The purpose of the work is the problem of researching the influence of chemical composition and structure on the indicators of operational stability of centrifugal two-layer rolling rolls made of high chromium cast iron by the coercimetric express method. In order to ensure the achievement of this goal, the following tasks were set and solved: conducting an analysis of the causes of the destruction of the surface layer of rolls; building a mathematical model for studying the influence of the chemical composition and structure of cast iron on the level of hardness and coercive force; using the coercimetric method to analyze the quality of rolled rolls. Conclusions. Forecasting the behavior of the rolls during operation is inextricably linked to the analysis of the main factors on which the level of properties and operational stability of the working layer depend. The properties of high-chromium alloys are closely related to the type of phases formed and their ratio. The amount of residual austenite and martensite in the structure of the alloy has the greatest influence on the properties of the alloy (in the studied interval of changes in the proportion of phases). The operational layer of two-layer high-chromium rolls is characterized by a high level of residual stresses. Exceeding the permissible level of stresses or their unfavorable distribution can cause premature destruction during the operation of the roll. With the help of the coercimetric express method, it is possible to solve a fairly wide range of tasks of quality control of rolls, related to the determination of the level and distribution of residual stresses in the working layer of the rolls. This is because the intensity of the process of formation of thermal cracks under conditions of thermo-cyclic loading largely depends on the level of residual compressive stresses. Too high a level of stresses or their unfavorable distribution can cause premature destruction of the working layer of the roll, because the typical type of destruction due to an unbalanced distribution of stresses is cracking. A local increase in the level of coercive force can be the basis of the prediction of crack formation.