Thermal Effects Research Articles

The behavior and model of methane adsorption on coal by ultrasonic enhancement

Ultrasonic technology can effectively improve the efficiency of coalbed methane (CBM) extraction and holds a broad application prospect. While the influence of the ultrasonic comprehensive effect on CBM output has been extensively studied, there is still a lack of in-depth discussion and detailed analysis of the specific influence of the single effect on methane adsorption. This article conducted an in-depth study of methane adsorption behavior in three different ways: ultrasonic comprehensive effect (UCE), thermal effect (UTE), and mechanical vibration effect (UMVE) by controlling the experimental conditions. The results indicated that CH4 adsorption was significantly inhibited by the UCE, and this inhibition was mainly influenced by the UTE. In contrast, the UMVE somewhat enhanced the adsorption of CH4. The moisture in the coal did not change the above trend. Furthermore, the promotion of CH4 adsorption by UMVE had an immediate effect, occurring only when UMVE was applied. The essence of promoting adsorption is that UMVE acts on the coal matrix and CH4 adsorption phase as an additional load, subsequently resulting in an increase in adsorption equivalent pressure. Based on the above understanding, the equivalent pressure parameter of CH4 adsorption under UMVE was proposed, and a mathematical model for CH4 adsorption under UMVE was constructed. In addition, a CH4 adsorption model under the UCE was established. The research results have certain reference significance for the application of ultrasonic in coalbed methane mining.

Investigating the Impact of Steam Enhancement on Combustion in a Swirl-Assisted Jet-Stabilized Gas Turbine Combustor

Abstract A newly developed gas turbine combustor system based on the swirl-assisted jet-stabilized concept using Jet A-1 and natural gas as reference fuel is tested under wet conditions to evaluate its combustion characteristics in the presence of steam. The effect of steam injection into the gas turbine combustor under both spray and superheated liquid fuel injection conditions is studied experimentally on an atmospheric test rig. To evaluate the effect of steam injection on combustion performance, the water-to-gas ratio (WGR) is varied from 0 to 32%. With increasing WGR = 0 to 16% and at stoichiometric condition, NOx reductions of -82% to -100% were observed during Jet A-1 and natural gas combustion, respectively. It is shown that the reduction of the combustion zone temperature due to the steam acting as a heat sink is the main cause of the NOx decrease. The operating range of the burner remained fairly constant for Jet A-1 until WGR = 20%, while it decreased significantly with increasing WGR for natural gas combustion. While the effect of the WGR on CO was modest, the greatest effect of the WGR was on the heat release zone intensity at a constant air to fuel ratio. In reducing the NOx levels of Jet A-1 and natural gas combustion, both thermal and chemical effects of steam injection were observed. However, steam acting as a heat sink and lowering the flame temperature, thereby reducing the thermal NO formation rate, was the dominant factor in NOx reduction.

Double flame dynamics in hotspot ignition

Hotspot ignition is a key problem in fundamental flame initiation, combustion control and prevention of abnormal combustion phenomena. Depending on the characteristics of the hotspot and the thermochemical condition of the reactive mixture, subsequent reaction front initiated from a hotspot can vary substantially. The current paper focus on the dynamics and chemistry for one of the most complicated scenarios - hotspot induced double flames, which include a cool and a hot flame segment. This work adopts a recently developed compressible reacting flow simulation code COGNAC to investigate the initiation and propagation of double flame dynamics from hotspot ignition in a one-dimensional spherical coordinate. The results have shown that under atmospheric pressure, double flame initiation is not feasible for sufficiently small hotspot. Under elevated pressures, double flame can be initiated within a much wider hotspot window, exhibiting complex flame dynamics, such as variations in cool and hot flame bifurcation behaviors and their initiation locations. Analysis on thermochemical structure and dynamics of double flame has shown that the interaction of cool and hot flames in a double flame structure is inherently intermutual, in that the leading cool flame enhances trailing hot flame speed through reform of the unburnt mixture, while the trailing hot flame initiation affects the leading cool flame via thermal expansion effects.

Experimental study on fragmentation characteristics of molten stainless steel discharged into liquid Lead-Bismuth Eutectic pool

The LFR is a candidate for the Generation-IV nuclear systems, where the process of MFCI differs from that occurred in LWRs and SFRs. In the absence of experimental study and widely applied theoretical models for LFRs, experiments on the interaction between molten SS and liquid LBE are conducted in this study under eight conditions. The morphological characteristics and fragment sizes of the products are analyzed based on the hydrodynamic effect parameter (We) and thermal effect parameter (Tic). Simplified thermal fragmentation models are established, where the innermost layer of the solidified shell is subjected to the maximum tangential compressive stress, while the outermost layer is subjected to the maximum tangential tensile stress. As the shell thickness increases, the total tangential stress of the outermost layer decreases. The fragmentation will occur when the maximum tangential stress on the shell exceeds the shell tensile strength.

Artificial intelligence based experimental investigation of underwater fiber laser transmission process during micro-channelling operation on PMMA

Industries that engage in laser-based material processing are increasingly turning to fiber lasers as one of the most effective laser systems available. Using a pulsed fiber laser system, an experimental investigation of underwater laser micro-channelling on hard to machine thick PMMA has been conducted in this research work. Submerged laser transmission cutting which is also known as underwater laser induced backside machining helps to generate clean kerf edge without presence of mushy region, which is very common during laser machining of thick PMMA with wavelength of near infrared region. Submerged conditions are used here for laser transmission micromachining in order to reduce adverse thermal effects and microcracking or charring inside the material. Pulse frequency, working power, and cutting speed have been selected as the input parameters. As machining responses, the depth of the micro-channel, the width of the kerf, and the width of the heat affected zone (HAZ) have been considered. To find the ideal parametric condition for simultaneously achieving numerous goals, Response Surface Methodology (RSM) and AI-based Teaching Learning-Based Optimisation (TLBO) have been used. The TLBO technique determined that the optimal laser machining settings are a power setting of 13.98 %, a pulse frequency of 50 kHz, and a cutting speed of 0.20 mm/sec. These parameters result in a minimum HAZ width of 4.1874 µm, a minimum kerf width of 22.3698 µm, and a maximum depth of cut of 37.1478 µm. Underwater laser processing reduces heat affected zone and redeposition surrounding micro-channels, creating a cleaner, finer structure.

Solid-state laser (266 nm) as an alternative to ArF excimer laser (193 nm) for corneal reshaping: Comparative numerical study of the thermal effect.

Laser corneal reshaping is a safe and effective technique utilized to treat common vision disorders. An advanced laser delivery system equipped with a pulsed UV laser with specific parameters is used to ablate parts of the cornea surface to correct the existing refractive error. The argon fluoride (ArF) excimer pulsed gas laser at 193 nm is the most employed type in the commercial devices for such treatments. This laser is generated using a mixture of Argon, Fluorine, and a significant amount of Neon gases. However, due to the ongoing Russian-Ukraine war, the availability of Neon gas is currently very limited, as this region is considered the primary supplier of pure Neon gas. Consequently we suggest replacing the common ArF laser source in the commercial devices with a solid-state (forth harmonic neodymium-doped yttrium aluminum garnet laser at 266 nm). This replacement uses the same operation parameters, optics, and scanning algorithm. Parameters from five commercial devices (Zeiss MEL 90, Technolas TENEO 317, Alcon Wave Light EX 500, Schwind Amaris 750 s, OptoSystems MICROSCAN VISUM) were compared with those of the i-ablation device, a research device that uses a 266 nm laser source. Our goal is to reduce production costs through a simple modification that has a significant impact. Consequently, the present study aims to find an alternative laser source for the current ArF laser without exchanging the complete system's design. This recommendation is based on a numerical simulation study. The thermal effect on a human cornea model was numerically evaluated using finite-element solutions of Pennes' bioheat equation on the COMSOL platform by applying two laser wavelengths. The results demonstrated that changing the laser source significantly impacts the thermal effect, even with the same laser settings. All studied devices showed a reduction in the thermal effect to below 40°C, compared with nearly 100°C under ordinary conditions.

Non-uniform variation characteristics of temperature field and corresponding thermal effect of longitudinal continuous slab ballastless track structure

The longitudinal continuous slab ballastless track structure (LCSBTS) easily suffers from interface and joint damage when subjected to extremely high-temperature loads, significantly affecting the running smoothness and safety of high-speed trains. This paper establishes a numerical model of the LCSBTS using the heat transfer principle and real-time shadow technology to replicate the time-varying evolution and spatial distribution of the temperature field. The corresponding thermal effect is obtained based on the sequential thermal-mechanical coupling method. The results show that the temperature variation and the corresponding thermal effect exhibit strong temporal-spatial non-uniformity on the horizontal and vertical planes of the LCSBTS. Solar radiation and heat convection are the dominant factors for the temperature field of the LCSBTS in the daytime and night, respectively, resulting in a higher temperature and greater thermal deformation on the sunny side than on the shady one. The temperature and vertical thermal deformation along the longitudinal direction vary periodically with a specific wavelength between the two adjacent rail support concrete blocks. The thermal deformation increments under the studied non-uniform temperature loads cause an interface damage increment. Finally, the consideration of a non-uniform temperature load produces remarkably different thermal effects from those given by the design temperature load.

Synergies of sugar-derived epoxy-silica hybrids and amino-functionalized silica NPs for advanced stone conservation

Innovative approaches to stone conservation materials are essential for addressing the challenges of preserving cultural heritage while meeting environmental and sustainability standards. Based on this premise, this study delves into the synergy between sol-gel processes and nanotechnology to develop advanced epoxy-silica hybrid materials tailored for stone conservation. This investigation specifically targeted the use of amino-functionalized mesoporous silica nanoparticles (NH2-SiO2 NPs) as interactive carriers for natural phenolic biocidal compounds within advanced sugar-based hybrid, demonstrating significant potential in the field of stone conservation. The novel products exhibited improved multifunctional properties attributed to the surface-modified NPs, which facilitated their intimate incorporation into the hybrid network. This integration promoted the creation of homogeneous materials with adapted flexibility, particularly critical for thermal expansion effects, and ensuring mechanical integrity even in outdoor environments. Furthermore, the encapsulation of natural biocidal compounds such as carvacrol and curcumin addressed their intrinsic drawbacks of volatility and coloration effects, preserving their efficacy while minimizing also plasticizing adverse effect on base thermoset. Indeed, the inclusion of curcumin-loaded NH2-SiO2 as dual bactericidal system provided the most favorable compatibility in terms of thermo-mechanical behavior. This system exhibited thermal resistance up to 350 °C and featured inter-joined flexible crystalline domains, distinguished by glass-transition temperatures of 67 and 99 °C. Furthermore, it exhibited enhanced hydrophobic properties reaching contact angles of 105°, and showcased an optimal live/dead ratio response against bacteria. The laboratory scale testing demonstrated a balanced set of features with significant capabilities in both recovering and maintaining the integrity of the lithic substrate, against common degradation patterns induced by prolonged acid exposure.

In Vitro Assay Development to Study Pulse Field Ablation Outcome Using Solanum Tuberosum.

Exposing cells to intense and brief electric field pulses can modulate cell permeability, a phenomenon termed electroporation. When applied in medical treatments of diseases like cancer and cardiac arrhythmias, depending on level of cellular destruction, it is also referred to as irreversible electroporation (IRE) or Pulsed Field Ablation (PFA). For ablation device testing, several pulse parameters need to be characterized in a comprehensive manner to assess lesion boundary and efficacy. Overly aggressive voltages and application numbers increase animal burden. The potato tuber is a widely used initial model for the early testing of electroporation. The aim of this study is to characterize and refine bench testing for the ablation outcomes of PFA in this simplistic vegetal model. For in vitro assays, several pulse parameters like voltage, duration, and frequency were modulated to study effects not only on 2D ablation area but also 3D depth and volume. As PFA is a relatively new technology with minimal thermal effects, we also measured temperature changes before, during, and after ablation. Data from experiments were supplemented with in silico modeling to examine E-field distribution. We have estimated the irreversible electroporation threshold in Solanum Tuberosum to be at 240 V/cm. This bench testing platform can screen several pulse recipes at early stages of PFA device development in a rapid and high-throughput manner before proceeding to laborious trials for IRE medical devices.

Electrical and electrochemical properties of A-site non-stoichiometry Ca0.67La0.22□0.11Ti(1−x)CrxO3−δ electrolyte materials for solid oxide fuel cells

Due to increasing global energy demands and environmental concerns, the search for alternative and environmentally friendly energy sources is of paramount importance. Solid oxide fuel cells (SOFCs) have emerged as a promising solution thanks to their high efficiency and minimal environmental impact. In this regard, perovskite oxides, with their unique properties, have attracted significant attention. This study investigates the dielectric dispersion, electrical features, scaling behavior, and optical defects of Ca0.67La0.22Ti0.85Cr0.15O3 with x = 0.15, CLT0.85Cr0.15. The presence of a vacancy in the A-site is denoted by the square in the formula. Relaxation phenomena were analysed using dielectric and modulus formalism, while the conductivity mechanism was explored through electrical conductivity measurements. The optical defects of CLT0.85Cr0.15 were analysed using electron paramagnetic resonance (EPR) spectroscopy. The findings revealed the formation of Cr3+–VO center defects. These defects serve as sources of in-gap electron traps, thereby enhancing the optical properties of CLT0.85Cr0.15, making it as a compelling material for various optical applications. The power density increased with temperature, reaching 0.73 W/cm2 at 850 °C, suggesting that CLT0.85Cr0.15 could be a promising electrolyte for IT-SOFCs. The peak in power density correlated with temperature due to thermal effects on ion motion. However, the open circuit voltage decreased with temperature increase, due to increased oxygen vacancies and electron/hole conduction in CLT0.85Cr0.15. The findings suggest that perovskite materials could revolutionize SOFCs technology, paving the way for more efficient and environmentally friendly energy solutions.

Study of the interaction between a cavitation bubble and nearby biomimetic gas-entrapping microtextured surfaces and the potential damage effects on the wall using the compressible multiphases volume of fluid model

In the study, a compressible multiphase volume of fluid considering the phase change and thermal effect is presented, the interaction between a cavitation bubble and nearby biomimetic gas-entrapping microtextured surfaces is investigated using this model, and the potential damage effects on the wall are carefully analyzed. Based on this interaction, the standoff distance is classified into three types. For γ > 2.0, the cavitation bubble remains spherical during the expansion phase because it is not influenced by the entrapped gas cavities. However, during the contraction phase, it generates a jet directed away from the wall. For 1.0 < γ < 2.0, the cavitation bubble is affected by the cavities, causing it to lose its spherical shape during the expansion phase. For 0 < γ < 1.0, the cavitation bubble is close to the gas cavities, mixing with the gas cavities during the expansion phase. Two processes are identified as the main reasons for the potential damage to the wall. Furthermore, compared to a flat wall surface, the peak of the pressure impulse on the wall with entrapping gas cavities decreases by 33%, and the peak of the heat transfer quantity decreases by 59%, significantly reducing the damage to the wall.

Thermal analysis of MHD unsteady Darcy‐Forchheimer thin film flow in a porous system

AbstractThis study has investigated a Darcy‐Forchheimer thin film flow over an extended horizontal surface with thermal radiation and chemical reaction effects. The governing time‐dependent equations have been non‐dimensionalized using similarity transformations and solved numerically using the fourth‐order Runge‐Kutta method and the shooting technique. The influence of magnetohydrodynamics, non‐uniform heat sourcing, viscous heat radiation, and chemical reactions on temperature, velocity, skin friction, Nusselt, and Sherwood numbers has been examined. Results have shown that porous media, magnetic field, and transient effects decrease the velocity profile, while thermal radiation and variable thermal properties enhance temperature distributions. Findings have indicated that the magnetic field and porosity enhance the skin friction coefficient whereas the heat transfer rate increases with Eckert number and Prandtl number. Rising the chemical reaction parameter from 0.2 to 0.5 rises the mass transfer rate by approximately 9.85%. The thermal analysis of MHD Darcy‐Forchheimer thin film flow in a porous system has been crucial for understanding heat transfer and fluid dynamics in complex environments. It helped in optimizing various engineering processes, such as cooling systems, filtration, and energy conversion, by providing insights into temperature distribution, convective heat transfer, and fluid behavior. This analysis has aided in designing efficient and reliable systems with improved performance and reduced energy consumption.

Effect of Sphingomonas polyaromaticivorans on spontaneous combustion of lignite during low-temperature oxidation

The inhibition of coal spontaneous combustion (CSC) by microorganisms presents an environmentally friendly method to reduce coal oxidation rates in mines and delay natural ignition. In this study, XRD, FTIR, and TG-DTG-DSC experiments were employed to analyze the inhibitory effect of microorganisms on CSC from both microstructural and macroscopic oxidation perspectives. The results indicated that microorganisms enhanced the ordering and graphitization of coal’s microcrystalline structure, reduced the number of functional groups, and disrupted aliphatic hydrocarbons and oxygen-containing groups. The average microcrystalline diameter and the number of effectively stacked aromatic layers decreased by 32.04 % and 27.22 %, respectively, while the total area of aliphatic hydrocarbon peaks decreased by 55.56 %. The characteristic temperature points shifted to higher zones, with the maximum weight loss rate temperature and burnout temperature exhibiting significant increases of 67.87℃ and 138.67℃, respectively. The thermal effect of coal oxidation was diminished, with total heat release decreasing by 77.8 J/mg. Additionally, the apparent activation energy (Ea) increased by 1.45 times, and the pre-exponential factor (ln A) reduced to 61.05 % of that of raw coal. This study establishes a foundation for future microbial inhibition of CSC.

Study on ultrasound-enhanced molecular transport in articular cartilage.

Local intra-articular administration with minimal side effects and rapid efficacy is a promising strategy for treating osteoarthritis(OA). Most drugs are rapidly cleared from the joint space by capillaries and lymphatic vessels before free diffusion into cartilage. Ultrasound, as a non-invasive therapy, enhances molecular transport within cartilage through the mechanisms of microbubble cavitation and thermal effects. This study investigated the mass transfer behavior of solute molecules with different molecular weights (479 Da, 40 kDa, 150 kDa) within porcine articular cartilage under low-frequency ultrasound conditions of 40 kHz and ultrasound intensities of 0.189 W/cm2 and 0.359 W/cm2. The results revealed that under the conditions of 0.189 W/cm2 ultrasound intensity, the mass transfer concentration of solute molecules were higher compared to passive diffusion, and with an increase in ultrasound intensity to 0.359 W/cm2, the mass transfer effect within the cartilage was further enhanced. Ultrasound promotes molecular transport in different layers of cartilage. Under static conditions, after 2 h of mass transfer, the concentration of small molecules in the superficial layer is lower than that in the middle layer. After applying ultrasound at 0.189 W/cm2, the molecular concentration in the superficial layer significantly increases. Under conditions of 0.359 W/cm2, after 12 h of mass transfer, the concentration of medium and large molecules in the deep layer region increased by more than two times. In addition, this study conducted an assessment of damage to porcine articular cartilage under ultrasound exposure, revealing the significant potential of low-frequency, low-intensity ultrasound in drug delivery and treatment of OA.

Breakthrough design of power handling capability‐enhanced slotted oversized substrate‐integrated waveguide power divider/combiner considering corona and thermal effects

Breakthrough design of power handling capability‐enhanced slotted oversized substrate‐integrated waveguide power divider/combiner considering corona and thermal effects

Ignition and flow combustion characteristics of hydroxylammonium nitrate - based liquid propellant based on electric method

Hydroxylamine nitrate (HAN)-based liquid propellants are characterized by high energy content and low toxicity ionic monopropellants, offering great potential application prospects in the space engine. This paper proposes an experimental system for electric ignition and combustion of HAN-based liquid propellant. The energy for decomposition, current, and combustion image of HAN-based liquid propellant are measured under different initial voltage, propellant volume, and the initial pressures in Ar and air atmospheres. The results show that the energy for decomposition decreased with an increase in initial voltage, propellant volume, and initial pressure. An increase in the initial voltage accelerates the reaction speed of HAN-based liquid propellant, and the energy for decomposition is approximately 3 J. An increase in the propellant volume decreases the equivalent resistance in the circuit, increasing the current and enhancing the thermal effect of the propellant. The accumulation of decomposition products and heat under high pressure reduced the energy for decomposition; the energy for decomposition is less than 1.5 J for the pressurization condition. Compared with the Ar atmosphere, the energy for decomposition of HAN-based liquid propellant shows better stability in the air atmosphere. The flow combustion device of HAN-based liquid propellant for the flow state is designed. The HAN-based liquid propellant is successfully ignited for different initial voltages and flow rates. The research results provide a reference for the design of space engine for HAN-based liquid propellant based on the electric ignition method.

Random thermal-vibration mechanisms of sandwich ventral fin-type plate-shell systems with porous functionally graded core

The stochastic thermal-vibration mechanisms within a sandwich ventral fin-type plate-shell system, featuring a porous functionally graded (FG) core, are exhaustively analyzed under various random loading conditions employing an innovative node-based, meshless computational approach. The studied structure is decoupled into several plates and open cylindrical panel according to the geometric characteristics, and the mechanical relationships at the structural boundaries or connection interfaces are equivalently simulated by using penalty parameters. Following the general Hamilton's principle, the meshless approach combined with the first-order shear deformation theory (FSDT) incorporating thermal effects is employed to derive the vibration equations of the sandwich ventral fin-type plate-shell systems. Also, the pseudo excitation method (PEM) is introduced to calculate stationary and nonstationary random responses. In order to verify the accuracy of the meshless algorithm in this study, the convergence and correctness are studied comprehensively. And then, the effects of some parameters such as temperature variation, porosity parameters, power-law index and random excitations on the thermal vibration characteristics of the sandwich ventral fin-type plate-shell systems with porous FG core are presented. The results show that the power-law index and temperature can increase the frequency parameter of the structure. The smooth power spectral density (PSD) excitation only affects the amplitude of the response curve, and does not affect the frequency corresponding to the peak. In the analysis of non-stationary random vibration, the influence of modulation parameters on response is very significant.

Thermal environmental and energy effects of vertical greening system under the influence of localized urban climates

Vertical greening system (VGS) can cool adjacent urban space and lower building conditioning energy use without consuming valuable land area, however the influence of local microclimate on the effects is understudied. To better understand how VGS behaves environmentally in localized urban climates, the study investigated the outdoor cooling and building energy-saving potential of a VGS in five local climate zones (LCZ) in Shanghai, using integrated modeling with ENVI-met and EnergyPlus. The model verification reasonably reflects the relative differences in thermal effects of VGS due to local climates. The result reveals that, under the maximum inter-LCZ differences in air temperature (Ta) and relative humidity (RH) of 1.4 °C and 5.3 %, the greatest inter-LCZ variations in cooling and humidifying effects of the VGS are 0.16 °C and 1.1 %, respectively. The VGS creates greater adjacent Ta reduction in higher-ranked LCZs, by up to 0.27 °C, but increases RH by 1.6 %. In summer, the VGS provides energy savings of 132–278 Wh/m2 with energy saving rates of 5.7–11.7 %. The annual energy savings are partially offset by the increase in winter heating, and the annual energy saving rates are reduced to 3.2–6.3 %. Of the savings, 92 % is due to shading, 8 % to cooling, and the humidifying effect has a negative impact (- 11 %). The findings underscore the impact of localized urban climates on the VGS thermal and energy performances, and support climate-responsive and performance-optimized urban VGS planning and application.

Unveiling Thermal and Athermal Effects in Strain Hardening Removal of A6061 Aluminum Alloy

AbstractThis study explored the application of a high-density pulsed electric current (HDPEC) to mitigate strain hardening in a cold-rolled A6061 aluminum alloy while examining the simultaneous application of HDPEC with furnace heating to reveal the contributions of thermal and athermal effects. The results showed that significant strain-hardening relief was achieved through the HDPEC treatment, particularly at 300 A/mm² for 260 ms, resulting in a 23% reduction in strength and an 86% increase in ductility. Microstructural analysis revealed a shift to fine and equiaxed grains with reduced dislocation density, which was primarily attributed to thermal effects. HDPEC annealing exhibits superior efficiency compared to the conventional annealing treatment, offering cost and time advantages. In addition, this study validated the synergistic impact of HDPEC and furnace heating, with furnace heating supplementing energy requirements, facilitating practical HDPEC implementation. These findings suggest that the HDPEC method and the combined method with conventional heating are promising alternatives for strain-hardening alleviation in A6061 aluminum alloy manufacturing, supporting the development of an eco-friendly and efficient process. Graphical Abstract

Evaluation of hydrogen storage performance of Ti0.25Zr0.25V0.15Nb0.15Ta0.2 high-entropy alloy using calorimetric technique

The features of phase transformations during interaction of BCC-type Ti0.25Zr0.25V0.15Nb0.15Ta0.2 high-entropy alloy (HEA) with hydrogen and the accompanying thermal effects have been examined using the Tian-Calvet calorimetric technique. The alloy was produced by the pendent drop melt extraction method in the form of microfibers and then coated with a thin layer of palladium to eliminate the preliminary high-temperature activation and enable first hydrogenation at room temperature. Two reaction stages were distinguished on the measured heat emission curves. Using XRD data, these stages were attributed to the formation of a BCC-type hydrogen solid solution and a phase transition to FCC-type dihydride phase. Recorded values of the reaction enthalpy decrease in absolute terms from 145 kJ/mol H2 (dilute solid solution) to 73–77 kJ/mol H2 (BCC→FCC) and to 20 kJ/mol H2 (H solution in FCC dihydride). The overall heat emission of the entire process as a whole is 110 kJ/ mol H2. The course of the dehydrogenation process depends strongly on the applied temperature and at 493 K results in the formation of a BCT-type monohydride, which was not detected during hydrogenation. The detailed calorimetric data obtained here significantly change the previously existing ideas about thermal effects during this type HEAs hydrogenation, based on calculations using the Van't-Hoff equation. The reported findings are of special importance for various hydrogen related applications of HEAs