Thermal Integration Research Articles

Solar-Driven Thermal and Mechanical Vapor Compressor Integrated Desalination System: Zero Emission, High Yield, and Cost Reduction

Solar-Driven Thermal and Mechanical Vapor Compressor Integrated Desalination System: Zero Emission, High Yield, and Cost Reduction

Ultra-Low-Potential Methanol Oxidation on Single-Ir-Atom Catalyst.

Methanol oxidation plays a central role to implement sustainable energy economy, which is restricted by the sluggish reaction kinetics due to the multi-electron transfer process accompanied by numerous sequential intermediate. In this study, an efficient cascade methanol oxidation reaction is catalyzed by single-Ir-atom catalyst at ultra-low potential (<0.1 V) with the promotion of the thermal and electrochemical integration in a high temperature polymer electrolyte membrane electrolyzer. At the elevated temperature, the electron deficient Ir site with higher methanol affinity could spontaneous catalyze the CH3OH dehydrogenation to CO under the voltage, then the generated CO and H2 was electrochemically oxidized to CO2 and proton. However, the methanol cannot thermally decompose with the voltage absence, which confirm the indispensable of the coupling of thermal and electrochemical integration for the methanol oxidation. By assembling the methanol oxidation reaction with hydrogen evolution reaction with single-Ir-atom catalysts in the anode chamber, a max hydrogen production rate reaches 18 mol gIr -1 h-1, which is much greater than that of Ir nanoparticles and commercial Pt/C. This study also demonstrated the electrochemical methanol oxidation activity of the single atom catalysts, which broadens the renewable energy devices and the catalyst design by an integration concept.

Ultra‐Low‐Potential Methanol Oxidation on Single‐Ir‐Atom Catalyst

AbstractMethanol oxidation plays a central role to implement sustainable energy economy, which is restricted by the sluggish reaction kinetics due to the multi‐electron transfer process accompanied by numerous sequential intermediate. In this study, an efficient cascade methanol oxidation reaction is catalyzed by single‐Ir‐atom catalyst at ultra‐low potential (&lt;0.1 V) with the promotion of the thermal and electrochemical integration in a high temperature polymer electrolyte membrane electrolyzer. At the elevated temperature, the electron deficient Ir site with higher methanol affinity could spontaneous catalyze the CH3OH dehydrogenation to CO under the voltage, then the generated CO and H2 was electrochemically oxidized to CO2 and proton. However, the methanol cannot thermally decompose with the voltage absence, which confirm the indispensable of the coupling of thermal and electrochemical integration for the methanol oxidation. By assembling the methanol oxidation reaction with hydrogen evolution reaction with single‐Ir‐atom catalysts in the anode chamber, a max hydrogen production rate reaches 18 mol gIr−1 h−1, which is much greater than that of Ir nanoparticles and commercial Pt/C. This study also demonstrated the electrochemical methanol oxidation activity of the single atom catalysts, which broadens the renewable energy devices and the catalyst design by an integration concept.

Industrial Park low-carbon energy system planning framework: Heat pump based energy conjugation between industry and buildings

The accelerating urbanization, rapid industrial development, and excessive consumption of fossil fuels pose survival challenges such as energy depletion and environmental degradation for humanity. In the context of industrial park development, constructing a low-carbon energy system, increasing the proportion of renewable energy, enhancing energy-level matching, and utilizing heat pumps for deep waste heat recovery are effective approaches to reduce fossil energy consumption and alleviate environmental pressures. Addressing issues such as diverse thermal flows in industrial sites, complex electricity-heat-cooling energy demands, and unclear industrial-building energy coupling mechanisms, this paper proposes a two-stage planning framework, comprising the following five steps: (1) constructing a waste heat utilization system centered around heat pumps, (2) establishing a mechanism for matching heat sources, equipment, and thermal sinks, (3) establishing an energy conversion model and energy quality quantification system, (4) optimizing waste heat utilization path allocation, and (5) conducting a system energy flow analysis. Case studies demonstrate that the proposed system achieves optimized matching of multiple heat sources and sinks in industrial and building scenarios through thermal integration, meeting diverse energy demands in the park, including electricity, cooling, and multi-grade heat. After coupling with traditional steam pipeline networks, the annual total cost and annual steam power consumption decrease by 33% and 39% respectively, with a waste heat contribution rate of up to 26% and a renewable energy penetration rate of up to 25%, and a waste heat recovery system payback period of 6 years. By establishing an energy quality quantification system and conducting multi-objective optimization considering losses and economic costs, this paper provides Pareto frontier solutions, offering references for engineering proposals. The proposed networked waste heat recovery system is characterized by low energy consumption and high economic efficiency, effectively integrating the energy characteristics of industrial parks and demonstrating engineering applicability.

Triple-objective optimization using ANN+NSGA-II for an innovative biomass gasification-heat recovery process, producing electricity, coolant, and liquefied hydrogen

A novel thermal integration approach is introduced for a biomass-driven gas turbine power plant that generates electricity, coolant, and liquefied hydrogen. The designed scheme encompassed an organic flash cycle, a bi-evaporator ejector refrigeration unit, a high-temperature water electrolyzer for hydrogen production, a multi-effect desalination cycle for supplying water for electrolysis process, and a Claude cycle for hydrogen gas liquefaction. The designed system's importance comes back to using biomass feedstock as the input fuel and utilizing the hydrogen liquefaction method. In addition to the possibility of deploying the system in remote areas, it provides the opportunity for hydrogen storage in a smaller volume for more accessible storage and transportation. On the other hand, using a comparative method for selecting an environmentally friendly fluid for the heat recovery subsystem is another crucial aspect of the present study from the environmental aspect. It is found that R161 is the appropriate choice among the seven studied working fluids. Subsequently, a comprehensive evaluation of the entire system's thermodynamic and environmental aspects is performed using an intelligent process. By considering energy and exergy efficiencies along with CO2 emissions as the objective functions, a thorough sensitivity analysis and a triple-objective optimization are carried out. Hence, artificial neural networks for the objectives are developed and integrated into the NSGA-II optimization method. Employing LINMAP decision-making, the values of objective are attained, exhibiting 39.6 % for energy efficiency, 36.1 % for exergy efficiency, and 631.7 kg/MWh for CO2 emissions. Considering the optimum solution, the proposed system is capable of producing electricity, cooling, and liquefied hydrogen with capacities of 4526 kW, 1875 kW, and 21.22 m3/day, respectively. Additionally, the scenario yields an exergoenvironmental index of 0.579 and an exergetic stability index of 0.61. and a liquefied hydrogen generation rate of 21.22 m3/day.

Calculation of grain boundary diffusion coefficients in γU-Mo using atomistic simulations

The γU-Mo alloy has been selected for the conversion of U.S. High-Performance Research Reactor (HPRR) fuel from highly enriched uranium to low enriched uranium as a part of the effort to reduce nuclear proliferation risks. Although γU-Mo alloys have the advantage of high uranium density and good overall irradiation performance, the irradiation-induced swelling and creep in the metal remain important design parameters since they influence the mechanical and thermal integrity of the fuel. To account for these design criteria, engineering scale models need fundamental properties, such as diffusion coefficients, as input. In this study, the diffusion of related species along grain boundaries in γU-Mo fuel is quantified considering that grain boundaries act as sinks for point defects, nucleation sites for gas bubbles, avenues for Coble creep, etc. The diffusivities of U and Mo in selected grain boundaries of γU-Mo alloys (γU-7Mo, γU-10Mo, and γU-12Mo) are obtained utilizing molecular dynamics simulations for a temperature range of 600 K - 1200 K with an interval of 100 K. The structures analyzed include symmetric tilt, asymmetric tilt, and twist grain boundaries. The grain boundary diffusion coefficients of U and Mo in the examined γU-Mo alloys are on the order of 10−14 to 10−11 m2s−1. It is observed that the U diffusivity in the grain boundary is higher than the Mo diffusivity in all cases and that the increase in Mo content of the alloy correlates to a decrease in the grain boundary diffusion. Xe diffusion along γU-10Mo grain boundaries is also calculated in this work, and the diffusivity of Xe in the γU-10Mo grain boundaries is found to be 8 to 15 orders of magnitude higher than the intrinsic Xe diffusivity in γU-10Mo depending on the temperature. The information gathered in this work can inform fuel swelling and creep models and help understand various other phenomena related to γU-Mo fuel performance.

Energy, exergy and sustainability analysis of a photovoltaic-thermal solar system with nano-enhancement and thermal energy storage integration

As a result of using various energy sources such as fossil fuels, harmful gases emerge and endanger the world's future. The search for different energy sources is to diminish the dangers that may arise in the future. Renewable energy sources are also the most basic for a sustainable future. This study aims to increase the performance of photovoltaic thermal collectors (PVT), which are used to obtain thermal energy from solar energy and produce electrical energy. The novelties of this experimental work are the analysis of a combination of a solar air heater and thermal energy storage via a phase change material technology and surface modifications on absorber plates, including a nanotechnological amendment. Furthermore, the adverse impacts on the environment of the manufactured systems were taken into account with the help of such parameters as waste exergy ratio and sustainability index. Initially, PVT with a V-grooved absorber surface (V-PVT) was built. In the second stage, nano-enhanced V-grooved PVT (NE/V-PVT) was produced, in which the absorber plate was coated by graphene nanoparticles. Then, a thermal energy storage entity was mounted onto the system, and the V-grooved PVT with the thermal energy storage entity (TS/V-PVT) was developed. 40 W absorber fans were used to provide airflow in these manufactured collectors. In addition, Styrofoam insulation material was used for the collector case, and a low-cost system was designed. Simultaneous experiments for each PVT were carried out. The waste exergy ratio (WER) and the sustainability index (SI) were also considered. Based on the experimental results, thermal efficiency was calculated as 40.60%, 54.01%, and 53.90% for V-PVT, NE/V-PVT, and TS/V-PVT, respectively. Furthermore, the coefficient of performance (COP) values were obtained as 2.67 for V-PVT, 4.28 for NE/V-PVT, and 3.49 for TS/V-PVT. The findings illustrated that nano-coating and V-grooved modifications on solar collectors substantially increased the system performance.

Enhanced water production in hemispherical solar stills via solar collector and thermal storage integration: experimental validation

ABSTRACT In arid regions that face water scarcity, solar distillation offers hope by meeting the increasing need for clean drinking water. This study investigates the integration of a hot water storage system, heated by a flat plate solar collector, into a hemispherical solar still. Placing the storage tank below the still's absorber enhances heat input and efficiently stores excess daytime thermal energy. Conducted in Bouismail from December 2022 to October 2023, the study yielded significant results: the modified solar still outperformed the conventional one, with production increases of 157% in winter and 207% in summer. Moreover, the modified still demonstrated remarkable efficiency improvement in summer, reaching 37.42% compared to 20.38% for the conventional still. The orientation of the fins within the storage tank, with respect to the hot water entrance orifice, significantly impacted water production, with alterations of the angle resulting in decreases of up to 25%. Increasing saltwater depth led to reduced distilled water output, with declines of up to 37.08% for the modified still. Economic analysis showed a slightly higher cost per liter of water produced by the modified still ($0.1897) compared to the simple one ($0.1446).

Multi-aspect assessment of a novel geothermal-driven polygeneration arrangement using water electrolyzer, methanol synthesis unit, and Goswami cycle

Geothermal energy’s renewable nature with minimal emissions compared to fossil fuels has led to valuable polygeneration models in geothermal-rich regions, promoting energy sustainability. Key challenges include improving integrated structures due to these resources’ low/medium temperature nature and assessing the feasibility of producing essential products (e.g., hydrogen and methanol), typically produced in structures with substantial pollution. The proposed system’s innovations focus on reducing irreversibility through thermal integration, introducing a negative CO2 emission structure, and utilizing CO2 hydrogenation based on geothermal energy for methanol production. Hence, the system encompasses a geothermal power plant, a Goswami cycle, a direct hydrogenation methanol synthesis unit, and a proton exchange membrane electrolyzer. The findings show generating methanol at a rate of 0.85 kg/s, domestic hot water at a rate of 2.231 kg/s, chilled water at a rate of 3.931 kg/s, and electric power at a capacity of 21,530 kW. Hence, the system’s thermal, electrical, and exergy efficiencies are determined to be 7.54 %, 3.87 %, and 47 %, respectively. Furthermore, the sum unit cost of products and the levelized energy cost equal 0.0272 $/GJ and 0.17 $/kWh, correspondingly. Additionally, a net present value of 65.86 M$ and a total yearly cost of 37.52 M$ are the results of the economic assessment. The current research demonstrates a negative CO2 emission from an environmental standpoint. The attainment of negative CO2 emissions is due to using CO2 as input material in the system. Also, the system’s net present value surpasses the total annual cost by 1.75 times, mainly due to its ability to produce products like methanol, generating revenue to offset initial costs. The proposed system is ideal for geothermal energy sites near seawater, promoting environmental preservation by reducing pollutants. Finally, it is suggested that the system’s operation be optimized and an experiential setup be used for future research.

Current and future development of thermal grids in Switzerland: an organizational perspective

IntroductionThermal grids are key to decarbonizing heating and cooling. However, their development is a complex socio-technical process. This study aims to (1) understand the thermal grid ecosystem’s development under changing political, economic and cultural frame conditions, (2) elicit actors’ perception of options for future development, and (3) identify concrete problem situations for the future development of thermal grids and describe how to address them.MethodsWe draw on 18 semi-structured interviews with decision-makers in utilities, municipal administrations, planning and engineering companies and intermediary organizations.ResultsWith increased strategic importance of thermal grids, the ecosystem has been in a phase of rapid growth and professionalization in the last 10–15 years. This is reflected in a rapid increase in the number of grids, but also in capability and capacity building and greater quality standards. This transformation has been supported by a resource pool (e.g., knowledge base, capacities and capabilities, networks or decision-support tools), built partly through the value network’s activities and partly through purposeful orchestration by associations, authorities, utilities and other actors. While policy developments, energy price fluctuations and changes in customer perceptions spurred demand, thermal grid development is limited by supply-side constraints, especially a skill shortage. Four interrelated problem situations were identified: (1) Municipalities lack the resources to manage the implementation of their energy strategies. (2) The modernization of thermal grids and integration of low-carbon heat sources entails high transaction costs. (3) The implementation of thermal grids is subject to delays and quality risks, with consequences for the timely achievement of decarbonization goals. (4) Customers face uncertainty on available options, as well as on the systemic impacts of their decisions.DiscussionBased on current practices, suggestions by the interviewees, as well as a comparison with the international literature, we identify four development areas to address these problem situations: (1) Empower and support municipalities. (2) Manage the scarcity of qualified workforce. (3) Leverage digital technology for the planning, realization and operation of thermal grids. (4) Pilot technological and organizational innovations together. This complements the set of previously suggested measures to support the development of thermal grids, which focused strongly on technical and regulatory aspects.

Aspects of Ammonia as Green Fuel for Propulsion Systems of Inland Water Vessels

Ships are a crucial backbone of the transport system for goods and people. However, the currently utilized fossil fuels require a green replacement. Ammonia produced from green hydrogen is an interesting, carbon‐free green fuel, which has been demonstrated to be promising for maritime applications. Its application under the specific boundary conditions of river ships and other inland water vessels still deserves a closer evaluation. In this work, ammonia as a green fuel for propulsion systems of inland water vessels is evaluated regarding several technological aspects. These include onboard decomposition for hydrogen release, combustion of ammonia–hydrogen mixtures in internal combustion engines and the thermal integration of the different components. To achieve favorable combustion properties of the fuel, a certain share of the ammonia has to be decomposed in an ammonia cracker to produce a mixture of hydrogen and ammonia. First single‐cylinder engine tests show that the combined combustion of ammonia and hydrogen allow an efficient and reliable process for the investigated high‐speed engine concept. Efficiency values of nearly 40% at part load already are achieved. With proper system integration, it is possible to reasonably operate small‐ and medium‐sized ships with ammonia as a green fuel.

Investigation of the Cd-Ratio difference method to measure the cross section of 186W(n,γ)187W at the Jordan Research and Training reactor

The neutron capture cross section of 186W(n,γ)187W was measured at different energies, including the thermal capture cross section (0.025 eV) and resonance integral. Neutron capture cross section values were determined using the activation technique and by applying the Cadmium-ratio difference method. Two irradiation locations at the Jordan Research and Training Reactor (JRTR) were used (NAA1 and NAA2). The thermal capture cross section values were determined to be 39.56 ± 0.69 ± 2.58b and 32.17 ± 3.72 ± 2.00b at NAA1 and NAA2, respectively. While resonance integral values were found to be 113.93 ± 8.20 ± 16.87b and 69.35 ± 26.63 ± 29.69b at NAA1 and NAA2, respectively. The present results of the resonance integral are not in good agreement with the most of the previous experimental and evaluated data as well as the theoretical calculations.

Development of characteristic equations of conical solar still by incorporating N identical concentrator collectors with/without photovoltaic panel: A comparative investigation

This paper focuses on the development of characteristic equations and performance analysis of a conical solar still (CSS) connected to N identical compound parabolic concentrator (CPC) collectors, with or without photovoltaic thermal (PVT) integration. The objective is to achieve sustainable solar distillation in line with the United Nations' sustainability goals. The thermal model is developed by formulating energy balance equations for each part followed by its experimental validation considering N=0and1. A fair agreement between analytical and experimental results is observed having correlation coefficients as 0.996, 0.993, 0.992, and 0.97, 0.98, 0.99 for water temperature, yield, and glass temperature for N = 0 and 1, respectively. The study considers three cases: CSS integrated with N identical partially covered PVTCPCs (case (i)), CSS integrated with N identical fully covered PVTCPCs (case (ii)), and CSS integrated with N identical CPCs (case (iii)). The performance of these cases is compared using climate conditions in New Delhi on a typical day in June. The findings indicate that the mean value of instantaneous efficiency for case (i) is higher by 67.75 % than case (ii), however lower by 22.22 % than case (iii). The study also investigates the influence of variations in mass-flow rate and N on the output of the active CSS.

Performance and cost potential for direct-fired supercritical CO2 natural gas power plants

Direct-fired supercritical CO2 (sCO2) power cycles are being explored as an attractive alternative to natural gas combined cycle (NGCC) plants with carbon capture and storage (CCS). Therefore, understanding their performance and cost potential is important for the commercialization of the technology. This study presents detailed techno-economic optimization results of natural gas-fired, utility-scale power plants based on the direct sCO2 power cycle, which is lacking in public literature. The study considered multiple plant configurations with varying levels of thermal integration with the plant air separation unit (ASU) to shows the systematic impact of thermal integration on plant performance and economics. Several design variables for each power cycle configuration were identified and optimized to minimize the levelized cost of electricity (LCOE). The optimized direct sCO2 power plants achieved ∼48 % plant efficiency (HHV basis) which is similar or slightly higher plant efficiencies than state-of-the-art NGCC plants based on the F-class gas turbine with carbon capture and storage (CCS). The LCOE of the optimized direct sCO2 plants is 13–17 % higher than the reference NGCC plants with CCS due to high capital costs associated with the ASU and sCO2 power block, though there is significant room for improvement due to high uncertainty in component capital costs for these new plants. Based on the results, direct sCO2 power cycles have the potential to achieve >50 % efficiency (HHV basis) with >98 % CO2 capture rate which can lead to significant efficiency improvement and CO2 emissions reductions compared to NGCC plants with CCS.

Preliminary design and analysis activities of the deuteron accelerator target for tritium breeding unit test

A breeding blanket (BB) is a key component that multiplies neutrons and generates tritium in the fusion demonstration reactor. Evaluation of the performance and reliability of the BB is a very important engineering task, and it is going through the ITER TBM program. The Korean DEMO program needs to complement the ITER TBM program to validate the BB, and the test facility is necessary to validate the BB in the continuous wave operation. Based on this need, the Korea Institute of Fusion Energy has initiated a pre-conceptual study to verify the long-term performance and reliability of the BB.This study deals with neutronics and engineering analyses of a solid beryllium (Be) target that generates neutrons through a deuteron accelerator for the fusion neutron source. In the neutronics analysis, the yield and energy spectrum of neutrons generated according to the incident particles and energy were analyzed. As a result, in the case of 40 MeV deuteron, the yield of neutrons with 10∼20 MeV similar to the fusion neutron was the highest in the forward direction of 1.08E+15 n/s. In addition, vanadium (V) was selected as the blistering mitigation layer (BML), and the thickness of the Be target and the BML were optimized through neutronics analysis to minimize the blistering. In the engineering analysis, a preliminary conceptual design of the target to cool the nuclear heating caused by the nuclear reaction was performed. To improve the cooling capacity of the target composed of Be-V-CuCrZr with the pressurized water coolant, the design of the target was optimized and its thermal integrity was evaluated. Next, thermal stress was evaluated by coupling the temperature distribution of the target obtained through thermal analysis with structural analysis. Through this, the preliminary design concept of the target that satisfies thermal and mechanical integrity requirements was derived.

A comprehensive multi-variable approach for evaluating the feasibility of integration a novel heat recovery model into a gas turbine power plant, producing electricity, heat, and methanol

Considering the importance of efficient thermal integration for a gas turbine cycle using its energetic flue gas, the current paper proposes an eco-friendly and efficient process integrated into a gas turbine cycle. The newly designed polygeneration structure produces power, hot water, and methanol. The components of this system include a heat provider unit, a direct carbon dioxide hydrogenation unit for the production of methanol, an ammonia Rankine cycle, a proton exchange membrane electrolyzer, a supercritical carbon dioxide power cycle, and two organic Rankine cycles. The feasibility of the proposed model is evaluated using a comprehensive multi-variable assessment from energy, exergy, economic, and environmental approaches. This system exhibits a power production capacity of 17197.23 kW and a methanol generation rate of 0.7573 kg/s. Also, the total irreversibility is equal to 68161.18 kW. Besides, the total energy and exergy efficiencies are found as 68.73% and 32.03%, respectively. This model's carbon dioxide emission is 18667.36 kgCO2/h, and its carbon footprint equals 0.2196 kgCO2/kWh. Furthermore, the economic analysis reveals that the project has an annual total cost of 194,602,338 and a net present value of 686,221,616. Besides, the computed total unit costs for products and energy are 0.3385 $/kWh and 89.81 $/GJ, respectively.

Enhancing solar distillation through beeswax-infused tubular solar still with a heat exchanger using parabolic trough collector

This scholarly investigation elucidates the imperative for advancing solar thermal desalination systems, an exigency compounded by the twin global challenges of burgeoning solar implementational proliferation alongside intensifying non-potable water scarcity. The primary research objective underlines manifesting the latent productivity within passive tubular solar still (TSS) configurations via an amalgamated active system through the integration of metallic thermal transfer constituents (heat exchanger) alongside parabolic trough collector (PTC). Additionally, accelerated vapor condensation kinetics are catalyzed by the inclusion of beeswax phase change material (PCM) within the tubular metallurgies. A thorough empirical analysis of said system scrutinizes the synergistic fusion of concentrated solar thermal capacities using concentrated solar power (CSP) paradigms in tubular solar photo-thermal frameworks with beeswax constituting the auxiliary PCM thermal sink. A bifurcated data set provides experimental controls lacking PCM alongside PCM incorporation with repeating data gathering phases assessing comparative solar distillation system performance. The culminating system productivity and efficiency results exhibit a 66.18 % and 54.04 % respectively enhancement. Thus, the amalgamation of PTC-augmented TSS with metallic thermal exchangers & PCM beeswax integration introduces pragmatic pathways for advancing intensive solar-powered desalination output. Further academic interrogation of enabling thermal and optical phenomena driving said performance optimization remains imperative.

Low-Carbon-Oriented Capacity Optimization Method for Electric–Thermal Integrated Energy System Considering Construction Time Sequence and Uncertainty

The interdependence of various energy forms and flexible cooperative operation between different units in an integrated energy system (IES) are essential for carbon emission reduction. To address the planning problem of an electric–thermal integrated energy system under low-carbon conditions and to fully consider the low carbon and construction sequence of the integrated energy system, a low-carbon-oriented capacity optimization method for the electric–thermal integrated energy system that considers construction time sequence (CTS) and uncertainty is proposed. A calculation model for the carbon transaction cost under the ladder carbon trading mechanism was constructed, and a multi-stage planning model of the integrated energy system was established with the minimum life cycle cost, considering carbon transaction cost as the objective function, to make the optimal decision on equipment configuration in each planning stage. Finally, a case study was considered to verify the advantages of the proposed capacity optimization method in terms of economy and environmental friendliness through a comparative analysis of different planning cases. Simulation results show that, compared with the scenario of completing planning at the beginning of the life cycle at one time, the proposed low-carbon-oriented capacity optimization method that considers construction time sequence and uncertainty can not only reduce the cost of the integrated energy system, but also help to enhance renewable energy utilization and reduce the system’s carbon emissions; the total cost of phased planning is reduced by 11.91% compared to the total cost of one-time planning at the beginning of the year.

Design and energy-saving strategy of sustainable pressure-swing distillation with thermally and electrically coupled intensification for separating ternary mixture with multiple azeotropes

The separation of ternary mixtures that form multiple azeotropes is frequently encountered in industry. Benefiting from the pressure-sensitive nature of the azeotropic mixture, the pressure-swing distillation (PSD) is promising to realise the separation without introducing foreign solvents. However, the wide application of PSD seems challenging from an energetic point of view. This work has developed a sustainable PSD process with thermally and electrically coupled intensification to decrease energy consumption, taking the separation of homogeneous acetonitrile/ethanol/water mixture as a demonstrating example. Two conventional PSD processes with different product sequences are designed through the ternary phase diagram and further optimised using the NSGA-II, considering multiple objectives, including total capital cost, total operating cost, and CO2 emissions. The optimal solution is selected by the TOPSIS analysis for each sequence and is then intensified with thermal heat integration and electricity-driven heat pump techniques. The results show that, in comparison to the non-heat-integrated PSD process, the proposed intensified design can dramatically reduce the total annual cost by up to 48%, simultaneously decreasing CO2 emissions by up to 60% and boosting energy efficiency. The present study can be of reference for designing a sustainable PSD process in ternary azeotropic separation.

Performance analysis of integrated Nuclear-Solar Energy system sharing same molten salt thermal energy storage

Advanced nuclear reactors may be deployed with integrated thermal energy storage to improve flexibility and maximize revenue. This presents opportunities for thermal integration with concentrating solar power (CSP) to generate component synergies and/or improve performance. In this study, a computational model is developed for an integrated nuclear and CSP system that both share the same molten salt thermal energy storage (TES). Optimized dispatch schedules are developed subject to various market conditions, and the ratio of the nuclear to CSP thermal output is also varied. Performance of the combined system is compared to separate nuclear and solar plants, to determine if there is an overall benefit that can be derived from sharing the TES. Given sufficient volatility in electricity prices (e.g., under CAISO market conditions), synergies of up to 8% in net revenue are observed as a result of sharing the same TES, primarily due to improved revenue from enabling operation of the turbine closer to its design point, as well as being able to better take advantage of higher electricity prices. The synergy benefits are largest when the nuclear and solar plants have similar thermal output. However, when prices are less volatile the opposite behavior can be observed and it can be preferable to operate the nuclear plant as a baseload generator.