Thermal Characterization Research Articles

Thermal characterization and moisture adsorption performance of calcium alginate hydrogel/silica gel/polyvinylpyrrolidone/expanded graphite composite desiccant

Solid desiccant dehumidification system can use low-grade energy for regeneration process and reduce the electrical energy consumption, thus saving energy and reducing carbon emissions. The choice of desiccant can significantly affect the dehumidification performance of the system. In the present study, the composite desiccant was synthesized by adding silica gel (SG), polyvinylpyrrolidone (PVP) and expanded graphite (EG) with calcium alginate hydrogel (CAH) as the matrix, named CAH/SG/EG. Subsequently, the characteristics of the samples were analyzed, and a dehumidification system was built to reveal the effects of different working conditions on the dehumidification performances. The results show that CAH/SG/20 wt.% EG has the optimal adsorption kinetics among all samples. Its moisture adsorption capacity reaches up to 1.009 g/g at 25 °C and 70 % relative humidity (RH), and its adsorption rate is 0.0179 g/(g·min). Especially, its moisture adsorption capacity can still reach 0.44 g/g at 30 % RH, showing a good adsorption capacity at lower RH. Simultaneously, the thermal conductivity of composites gradually increases from 0.449 W/(m·K) to 0.716 W/(m·K) with the addition of EG, increasing by about 60 %. In addition, the dehumidification performance of CAH/SG/20 wt.% EG is higher than that of CAH/SG, and the dehumidification performance of the system shows an ascending, descending and descending trends with the increase of inlet air moisture content, inlet air temperature and inlet air flow, respectively.

Thermal characterization and preclinical validation of a novel carbon dioxide cryotherapy system

Thermal characterization and preclinical validation of a novel carbon dioxide cryotherapy system

The generation mechanism of cutting heat and the theoretical prediction model for temperature on the rake face of the cutting tool in Zirconia ceramics

Cutting temperature and its distribution are crucial factors influencing tool strength and wear rate, due to the hardness and brittleness of Zirconia (ZrO2) ceramics, significant challenges arise in both direct temperature measurement in the cutting zone and theoretical analysis of cutting heat. Thus, focusing on the turning characteristics of ZrO2 ceramics, this study analyzes the mechanism of cutting heat generation and proposes utilizing thermodynamic state equations to determine the cutting heat source on rake face of tool. Based on the heat source method, a theoretically prediction model for temperature distribution on rake face is established. This model considers primary cutting parameters, workpiece material properties, crack fracture characteristics of the machined surface, and thermal characterizations of the tool material. The relationship between tool wear and cutting temperature is experimentally analyzed to determine the characteristic temperature that indicates the initial stage of tool wear. The validity of the theoretical model is verified, as the predicted results show high consistency with experimental results within the range of experimental parameters, with a relative error within 15.2 %.The results reveal the highest temperature during brittle cutting occurs within the cutting layer area, with the highest temperature occurring approximately 50 μm from the tool tip, followed by a gradual decrease beyond 150-200 μm. This study also demonstrates that cutting heat in ceramic turning does not solely originate from friction heat between tool flank-workpiece but also includes impact heat from tool rake face-workpiece, which under certain cutting parameters exerts a more significant influence on cutting temperature. This model can facilitate the selection and optimization of cutting process parameters for brittle materials and provide a theoretical basis for analyzing the relationship between tool thermal damage, thermophysical properties, and tool wear.

Electro-optical and thermal characterization of copper tartrate crystals grown in silica gel

Copper Tartrate crystals were grown by Gel Growth technique by single diffusion method. Silica gel of Optimum specific gravity was set with tartaric acid at optimum pH and aging period. Band gap of copper tartrate crystal is determined using to be 5.24 eV. In PL spectra broad peak is observed at nearly 367.44186 nm in the range 287 nm to 458 nm along with the sharp, intense transmission maxima peak at wavelength nearly 505.03876 nm which is characteristic of a material composition and electronic band structure. This shows the transparency of it in UV-Visible region and it as a filter in this range TGA analysis concludes that Copper tartrate has loss of one-half water molecule as crystalline water and is stable up to 85.02 ℃DSC analysis assigns the temperature value 314.5 ℃ as melting point and apparent enthalpy of fusion determined is 10.18 mW.

Thermal Characterization of Ferroelectric Al1-xBxN for Nonvolatile Memory.

Boron (B)-substituted wurtzite AlN (Al1-xBxN) is a recently discovered wurtzite ferroelectric material that offers several advantages over ferroelectric Hf1-xZrxO2 and PbZr1-xTixO3. Such benefits include a relatively low growth temperature as well as a thermally stable, and thickness-stable ferroelectric polarization; these factors are promising for the development of ferroelectric nonvolatile random-access memory (FeRAM) that are CMOS-compatible, scalable, and reliable for storing data in harsh environments. However, wurtzite ferroelectric materials may undergo exacerbated self-heating upon polarization switching relative to other ferroelectric materials; the larger energy loss is anticipated due to the higher coercive field and remanent polarization. This work provides insight into the polarization switching-induced self-heating of future FeRAM based on Al1-xBxN. It was experimentally observed that the thermal conductivity of Al1-xBxN thin films drops from 40.9 W m-1 K-1 to 4.35 W m-1 K-1 (which is 2 orders of magnitude lower than that of bulk AlN) when the B composition (x) increases from 0 to 0.18. The transient thermal response of an Al0.93B0.07N metal-ferroelectric-metal (MFM) capacitor was investigated using micro-Raman thermometry and validated via device thermal modeling. Further simulation studies reveal that the large heat generation rate and the low thermal conductivity is predicted to induce an instantaneous temperature rise that may exceed 150 °C in a FeRAM device based on a 5 nm thick Al1-xBxN film at GHz frequency switching. In addition, thermal crosstalk within a FeRAM cell array exacerbates the self-heating, resulting in a predicted steady-state temperature rise that is an order of magnitude higher than that of a single bit-cell.

Liquorilactobacillus hordei SK6 and Liquorilactobacillus mali SK26 from Traditional Water Kefir Produce Dextrans with Technological Roles.

The significance of exopolysaccharides (EPS) in various applications has garnered increasing attention. In this study, two bacteria, Liquorilactobacillus hordei SK6 and Liquorilactobacillus mali SK26, isolated from traditional water kefir grains, produced 8.89g/L and 7.2g/L of homopolymeric glucan, respectively. NMR analysis revealed that both glucans were dextrans composed of (1 → 6)-linked α-D-glucose units, with (1 → 3)-linked α-D-glucose units serving as branching points, accounting for 5.3 ± 0.2% in dextran SK6 and 2.7 ± 0.15% in SK26. FTIR and XRD analyses further confirmed the amorphous nature of the dextrans, although dextran SK6 exhibited micro-arranged structures. Thermal characterization using TGA and DSC showed degradation temperatures of 298.5°C for dextran SK6 and 282.1°C for dextran SK26. Clear differences in morphological properties were observed using AFM and SEM. These findings provide valuable insights into dextran-producing strains and their potential applications in various industries.

Thermal and Structural Characterization of Coke Deposition on Spent NiMo Catalyst Used During Catalytic Upgrading of Heavy Oil

Catalyst deactivation has become a major concern in the refining industry globally. The deactivation of hydroprocessing catalyst by coke deposition reduces its useful life, the on-stream time of the process involved and the profitability of upgrading heavy oils to useful products. There are various methods used in thermal and structural characterization but for the purpose of this research journal, Thermogravimetric Analysis (TGA), Scanning Electron Microscopy (SEM), X-Ray Diffraction (XRD) and Fourier Transform Infrared (FTIR) were carried out on both fresh and spent NiMo catalyst. The TGA results of the spent catalyst samples indicates the presence of coke species with the major portion of the species being ‘medium’ and ‘hard’ coke (second and third stage). There was also no significant change in loss of weight with change in heating rate. In comparison to the fresh catalyst, the SEM micrograph of the used catalyst indicates the formation of poor porous-structure and block-shaped crystallites depicting the sintering of particles because of the higher calcination temperature. O–C–O bond stretching vibrations with an anatase morphology were observed using FTIR on the spent catalyst sample confirming the presence of the coke species while the XRD results showed the formation and nature of carbonaceous deposits on the spent catalyst’s surfaces. A rutile phase with a tetragonal symmetry was detected for spent NiMo diffraction peaks, with the major phase indicating the presence of Carbon with a hexagonal phase.

A study of epoxy based polymer composites: Tailoring mechanical and piezoelectric characteristics

AbstractIn this study, epoxy based piezoelectric polymer composites were fabricated using two different curing agents and varying compositions of poly(vinylidene) fluoride (PVDF), barium titanate (BaTiO3), and conductive silver nanoparticles. The effect of piezoelectric ceramic and conductive nanofillers on enhancing the PVDF β phase within the composite structure was investigated. Structural, thermal, and morphological characterizations of the polymer composites were performed using x‐ray diffraction, differential scanning calorimetry, and scanning electron microscopy. Furthermore, a comprehensive analysis of mechanical properties and fracture toughness was conducted in addition to the piezoelectric behavior. A voltage output of 1.35 V was generated by a polymer composite containing 20 wt% BaTiO3, with a Young's modulus of 2 GPa and a fracture energy of 2.3 kJ/m2. The findings of this study contribute to expanding the knowledge and understanding of piezoelectric polymer composites, enabling their potential utilization in various scientific and technological applications.Highlights Enhancing mechanical and piezoelectric properties of epoxy based piezoelectric composites. A clear and comprehensive description of the experimental procedures employed. Comparative analysis methods: structural, thermal, mechanical, fracture, and piezoelectric property analyses.

Effect of Fiber Loading on Green Composites of Recycled HDPE Reinforced with Banana Short Fiber: Physical, Mechanical and Morphological Properties

Currently, research on composite materials derived from natural fibers and agro-industrial waste has generated industrial proposals for producing useful materials with sufficient mechanical strength for applications involving the reuse of waste for secondary purposes. The objective of this study was to determine the influence of fiber content on the final tensile strength of the composite material, serving as a reference for the manufacture of plates. To achieve this, high-density polyethylene (HDPE) composites reinforced with short banana fibers were prepared using a blade mill and hot compression molding techniques. Two levels of short banana fiber content—10% and 20% by weight—were used, along with two types of HDPE: virgin and recycled. We evaluated the effect of adding short banana fibers on the mechanical properties of the composite, specifically tensile strength, according to the ASTM D638 standard for polymeric materials. These results were correlated with the structural properties obtained through morphological, chemical, and thermal characterization of the developed materials. The mechanical evaluation results showed that the tensile strength and elastic modulus depend on the short banana fiber content and the type of high-density polyethylene. Thermogravimetric analysis revealed that the composites decompose faster than the pure polymers (virgin and recycled HDPE). Based on these findings, the composite material prepared under optimal conditions is recommended for use in walls or construction boards where high tensile strength is not critical, due to the decreased mechanical properties resulting from the incorporation of agro-industrial waste.

Cellulose of sisal fibers integration in papermaking: mechanical and thermal characterization

Cellulose of sisal fibers integration in papermaking: mechanical and thermal characterization

(Ultra)wide bandgap semiconductor heterostructures for electronics cooling

The evolution of power and radiofrequency electronics enters a new era with (ultra)wide bandgap semiconductors such as GaN, SiC, and β-Ga2O3, driving significant advancements across various technologies. The elevated breakdown voltage and minimal on-resistance result in size-compact and energy-efficient devices. However, effective thermal management poses a critical challenge, particularly when pushing devices to operate at their electronic limits for maximum output power. To address these thermal hurdles, comprehensive studies into thermal conduction within semiconductor heterostructures are essential. This review offers a comprehensive overview of recent progress in (ultra)wide bandgap semiconductor heterostructures dedicated to electronics cooling and are structured into four sections. Part 1 summarizes the material growth and thermal properties of (ultra)wide bandgap semiconductor heterostructures. Part 2 discusses heterogeneous integration techniques and thermal boundary conductance (TBC) of the bonded interfaces. Part 3 focuses on the research of TBC, including the progress in thermal characterization, experimental and theoretical enhancement, and the fundamental understanding of TBC. Parts 4 shifts the focus to electronic devices, presenting research on the cooling effects of these heterostructures through simulations and experiments. Finally, this review also identifies objectives, challenges, and potential avenues for future research. It aims to drive progress in electronics cooling through novel materials development, innovative integration techniques, new device designs, and advanced thermal characterization. Addressing these challenges and fostering continued progress hold the promise of realizing high-performance, high output power, and highly reliable electronics operating at the electronic limits.

Physics-of-failure based lifetime modelling for SiC based automotive power modules using rate- and temperature-dependent modelling of sintered silver

The new generations of automotive power modules pose new challenges and requirements for the die-related packaging technologies as well as the assessment of reliability and lifetime. The use of sintered silver for the die-related packaging in particular has proven promising and enables new designs such as a sintered die attach combined with a sintered top side interconnection comprising a copper foil and copper ribbon bonds. However, the empirical lifetime models for power modules developed over many years are not suitable any more. A holistic Physics-of-Failure approach can provide remedy as it allows for a significant reduction of testing time via finite element simulations. This approach requires a detailed understanding of the relevant failure mechanisms as well as an electrical, thermal and mechanical characterisation of the involved materials and subsequent field coupled modelling. A failure analysis of the complete power module revealed that the top side sinter layer connecting the copper foil to the semiconductor die is prone to degradation. Therefore, the core of this work is the mechanical characterisation of porous sintered silver and, in particular, the primary and secondary creep behaviour. A newly developed creep model which – for the first time – takes load reversal for primary creep into account is implemented with a subroutine. This allows for lifetime simulations within a Physics-of-Failure framework resulting in a first lifetime model on module level for a complex automotive power module employing sintered silver.

Optical, thermal, and radiation shielding characterization of bismuth-modified zinc-lithium-tungsten-borate glass

Abstract This study examines the optical, thermal, and radiation attenuation properties of zinc-tungsten-lithium-borate glass modified with Bi2O3, synthesized using melt-quench techniques. The resulting glass samples display a significant physical property, with density increasing from 3.22 g/cm³ to 4.84 g/cm³ as Bi2O3 concentration increase from 2 to 16 mol%. The optical band gap narrows from 2.9 eV to 2.55 eV, while the refractive index increases from 2.42 to 3.49, indicating a shift in absorption to lower energy levels. Higher Bi2O3 concentrations reduce optical non-linearity while enhancing the linear optical properties of the synthesized glasses. The formation of orthoborate anions suggests that Bi3+ ions in the glasses act as network modifiers, disrupting the borate framework and introducing structural disorder. Additionally, thermal properties, including glass transition temperature (T_g), crystallization temperature (T_c), and melting temperature (T_m), decrease with increasing Bi2O3 concentration. The radiation shielding effectiveness is significantly improved, with the linear attenuation coefficient (LAC) increasing from 0.56 cm⁻¹ to 1.35 cm⁻¹ at 0.284 MeV and from 0.127 cm⁻¹ to 0.186 cm⁻¹ at 2.506 MeV as Bi2O3 content rises from 2 mol% to 16 mol%. For a glass thickness of 1 cm, the radiation protection efficiency reaches approximately 74% for a photon energy of 0.284 MeV in the sample doped with 16 mol% Bi2O3. The glass's remarkable combination of high transparency and effective radiation attenuation, positions it as a promising option for radiation shielding applications.

Investigating the Impact of Nano‐Metal Oxides (Copper and Iron) on the Thermal Decomposition Behavior of Advanced Propellants with Nitrocellulose/Polyurethane Binders

AbstractThis research delves into the combined effects of green nano metal oxides (copper and iron) and polyurethane (PU) modification on the thermal degradation kinetics of propellant based on solid ammonium nitrate composite modified simple base (CMSB). Surface modification of ammonium nitrate particles was achieved through repeated spray coating, ensuring effective catalyst binding. The formulated compositions of propellants underwent thorough thermal characterization, including thermogravimetric (TG) and differential scanning calorimetry (DSC) analyses. TG analysis revealed a significant decrease in the propellant's thermal degradation temperature, attributed to AN modification with nano metal oxides (nMOs) and the use of PU/NC as a binder. Isoconversional kinetic methods (It‐KAS, It‐FWO, and VYA/CE) were employed for further analysis, allowing prediction of kinetic parameters. Additionally, kinetic analysis results allowed calculation of the critical ignition temperature. The thermokinetic results underscore the substantial impact of nMOs particles and PU modification regarding the reactivity and catalytic performance of propellant containing ammonium nitrate, leading to a noteworthy reduction in activation energy and critical ignition temperature. Furthermore, modifying the binder with nitrocellulose and incorporating nanoparticles significantly reduces ignition delay and combustion duration while increasing flame intensity in CMDB solid propellants, enhancing overall combustion efficiency.

Hygrothermal characterization of cement mortar composites incorporating micronized miscanthus fibers

This work investigates both the moisture dependence of thermal properties and the hygric behavior of cement mortars incorporating different proportions of micronized miscanthus fibers up to ∼7 wt%. The experimental program encompasses thermal characterization at dry (10 % RH), moderate (50 % RH), and saturated (100 % RH) states of samples, along with hygric characterization of the various mortar specimens through sorption-desorption tests, water vapor permeability assessment, Moisture Buffer value (MBV) determination, and capillary absorption tests. Thermal measurements showed a significant decrease in thermal conductivity with the addition of fibers. For a given biobased mortar composition, conductivity values were almost identical at dry/moderate RH level but exhibited an increase at saturation. This shift was attributed to the fibers' absorptive properties, which lead to a higher water content within the samples in saturated humidity environments. Collectively, the moisture sorption, moisture buffering capacities, water vapor permeability, and capillary absorption properties demonstrated consistent enhancement with rising fiber content, confirming the significant impact of plant fibers on the material's hygrothermal properties. In addition, the GAB model (Guggenheim- Anderson- de Boer) was used to fit the sorption and desorption isotherms, yielding a good correspondence with experimental data. Finally, mortars with the higher fiber contents (M7.5 F and M10F with 5.70 wt% and 6.94 wt% of fibers, respectively) combined high hygroscopicity and low thermal conductivity values (even under moisture-saturated conditions), making them promising candidates for applications requiring both good hygric performance and effective insulation properties.

Epoxidation of Residual Soybean Oil and Thermal Characterization of Residual Epoxidized Soybean Oil Crosslinked with Fumaric Acid

Epoxidation of Residual Soybean Oil and Thermal Characterization of Residual Epoxidized Soybean Oil Crosslinked with Fumaric Acid

Thermal characterization methodologies for experimental minichannel heat sink designs in printed circuit board assemblies

There has been a growing demand for novel, highly efficient, power-saving cooling solutions in recent years. In many cases, standard cooling techniques offer only limited opportunities to prevent the overheating of circuits. Such issues concern high-speed Printed Circuit Board Assemblies (PCBA) in data centers and telecommunication racks, where the flow of the cooling medium is obstructed due to the lack of space. Size limitations can also be a serious problem when cooling high-power devices because the devices consume a large space. Since the heat sink-based cooling solutions and the sophisticated IC packages only deal with one possible heat flow path, we were given the idea of enhancing the secondary heat flow path towards the Printed Circuit Board (PCB). Led by this intention, the idea of creating an embedded minichannel system inside the circuit board and circulating the cooling agent was realized. Through this method, we could decrease the board-to-ambient thermal resistance significantly. This paper presents the demonstration and feasibility study of this method. One of the main aims of this study is to demonstrate the applicability of the proposed concept in PCBAs, where the primary concerns are the low-cost manufacturability and available space. The other goal is to create an adaptation of the standard thermal characterization methodologies to deal with the specific dissipating components in the PCBA demonstrators. In the first part, the manufacturing technology is elaborated on, and its efficiency is characterized by thermal transient testing and Computational Fluid Dynamics (CFD) simulations. For these use cases, it was noted that the cumulative thermal resistance decreased by approximately 60 % when a volumetric flow rate of 100 ccm was applied in the minichannels. In the second part, a more sophisticated technology demonstration is realized and characterized by adding the proposed embedded minichannel heat sink to an existing high-speed PCBA. A specific thermal transient testing was implemented specifically for this use case, and it was carried out on programmable logic devices by utilizing general-purpose programmable logic to construct the necessary measurement methods. In the future, this feature can be used in different logic circuit designs where it is not possible to determine the junction temperature directly.

Hydrolysis of poly(ester urethane): In-depth mechanistic pathway determination through thermal and chemical characterization

Many structure/property relationships of hydrolyzed poly(ester urethane) (PEU) – a thermoplastic – have been reported. Examples include changes in molecular weight vs. elongation at break and crosslink density vs. mechanical strength. However, the effect of molecular weight (or molar mass) reduction on some physical, thermal, and chemical properties of hydrolyzed PEU have not been reported. Therefore, a large set of hydrolyzed PEU (Estane®5703) samples were obtained from two aging experiments: 1) accelerated aging conducted under various environments (air, nitrogen, moisture) and at 64 °C and below for almost three years, and 2) natural aging conducted under ambient conditions for more than three decades. The hydrolyzed samples were characterized via multi-detection gel permeation chromatography (GPC), thermogravimetric analysis (TGA), modulated differential scanning calorimetry (mDSC), UV–vis spectroscopy, nuclear magnetic resonance (NMR), and Fourier-transform infrared (FTIR) spectroscopy techniques. Hydrolysis of ester linkages in the soft-segments decreases both the molecular weight (Mw) and the melting point (Tm) of Estane (from ∼55 °C to 39 °C). Aging above this Tm, increased mobility of polymer chains and water diffusivity in the PEU matrix alter the PEU degradation pathway from those expected at aging temperatures below this Tm and have significant bearing on the critical molecular weight (MC) at which the physical, chemical, thermal, and mechanical properties of Estane change abruptly. While a MC value of 20 kDa is found for PEU hydrolysis at mild temperatures (e.g., as low as 39 °C), the value of MC increases with increasing aging temperatures. To complement the existing structure/property relationships reported in the literature, more correlations are obtained, which include the effect of Mw on polydispersity, intrinsic viscosity (Mark-Houwink equation), UV extinction coefficient, and dn/dc (GPC analysis) values. Furthermore, we seek to bolster previously reported aging models for PEU by developing a practical model with which the extent of degradation and material performance can be predicted based on aging under different temperature ranges both above and below the melting point of Estane.

Effect of Mild Conditions on PVA-Based Theta Gel Preparation: Thermal and Rheological Characterization.

Polyvinyl alcohol (PVA), possessing a strong ability to form hydrogels, has been widely used for various pharmaceutical and biomedical applications. In particular, the use of PVA-PEG in the form of theta gels for altered cartilage treatment has attracted an enormous amount of attention in the last 20 years. In this paper, we prepared 42 PVA-PEG in the form of theta gels at room temperature in an aqueous environment, testing the crystallization occurrence at basic pH (10 or 12). Using a statistical approach, the effect of PEG molecular weight, PVA molecular weight and alkaline pH values on water content and mechanical performance was evaluated. The used procedure permitted the theta gels to maintain swelling properties comparable to those of human cartilage, from 60% to 85%, with both polymers having the same influence. PEG MW mainly affected the hydrophilic properties, whereas the thermal properties were mostly influenced by the PVA. The shear and compression mechanical behavior of the produced materials were affected by both the polymers' MWs. The sample obtained using PVA 125 kDa with PEG 20 kDa as a porogen appeared to be the most suitable one for cartilage disease treatment, as it had an equilibrium shear modulus in the range of 50-250 kPa, close to that of native articular cartilage, as well as optimal mechanical response under compression along the entire analyzed frequency range with a mean value of 0.12 MPa and a coefficient of friction (COF) which remained under 0.10 for all the tested sliding speeds (mm/s).

A comprehensive investigation of the impact of carbon-supported metal complexes of triaminoguanidine on the characteristics of a double-base propellant

ABSTRACT In this study, triaminoguanidine complexes grafted onto activated carbon (AC-TAG-Fe and AC-TAG-Co) were designed and investigated for their catalytic effect on the thermolysis of a double base propellant consisting of nitrocellulose (NC) and diethylene glycol dinitrate (DEGDN). The successful synthesis of transition metal complexes with triaminoguanidine and their subsequent grafting onto activated carbon were confirmed using various analytical techniques, including Fourier Transform Infrared Spectroscopy, Raman Spectroscopy, X-ray Diffraction, and Scanning Electron Microscopy. Thermal characterization using Thermogravimetric Analysis and Differential Scanning Calorimetry provided valuable insights into the thermal properties and reactivity of the elaborated NC/DEGDN-based composites. Importantly, the addition of various additives resulted in notable improvements in both the enthalpy of reaction and density. Isoconversional kinetic studies revealed that the incorporation of TAG-Fe and TAG-Co complexes reduced the apparent activation energy of the NC/DEGDN composite from 137.4 kJ/mol to 135.4 kJ/mol and 114.8 kJ/mol, respectively, suggesting their catalytic effect. Furthermore, it is found that the addition of activated carbon (AC) resulted in an increase in activation energy to 154 kJ/mol, whereas grafting TAG-Fe and TAG-Co complexes onto AC as a catalytic support subsequently reduced activation energy to 119 kJ/mol and 112 kJ/mol, respectively. Overall, this research serves as a valuable reference for future studies focusing on investigating the catalytic combustion characteristics of double-base solid propellants.