In the present study, an exercise has been devoted to establish an analytical model for thermal performance and optimization of a constructal fin subject to variable thermal conductivity of fin material and convective heat transfer coefficient over the fin surface. For the adaptation of these considerations, the governing energy equation for the stem as well as the flange becomes nonlinear. A new analytical scheme based on the Adomian decomposition method has been established for the solution process. As the present study is an analytic, it can be extended to the analysis for determining the optimum dimensions of fins satisfying either the maximization of rate of heat transfer for a given fin volume or the minimization of fin volume for a desired heat transfer rate. From the results, it can be highlighted that the present model predicts the fin performance always an under value in comparison with that the published results whereas the optimum heat transfer rate determined by using the present analysis gives an over value. The effect of different geometric and thermophysical parameters on both the fin performance and optimization has been studied. For a comparative study, the present and published results are executed for a wide range of thermogeometric parameters.