Theory Of Open Quantum Systems Research Articles

Applicability of Mean-Field Theory for Time-Dependent Open Quantum Systems with Infinite-Range Interactions.

Understanding quantum many-body systems with long-range or infinite-range interactions is of relevance across a broad set of physical disciplines, including quantum optics, nuclear magnetic resonance, and nuclear physics. From a theoretical viewpoint, these systems are appealing since they can be efficiently studied with numerics, and in the thermodynamic limit are expected to be governed by mean-field equations of motion. Over the past years the capabilities to experimentally create long-range interacting systems have dramatically improved permitting their control in space and time. This allows us to induce and explore a plethora of nonequilibrium dynamical phases, including time crystals and even chaotic regimes. However, establishing the emergence of these phases from numerical simulations turns out to be surprisingly challenging. This difficulty led to the assertion that mean-field theory may not be applicable to time-dependent infinite-range interacting systems. Here, we rigorously prove that mean-field theory in fact exactly captures their dynamics, in the thermodynamic limit. We further provide bounds for finite-size effects and their dependence on the evolution time.

Stochastic Schrödinger equation for hot-carrier dynamics in plasmonic systems

We present a multiscale method coupling the theory of open quantum systems with real-time ab initio treatment of electronic structure to study hot-carrier dynamics in photoexcited plasmonic systems. We combine the Markovian Stochastic Schrödinger equation with an ab initio GW coupled to the Bethe–Salpeter (BSE) equation description of the electronic degrees of freedom, interacting with a metallic nanoparticle modeled classically according to the polarizable continuum model. We apply this methodology to study the effect of relaxation (T1) and pure dephasing (T2) times on the hot-carrier dynamics in a system composed of a quantum portion described at GW/BSE level, i.e., a CHO fragment adsorbed on a vertex of a rhodium nanocube, and of the rest of the nanocube, treated classically, when irradiated with a 2.7 eV light pulse, inspired by the experimental results on plasmon-driven CO2 photoreduction. A net hole injection from rhodium to CHO is observed, with and without the classical portion of the nanocube. The nanocube effect is to enhance the generated charge population by two orders of magnitude. The nonradiative decay, via a relaxation time T1 based on the energy-gap law, produces a rapid decrease of the charge population. Results with T2 only show that a charge injection retarded with respect to the pulse, which is present in the coherent dynamics, disappears when coherence is erased.

Recovering Complete Positivity of Non-Markovian Quantum Dynamics with Choi-Proximity Regularization

A relevant problem in the theory of open quantum systems is the lack of complete positivity of dynamical maps obtained after weak-coupling approximations, a famous example being the Redfield master equation. A number of approaches exist to recover well-defined evolutions under additional Markovian assumptions, but much less is known beyond this regime. Here, we propose a numerical method to cure the complete-positivity violation issue while preserving the non-Markovian features of an arbitrary original dynamical map. The idea is to replace its unphysical Choi operator with its closest physical one, mimicking recent work on quantum process tomography. We also show that the regularized dynamics is more accurate in terms of reproducing the exact dynamics, which allows us to heuristically push the utilization of these master equations in moderate coupling regimes, where the loss of positivity can have a relevant impact. Published by the American Physical Society 2024

Dynamics of a Quantum System Interacting with White Non-Gaussian Baths: Poisson Noise Master Equation.

Quantum systems are unavoidably open to their surrounding degrees of freedom. The theory of open quantum systems is thus crucial to understanding the fluctuations, dissipation, and decoherence of a quantum system of interest. Typically, the bath is modeled as an ensemble of harmonic oscillators, which yields Gaussian statistics of the bath influence on the quantum systems. However, there are also phenomena in which the bath consists of two-state systems, spins, or anharmonic oscillators; therefore, the non-Gaussian properties of the bath become important. Nevertheless, a theoretical framework to describe quantum systems under the influence of such non-Gaussian baths is not well established. Here, we develop a theory to describe quantum dissipative systems affected by Poisson noise properties of the bath, because the Lévi-Itô decomposition theorem asserts that Poisson noise is fundamental in describing arbitrary white noise beyond Gaussian properties. We introduce a quantum bath model that allows for the consistent description of dissipative quantum systems. The obtained master equation reveals non-Gaussian bath effects in the white noise regime, and provides an essential step toward describing open quantum dynamics under the influence of generic baths.

On Time-Dependent Projectors and a Generalization of the Thermodynamical Approach in the Theory of Open Quantum Systems

On Time-Dependent Projectors and a Generalization of the Thermodynamical Approach in the Theory of Open Quantum Systems

Exact Non-Markovian Quantum Dynamics on the NISQ Device Using Kraus Operators.

The theory of open quantum systems has many applications ranging from simulating quantum dynamics in condensed phases to better understanding quantum-enabled technologies. At the center of theoretical chemistry are the developments of methodologies and computational tools for simulating charge and excitation energy transfer in solutions, biomolecules, and molecular aggregates. As a variety of these processes display non-Markovian behavior, classical computer simulation can be challenging due to exponential scaling with existing methods. With quantum computers holding the promise of efficient quantum simulations, in this paper, we present a new quantum algorithm based on Kraus operators that capture the exact non-Markovian effect at a finite temperature. The implementation of the Kraus operators on the quantum machine uses a combination of singular value decomposition (SVD) and optimal Walsh operators that result in shallow circuits. We demonstrate the feasibility of the algorithm by simulating the spin-boson dynamics and the exciton transfer in the Fenna-Matthews-Olson (FMO) complex. The NISQ results show very good agreement with the exact ones.

Quantum Hall and Shubnikov-de Haas Effects in Graphene within Non-Markovian Langevin Approach

The theory of open quantum systems is applied to study galvano-, thermo-magnetic, and magnetization phenomena in axial symmetric two-dimensional systems. Charge carriers are considered as quantum particles interacting with the environment through a one-body (mean-field) mechanism. The dynamics of charge carriers is affected by the average collision time that takes effectively into account two-body effects. The functional dependencies of the average collision time on the external uniform magnetic field, concentration and temperature are phenomenologically treated. Analytical expressions are obtained for the tensors of electric and thermal conductivity and/or resistivity. The developed theory is applied to describe the Shubnikov-de Haas oscillations and quantum Hall effect in graphene and GaAs/AlxGa1−xAs heterostructure. The dependencies of magnetization and thermal conductivity on the magnetic field are also predicted.

Using nanokelvin quantum thermometry to detect timelike Unruh effect in a Bose–Einstein condensate

It is found that the Unruh effect can not only arise out of the entanglement between two sets of modes spanning the left and right Rindler wedges, but also between modes spanning the future and past light cones. Furthermore, an inertial Unruh–DeWitt detector along a spacetime trajectory in one of these cones may exhibit the same thermal response to the vacuum as that of an accelerated detector confined in the Rindler wedge. This feature thus could be an alternative candidate to verify the “Unruh effect”, termed as the timelike Unruh effect correspondingly. In this paper we propose to detect the timelike Unruh effect by using an impurity immersed in a Bose–Einstein condensate (BEC). The impurity acts as the detector which interacts with the density fluctuations in the condensate, working as an effective quantum field. Following the paradigm of the emerging field of quantum thermometry, we combine quantum parameter estimation theory with the theory of open quantum systems to realize a nondemolition Unruh temperature measurement in the nanokelvin (nK\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\ extrm{nK}$$\\end{document}) regime. Our results demonstrate that the timelike Unruh effect can be probed using a stationary two-level impurity with time-dependent energy gap immersed in a BEC within current technologies.

The local approach to the theory of open optical quantum systems and “violation” of the second law of thermodynamics

Being correctly calculated, energy flows between thermostats into which nonresonantly coupled quantum harmonic oscillators decay, there is no violation of the second law of thermodynamics in using the local approach reported earlier.

Memory Tensor for Non-Markovian Dynamics with Random Hamiltonian

In the theory of open quantum systems, the Markovian approximation is very widespread. Usually, it assumes the Gorini–Kossakowski–Sudarshan–Lindblad (GKSL) equation for density matrix dynamics and quantum regression formulae for multi-time correlation functions. Nevertheless, now, quantum non-Markovianity is being actively studied, especially the non-Markovianity of multi-time correlations. In this work, we consider dynamics with a random Hamiltonian, which can lead to GKSL dynamics of the density matrix for some special cases, but correlation functions generally do not satisfy the quantum regression formulae. Despite the fact that random Hamiltonians have been actively studied, dynamics with such Hamiltonians has been little discussed from the viewpoint of multi-time correlations. For specific models with a random Hamiltonian, we provide the formulae for multi-time correlations which occur instead of the usual regression formulae. Moreover, we introduce and calculate the memory tensor, which characterizes multi-time correlations against the Markovian ones. We think that, despite being applied to specific models, the methods developed in this work can be used in a much broader setup.

Machine-learned correction to ensemble-averaged wave packet dynamics.

For a detailed understanding of many processes in nature involving, for example, energy or electron transfer, the theory of open quantum systems is of key importance. For larger systems, an accurate description of the underlying quantum dynamics is still a formidable task, and, hence, approaches employing machine learning techniques have been developed to reduce the computational effort of accurate dissipative quantum dynamics. A downside of many previous machine learning methods is that they require expensive numerical training datasets for systems of the same size as the ones they will be employed on, making them unfeasible to use for larger systems where those calculations are still too expensive. In this work, we will introduce a new method that is implemented as a machine-learned correction term to the so-called Numerical Integration of Schrödinger Equation (NISE) approach. It is shown that this term can be trained on data from small systems where accurate quantum methods are still numerically feasible. Subsequently, the NISE scheme, together with the new machine-learned correction, can be used to determine the dissipative quantum dynamics for larger systems. Furthermore, we show that the newly proposed machine-learned correction outperforms a previously handcrafted one, which, however, improves the results already considerably.

Biological efficiency in processing information in green plants

The detection and processing of environmental information is a fundamental attribute of all living systems. This article approaches the question of how efficiently plants process that information, considering it likely that differential efficiency among different species may help explain differential survival. The primary routes of information transfer, that is, signal transduction, are relatively well understood. It is pointed out, based on current understanding, that erasure of such information may be of equal importance to its acquisition. This in turn could provide a simple means of quantifying the acquisition of information by a plant and the efficiency in doing so. However, wild plants live in an environment that is noisy. A useful analogy to deal with such situations can be found in quantum theory of open systems, wherein processes are both well-characterized and well understood, unlike those in plants. This paper develops this theme from quantum information processing and provides a mean of transferring such quantum characterization to biological dynamical situations. The article concludes with discussion on communication theory, indicating that there is a dearth of experimental results that can currently be used to investigate information processing but suggesting how progress can be made in this important programme.

Environment assisted quantum model for studying RNA-DNA-error correlation created due to the base tautomery

The adaptive mutation phenomenon has been drawing the attention of biologists for several decades in evolutionist community. In this study, we propose a quantum mechanical model of adaptive mutation based on the implications of the theory of open quantum systems. We survey a new framework that explain how random point mutations can be stabilized and directed to be adapted with the stresses introduced by the environments according to the microscopic rules dictated by constraints of quantum mechanics. We consider a pair of entangled qubits consist of DNA and mRNA pair, each coupled to a distinct reservoir for analyzing the spreed of entanglement using time-dependent perturbation theory. The reservoirs are physical demonstrations of the cytoplasm and nucleoplasm and surrounding environments of mRNA and DNA, respectively. Our predictions confirm the role of the environmental-assisted quantum progression of adaptive mutations. Computing the concurrence as a measure that determines to what extent the bipartite DNA-mRNA can be correlated through entanglement, is given. Preventing the entanglement loss is crucial for controlling unfavorable point mutations under environmental influences. We explore which physical parameters may affect the preservation of entanglement between DNA and mRNA pair systems, despite the destructive role of interaction with the environments.

Open Systems, Quantum Probability, and Logic for Quantum-like Modeling in Biology, Cognition, and Decision-Making.

The aim of this review is to highlight the possibility of applying the mathematical formalism and methodology of quantum theory to model behavior of complex biosystems, from genomes and proteins to animals, humans, and ecological and social systems. Such models are known as quantum-like, and they should be distinguished from genuine quantum physical modeling of biological phenomena. One of the distinguishing features of quantum-like models is their applicability to macroscopic biosystems or, to be more precise, to information processing in them. Quantum-like modeling has its basis in quantum information theory, and it can be considered one of the fruits of the quantum information revolution. Since any isolated biosystem is dead, modeling of biological as well as mental processes should be based on the theory of open systems in its most general form-the theory of open quantum systems. In this review, we explain its applications to biology and cognition, especially theory of quantum instruments and the quantum master equation. We mention the possible interpretations of the basic entities of quantum-like models with special interest given to QBism, as it may be the most useful interpretation.

Thermal and atomic effects on coupled-channels heavy-ion fusion

Stellar nuclear fusion reactions take place in a hot, dense plasma within stars. To account for the effect of these environments, the theory of open quantum systems is used to conduct pioneering studies of thermal and atomic effects on fusion probability at a broad range of temperatures and densities. Since low-lying excited states are more likely to be populated at stellar temperatures and increase nuclear plasma interaction rates, a 188Os nucleus was used as a target that interacts with an inert 16O projectile. Key results showed thermal effects yield an average increase in fusion probability of 15.5% and 36.9% for our test nuclei at temperatures of 0.1 and 0.5 MeV respectively, compared to calculations at zero temperature. Thermal effects could be tested in a laboratory using targets prepared in excited states as envisaged in facilities exploiting laser-nucleus interactions.

The Open Systems View and the Everett Interpretation

It is argued that those who defend the Everett, or ‘many-worlds’, interpretation of quantum mechanics should embrace what we call the general quantum theory of open systems (GT) as the proper framework in which to conduct foundational and philosophical investigations in quantum physics. GT is a wider dynamical framework than its alternative, standard quantum theory (ST). This is true even though GT makes no modifications to the quantum formalism. GT rather takes a different view, what we call the open systems view, of the formalism; i.e., in GT, the dynamics of systems whose physical states are fundamentally represented by density operators are represented as fundamentally open as specified by an in general non-unitary dynamical map. This includes, in principle, the dynamics of the universe as a whole. We argue that the more general dynamics describable in GT can be physically motivated, that there is as much prima facie empirical support for GT as there is for ST, and that GT could be fully in the spirit of the Everett interpretation—that there might, in short, be little reason for an Everettian not to embrace the more general theoretical landscape that GT allows one to explore.

Quantum spin models for numerosity perception.

Humans share with animals, both vertebrates and invertebrates, the capacity to sense the number of items in their environment already at birth. The pervasiveness of this skill across the animal kingdom suggests that it should emerge in very simple populations of neurons. Current modelling literature, however, has struggled to provide a simple architecture carrying out this task, with most proposals suggesting the emergence of number sense in multi-layered complex neural networks, and typically requiring supervised learning; while simple accumulator models fail to predict Weber's Law, a common trait of human and animal numerosity processing. We present a simple quantum spin model with all-to-all connectivity, where numerosity is encoded in the spectrum after stimulation with a number of transient signals occurring in a random or orderly temporal sequence. We use a paradigmatic simulational approach borrowed from the theory and methods of open quantum systems out of equilibrium, as a possible way to describe information processing in neural systems. Our method is able to capture many of the perceptual characteristics of numerosity in such systems. The frequency components of the magnetization spectra at harmonics of the system's tunneling frequency increase with the number of stimuli presented. The amplitude decoding of each spectrum, performed with an ideal-observer model, reveals that the system follows Weber's law. This contrasts with the well-known failure to reproduce Weber's law with linear system or accumulators models.

Introduction to the theory of open quantum systems

This manuscript is an edited and refined version of the lecture script for a one-semester graduate course given originally at the PhD school in the Institute of Physics of Polish Academy of Sciences in the Spring/Summer semester of 2022. The course expects from the student only a basic knowledge on graduate-level quantum mechanics. The script itself is largely self-contained and could be used as a textbook on the topic of open quantum systems. The program of this course is based on a novel approach to the description of the open system dynamics: It is showed how the environmental degrees of freedom coupled to the system can be represented by a multi-component quasi-stochastic process. Using this representation one constructs the super-quasi-cumulant (or super-qumulant) expansion for the system’s dynamical map-a parametrization that naturally lends itself for the development of a robust and practical perturbation theory. Thus, even an experienced researcher might find this manuscript of some interest.

Effective-Hamiltonian Theory of Open Quantum Systems at Strong Coupling

A new technique for open quantum dynamics, combining reaction coordinate mappings and the polaron transform, allows for efficient description of strong system-bath couplings, opening the way for novel applications in nanoscale transport and thermodynamics.

Cooling with fermionic thermal reservoirs.

The quantum reservoirs commonly considered in open-quantum systems theory are those modeled by quantum harmonic oscillators, which are called bosonic reservoirs. Recently, quantum reservoirs modeled by two-level systems, the so-called fermionic reservoirs, have received attention due to their features. Given that the components of these reservoirs have a finite number of energy levels, unlike bosonic reservoirs, some studies are being carried out to explore the advantages of using this type of reservoir, especially in the operation of heat machines. In this paper, we carry out a case study of a quantum refrigerator operating in the presence of bosonic or fermionic thermal reservoirs, and we show that fermionic baths have advantages over bosonic ones.