena are investigated. Thermal lens analysis of dispersed solutions and systems with photoinduced activity is associated with a large number of side effects, the impact of which on trueness is not always possible to determine. It is necessary to take into account the physicochemical properties and optical and morphological features of the nanophase and components exhibiting photoinduced activity. The results obtained make it possible to reduce systematic and random errors in determining the thermal-diffusivity-based and absorbance-based photothermal signals for liquid objects, and also contribute to a deeper understanding of the physicochemical processes in the sample.

Graphene incorporated zinc oxide hybrid nanofluid for energy-efficient heat transfer application: A thermal lens study

The work focuses on the development of a hybrid nanofluid (NF) comprising zinc oxide-graphene (ZG) to address heat transfer (HT) limitations in thermal systems. The study employs a highly sensitive mode-mismatched dual-beam thermal lens (MDTL) method to analyze the lattice dislocation-induced thermal diffusivity (D) modifications of the hybrid NF. The hybrid composite (HC) is synthesized by solid-state mixing and annealing of ZG. The formation of ZG hybrid composites is revealed through X-ray diffraction (XRD), Fourier transform infrared, X-ray photoelectron, and Raman spectroscopic analyses. The structural dislocations present in the HC are understood from XRD and Raman analyses. Ultraviolet-visible and photoluminescence spectroscopic studies revealed the optical properties of the samples. The MDTL study is carried out by preparing the NFs of the synthesized samples in the base fluid, ethylene glycol (EG), and reveals the impact of crystallite defects on the thermal characteristics of the synthesized composites. Thus, the study suggests the potential capability of ZG composites in tuning the thermal behaviour of EG for HT applications.

Scaling laws for high energy Gaussian beams propagation through the atmosphere

In order to meet the requirements of rapid evaluation of high-energy lasers for practical applications, this paper constructs scaling laws for Gaussian beams propagation through the atmosphere. Firstly, the beam spreading due to single effects including diffraction, optical turbulence and thermal blooming is scaled to identify suitable scaling factors. Then, the scaling functions of the effective radius with multi-effect interaction are established step by step, and the scaling exponents are fixed by genetic algorithm. Finally, the scaling laws of the far-field mean intensity of high-energy laser propagating through atmosphere are constructed. Comparison with the simulations in given scenarios reveals the mean relative error of the scaled mean intensity.

Filament-induced breakdown spectroscopy of solids through highly scattering media.

Ultrafast laser pulse filamentation in the air can be used for remote sensing by exciting a characteristic optical emission, which is usually referred to as filamentation-induced breakdown spectroscopy. In environments that impede light propagation, such as fog, haze, or clouds, scattering makes it challenging to propagate laser beams and retrieve generated optical signatures. We demonstrate the effectiveness of laser filamentation for simultaneously clearing the path for intense femtosecond pulse propagation in a highly scattering medium, generation of luminous plasma on a solid target, and counter-propagation of a characteristic spectroscopic signal over a cleared channel along the filament path. In a dense cloud, the counter-propagating signal predominantly transits the cleared on-axis path but is highly affected by the negative thermal lensing of a Gaussian beam. These insights enhance our understanding of laser filamentation in atmospheric sensing and could substantially improve remote detection capabilities in poor visibility conditions.

Competition between turbulence and thermal blooming of coherent vortex beam array propagating in non-Kolmogorov marine atmosphere

Competition between turbulence and thermal blooming of coherent vortex beam array propagating in non-Kolmogorov marine atmosphere

Effect of steady-state thermal blooming on partially coherent radially polarized beams propagating in the atmosphere

We undertake a computational study of the steady-state thermal blooming effect on a special class of partially coherent vector beams, called partially coherent radially polarized (PCRP) beams, propagating through the atmosphere. A computational propagation model that is based on a multi-phase screen method is established to simulate partially coherent vector beams. With the use of this model, the propagation properties of PCRP beams with different initial powers and spatial coherence widths are studied in detail, including average intensity distribution, r.m.s. beam width, and polarization. Our results unveil that PCRP beams can effectively reduce or overcome the negative effects caused by thermal blooming when the initial coherence width falls below a certain threshold. Further, it is shown that the spatial distribution of degree of polarization (DOP) is significantly affected by the thermal blooming during beam propagation, whereas the global DOP (integrating the DOP over a beam’s cross-section) is not.

Impact of molecular convection in time-resolved thermal lensing: a computational exploration

In this study, we comprehensively investigate thermal lens (TL) spectroscopy, known for its ultra-sensitivity in probing molecular properties through nonlinear heating responses to femtosecond lasers. Using time-resolved TL spectroscopy and numerical simulations, we focus on the influence of convection on heat generation and the resulting phase shift in the probe beam. We examined single-beam, dual-beam same wavelength, and dual-beam different wavelength scenarios, systematically investigating power dependence, pump beam spot size, and sample length limitations. Our findings reveal a direct relationship between the TL effect and pump power, resulting in decreased probe beam transmittance with increasing convection. Additionally, the TL strength grows within the Rayleigh regime as the sample length increases. Utilizing the same wavelength for the probe beam enhances the TL effect in dual-beam setups. Notably, tight focusing of the pump beam substantially reduces the lag between convection and conduction. Our empirical results closely match the experimental data, providing a thorough explanation of the TL process and its underlying principles. These insights can be applied to design and optimize TL-based optical devices and systems for higher sensitivity, highlighting the potential of TL spectroscopy in advanced molecular property probing.

Diode-pumped continuous-wave single- and dual-wavelength Yb:GMBO lasers

The diode-pumped continuous-wave (CW) single- and dual-wavelength Yb:GdMgB5O10 (Yb:GMBO) lasers were demonstrated. The thermal lens focal lengths of the Yb:GMBO crystal in the directions of the Y and Z axes was calculated and measured, and the sizes of the wavelengths in the Yb:GMBO crystal was calculated for optimal mode matching between laser and pump beams. A birefringent filter (BF) was placed in the linear cavity for wavelength tuning at 1011, 1035, and 1059 nm, respectively. Among these wavelengths, 1011 and 1035 nm were realized for the first time. Additionally, by rotating the BF and changing the transmittance of the output coupler, the gain and loss of the emission lines were balanced, and simultaneous dual-wavelength laser operating at 1035 and 1059 nm, 1011 and 1035 nm, 1011 and 1059 nm was obtained, respectively.

Design of an Optimized Terahertz Time-Domain Spectroscopy System Pumped by a 30 W Yb:KGW Source at a 100 kHz Repetition Rate with 245 fs Pulse Duration

Ytterbium laser sources are state-of-the-art systems that are increasingly replacing Ti:Sapphire lasers in most applications requiring high repetition rate pulse trains. However, extending these laser sources to THz Time-Domain Spectroscopy (THz-TDS) poses several challenges not encountered in conventional, lower-power systems. These challenges include pump rejection, thermal lensing in nonlinear media, and pulse durations exceeding 100 fs, which consequently limit the detection bandwidth in TDS applications. In this article, we describe our design of a THz-TDS beamline that seeks to address these issues. We report on the effectiveness of temperature controlling the Gallium Phosphide (GaP) used to generate the THz radiation and its impact on increasing the generation efficiency and aiding pump rejection while avoiding thermal distortions of the residual pump laser beam. We detail our approach to pump rejection, which can be implemented with off-the-shelf products and minimal customization. Finally, we describe our solution based on a commercial optical parametric amplifier to obtain a temporally compressed probe pulse of 55 fs duration. Our study will prove useful to the increasing number of laboratories seeking to move from the high-energy, low-power THz time-domain spectroscopy systems based on Ti:Sapphire lasers, to medium-energy, high-power systems driven by Yb-doped lasers.

Unravelling molecular interactions in various alcohol-water binary mixtures using femtosecond laser-induced thermal lens spectroscopy

The FTLS (femtosecond laser-induced thermal lens spectroscopy) technique was utilized to explore the photothermal response and heat transfer dynamics in various water-based binary mixtures containing monohydric and polyhydric alcohols. Our results highlight the significant influence of intermolecular hydrogen bonding interactions and the molecular properties of the mixture constituents on the photothermal behavior of both pure solvents and their binary mixtures. Notably, we observed distinct effects of water inclusion on the heat transfer characteristics of monohydric alcohols (such as methanol and ethanol) compared to polyhydric alcohols (such as ethylene glycol (Etg) and glycerol (Gly)). This discrepancy can be attributed to the formation of unique molecular structures via hydrogen bonding interactions, which effectively hinders the natural molecular dynamics of short-chain length alcohols. Conversely, polyhydric alcohols like Etg and Gly exhibit contrasting photothermal characteristics due to their extensive intermolecular hydrogen bonding. Our investigations reveal that molecular attributes, such as chain length and the number of hydroxyl (-OH) groups, play a crucial role in altering the heat transfer mechanisms and thermal lens signal characteristics of the mixtures. These findings emphasize the sensitivity of FTLS as a probe for understanding the effects of intermolecular hydrogen bonding interactions on the molecular dynamics and thermo-optical properties of aqueous-alcoholic solutions.

Enhanced laser performance in an LD end-pumped YAP/Tm:YAP/YAP bonding rod with concave end faces

We demonstrate the effects of thermal bonding and concave end faces on the laser performance of 795 nm LD end-pumped Tm:YAP crystals for the first time. Analysis of the thermal focal length shows that the thermal lensing effect can be effectively compensated by the concave end faces. By combining the thermal bonding with the concave end faces, a maximum output power of 42.5 W is achieved on the concave YAP/Tm:YAP/YAP bonding rod with a negative curvature radius of 500 mm, corresponding to a slope efficiency of 47.4% and an optical-optical (O-O) conversion efficiency of 41.6%. Moreover, the beam quality factors Mx2/My2 are fitted to 1.67/1.69. Compared with the flat YAP/Tm:YAP/YAP bonding rod, the concave YAP/Tm:YAP/YAP bonding rod significantly increases the maximum output power from 36.56 W to 42.5 W, with an approximately 4% improvement in both the slope efficiency and O-O conversion efficiency. These results indicate that the combination of thermal bonding and concave end faces can effectively improve the heat dissipation capacity and mitigate the thermal lensing effect, thereby yielding near-infrared (NIR) laser output with high performance.

Continuous-wave degenerate cavity laser for optical imaging in scattering media.

Lasers play a significant role in optical communication, medical, and scientific research, owing to their high brightness and high coherence. However, the high spatial coherence will lead to specific challenges, such as speckle noise in imaging and wavefront distortion during propagation through scattering media. Here, a continuous-wave (cw) degenerate cavity laser (DCL) with low spatial coherence is demonstrated with efficient suppression of the thermal lensing effect from the gain crystal. Experimentally, a cw degenerate laser output with about 2000 transverse modes corresponding to a speckle contrast of about 0.0224 is achieved. This laser can be used for speckle reduction and is robust against atmospheric turbulence, which may find applications in the field of laser imaging technology and illumination.

Room-temperature high-power laser emission of erbium-doped fluorite crystals at 2.8 µm.

We report on a high-power continuous-wave (CW) laser at 2.8 µm employing erbium (Er)-doped fluorite crystals as gain materials. With an optimized Er3+ ion concentration, thin "slab" geometry of the sample matching with the tailored pump beam profile and compensated negative thermal lens using a pair of concave mirrors cavity configuration, a highest power of 14.5 W is achieved from a dual-end-pumped Er:CaF2 laser, which, to the best of our knowledge, presents the record power from the room-temperature Er-bulk lasers in the 3-µm spectral range. In addition, 8.05 W output power is obtained from the Er:SrF2 laser with an RMS power stability of 0.35%. This work indicates that Er-doped fluorite crystals with large-scale available fabrication are promising candidates for high-power laser emission at ∼3 µm.