Increase In Thermal Conductivity Research Articles

Enhanced thermoelectric properties of n-type sulfide compound Bi2SeS2 by Cl doping

Sulfides composed of an eco-friendly and low-cost composition have received widespread attention as a substitute for traditional thermoelectric materials. However, n-type sulfides with high performance are rare compared with p-type ones. This work revealed that Bi2SeS2 with n-type conductivity characteristics is a potential thermoelectric material, whose ZT value reaches ∼ 0.70 at 773 K for the Cl doped sample Bi2Se0.98S2Cl0.02. Cl serving as a carrier donor can increase the electrical conductivity by optimizing the carrier concentration. Coupled with a moderate Seebeck coefficient in the range of 100–200 μV/K, a high power factor of ∼6.46 μWcm−1K−2 at 773 K was achieved. In addition, the lattice thermal conductivity reduces because of the formation of precipitates, as well as the induced mass and stress fluctuations due to the doping of heterogeneous Cl element, which effectively suppress the increase in total thermal conductivity. The combination of optimized power factor and low thermal conductivity leads to a final high ZT value, which is relatively higher than or comparable to most other reported n-type sulfide thermoelectric material.

Lauric acid based form-stable phase change material for effective electronic thermal management and energy storage application

Poor thermal management in electronic systems can lead to higher junction temperatures, accelerating failure mechanisms and reducing component lifespan. Integrating efficient thermal management techniques, such as heat sinks, is essential for ensuring durability and efficiency of electronic equipment. Heat sinks have limited capacity, but integrating phase change materials (PCMs) enhances cooling performance by harnessing latent heat storage. However, leakage and low thermal conductivity limit PCM's effectiveness. The current study developed highly conductive leakage-proof PCMs based composites using an ultrasonic and vacuum impregnation method with lauric acid as base, hexagonal boron nitride and expanded graphite as additives. The results demonstrate persistence of chemical integrity, as proven by FTIR analysis, and complete encapsulation of PCMs inside the expanded graphite structures. The form-stable composite PCMs exhibit a 450% increase in thermal conductivity and 77% photo-transmittance decrease compared to base PCMs. Despite a trade-off of a 11.5% reduction in latent heat, the composite demonstrates thermal stability up to 220 °C. Further, excellent chemical and thermal reliability is maintained even after 500 cycles. Furthermore, in thermal management for heat sink, the form stable composite efficiently dispersed heat, resulting in a 16 °C decrease in peak temperature compared to the heat sink without the composite.

Effect of γ-radiation on silica aerogel and composite material for thermal insulation applications in nuclear power pipeline

SiO2 aerogel and its composite materials are considered as promising high-temperature thermal insulation materials due to their high porosity, low density and low thermal conductivity. However, a major obstacle for their application in nuclear power systems is the currently insufficient mechanism of the radiation effect. This study therefore aimed to investigated the changes in the microstructure, hydrophobic properties and thermal insulation properties of aerogel and ultrafine glass fiber reinforced aerogel composite (uGF/SiO2 aerogel) before and after γ-radiation, and explore the mechanism of the γ-radiation effect of aerogel materials. With an increase in cumulative radiation dose, the microstructure of aerogel suffered significant radiation damage, causing a gradual increase in crystallinity and thermal conductivity. When the cumulative dose reached 1700 kGy, the nanoparticles in the aerogel agglomerated and crystallized significantly, leading to an approximately 30 % increase in thermal conductivity. Notably, at the radiation of 1700 kGy, the uGF/SiO2 aerogel exhibited excellent structure stability, with a thermal conductivity of 31.60 mW/m·K, which was 3.27 % higher than that of unirradiated sample. This indicated the uGF/SiO2 aerogel exhibited excellent thermal performance and thermal stability even after γ-radiation. The study on the radiation effect of aerogel materials offers valuable insights for the composition optimization of aerogel used in nuclear power applications.

Performance analysis and optimization of an annular thermoelectric generator integrated with vapor chambers

To overcome the structural barriers of conventional annular thermoelectric generators (ATEGs), a new ATEG integrated with vapor chambers (VCs) is proposed in this paper, where the use of VCs enables a large hot-end contact area and a high temperature uniformity for traditional planar thermoelectric modules. Besides, a numerical model for the ATEG is built to conduct performance analysis and optimization under different parameters. Results suggest that the heat absorption of the ATEG increases with the increase of the number of VCs, thereby boosting the output power of the system. When the flow rate is lower than 35 g/s, the optimal number of VCs for the ATEG is 12, with the highest output power, conversion efficiency, net power, and net efficiency of 287.3 W, 5.36 %, 214.1 W, and 3.99 %, respectively, at the exhaust temperature of 800 K. Besides, the exhaust temperature does not affect the optimal result, while the ATEG should be designed with fewer VCs when applied to the waste heat recovery with a larger flow rate. The increase in the VC thermal conductivity is not related to heat absorption but can improve temperature uniformity, and the thermal conductivity of 4000 W m−1 K−1 already meets performance requirements. This study provides new perspectives on the structure design of ATEGs.

Investigation of the thermal conductivity of SiO2 glass using molecular dynamics simulations

AbstractA recent study showed that generating local crystalline paths within a glassy matrix provides only a moderate increase in thermal conductivity until the path fills most of the total volume. It was indicated that percolation theory governs the thermal conductivity in such crystalline‐implanted glass composites. In this study, we use computer simulations to investigate the effect of partial vitrification by breaking structural order of silica crystals by local vitrification. Such locally vitrified crystal structures are made by the bond‐transposition method, where the extent of vitrification can be tuned. Also, we test melt‐quenching of three SiO2 crystalline structures (α‐quartz, coesite, and stishovite) to make silica glasses with different densities. The cooling rates and pressures were varied during the melting process in order to obtain glass structures with varied degrees of order. Our results show that the thermal conductivity of silica glasses calculated using Green–Kubo relation decreases rapidly as soon as the crystallinity is disturbed by bond transition or generated local glassy phase. This implies the phonon mean free path rapidly shrinks with even a small number of scatterers, regardless of the original polymorph. Through the investigation of the pressure effect, a strong proportional relation between the thermal conductivity and the density is found among all silica samples. Such correlation can be accounted by assuming a constant integral term in the Green–Kubo relation without the volume scaling, which is reasonable based on a weak dependence of κV on the density of silica glass except with a slight increase at low quench pressures. We hypothesize that when the quench pressure increases moderately, an increase of characteristic ring size tends to generate a more flexible SiO2 structure which results more phonon scattering. Green–Kubo modal analysis further shows that the contribution from modes at low frequencies is suppressed when SiO2 is melt‐quenched at higher pressure and vice versa.

Simulation Analysis of the Freezing Process For Achieving Bidirectional Freezing Coating Via the Freeze-Casting Technique

To delve deeper into the shapes and positions of the solidification front, as well as the detailed temperature distributions under various solidification conditions, this study employed the commercial software ANSYS FLUENT to conduct a meticulous numerical simulation of the two-dimensional solidification process in freeze casting. As part of the research, the enthalpy-porous media solidification/melting model was chosen as the core theoretical framework, and the accuracy of the numerical calculations was verified by comparing them with locally measured temperature changes from experiments. Subsequently, we further examined the influence mechanisms of factors such as cold source temperature, solid content, mold depth, and mold thermal conductivity on the speed of the solidification front. This is crucial because, in the freeze casting process, the speed of the solidification front directly determines the formation and evolution of macropore structures. The results of the simulation analysis indicate that an increase in mold thermal conductivity, a decrease in cold source temperature, a shallower mold depth, and a higher solid content all lead to a corresponding increase in the movement speed of the solidification front. These simulation outcomes not only provide strong theoretical support for optimizing the process parameters of freeze casting but also aid in achieving more precise control over the microstructure of materials, thus enabling a more efficient and accurate material preparation process.

Valorization of waste Ti6Al4V chips for epoxy composite production: A circular economy approach

AbstractWith increasing awareness of the circular economy, utilizing waste materials from titanium alloys for polymer composites offers numerous advantages. In this study, medical‐grade titanium alloy, Ti6Al4V chips were finely ground and mixed with epoxy resin to produce particulate‐reinforced composites. The tensile strength showed a 32% improvement compared to the neat epoxy. Similar results were observed for the flexural test, showing a 36% improvement in the composites. Moreover, a substantial 96% increase in thermal conductivity was observed, significantly expanding the potential application areas for the epoxy‐based composites. These improvements were achieved without the use of superfine nanoparticles or other expensive additives. This underscores the potential of a circular approach in the materials world, offering many new opportunities while promoting sustainability.Highlights Circular utilization of titanium powders in polymer composites. Demonstrated effectiveness of titanium milling in composite production. Production of low‐cost, affordable composites suitable for diverse applications. Remarkable thermal conductivity values. Attainment of finely tuned mechanical properties.

Developing heat-conductive concrete with graphite-modified recycled aggregates

This study tackles temperature-induced cracks in contemporary concrete by addressing their low thermal conductivity. Heat-conductive concrete was developed by using graphite-modified recycled coarse aggregates. Through thorough evaluation of coating methods and aggregate types, we enhance thermal conductivity of recycled aggregates by up to 86 % while improving apparent density, water absorption, and crushing value. Employing a one-pot method (Method B) with the graphite to cement ratio of 1:1 establishes an efficient thermal pathway within concrete, resulting in a significant 1.9-fold increase in thermal conductivity without compromising mechanical properties. Advanced imaging techniques and simulations confirm the pivotal role of this pathway in enhancing thermal properties, offering a cost-effective, eco-friendly solution for sustainable construction.

Phase Change Materials for Thermal Energy Storage: A Concise Review

Thermal energy and its storage systems play an extensive role in day-to-day life. They store renewable energy and are capable of recovering generated heat from different systems. Storage of thermal energy can be classified into three types: sensible, latent and sorption heat storages. Thermal heat storages use different types of materials based on their capacity of heat storage, stability of duration and thermal conductivity. Various phase change materials (PCMs) that are suitable for thermal storage are reported. Low conversion ability limits their effectiveness. We reviewed some of the traditional materials synthesized recently that are used for thermal energy storage (TES). Recently developed TES materials exhibit high thermal conductivity, reduced super cooling and multiple phase change temperatures. Nano-enhanced PCMs produced an increase in thermal conductivity up to 32% with a reduction in latent heat by 32%. At this juncture, MXenes with high performance and extraordinary properties (thermal, mechanical, etc.) are of special significance. MXenes displayed an increased thermal conductivity up to 16% and 94% efficiency. In view of their structure and adaptability to be used in thermal storage systems, an attempt was made to review their role also in thermal storage applications. It is observed that MXenes highly impact storage and efficiency. Apart from MXenes, various types of PCMs along with their thermal characteristics are presented.

In-situ study of σ phase evolution in 25Cr-7Ni duplex stainless steel (DSS): Unrevealing critical insight

The current understanding of the formation mechanism and kinetics of the σ phase in DSS remains ambiguous. This study investigates the in-situ evolution of the σ phase in DSS through a multi-faceted approach. Distinct σ phase formation mechanisms were identified at 850 °C and 950 °C, with short-range diffusion of eutectoid decomposition at 850 °C and long-range diffusion of nucleation and growth at 950 °C. In-situ X-ray diffraction (XRD) revealed that the lattice parameter of the γ phase peaks at ∼ 600 °C. The thermal expansion coefficient (CTE) of the γ phase is 1.8 times higher than that of the α phase at low temperatures. Interestingly, the convergence of the CTEs of the α and γ phases above 600 °C triggers σ nucleation. The strain field diagram shows maximum impinging strain at the lattice parameter maxima just before the σ formation range. The adverse effects of the σ phase on DSS heat transport properties were also explored, showing an initial increase in thermal conductivity with an increasing γ volume fraction, followed by an 18 % decrease upon σ evolution. First-principle calculations highlight the correlation between Ni enrichment and lattice parameter maxima, supporting these findings.

The Effect of Expanded Graphite Content on the Thermal Properties of Fatty Acid Composite Materials for Thermal Energy Storage.

The mass content of expanded graphite (EG) in fatty acid/expanded graphite composite phase-change materials (CPCMs) affects their thermal properties. In this study, a series of capric-myristic acid/expanded graphite CPCMs with different EG mass content (1%, 3%, 5%, 8%, 12%, 16%, and 20%) were prepared. The adsorption performance effect of EG on the PCMs was observed and analyzed. The structure and thermal properties of the prepared CPCMs were characterized via scanning electron microscopy, differential scanning calorimetry, thermal conductivity measurements, and heat energy storage/release experiments. The results show that the minimum mass content of EG in the CPCMs is 7.6%. The phase-change temperature of the CPCMs is close to that of the PCMs, at around 19 °C. The latent heat of phase change is equivalent to that of the PCM at the corresponding mass content, and that of phase change with an EG mass content of 8% is 138.0 J/g. The CPCMs exhibit a large increase in thermal conductivity and a significant decrease in storage/release time as the expanded graphite mass content increases. The thermal conductivity of the CPCM with a mass content of 20% is 418.5% higher than that with a mass content of 5%. With an increase in the EG mass content in CPCMs, the heat transfer mainly transitions from phase-change heat transfer to thermal conductivity.

One-pot complexation of phytic acid and polyethyleneimine on cellulosic microfibers towards insulative and flame-resistant foam

Flame resistance is required for the deployment of bio-based materials, especially those forming cellular structures that endow thermal insulation. This study proposes a one-pot strategy to prepare cellular lignocellulosic composites with excellent flame resistance. Lignocellulosic microfibers were used as the substrate onto which a flame-retardant complex consisting of P-containing phytic acid (PA) and N-containing polyethyleneimine (PEI) was formed. Following the prediction of ab initio molecular dynamics simulation, PA and PEI are integrated onto MF-CTMP following a single-step complexation assembly triggered by pH effects. The PA-PEI modified MF-CTMP can be readily transformed into a composite solid foam by dewatering a wet foam followed by oven drying. At the expense of a slightly reduced thermal insulation (thermal conductivity increase from 33.6 ± 0.6 to 40.0 ± 0.6 mW/(m·K)) the presence of PA-PEI complexes significantly improved the mechanical performance of the foam and uniquely endows it with flame resistance. Compared to unmodified MF-CTMP foams, the composite foams showed significant improvement in the Young's, specific compression, and flexural moduli (increased by 13.5, 5.5, and 7.3 folds, respectively), a high oxygen index (up to 40.8 %) and self-extinguishing effects. The results suggest the suitability of the introduced lignocellulosic foam as an alternative to traditional synthetic polymer-based counterparts as well as inorganic matter for insulation, particularly relevant to the building sector.

Heat transfer enhancement of three-dimensional oscillating heat pipe based on evaporation surface hydrophilicity regulation for thermal management

To improve the thermal management performance of high heat flux components in confined spaces, two three-dimensional oscillating heat pipes (3D-OHPs) with different adiabatic section lengths were designed in this work. 3D-OHPs with surfaces of different hydrophilicity was fabricated using alkaline-assisted oxidation technology, and the impact of surface hydrophilicity on the heat transfer performance of 3D-OHPs was investigated experimentally. The results indicated that the greater the hydrophilicity of the 3D-OHP, the better its start-up and heat transfer performance. A 3D-OHP with a shorter adiabatic section demonstrates slightly inferior start-up performance under identical hydrophilicity conditions but exhibits better overall heat transfer performance. It is also found that the 3D-OHP can initiate at 20 W under four distinct hydrophilicity conditions. Compared to the untreated 3D-OHP, the super-hydrophilic 3D-OHP reduces start-up temperature by 17.76 % and start-up time by 35.31 %. Under high-power conditions, the super-hydrophilic 3D-OHP exhibits a 37.6 % increase in thermal conductivity and a 61.5 % improvement in temperature uniformity compared to the untreated 3D-OHP. Furthermore, the thermal resistance and evaporation section temperature of the super-hydrophilic 3D-OHP are reduced by 56.69 % and 14.33 %, respectively. This study can broaden the approach to enhance the heat transfer performance of 3D-OHP and provide more application scenarios for the thermal management of power devices.

Heat transfer in radiative hybrid nanofluids over moving sheet with porous media and slip conditions: Numerical analysis of variable viscosity and thermal conductivity

Our current numerical investigation aims to estimate the thermal transport properties of hybrid nanofluids on a moving surface that is being shrinked horizontally. The hybrid nanoparticles consist of alumina (Al2O3) and copper (Cu), suspended in water as the base fluid. The transportation phenomenon takes place in a Darcy-Forchheimer medium, which is a porous material that exhibits thermal radiation, variable viscosity, variable thermal conductivity, Joule heating, viscous dissipation, and the effects of velocity and thermal slip conditions. The governing partial differential equations (PDEs) are converted using suitable similarity transformations into non-linear ordinary differential equations (ODEs). The equations were solved using the shooting technique with the RK-IV algorithm in the MATHEMATICA program. Dimensionless velocity, temperature, skin friction, and Nusselt numbers all provide numerical outcomes. Graphs and tables show the results of an investigation into the influence of different physical characteristics on these numbers. The velocity profile exhibits an upward trend when the velocity slip and nanoparticles volume fraction rise, but a downward trend when the viscosity and Prandtl number are varied. if the thermal slip and variable Prandtl number grow, the temperature profile falls. Conversely, if the nanoparticles volume fraction and variable thermal conductivity increase, the temperature profile increases. The skin friction and Nusselt number exhibit an upward trend as the volume percentage of nanoparticles and the viscosity of the system rise. At a Prandtl number of 6.2 and a nanoparticle volume fraction of 1 %, the Xue model demonstrates a heat transfer rate increase that is 5.32 % superior to the Yamada-Ota model and 3.18 % superior to the Hamilton-Crosser model for nanofluid. In the case of hybrid nanofluid, the Xue model exhibits a 19.01 % superiority over the Yamada-Ota model and 12.197 % superior to the Hamilton-Crosser model.

Heat transfer efficiency of thermoelastic shaped phase change materials enhanced by pressure

As the melt front gradually moves away from the heat source during the heat transfer process, phase change materials (PCMs) inevitably cause the heat transfer efficiency to decrease with heat transfer time, especially for a shaped PCM (SPCM). In this study, it is proposed to compress the SPCM phase-changed region by pressure to reduce the thermal resistance between the heat source and the phase transition interface, thus slowing down the rate of heat transfer efficiency decrease. We established a one-dimensional semi-infinite compression heat transfer theoretical model and prepared a thermoelastic SPCM (TESPCM) for compression heat transfer experiments, which verified the reliability of the theoretical model. Experimental demonstrate that the pressure enhancement contributes to the heat transfer efficiency and becomes more pronounced with heat transfer time. The pressure-enhanced heat transfer was analyzed by the theoretical model with the following conclusions: pressure enhancement not only improves the latent heat utilization, heat transfer cut-off time, and maximum tolerable heat flux of TESPCM but also increases the specific energy and specific power of TESPCM. The effect of pressure on heat transfer efficiency tends to accelerate with increasing compression. Furthermore, the improvement of heat transfer by pressure enhancement becomes more significant with the increase of thermal conductivity, but the effect of latent heat on temperature control decreases with the increase of compression.

Effect of layering outerwear on innerwear and air gap between the two layers on thermal comfort properties of knitted fabrics

PurposeIn everyday life, people generally wear two layers of clothes (a knitted vest and a knitted t-shirt) during the summer. It is essential to understand which types of innerwear and outerwear maximize comfort. The primary objective of this research is to investigate the influence of layering outerwear on innerwear, as well as the air gap between two layers, on thermal comfort properties.Design/methodology/approachIn this study, a total of 12 combinations were created from four vest fabrics and three T-shirt fabrics. The thermal properties (thermal conductivity, thermal resistance, thermal absorptivity, thermal diffusion and peak heat flow) were evaluated for the individual inner and outer layers. Each inner layer was layered with an outer layer to observe the effect of layering on the thermal properties. An air gap of 2 mm was introduced between the inner and outer layers to study the effect of air gap on thermal properties.FindingsTencel fibre exhibits higher thermal conductivity and absorptivity than cotton and polyester. Upon layering an outer layer on an inner layer, the thermal conductivity and thermal absorptivity increase to a slight extent, thermal resistance and diffusion increase drastically and the peak heat flow reduces. With an air gap between the two layers, the thermal conductivity did not improve, the difference in thermal resistance among all the combinations reduced, the thermal absorptivity of the combination textiles was lower than that of the innerwear alone, the thermal diffusion increased and the peak heat flow diminished for all the combinations.Practical implicationsIn practice, this comprehensive thermal comfort analysis provides specific combinations of inner and outer articles of clothing that are most appropriate for enhancing comfort during the summer season.Originality/valueThough there are many studies on the effect of multilayer fabrics on thermal properties, no extensive research analyses the influence of innerwear and outerwear combinations on thermal comfort properties.

Viability of hybrid and alkali-activated slag materials for thermal energy storage: Analysis of the evolution of mechanical and thermal properties

Technological progress is needed to develop renewable energies. Improvements should be especially focused on the energy storage element to help correct the mismatch between energy supply and demand. In concentrated solar power (CSP) plants, ordinary concrete made of Portland cement (PC) has been proven to be a good thermal energy storage (TES) medium. However, the substantial environmental impact of PC manufacturing makes it necessary to develop new materials. Thus, in this work, alternative alkali-activated mortars (AAM) and hybrid materials (HM) have been developed using blast furnace slag to replace PC. This has been done in order to study their stability at high temperature (up to 500 °C) and their viability to operate as TES, undergoing thermal cycles between 200 °C and 400 °C, as they would in CSP technologies. Studying the mechanical and thermal properties after the thermal treatments has revealed that the alternative materials offer improved mechanical properties as well as very good thermal conductivity and storage capacity values. In particular, the best results in terms of mechanical properties were achieved by the AAM system, where the compressive strength value is increased with respect to the reference PC sample by 195% after exposure to 500 °C and by almost 97% after 20 thermal cycles between 200 °C and 400 °C. Furthermore, in terms of thermal properties, the AAM system showed a 31% increase in thermal conductivity after thermal exposure compared to PC. In addition, both AAM and HM systems demonstrated substantial improvements in specific heat and thermal storage capacity, outperforming PC by up to 46% during CSP-like thermal cycles. These promising results open new doors to the study of these alternative materials, such as TES, as they are more suitable than PC from an operational point of view.

Thermal characterization of thin films: A chip-based approach for in-plane property analysis

Accurate measurement of thermal properties in thin films is crucial for optimizing devices and deepening our understanding of heat transfer at nano and micro scales. This study presents a combined experimental and computational investigation on a chip-integrated technique for the assessment of in-plane thermal properties of thin films. This method stands out by incorporating inherent error cancelation to lessen the impact of radiative heat loss and allows simultaneous, independent determination of both thermal conductivity and diffusivity through straightforward linear fittings from the same dataset, reducing error propagation. We examine an 84 nm thick SiNx membrane over a temperature range from 100 K to nearly 500 K, aligning with previous studies. Further investigations into a conducting polymer film post-doping demonstrate a notable increase in both thermal conductivity and diffusivity, corroborating scanning thermal microscopy observations, confirming the technique's efficacy and reliability.

The impact of helium clusters on the electronic thermal transport properties of tungsten plasma-facing materials at finite temperatures

In this work, we investigated the impact of different concentrations of helium (He) impurities on the electronic thermal transport properties of tungsten plasma-facing materials (W-PFMs) at finite temperatures using the W-He tight-binding (TB) potential model. We found that the electronic transport performance decreases with increasing He atom concentration at different sites, where the greatest reduction in the electrical conductivity of the system is caused by the introduction of He atoms at neighboring tetrahedral sites. As the temperature increases, the electrical conductivity decreases, while the electronic thermal conductivity increases. Importantly, the higher the temperature is, the weaker the response of the electrical conductivity and electronic thermal conductivity to the He atom concentration. We suggest that this behavior is attributed to the diverse contributions of scattering mechanisms within various temperature ranges. Furthermore, as the temperature increases, the electron scattering mechanism gradually transitions from electron-impurity scattering to electron-electron scattering. Additionally, our calculated atomic resolved electrical conductivity data indicate that at lower temperatures, the electrical conductivity is predominantly contributed by W atoms around the He cluster.

In-situ microfibrilization of liquid metal droplets in polymer matrix for enhancing electromagnetic interference shielding and thermal conductivity

Herein, liquid metal microfibers (LMM) were constructed in poly (ε-caprolactone) (PCL) matrix and PCL/carbon nanotubes (CNT) composites via an in-situ microfibrilization of liquid metal (LM) droplets by a layer-by-layer stacking method. The aspect ratios of LMMs in the composites can be easily adjusted by controlling the number layers. The effect of LMM aspect ratios on electromagnetic interference (EMI) shielding effectiveness (SE) and thermal conductivity is discussed. The results show that the EMI SE value and the thermal conductivity increase with increasing aspect ratios of LMMs. In addition, the EMI shielding mechanism of PCL/LMM and PCL/LMM/CNT composites is evaluated comprehensively through the combination of electromagnetic simulation and experimental investigation. The efficiently conductive network can be formed in the composites with LMMs, which enhance EMI SE and thermal conductivity. Furthermore, the electric field distribution on the LMM surface is uneven, which enhances the polarization loss ability to electromagnetic waves.