Temperature Gradient Research Articles

Optical super-resolution nanothermometry via stimulated emission depletion imaging of upconverting nanoparticles.

From engineering improved device performance to unraveling the breakdown of classical heat transfer laws, far-field optical temperature mapping with nanoscale spatial resolution would benefit diverse areas. However, these attributes are traditionally in opposition because conventional far-field optical temperature mapping techniques are inherently diffraction limited. Optical super-resolution imaging techniques revolutionized biological imaging, but such approaches have yet to be applied to thermometry. Here, we demonstrate a super-resolution nanothermometry technique based on highly doped upconverting nanoparticles (UCNPs) that enable stimulated emission depletion (STED) super-resolution imaging. We identify a ratiometric thermometry signal and maintain imaging resolution better than ~120 nm for the relevant spectral bands. We also form self-assembled UCNP monolayers and multilayers and implement a detection scheme with scan times >0.25 μm2/min. We further show that STED nanothermometry reveals a temperature gradient across a joule-heated microstructure that is undetectable with diffraction limited thermometry, indicating the potential of this technique to uncover local temperature variation in wide-ranging practical applications.

Nu–Gr correlation for laminar natural convection heat transfer from a sphere submitted to a constant heat flux surface

The work numerically investigated laminar natural convection heat transfer from the single sphere with a constant heat flux surface in air over the wide range of Grashof number (10≤Gr≤107\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$10 \\le Gr \\le 10^{7}$$\\end{document}). The more efficient and precise numerical method based on Bejan et al. was employed here, the accuracy of which has been confirmed through validation against a single sphere case. The heat transfer characteristics were systemically analyzed in terms of isothermal contours and streamlines around the sphere, dimensionless temperature and velocity profiles. Additionally, local Nusselt number as well as local pressure and friction drag coefficients were studied with different Grashof number. In comparison to the sphere with uniform heat flux surface, the heat transfer from the isothermal sphere was found to be enhanced attributable to a more robust buoyancy force and a steeper temperature gradient. Moreover, the average Nusselt number for the sphere with a constant heat flux between 60.4 and 98.6% of the isothermal sphere’s value, this range being contingent upon the specific Grashof number. What’s more, the proposed correlation addresses a notable void in the predictive understanding of heat transfer from the sphere with uniform heat flux, which is scenario prevalent in various engineering applications, particularly for the cooling of electrical and nuclear systems, and offer values for academic research.

Implementing the finite element numerical approach to optimize thermosolutal convection (TSC) energy imparted by discrete heat and solute sources in generalized Newtonian fluid flow in square enclosure

AbstractMesmerizing utilizations of thermosolutal convection (TSC) have been found in metallurgical and petrochemical procedures, crystal growth, thermal exchangers, nuclear waste disposal, and building environment control. In the current study, we considered three heat and solute sources on the left boundary of the cavity, which raises the significance of studying multiple chemical and civil engineering phenomena. Therefore, the prime motivation to commence this work is to attain the optimization of thermosolutal attributes characterized by non-Newtonian (power–law) liquid in the presence of installed sources. For this purpose, the natural convective flow governed by the nonpersistent impact of buoyancy forces is encompassed in the square enclosure. In addition to the source location, the vertical boundaries are considered to be cold, whereas the horizontal boundaries are kept insulated. Owing to the free convective flow, no compositional and thermal gradients are induced by lid movement, and all walls are prescribed with no-slip constraints. To examine the transport mechanism, structuring of problem is attained in the form of dimensional governing expressions by employing conservation laws. Subsequently, constitutive equations in a dimensionless format are accessed through similar variables. The finite element approach is employed to find the solution using COMSOL Multiphysics software. The deviations in the thermal and solutal fields are examined against the involved physical parameters by illustrating graphs and tables. Quantities of interest, such as the mean Nusselt and Sherwood numbers, are also computed against sundry parameters. The assurance of the computed results is validated by constructing a comparison with published studies. A grid sensitivity test is also executed to ensure the credibility of the built-in software (COMSOL). It is observed that the averaged heat and mass flux coefficient diminishes with an elevation in the magnitude of the power-law index (n), irrespective of the change in other involved parameters. The average Sherwood number tends to increase for a positive magnitude of (N) in contrast to negative values of (N). The average heat flux and average mass flux coefficients increase until the Prandtl number (Pr) reaches a value of 5 in shear thinning case at $$Ra\ge {10}^{5},$$ R a ≥ 10 5 , whereas, for n > 1 there is no substantial effect on either the average heat flux coefficient or average mass flux coefficient.

Linear and weakly nonlinear analyses of double‐diffusive convection in porous media with chemical reaction using LTNE model

AbstractThe onset of convection in a horizontal porous layer with chemical reaction and local thermal nonequilibrium is investigated. The nondimensional governing equations have been solved using the normal mode technique, which results in an eigenvalue problem. The analytical expressions for both stationary and oscillatory Rayleigh numbers are obtained. The effect of different parameters has been investigated and presented. The amplitude equation is derived using weakly nonlinear theory. Nusselt number is calculated using an amplitude equation to investigate heat transport. When modeling a fluid‐saturated porous medium, previous research on double‐diffusive convection has uniformly operated under the assumption of local thermal equilibrium (LTE) between the fluid and solid phases at all points within the medium. This standard practice assumes a minimal temperature gradient between the phases at any given location. However, in practical scenarios involving high‐speed flows or significant temperature differentials between the fluid and solid phases, the LTE assumption proves insufficient.

High Power Factor Flexible Ag2Te Film on Nylon by a Wet Chemical Method for Power Generator.

Herein, we develop a facile wet chemical method for the synthesis of Ag2Te powders at room temperature and flexible Ag2Te/nylon thermoelectric (TE) films are prepared by vacuum-assisted filtration of the synthesized Ag2Te powders and then hot pressing. Because of the good crystallinity of Ag2Te grains and continuous grain boundaries, an optimized film exhibits a power factor of 513 μW m-1 K-2 at 300 K, which stands among the highest values reported for Ag2Te-based films to date. In addition, the film also has good flexibility. A four-leg flexible TE device assembled with the film generates a power density of 5.46 W m-2 at a temperature gradient of 31.8 K. This work provides a facile and environmentally friendly method for preparing flexible Ag2Te films.

Transient behavior of oxide fuels with controlled microstructure and Cr2O3 additive

Microstructure and Cr2O3 doping profoundly impact the thermal-mechanical properties and fracture of oxides fuels. It is a challenge to study the transient behavior of nuclear fuels under loss-of-coolant-event (LOCA). In this study, the crack behavior of UO2 pellets with controlled grain structure and Cr2O3 doping was tested with rapid power ramping (300−900 °C per min) mimicking a prototypical LOCA heating profile. Dense micron-sized UO2 pellets display well-maintained integrity without cracking with the ramping up to 1500 °C at a heating rate of 8 °C per second. Fracture occurs in both pure and Cr2O3-doped dense nano-sized UO2 pellets. The Cr2O3 doped oxide fuel pellet with a larger grain size (~ 22.2 μm) displays the best performance under LOCA testing due to its highest thermal conductivity under high temperature. FEA calculations suggest a temperature gradient across the fuel pellet during transient testing, resulting in residual stress and cracking, which can be correlated with their thermal-mechanical properties.

Large anomalous Nernst conductivity of L10-ordered CoPt in CoPt composition-spread thin films

We demonstrate a high-throughput experimental characterization of anomalous Nernst conductivity ( αxyA ) of L10-ordered CoPt using Co1–x Pt x composition-spread thin films on MgO(100) substrates. The compositional dependence of the anomalous Nernst effect, anomalous Hall effect (AHE) and Seebeck effect is systematically measured. As increasing the Pt concentration, the crystal structure in the composition-spread film grown at 500 °C changes from face-centered cubic (fcc) Co, A1-disordered CoPt, L10-ordered CoPt, A1-CoPt to fcc Pt. The largest αxyA of 2.52 A m–1 K–1 is obtained in L10-CoPt for Pt-rich composition of x = 70%, which is larger than that for an additionally fabricated nearly stoichiometric L10-Co48Pt52 reference uniform film. The contribution from direct conversion of a temperature gradient to a transverse charge current through αxyA is dominant to the total anomalous Nernst coefficient compared to the AHE-related contribution. From a scaling analysis of the AHE, the intrinsic contribution is found to be dominant for x = 70%. A theoretical calculation for αxyA of L10-Co50Pt50 agrees with the experimental αxyA value for the nearly stoichiometric reference film by considering on-site Coulomb interaction for Co atoms. We also point out the possible electron doping effect by the addition of Pt in L10-CoPt, which could explain the larger αxyA for the off-stoichiometric Pt-rich composition than that for the nearly stoichiometric one. Our experimental and theoretical results suggest the potential of L10-CoPt with a large αxyA originating from the intrinsic mechanism for future thermoelectric applications.

Research on Temperature Distribution and Gradient Prediction of U-Shaped Girder Bridge under Solar Radiation Effect

With the development of bridge engineering, U-shaped girder bridges have been applied in numerous bridge designs due to their structural characteristics. However, the U-shaped girder bridge is sensitive to solar radiation effects, leading to uneven temperature distributions that can affect the service performance of the structure. Thus, this study proposes an analysis method for the temperature distribution of U-shaped girder bridges and develops a prediction model to estimate temperature gradients. First, an improved ASHRAE clear sky model is proposed to calculate the structural shadow areas under sunlight, which provides a basis for the numerical simulation of U-shaped girder bridges under solar radiation effect. Then, a three-dimensional finite element model of the U-shaped girder bridge is established, and its correctness is verified by comparing with the actual temperature data. The temperature distribution of the U-shaped girder bridge under solar radiation is simulated using the verified model to obtain the maximum temperature difference and temperature variation characteristics. Finally, a prediction model for the temperature gradient is developed using nonlinear fitting approaches, and its accuracy is confirmed through comparison with actual data. The results indicate that the temperature distribution of the U-shaped girder bridge has minor changes along the longitudinal direction, while there are significant changes in the transverse distribution; the temperature distribution exhibits nonlinear changes in the height direction of the two side webs and the lateral direction of the bottom slab, with the maximum temperature difference reaching 17 °C; the fitting effect of the prediction model is very good, the correlation coefficients of the fitting curve and the actual data are all greater than 88%, providing a basis for the analysis of the temperature effects on U-shaped girder bridges and its application in design specifications.

Interface charge accumulation in bi-layer dielectrics between cable and accessory insulation under temperature gradient

Bi-layer dielectrics are a feature of high-voltage direct-current cable and accessory systems, giving rise to the interfaces between the cable and accessory insulation. The interfaces act as preference sites for space charge build-up and are therefore regarded as potential breakdown initiation sites. A further complication is that during the operation of cable, a temperature gradient (TG) will be produced across the bi-layer insulation. In this paper, carbon black (CB) nanoparticles with 0, 0.5, 1, 1.5, 3.5 and 5.5 wt% are doped into silicon rubber (SR), space charge distributions in bi-layer dielectrics composed of cross-linked polyethylene (XLPE) and CB/SR nanocomposites under DC voltage and TG are measured using the pulsed electroacoustic method, and the effects of the doping proportion of CB nanoparticles and the TG on the bi-layer interface charge behavior are investigated. The experimental results show that under the TG, CB nanoparticles doped into SR can effectively suppress the interface charge accumulation, the amount of the interface charge decreases with the increase of the doping proportion from 0 to 1.5 wt% but increases with the increase of the doping proportion from 1.5 to 5.5 wt%, and the CB nanoparticle with 1.5 wt% shows relatively better suppression effect on the interface charge accumulation. With the increase of the TG, the amount of the interface charge increases initially and then decreases.

A Nonlinear Full-Field Conceptual Model for ENSO Diversity

Abstract As the strongest year-to-year fluctuation of the global climate system, El Niño–Southern Oscillation (ENSO) exhibits spatial–temporal diversity, which challenges the classical ENSO theories that mainly focus on the canonical eastern Pacific (EP) type. Besides, the complicated interplay between the interannual anomaly fields and the decadally varying mean state is another difficulty in current ENSO theory. To better account for these issues, the nonlinear two-region recharge paradigm model is extended to a three-region full-field conceptual model to capture the physics in the western Pacific (WP), central Pacific (CP), and EP regions. The results show that the extended conceptual model displays a rich dynamical behavior as parameters setting the efficiencies of upwelling and zonal advection are varied. The model can not only generate El Niño bursting behavior but also simulate the statistical asymmetries between the two types of El Niños and the warm and cold phases of ENSO. Finally, since both the anomaly fields and mean states are simulated by the model, it provides a simple tool to investigate their interactions. The strengthening of the upwelling efficiency, which can be seen as an analogy to a cooling thermocline associated with the oceanic tunnel to the midlatitudes, will increase the zonal gradient of the mean state temperature between the WP and EP, i.e., resembling a negative Pacific decadal oscillation (PDO) pattern along the equatorial Pacific. The influence of the zonal advection efficiency is quite the opposite, i.e., its strengthening will reduce the zonal gradient of the mean state temperature along the equatorial Pacific.

Safety Evaluation for Fabricated Small Box Girder Bridges Based on Fuzzy Analytic Hierarchy Process and Monitoring Data

During the operation of fabricated small box girder bridges, which face safety issues such as structural degradation and failure, there is an urgent need to propose a safety evaluation method to cope with the possible risks. This article quantitatively evaluates the safety state of a fabricated small box girder bridge in Wuhan City based on Fuzzy Analytic Hierarchy Process (FAHP) and structural health monitoring (SHM) data. Firstly, the FAHP model is established, and stress, deformation, and temperature are selected as evaluation factors. The safety thresholds of stress and deformation are determined by combining the industry specifications and the historical statistical patterns of the massive SHM data. The temperature field of the bridge is simulated and analyzed by combining ANSYS, HYPERMESH, and TAITHREM, and the most unfavorable temperature gradient is determined as a threshold for the safety evaluation. Finally, the scores of indexes of the bridge are determined based on the measured SHM data, which in turn provides a quantitative description of the safety state. The results show that the thresholds determined by the joint industry specifications and the massive SHM data are reasonable; the temperature field simulation model established in this article is consistent with the measured results, and can accurately determine the temperature gradient of the bridge. The safety evaluation result from the FAHP model is the same as the field test results, which verifies the effectiveness and applicability of the proposed method to actual bridge projects.

AscentAM: A Software Tool for the Thermo-Mechanical Process Simulation of Form Deviations and Residual Stresses in Powder Bed Fusion of Metals Using a Laser Beam

Due to the tool-less fabrication of parts and the high degree of geometric design freedom, additive manufacturing is experiencing increasing relevance for various industrial applications. In particular, the powder bed fusion of metals using a laser beam (PBF-LB/M) process allows for the metal-based manufacturing of complex parts with high mechanical properties. However, residual stresses form during PBF-LB/M due to high thermal gradients and a non-uniform cooling. These lead to a distortion of the parts, which reduces the dimensional accuracy and increases the amount of post-processing necessary to meet the defined requirements. To predict the resulting residual stress state and distortion prior to the actual PBF-LB/M process, this paper presents the finite-element-based simulation tool AscentAM with its core module and several sub-modules. The tool is based on open-source programs and utilizes a sequentially coupled thermo-mechanical simulation, in which the significant influences of the manufacturing process are considered by their physical relations. The simulation entirely emulates the PBF-LB/M process chain including the heat treatment. In addition, algorithms for the part pre-deformation and the export of a machine-specific file format were implemented. The simulation results were verified, and an experimental validation was performed for two benchmark geometries with regard to their distortion. The application of the optimization sub-module significantly minimized the form deviation from the nominal geometry. A high level of accuracy was observed for the prediction of the distortion at different manufacturing states. The process simulation provides an important contribution to the first-time-right manufacturing of parts fabricated by the PBF-LB/M process.

Mechanical behavior and thermal damage characterization of granite after flame jet-water cooling treatment

Flame jet-assisted mechanical rock drilling is expected to solve the hard-rock crushing challenges in underground engineering such as mining, tunneling, and drilling. Therefore, it is important to investigate mechanical behavior of the rock after flame jet-water cooling treatment. In this paper, granite blocks were subjected to flame jet-water cooling treatment, which means the rapid heating of the granite using a flame with a temperature of 1564 °C, followed by water cooling. Then, physico-mechanical behaviors of samples at different distances (all the distances mentioned later mean the vertical distance between the sample axis and the flame jet-water cooling path) were measured. Results showed physico-mechanical parameters of the sample increased as the distance increased. The Vp (P-wave velocity), UCS (uniaxial compressive strength) and BTS (Brazilian tensile strength) of the samples increased from 3171.7 m/s, 84.84 MPa and 5.01 MPa at 0 mm to 3619.3 m/s, 145.86 MPa and 7.30 MPa at 70 mm, respectively. Meanwhile, physico-mechanical parameters of samples at 70 mm all reached more than 95 % of those of untreated samples. As the distance increased, cumulative AE counts at peak stress gradually enhanced, and failure modes of uniaxial samples shifted from shear to tensile splitting failure. The SEM (scanning electron microscope) images illustrated that the closer to the flame jet-water cooling path, the more thermal cracks produced in the sample. Meanwhile, the damage factor can well characterize the thermal damage degree of granite. According to the variation of physico-mechanical parameters and SEM images of samples with distances, it can be assumed that the thermal damage width of granite after flame jet-water cooling was about 140 mm. It was much greater than the 50 mm width of spalling pits, which greatly increased the feasibility of thermal-assisted mechanical rock drilling. The tensile stress induced by the temperature gradient below the spalling pit is the fundamental cause of thermal damage to the rock, which is further aggravated by water cooling. The findings can provide some guidance for flame jet-assisted mechanical rock drilling.

Numerical Simulation and Experimental Comparison of System Analysis Module 1D Mixing Model for Cold Shock Transients in the Gallium Thermal-Hydraulic Mixing Facility

Liquid metals are being investigated as coolants in many advanced reactor designs because of their high thermal conductivity and effectiveness at high temperatures. However, they often pose challenges to reactor operation and safety because of the complex thermal mixing and stratification in the plenum of pool-type reactor designs. The advanced system analysis code System Analysis Module (SAM) currently under development at Argonne National Laboratory aims to develop and implement thermal mixing models to accurately capture these complex thermal fluid behaviors. In this study, the SAM thermal mixing model was compared against experimental data from the Gallium Thermal-Hydraulic Experiment facility, a scaled liquid metal test facility that uses gallium as a surrogate fluid to investigate the stratification and thermal mixing of low-Prandtl-number fluids in the upper plenum of a liquid metal–cooled reactor. Two cold shock transient cases were used: one with stable stratified flow (Ri = 32) and one with stronger thermal mixing (Ri = 0.5). The resultant temperatures were then compared with the experimental temperatures over the entire plenum to assess the ability of the mixing models to capture the thermal behavior and to better correspond mixing parameters to various flow scenarios. Generally, the zero-dimensional mixing model was more capable of capturing the bulk temperature of the component modeled assuming that an accurate mass flow rate was provided, but it was inherently unable to capture thermal gradients in space. The one-dimensional mixing model was capable of capturing that the thermal gradients provided accurate selection of the mixing coefficients. The temperature at the outlet junction was compared over time for each of the mixing models with the recorded experimental temperature. The implemented mixing models demonstrated the ability to effectively capture the overall thermal behavior for stronger mixing scenarios but struggled with more stably stratified flows. It was found that a system analysis code’s covering of the entire range of different operating conditions still remains a challenging task, and it is suggested that further model and closure improvements are necessary to accurately capture complex thermal mixing and stratification phenomena.

Numerical Simulation and Experimental Comparison of System Analysis Module 1D Mixing Model for Cold Shock Transients in the Gallium Thermal-Hydraulic Mixing Facility

Liquid metals are being investigated as coolants in many advanced reactor designs because of their high thermal conductivity and effectiveness at high temperatures. However, they often pose challenges to reactor operation and safety because of the complex thermal mixing and stratification in the plenum of pool-type reactor designs. The advanced system analysis code System Analysis Module (SAM) currently under development at Argonne National Laboratory aims to develop and implement thermal mixing models to accurately capture these complex thermal fluid behaviors. In this study, the SAM thermal mixing model was compared against experimental data from the Gallium Thermal-Hydraulic Experiment facility, a scaled liquid metal test facility that uses gallium as a surrogate fluid to investigate the stratification and thermal mixing of low-Prandtl-number fluids in the upper plenum of a liquid metal–cooled reactor. Two cold shock transient cases were used: one with stable stratified flow (Ri = 32) and one with stronger thermal mixing (Ri = 0.5). The resultant temperatures were then compared with the experimental temperatures over the entire plenum to assess the ability of the mixing models to capture the thermal behavior and to better correspond mixing parameters to various flow scenarios. Generally, the zero-dimensional mixing model was more capable of capturing the bulk temperature of the component modeled assuming that an accurate mass flow rate was provided, but it was inherently unable to capture thermal gradients in space. The one-dimensional mixing model was capable of capturing that the thermal gradients provided accurate selection of the mixing coefficients. The temperature at the outlet junction was compared over time for each of the mixing models with the recorded experimental temperature. The implemented mixing models demonstrated the ability to effectively capture the overall thermal behavior for stronger mixing scenarios but struggled with more stably stratified flows. It was found that a system analysis code’s covering of the entire range of different operating conditions still remains a challenging task, and it is suggested that further model and closure improvements are necessary to accurately capture complex thermal mixing and stratification phenomena.

Statistics of kinetic and thermal energy dissipation rates in vibrational turbulent Rayleigh–Bénard convection with rough surface

In this paper, the statistical properties of the kinetic εu and thermal εθ dissipation rates in two-dimensional (2D) turbulent Rayleigh–Bénard convection (RBC) are studied by using the thermal lattice Boltzmann method (LBM). A series of direct numerical simulations (DNS) are implemented in a square cell with the unit aspect ratio for the Rayleigh number Ra = 108 and Prandtl number Pr = 4.38. The roughness height h* and vary the vibration frequency ω* from 0 to 1000 are fixed in the vibrational RBC with rough plates to explore their effect on the kinetic and thermal dissipation rates. The global features indicate that the εu and εθ are more intense in the regions with high gradients of velocity and temperature, which is in good agreement with the previous work. The scalings of Nu∼ω *0.55±0.1 and Re∼0.59±0.2 are proposed between the ensemble averaged Nusselt number Nu and Reynolds number Re. The probability density functions (PDFs) of both logarithmic kinetic dissipation rate lg εu and thermal dissipation rate lg εθ are not conformed to the log-normal distributions. Through the analysis of the time-averaged εu and εθ vertical profiles, it is further demonstrated that the local dissipation rates from the boundary layer region are still the major contribution in the vibrational RBC with rough plates.

Highly efficient storage of cavity SPDC single photons in room temperature gradient echo memory

Highly efficient storage of cavity SPDC single photons in room temperature gradient echo memory

Do ceiling fans in rooms help to reduce or disperse the transmission of breathing aerosols?

The main focus of this study is the transmission of SARS-CoV-2 through virus-laden aerosols in enclosed spaces that utilize ceiling fans. The impact of an air circulation of ceiling fans on virus transmission is not clear. Computational modeling is employed to investigate aerosol transmission within an enclosed space that features ceiling fans. The aerosol concentration is modeled using a transport equation, and the probability of infection distribution across individuals’ breathing zones is assessed. The particle removal efficiency for two ceiling fan speeds of 10 and 35 rad/s is calculated to evaluate the effect of the ceiling fan’s shear flows on the spread of breathing aerosols. The simulated breathing aerosol considers various environmental situations, including thermal gradients, thermally active surface interaction, and deformability. The results indicate that increasing the ceiling fan speed within an enclosed space causes the aerosol cloud to circulate within the room rather than exiting it. Therefore, ceiling fans may not effectively suppress breathing aerosols and could increase transmissibility. Understanding aerosol behavior is essential in reducing the risk of SARS-CoV-2 transmission in enclosed spaces.

Validation and Application of Satellite-Derived Sea Surface Temperature Gradients in the Bering Strait and Bering Sea

The Arctic is one of the most important regions in the world’s oceans for understanding the impacts of a changing climate. Yet, it is also difficult to measure because of extreme weather and ice conditions. In this work, we directly compare four datasets from the Group for High-Resolution Sea Surface Temperature (GHRSST) with a NASA Saildrone deployment along the Alaskan Coast and the Bering Sea and Bering Strait. The four datasets used are the Remote Sensing Systems Microwave Infrared Optimally Interpolated (MWIR) product, the Canadian Meteorological Center (CMC) product, the Daily Optimally Interpolated Product (DOISST), and the Operational Sea Surface Temperature and Ice Analysis (OSTIA) product. Spatial sea surface temperature (SST) gradients were derived for both the Saildrone deployment and GHRSST products, with the GHRSST products collocated with the Saildrone deployment. Overall, statistics indicate that the OSTIA product had a correlation of 0.79 and a root mean square difference of 0.11 °C/km when compared with Saildrone. CMC had the highest correlation of 0.81. Scatter plots indicate that OSTIA had the slope closest to one, thus best reproducing the magnitudes of the Saildrone gradients. Differences increased at latitudes > 65°N where sea ice would have a greater impact. A trend analysis was then performed on the gradient fields. Overall, positive trends in gradients occurred in areas along the coastal regions. A negative trend occurred at approximately 60°N. A major finding of this study is that future work needs to revolve around the impact of changing ice conditions on SST gradients. Another major finding is that a northward shift in the southern ice edge occurred after 2010 with a maxima at approximately 2019. This indicates that the shift of the southern ice edge is not gradual but has dramatically increased over the last decade. Future work needs to revolve around examining the possible causes for this northward shift.

Occurrence of ceramides in the Acidobacterium Solibacter usitatus: implications for bacterial physiology and sphingolipids in soils

Sphingolipids have long been of interest to the scientific community for their roles in eukaryotic cell structuring and disease pathology. Less is known about the occurrence and function of these diverse compounds in the bacterial domain of life, with most studies on bacterial sphingolipids focused on eukaryotic disease research and host-pathogen or host-symbiont interactions. Thus, bacterial contributions to environmental sphingolipid pools are poorly understood and the function of these lipids outside of pathogenicity remains largely unexplored. This report marks the first instance of sphingolipid production in a member of the phylum Acidobacteria, a globally ubiquitous phylum of soil bacteria. The occurrence of core- and intact-ceramides is reported for the Acidobacterium Solibacter usitatus under various environmentally relevant conditions. Shifts in the production of ceramides across temperature, pH, and oxygen gradients in this organism suggest that these compounds play a role in the physiological adaptation to environmental fluctuations. Additionally, the genetic basis of bacterial ceramide biosynthesis in this species is assessed and used to explore the potential for ceramide biosynthesis across the bacterial domain of life. The extent of the biosynthetic potential for Acidobacteria to produce ceramides coupled to the abundance of their genes in soil metagenomes suggests that soil sphingolipids should not be solely attributed to eukaryotic production.