Thermal Energy Storage Device Research Articles

Numerical study on the combined application of multiple phase change materials and gradient metal foam in thermal energy storage device

Latent heat thermal energy storage (LHTES) offers significant energy-saving benefits, but its application is limited due to the low thermal conductivity of phase change material (PCM). To address this issue, this article studied the combined application of metal foam structures with different porosity gradients and multiple PCMs with different melting points through numerical simulation to accelerate the melting of PCM and enhance system efficiency. The results showed that the application of multiple PCMs improved the heat transfer performance of the system, reducing the complete melting time by 9.18% compared to using a single PCM with uniform metal foam. Based on the multi-PCM storage system with an average porosity of 0.90, this article designed metal foam structures with one-dimensional and two-dimensional porosity gradients and explored their impacts. The results indicated that in the structure with a one-dimensional porosity gradient along the heat flow direction, the positive gradient decreased thermal resistance, further reducing the complete melting time by 6.18%, while the negative gradient increased it by 19.78%. However, the temperature non-uniformity was lowest with the negative gradient and highest with the positive gradient. The optimal two-dimensional porosity gradient multi-PCM storage model not only reduced thermal resistance but also effectively solved the issue of uneven melting, reducing the complete melting time by 17.96% and increasing the energy storage efficiency by 20.16% compared to the single PCM system with uniform porosity. Furthermore, the article conducted a dimensionless analysis of the optimal structure and different gradient structures, establishing formulas for the liquid fraction concerning modified Fourier number, modified Stefan number, and modified Rayleigh number.

Influence of activation energy and multidiffusive quadratic convective nanoliquid flow past a cone and wedge

The present problem aims to examine the impact of quadratic buoyancy-driven flow nanofluid flow on two specific geometries such as cone and wedge in the presence of binary chemical reactions with activation energy, using liquid hydrogen species. This analysis is relevant for various industrial applications and are widely used in thermal energy storage devices for cooling or heating processes. The fluid flow model's governing equations are numerically solved using a fifth-order boundary value approach in matrix laboratory (MATLAB). In order to obtain the numerical solution, we initially transformed the coupled equations of the flow model and the partial differential equations into ordinary differential equations using similarity variables. The graphs and tables illustrate the importance of different physical factors that impact fluid flow and heat transfer. The quadratic combined convection parameter leads to an augmentation in fluid velocity while also inducing an elevation in frictional forces between the object's surface and the fluid. The increased in values of Schmidt number cause a decrease in mass diffusivity, which in turn leads to lower concentration profiles and improved mass transport efficiency. The activation energy is directly proportional to the decreased amplitude of the concentration profiles of liquid hydrogen species.

Self-regulating thermal energy storage device

Self-regulating thermal energy storage device

Performance evaluation of underground thermal storage integrated dual-source heat pump systems

The increasing demand for electricity stresses the existing electric grids. Buildings consume 73% of all U.S. electricity and are responsible for 30% of U.S. greenhouse gas emissions. Integrating thermal energy storage (TES) in building heating/cooling systems, which consume considerable electricity, can mitigate the challenges to electric grids. This study reports on a novel thermal energy storage device integrated heat pump system to reshape the building electricity demand profile while maintaining thermal comfort. The annual performance of the proposed system has been evaluated through a dynamic system simulation with high fidelity in the Modelica platform. The dynamic model of the novel hybrid component named ‘dual purpose underground thermal battery’ was developed and validated. It was then incorporated into the system model. Given a time-of-use tariff, a rule-based control strategy was designed to shift the electric demand and switch the heat pump source for a typical single-family house in different climate zones of the United States. The system performance of the new TES-integrated dual-source heat pump was compared with that of a conventional air-source heat pump system. The results indicate that the proposed system can reduce the annual HVAC electricity cost by up to 52% while saving 45.2% on electricity consumption. In the Northern areas, the annual peak load of the HVAC system can be reduced by 64.9%. However, this reduction is less in the Southern areas as the system’s higher efficiency in winter dominates the overall energy-saving potential.

Heat transfer investigation of nano – Encapsulated phase change materials (NEPCMs) in a thermal energy storage device

Phase change natural convection heat transport and flow features of a variety and new types of hybrid nanoliquids, suspension of Nano – encapsulated phase change materials (NEPCMs), within a square cavity is inspected theoretically in this analysis. The capsules are arranged with a shell and a PCM as a core. The shell of this NEPCM prevents the phase change material from the direct interaction of hot fluid and from the leakage. The heat capacity of the suspension contains latent heat generated at the time of phase change. The modeled equations are numerically scrutinized with Finite element method. Variable thermal conductivity parameter 1≤Nc≤5, variable viscosity parameter 1≤Nv≤5, radiation number 0.5≥R≥0.1, Rayleigh parameter 102≤Ra≤103, volume fraction of NEPCMs1%≤ϕ≤5% and fusion temperature (0.2≤θf≤1.0) impact on the patterns of heat capacity ratio, isotherms and velocity lines are examined in detail. The results indicates that, as the volume fraction values of NEPCMs amplifies from 1% to 5% the rates of heat transfer of the nanoliquid magnifies 42% compared to the host fluid. Non – dimensional rates of heat transport magnifies with growing (Ste) values.

Thermal Characterization of [C2Im][NO3] and Multivalent Nitrate Salts Mixtures

Due to their intrinsic properties, the current applicability of ionic liquids is enormous. In particular, their use in electrochemistry is beyond question. Numerous studies on these compounds and their mixtures, especially with lithium salts, focus on their use as electrolytes for batteries and other energy storage devices. This includes thermal energy storage devices, where 4th generation ionic liquids and their derivatives show a huge potential. Nevertheless, considering the uneven availability of the raw materials, such as lithium, research has extended to mixtures of these compounds with other salts of different metals that are more abundant and widely distributed, such as magnesium or aluminum. This work presents a comprehensive thermal characterization, using differential scanning calorimetry and thermogravimetry, of the protic ionic liquid ethylimidazolium nitrate and its mixture with magnesium and aluminum nitrate salts at different concentrations. Additionally, a comparison between these results and previous studies of mixtures of this ionic liquid with lithium nitrate, as well as mixtures of the protic ionic liquid EAN with the same metal salts, was also performed. The results indicated that the salt addition tends to broaden and reduce crystallization and melting peaks, while the glass transition becomes more visible and shifts to higher temperatures with increasing salt concentration. This is due to the disorder generated by the rearrangement of ions in the polar domains, which erodes the hydrogen bond network of the protic ionic liquid. Nevertheless, the thermal stability of the blended samples does not change significantly compared to the bulk ionic liquid.

Numerical investigation of the effect of an air layer on the melting process of phase change materials

Designing more effective thermal energy storage devices can result from understanding how air layers impact the melting process. The total efficiency of these systems can be improved by optimizing the melting process of the phase change materials (PCMs), which are utilised to store and release thermal energy. The current study utilises an analysis to evaluate how an air layer would affect melting of the PCM. The enthalpy-porosity combination based ANSYS/FLUENT 16 software is specifically used to accomplish this study, considering the paraffin wax (RT42) as the PCM. The study reveal that the presence of an air layer would impact the dissolution process. This result is assured an increase of melting time of PCM by 125% as a result to having an air layer of 5 cm thickness compared to a cell without an air layer. Furthermore, an increase of the layer thickness beyond 5 cm has a progressive effect on the melting time of PCM. One important component that affects the melting process is the existence of an air layer above the cell. Greater heat transfer resistance from thicker air layers prolongs the time needed to finish melting. The efficient heat transmission of PCM is shown to be reduced when there is an air layer above the cell. The melting process gradually slows down as the air layer thickness rises, which reflects the decreased heat transmission. These results highlight how crucial it is to take the environment into account while creating PCM-filled energy storage cells.

Thermal management of high-powered short-duration electronics aided by a phase change material thermal energy storage

Quantifying the performance of phase change materials (PCMs) for thermal energy storage in high-power short-duration electronics applications requires performing tests that push the material to its limit. This involves designing experiments to test solid-liquid PCMs in near real-world thermal load conditions to test its performance. Conventional cooling methods are sized to manage the maximum loading the cooling system will be subjected to in its operation, even if this loading occurs for a short period of time. This design ethos is inefficient and results in heavy and expensive equipment being used in an application where it will be underutilized most of its useful life. In this work, a PCM thermal energy storage (TES) device was built using a plate-and-frame heat exchanger and investigated to determine the suitability of this system to manage the temperature of high-power electronics with a low duty cycle. These experiments showed how a PCM-TES can be used in conjunction with conventional temperature management equipment to create a reliable cooling solution while allowing the conventional cooling components to be decreased in size and capacity. This work shows that, for a given application, a cooling system can be more efficiently designed with the use of a PCM-TES and opens the door to additional research on this topic.

Engineering lightweight Poly(lactic acid) graphene nanoribbon nanocomposites for sustainable and stretchable electronics: Achieving exceptional electrical conductivity and electromagnetic interference shielding with enhanced thermal conductivity

The challenge of creating flexible and sustainable electronics with properties such as lightweight, electrical and thermal conductivity, and electromagnetic interference (EMI) shielding is addressed in this study. Carbon nanotubes and graphene are commonly used in flexible electronic devices, but gaps exist in their conductivity and flexibility. A novel and scalable fabrication method is introduced, involving the creation of bio-based nanocomposites by integrating flexible and high aspect-ratio graphene nanoribbons (GNRs) into a poly (lactic acid) (PLA) matrix. The nanocomposites were drawn above the glass transition temperature (Tg) of PLA, resulting in the formation of extended shish structures, as observed in scanning electron microscope (SEM) images. These structures significantly enhanced thermal and electrical conductivities, as well as EMI shielding features. The combination of flexible GNR nanofillers with uniaxial stretching led to a substantial increase in Young's modulus, tensile strength, and toughness by approximately 550 %, 440 %, and 600 %, respectively, most likely due to the increased network connection despite the higher flexibility of GNRs. Moreover, in-plane thermal conductivity registered a notable enhancement of approximately 110 %. The EMI shielding reached 26 dB, with an absorption contribution to EMI shielding of around 45 %. Additional improvement was achieved through foaming of the stretched samples, resulting in multilayer structures with alternative extended shish and foam structures. Furthermore, a significant augmentation of approximately 33 dB in total EMI shielding of the foamed samples, accompanied by an 85 % increase in SEA was documented. These promising findings underscore potential applications across diverse domains, including thermal interface materials, electronic packaging, capacitors, and energy storage devices, with a specific emphasis on the realm of sustainable and stretchable electronics.

Thermal analysis of a viscoelastic Maxwell hybrid nanofluid with graphene and polythiophene nanoparticles: Insights from an artificial neural network model

The utilization of solar radiation by converting them into thermal energy is discussed in this paper. Nanoparticles improve the ability of heat transfer therefore, it is beneficial in the use of solar thermal systems and energy storage devices. The novel mixture of nanoparticles Graphene and Polythiophene in base fluid, which has high thermodynamic properties for the improvement of thermal effect with electromagnetic effect by using Maxwell fluid model is discussed. Polyvinyl alcohol water is taken as base fluid flowing through a moveable flat plat. The governing partial differential equations are transformed into ordinary differential equations. The semi-analytical technique, homotopy analysis method is used to obtain the solution of the ordinary differential equations. The velocity is enhanced with magnetic and electric field strength. The increase of the Prandtl number, Eckert number and chemical reaction parameter, exceeds the thermal effect which produces more entropy generation and heat enhancement. The results show that the hybrid nanofluid with this Novel mixture is highly thermodynamic with higher entropy and rapid thermal augmentation which can be used in energy production and energy storage devices. A novel intelligent numerical computing technique multi-layer perceptron with feed-forward back-propagation, an artificial neural networking method with the Levenberg-Marquard algorithm is used in this model. The data is gathered for the neural networking method training, validation, and testing. The efficiency of the model is obtained and mean square error is obtained by artificial neural networking.

Temperature and salt concentration behavior of a compact rectangular salinity gradient solar pond

Design of economical and effective solar ponds which are useful thermal energy storage devices, remains a huge challenge. The present work aims at investigating the thermal performance of low cost mini salt gradient solar pond. The portable pond was fabricated as a rectangular configuration having a volume of 0.5m3. Polystyrene and high density polyethylene sheets were employed for insulating the walls. The top of the pond was covered with a slender glass so that the dust accumulation could be prevented without affecting the absorption of solar radiation. Sodium chloride salt was used as the medium and the three salt gradient regions namely lower convective, non-convective, and upper convective regions were established through injection filling technique. The temperature and salt gradient data were observed experimentally for a period of 20 days at Coimbatore, India. The pond could absorb significant amount of available radiation (around 65%) and the maximum temperature of the pond was observed to be 49oC. Frequent washing of the water surface is necessary to maintain stable salt gradient. Nevertheless, portable pond fabricated with low cost materials exhibited good potential of storing solar energy for solar thermal applications.

A Eulerian Numerical Model to Predict the Enhancement Effect of the Gravity-Driven Motion Melting Process for Latent Thermal Energy Storage.

Latent thermal energy storage (LTES) devices can efficiently store renewable energy in thermal form and guarantee a stable-temperature thermal energy supply. The gravity-driven motion melting (GDMM) process improves the overall melting rate for packaged phase-change material (PCM) by constructing an enhanced flow field in the liquid phase. However, due to the complex mechanisms involved in fluid-solid coupling and liquid-solid phase transition, numerical simulation studies that demonstrate physical details are necessary. In this study, a simplified numerical model based on the Eulerian method is proposed. We aimed to introduce a fluid deformation yield stress equation to the "solid phase" based on the Bingham fluid assumption. As a result, fluid-solid coupling and liquid-solid phase transition processes become continuously solvable. The proposed model is validated by the referenced experimental measurements. The enhanced performance of liquid-phase convection and the macroscopic settling of the "solid phase" are numerically analyzed. The results indicate that the enhanced liquid-phase fluidity allows for a stronger heat transfer process than natural convection for the pure liquid phase. The gravity-driven pressure difference is directly proportional to the vertical melting rate, which indicates the feasibility of controlling the pressure difference to improve the melting rate.

Experimental and analytical study on continuous frozen/melting processes of latent thermal energy storage driven by bubble flow

It is emphasized direct contact method that introduced to the frozen/melting processes has a high value of development due to the role for mitigating thermal stratification, reducing phase separation and enhancing heat transfer efficiency. However, the absence of fixed solid heat transfer walls can lead to discontinuous switch and difficult-to-control problem during frozen/melting processes. In this paper, the latent thermal energy storage device driven by bubble flow is experimentally investigated. With the usage of low melting point paraffin and the pattern of free expansion in a cabinet, continuous switch between the frozen and the melting process can be realized. Phase change processes, temperatures, heat transfer efficiency, volume change and pressure drops are measured and analyzed. A dynamic analytical model to describe the processes is also developed based on the ε - NTU method. The results show that the heat transfer efficiency can reach to 0.8 at least in all the experimental cases. Moreover, this study records the pressure difference of the gas flow, predicts the required input mechanical work and analyses the volumetric heat transfer coefficient, which help to reveal feasibility of the device.

Ferrosilicon alloys at the core of new thermal energy storage devices

Ferrosilicon alloys at the core of new thermal energy storage devices

State-of-the-art and challenges towards a Molecular Solar Thermal (MOST) energy storage device

In this minireview, the recent advances and limitations of MOlecular Solar Thermal (MOST) energy storage technology are discussed, including a discussion of the photoisomerization and the catalytic back-conversion reactions.

PERFORMANCE OF HEAT PUMP BASED ON COMPOSITE ADSORBENT ‘SILICA GEL – CRYSTALLINE HYDRATE’

Performance of an adsorptive heat pump has been studied. The factors affecting the efficiency of its work have been analyzed. Operating parameters and efficiency of adsorptive heat pumps and adsorptive heat storage devices have been compared. An algorithm of calculating the basic operating characteristics of an adsorption heat pump in heat supply systems has been proposed. It involves calculating the mass transfer coefficient, final absolute humidity of the air flow passed though adsorbent layer, the water uptake or adsorption and the useful heat of adsorption and heat of condensation, determination of heat inputs for the operation of the device such as heating the adsorbent, case of the device, hydraulic circuit, the water in the tank and adsorbed water, heat of desorption and heat of evaporation, estimation the coefficient of energy performance. The evaluation criteria of the efficiency of adsorptive heat pumps and heat storage devices have been compared. It is shown that the operating parameters of the adsorptive heat pump and the adsorptive thermal energy storage device based on composite adsorbents ‘silica gel – sodium sulfate’ and ‘silica gel – sodium acetate’ are the same, i.e. airflow rate 0.08 - 0.1 m3/s and initial absolute humidity of airflow 0.03 – 0.04 kg/m3, which are corresponded with maximal efficiency of the device. The temperature of the humid air flow directed to the adsorbent layer is suggested to be set at 20 – 40 °C. The measures to increase the efficiency of the adsorptive heat pump are proposed. It is shown that ultrasonic air humidification allows to increase the coefficient of energy performance by almost 2 times compared to steam humidification. The obtained results can be used for developing energy-efficient heating systems of residential premises.

Charging/discharging performance and corrosion behavior of a novel latent heat thermal energy storage device with different fin plate materials

The use of low-grade industrial waste heat for building heating could facilitate the decarbonization of heat sector, which accounts for a large share of energy consumption worldwide. However, the uncontrollable fluctuation characteristics of heat source and mismatch between energy supply and demand greatly limit its large-scale application. Notably, latent heat thermal energy storage (LHTES) technology, showing remarkable advantages in terms of energy storage density, heat storage temperature (nearly constant), technology maturity and cost, could effectively solve the above problem. Hence, this work specially focused on LHTES device that utilized fin plate for improving performance of heat harvesting and reuse. Furthermore, charging/discharging performance and corrosion behavior of a novel device with different fin plate materials (brass, aluminum and stainless steel) were investigated. Results showed that temperature difference between plate surface and melting point above 10 °C effectively shortened charging time more than 45.7 %. A higher thermal conductivity of fin material contributed to a better thermal performance. Aluminum and stainless steel preferred to be used as fin plate materials of targeted hydrated salt owing to their low corrosion rate of 0.016 and 0.002 mg/(cm2·yr), respectively. This work was expected to provide a guidance on designing a LHTES device applied in building heating.

Experimental analyses of solidification phenomena in an ice-based thermal energy storage system

Latent thermal energy storage devices can efficiently store surplus thermal energy during off-peak hours. The system's phase change material (PCM) improves energy storage capacity and isothermal properties. Most PCMs have weak thermal conductivity, which hampers heat transfer. Thus, the present analysis involves an insight into the heat transfer characteristics and thermal performance of a vertical tube-in-tank cold storage system. The objective of this investigation is to gain a better understanding of the significance of buoyancy-driven convection within the side bulk region during the discharging of water as PCM in the heat exchanger. A series of experiments are conducted to investigate the effect of varying the initial bulk temperature on the rate of PCM solidification. The effects of three distinct initial bulk temperatures which are 20 °C, 15 °C, and 5 °C on the solidified mass fraction, thermal performance, and heat transfer rate at various radial and axial locations in PCM are examined. It is seen that PCM experienced a varying cooling rate with varying axial height and is found to be the highest in the bottom region. PCM temperature decreases from top to bottom under the cases of 20 °C and 15 °C, respectively. In contrast, a narrow-ranged thermocline layer is observed under 5 °C bulk temperature, making uniform temperature distribution within the bulk. The influence of bulk natural convection prevails in the later stages of the discharging process under 5 °C bulk, whereas it predominantly exists during the initial stages of solidification under bulk temperatures of 20 °C and 15 °C.

Heat transfer enhancement and applications of thermal energy storage techniques on solar air collectors: A review

Solar air collectors have been used in a variety of industrial applications, prompting a study and summary of various studies on the topic. Solar collectors’ exceptional energy conversion and storage outputs have piqued curiosity in the field of energy research. The current review study focuses on solar thermal application advancements and provides an overview of thermal energy storage devices and solar collectors. This paper presents and discusses a variety of solar collectors, both concentrating and non-concentrating. The energy storage media utilized in these plants, phase change material with melting temperatures exceeding 300°C, was exam-ined. The goal of this study is to provide the necessary information for advanced investiga-tions in the development of cost-effective high-temperature thermal storage systems. Finally, a summary of the presentation, as well as potential solar power plants are reviewed.

Enhancing the performance of composite phase change materials using novel triply periodic minimal surface structures

Organic phase change materials (PCMs) are widely used in thermal management applications owing to their high latent heats of fusion and low cost. Unfortunately, their poor thermal conductivities severely hamper the thermal transport process. Hence, PCMs are often hybridized with high thermal conductivity materials that promote phase change for time-sensitive applications and potentially increase the power density of thermal energy storage (TES) devices. Optimized thermally conductive networks with high-latent-heat PCM matrices are critical in the thermal management of high heat flux applications. With advancements in additive manufacturing, it has become easier to create complex topologies, such as triply periodic minimal surfaces (TPMS), that can further augment the performance of composite PCMs. TPMS surfaces have shown great promise in improving thermal transport performance but investigations into their thermal properties remain limited. In this study, the thermal performances of PCM infused TPMS structures of wall thicknesses varying from 0.4 mm to 0.8 mm were systematically investigated. The TPMS structures were designed using level-set equations, and each system of structures was fabricated by selective laser melting, a metal additive manufacturing technique. Numerical investigations were performed to understand the phase change dynamics of PCM in TPMS cells and experiments were performed to determine their thermal properties and phase change performance for thermal energy storage applications. Our simulations revealed that for structures with uniform wall thickness of 0.4 mm, the novel Neovius structure resulted in the highest effective thermal conductivity enhancement. For a given thickness, it is thus hypothesized that more complex TPMS topologies have higher surface areas and volumes which enhance their thermal conductivities. However, the complex shape of the Neovius structure could not be further uniformly thickened without self-intersecting geometries. Ultimately, a balance of both the surface area and thickness of the TPMS cell determines the thermal conductivity enhancement. Overall, the 0.6 mm thick IWP cells had the highest thermal conductivity of 13.84 W/m K, which was consistently verified in experiments. This is likely due to the fact that it has a larger surface area than the P structure but is also thicker than the 0.4 mm Neovius structure. To further demonstrate the potential application of our PCM-based TPMS design, low temperature thermal cycling tests were performed. Our results showed the IWP cell structure promoted a more uniform temperature distribution as compared to the P cell. Phase change in the 0.6 mm thick IWP cell structure was completed 1.4 times faster than the 0.8 mm thick P cell and 1.8 times faster than the 0.6 mm thick P cell. The purpose of this study is to provide useful guidelines for the selection of TPMS structures for various applications such as battery packs and spacecraft and to open doors for the co-optimization of materials and device geometry for enhanced energy and power density.