Theoretical Study Research Articles

Double transition metal MXenes for enhanced electrochemical applications: Challenges and opportunities

AbstractDouble transition metal (DTM) MXenes are a recently discovered class of two‐dimensional composite nanomaterials with excellent potential in energy storage applications. Since their emergence in 2015, DTM MXenes have expanded their composition boundary beyond traditional single‐metal carbide and nitride MXenes. DTM MXenes offer tunable structures and properties through variations in the constituent transition metals and positioning within the layered lattice. These MXenes can exist in two primary forms: ordered DTMs and solid solutions. The compositional versatility of DTM MXenes offers opportunities to enhance their performance in electrochemical energy storage applications. However, the quality, stability, and surface chemistry of DTM MXenes are influenced by several factors, including the etching process, etchant type, and synthesis route. Currently, limited literature is available on experimentally synthesized DTM MXenes, with most studies focusing on carbide‐based MXenes. Most of the articles have dedicated their efforts only to generalized synthesis strategies. Although extensive theoretical studies have explored the suitability of etchants, synthesis parameters, and methods for producing high‐quality MXene with selective terminal functional groups, their stability issues have not been thoroughly examined. This review addresses various types of DTM MXenes, their synthesis techniques, and the impact of these methods on their physicochemical properties and electrochemical performance. Additionally, it provides a critical analysis of the causes of instability in MXenes, particularly DTMs, from synthesis to application. The challenges associated with these materials are discussed, along with opportunities and prospects for enhancing synthesis, structural tuning, surface modification, and applications in electrochemical energy storage.image

Cr dopant mediates hydroxyl spillover on RuO2 for high-efficiency proton exchange membrane electrolysis

Simultaneously improving the activity and stability of catalysts for anodic oxygen evolution reaction (OER) in proton exchange membrane water electrolysis (PEMWE) remains a notable challenge. Here, we report a chromium-doped ruthenium dioxide with oxygen vacancies, termed Cr0.2Ru0.8O2-x, that drives OER with an overpotential of 170 mV at 10 mA cm−2 and operates stably over 2000 h in acidic media. Experimental and theoretical studies show that the synergy of Cr dopant and oxygen vacancy induces an unconventional dopant-mediated hydroxyl spillover mechanism. Such dynamic hydroxyl spillover from Cr dopant to Ru active site changes the rate-determining step from OOH* formation to O2 formation and thus greatly improves the OER performance. Moreover, the Cr dopant and oxygen vacancy also play a crucial role in stabilizing surface Ru and lattice oxygen in the Ru-O-Cr structural motif. When assembled into the anode of a practical PEMWE device, Cr0.2Ru0.8O2-x enables long-term durability of over 200 h at an ampere-level current density and 60 degrees centigrade.

Non‐Monotonic Variation of the Low Lattice Thermal Conductivity with Temperature in Penta‐HgO2 Sheet

AbstractInspired by the experimental synthesis of bulk HgO2 with the potential of exfoliation to form a penta‐HgO2 sheet composed entirely of pentagonal motifs, a detailed theoretical study on the lattice thermal conductivity by using first‐principles calculations combined with the unified theory of thermal transport is performed. It is found that the penta‐HgO2 sheet is semiconducting with an indirect bandgap of 1.18 eV and possesses a low lattice thermal conductivity of 2.07 W m−1 K−1 (3.28 W m−1 K−1) along the x (y)‐direction at 300 K. More interestingly, the variation of its thermal conductivity with temperature is non‐monotonic, different from most cases. The phonon dispersion, phonon scattering, and phonon coherence is further systematically investigated to understand the underlying physics. This results suggest that the strong intrinsic anharmonicity resulting from its unique atomic configuration with the buckled structure and the heavy element of Hg leads to a high scattering rate, resulting in the ultralow particle‐like thermal transport of 0.20 W m−1 K−1 (0.01 W m−1 K−1) in the x (y)‐direction, while the narrow average frequency interval and strong phonon linewidth are responsible for the dominant coherent thermal transport and non‐monotonic variation of the low lattice thermal conductivity of the penta‐HgO2 sheet.

Theoretical and experimental studies on 2D β-NiS battery-type electrodes for high-performance supercapacitor

Recently, quirky features and eccentric structures of transition metal sulfides have grasped great attention to remove roadblocks and unwrap fresh avenues for electrodes in energy storage devices. Herein, we developed a 2D beta phase nickel sulfide nanosheets (2D β-NiS NSs) electrode with remarkable enhancement in charge storage properties. When served as active electrodes for electrochemical tests, 2D NiS NSs exhibited ultra-high capacitance of 2693 Fg−1 at 1 mVs−1 and specific capacity of 219 mAhg−1 at 1 Ag−1. The symmetric battery type solid-state supercapacitor device comprising 2D β-NiS NSs electrodes exhibits specific capacity of 83.43 mAhg−1at 2 Ag−1 over broad potential range of 0.7V with good cycling performance, and energy and power density of 28.9 Whkg−1 (@ 2 Ag−1) and 21 kWkg−1 (@ 6 Ag−1) respectively. Complementary first-principles density functional theory (DFT) calculations accomplished to explore the electrolyte ion interactions with nickel sulfide nanostructures defining 2D NiS NSs as a potential candidate for real-time applications.

Large Spin Polarization from symmetry-breaking Antiferromagnets in Antiferromagnetic Tunnel Junctions

Efficient detection of the magnetic state is a critical step towards useful antiferromagnet-based spintronic devices. Recently, finite tunneling magnetoresistance (TMR) has been demonstrated in tunnel junctions with antiferromagnetic electrodes, however, these studies have been mostly limited to junctions with two identical antiferromagnet (AFM) electrodes, where the matching of the spin-split Fermi surfaces played critical role. It remains unclear if AFMs can provide a finite net spin polarization, and hence be used as a spin polarizer or detector. In this work, we experimentally fabricate single-sided antiferromagnetic tunnel junctions consisting of one AFM electrode (Mn3Sn) and one ferromagnet (FM) electrode (CoFeB), where the spin polarized tunneling transport from AFM is detected by the FM layer. We observe a high TMR at cryogenic temperature (>100% at 10 K) in these asymmetric AFM tunnel junctions, suggesting a large effective spin polarization from Mn3Sn despite its nearly vanishing magnetization. The large TMR is consistent with recent theoretical studies where the broken symmetry in non-collinear AFMs is predicted to lift the spin degeneracy in the band structure. Our work provides strong evidence that spin polarized electrical transport can be achieved from AFMs.

Sulfur doping induced 3D hierarchical porous BiOI–Bi2S3 S-scheme heterojunction with regulated oxygen vacancies for a four-pronged enhanced photocatalytic degradation towards four representative pollutants

It is challenging and still difficult to adjust and boost the catalytic performance of photocatalysts via the synergistic achievement of heteroatom doping, vacancies engineering, morphology regulation, and appropriate structural design. Herein, we developed an efficient method to synthesize 3D hierarchical porous BiOI–Bi2S3 S-scheme heterojunction with oxygen vacancies (Ov-BBS) induced by sulfur doping and systematically investigated regulation of oxygen vacancies by sulfur doping and their effects on photocatalytic performance. Results showed that sulfur species promoted the formation of S-scheme heterojunction but depleted oxygen vacancies in Ov-BiOI. The optimal sulfur doped catalyst (Ov-BBS-0.1) exhibited excellent UV–vis light photocatalytic activity towards four representative pollutants, affording removal rate of 97.1 % for MB, 97.6 % for RhB, 99.4 % for Cr(VI), and 92.0 % for TC, respectively, which were higher than those of pristine Bi2S3, BiOI, Ov-BiOI, Ov-BiOI/Bi2S3 mixture, Ov-BBS-0.05, and Ov-BBS-0.2. Deep characterizations and theoretical studies certified that the four-pronged enhancement strategy of 3D hierarchical porous structure, oxygen vacancies, sulfur doping and the constructed S-scheme heterojunction, not only enriched accessible active sites, but also promoted electronic polarization and modulated electronic structure, resulting in rapid separation and migration of photogenerated carriers. Moreover, considering the excellent stability and cyclic photocatalytic performance, the film prepared by pumping Ov-BBS dispersion was also satisfactory in the practical application of circulating sewage treatment. Overall, the present work provides a novel approach for the design of more photocatalysts with high efficiency.

A theoretical study of a radiofrequency wave propagation through a realistic turbulent marine atmospheric boundary layer based on large eddy simulation

This study aims at modeling and investigating the impact of realistic turbulence inhomogeneity on radiowave propagation by utilizing large eddy simulations (LES). An up-to-date version of the X-LES method for generating realistic turbulent phase screens is first introduced. It combines atmospheric simulations with the classical Tatarski statistical modeling. This method naturally incorporates vertical turbulence inhomogeneity into phase screens at scales resolved by LES. It is then extended to sub-grid scales by weighting statistically generated phase variations with the vertical profile of the turbulent structure constant extracted from atmospheric data. This method is applied to replicate turbulence of a classical tropical marine atmospheric boundary layer. The impact of the generated medium on the propagation of a 10 GHz spherical wave emanating from a Gaussian aperture is analyzed through a statistical study of log-amplitude profiles performed for three different source altitudes. Results first show that contrary to a classical homogeneous turbulence modeling, log-amplitude profiles resulting from the propagation into inhomogeneous turbulence exhibit a statistical heterogeneity strongly dependent of source altitude. Furthermore, classical stochastic phase screen generation from a homogeneous Von-Kàrmàn Kolmogorov spectrum seems to give a statistically significant underestimation of the actual impact of turbulence compared to the X-LES method.

Design resistance strengths of composite steel box girder bridge using different codes

Bridges design based on prescriptive normative rules regarding loads and their combinations, safety factors, material properties, analysis methods, required verifications, and other issues that are included in design codes. In addition, Composite Steel Box Girder (CSBG) bridges present a prominent structural solution for straight and curved bridges with moderate spans, because of their large bending resistance and high torsional stiffness as well as rapid erection. This paper aims to perform a detailed theoretical comparative study between fundamental calculations of the design resistance strengths of shear, Vn or VRd, and flexure, Mn or MRd, in positive (sagging) and negative (hogging) moment regions, of CSBG highway bridges. The comparison is involved with design specification methodologies proposed by Egyptian Code of Practice (ECP-207-part 6), Bridge Design Specifications (BDS) presented by Association of State Highway and Transportation Officials (AASHTO), and European Standard (EC-4). On its turn, the study aims to standing on differences and similarities between considered standards in the design of such bridges.

Interplay of luminescence and magnetic phenomena in Mn-doped ZnS zinc blende nanocrystals: Influence of magnetic doping

This research comprehensively investigates the interplay between luminescence and magnetic phenomena in the zinc blende phase of manganese-doped and undoped zinc sulfide. The study involves the synthesis of zinc sulfide nanocrystals through a soft chemical method, followed by an in-depth experimental characterization. Theoretical studies were conducted using a 2 × 2 × 2 supercell model with 64 atoms to explore the impact of native defects and manganese doping on zinc sulfide's the electronic, magnetic, and optical properties. The research findings offer a detailed physical description of magnetic and optic phenomena observed, underpinned by a strong correlation between theoretical predictions and experimental results. An essential contribution of this work is developing a depiction that elucidates the relationship between optical transitions and spin-exchange in the context of these phenomena.

Multiexciton spectra of molecular aggregates: application to photosynthetic antenna complexes.

We perform theoretical studies of nonlinear spectral responses of molecular aggregates upon multiple electronic excitations. It is shown that the transient absorption (TA) spectra exhibit gradual shifting to short wavelengths upon an increase in excitation energy accompanied by population of higher-order exciton manifolds. This transformation of the TA profile reflects a character of the exciton splitting and, therefore, is strongly dependent on the aggregate shape and size as well as on the exciton couplings and disorder of the site energies. The theory is applied for modeling of the intensity-dependent TA spectra of a light-harvesting LH1 antenna from a photosynthetic purple bacterium. Fitting of the data allowed verification of the exciton model of the complex (enabling us to differentiate between the correlated (elliptical) and uncorrelated energetic disorder). We found that the difference between the TA spectra corresponding to the absorption of one and two quanta suggests the presence of strong uncorrelated disorder (in agreement with earlier models of bacterial LH1/LH2 antennas). Nonlinear spectroscopy with multiple excitations may also be useful for exploring the exciton structure of other photosynthetic antennas and similar molecular systems.

Theoretical Study of Metal-Ligand Interactions in Lead Complexes with Radiopharmaceutical Interest.

The 203Pb and 212Pb lead radioisotopes are attracting growing interest as they can aid in the development of personalized, targeted radionuclide treatment for advanced and currently untreatable cancers. In the present study, the bonding interactions of Pb2+ with twelve macrocyclic ligands, having an octa and nona coordination, were assessed using Density Functional Theory (DFT) calculations. The molecular structures in an aqueous solution were computed utilizing the polarized continuum model. The preference for the twisted square antiprismatic (TSAP) structure was confirmed for ten out of the eleven cyclen-based complexes. The characteristics of the bonding were assessed using a Natural Energy Decomposition Analysis (NEDA). The analysis revealed a strong electrostatic character of the bonding in the complexes, with minor variations in electrical terms. The charge transfer (CT) had a comparable energetic contribution only in the case of neutral ligands, while in general, it showed notable variations regarding the various donor groups. Our data confirmed the general superiority of the carboxylate O and aromatic N donors. The combination of the selected efficient pendant arms pointed out the superiority of the acetate pendant arms and the lack of significant cooperation between the different pendant arms in the probed ligands. Altogether, the combination led only to a marginal enhancement in the total CTs in the complexes.

Thermal tides in the middle atmosphere at mid-latitudes measured with a ground-based microwave radiometer

Abstract. In recent decades, theoretical studies and numerical models of thermal tides have gained attention. It has been recognized that tides have a significant influence on the dynamics of the middle and upper atmosphere; as they grow in amplitude and propagate upward, they transport energy and momentum from the lower to the upper atmosphere, contributing to the vertical coupling between atmospheric layers. The superposition of tides with other atmospheric waves leads to non-linear wave–wave interactions. However, direct measurements of thermal tides in the middle atmosphere are challenging and are often limited to satellite measurements in the tropics and at low latitudes. Due to orbit geometry, such observations provide only a reduced insight into the short-term variability in atmospheric tides. In this paper, we present tidal analysis from 5 years of continuous observations of middle-atmospheric temperatures. The measurements were performed with the ground-based temperature radiometer TEMPERA (TEMPErature RAdiometer), which was developed at the University of Bern in 2013 and was located in Bern (46.95° N, 7.45° E) and Payerne (46.82° N, 6.94° E). TEMPERA achieves a temporal resolution of 1–3 h and covers the altitude range between 25–50 km. Using an adaptive spectral filter with a vertical regularization (ASF2D) for the tidal analysis, we found maximum amplitudes for the diurnal tide of approximately 2.4 K, accompanied by seasonal variability. The maximum amplitude was reached on average at an altitude of 43 km, which also reflected some seasonal characteristics. We demonstrate that TEMPERA is suitable for providing continuous temperature soundings in the stratosphere and lower mesosphere with a sufficient cadence to infer tidal amplitudes and phases for the dominating tidal modes. Furthermore, our measurements exhibit a dominating diurnal tide and smaller amplitudes for the semidiurnal and terdiurnal tides in the stratosphere.

Shear behavior of reinforced concrete beams with high-strength reinforcements after high temperatures

This paper investigates the effect of steel reinforcement configured with different strengths after different high temperatures on the shear performance of the test beams, a total of 20 reinforced concrete (RC) beams, through experiments, numerical analyses and theoretical studies, in order to understand the key factors affecting the shear performance of the beams. The test revealed that the mechanical properties of concrete and steel reinforcement showed a trend of increasing and then decreasing after high temperatures. Increasing the stirrup ratio and stirrup strength can significantly improve the crack resistance and shear capacity of the beams, as well as the deformation performance of the beams. The residual shear strengths of test beams with high-strength stirrups after exposure to high temperatures are significantly greater than those of ordinary reinforced concrete beams. Specifically, the shear capacity of beams with high-strength stirrups after exposure to 800°C increased by 23.7% compared to ordinary beams, and the mid-span deflection performance increased by 28.7%. The stresses in the shear span region of the test beams after high temperature were more concentrated at the diagonal and the number of cracks was significantly reduced. In this paper, a simplified formula for calculating the residual shear capacity of RC beams after room and high temperatures is proposed, which can well predict the test results.

Multicolor Emission in o-Carborane Derivatives Induced by Conformation Diversity through C-C Double Bond Substitution.

Rationally designed molecules with versatile conformations are ideal candidates for creating challenging single component-based multicolor emissive materials. Herein, a new strategy is presented by introducing a C-C double bond in an o-carborane derivative. Compared to a linear connection using a C-C triple bond (CbPyY), a C-C double bond connection (CbPyE) exhibited a zigzag structure and unique fluorescence behavior. Yellow, yellowish orange, and red crystals or films of CbPyE can be obtained, while only orange ones of CbPyY were achieved under the same condition. Single crystal XRD and theoretical calculation studies revealed the zigzag structure brings asymmetry to one arm of CbPyE, which causes conformation diversity and leads to the multicolor emission. Interestingly, different emissions showed different responses to acetone vapor; the yellow one showed much higher sensitivity and faster response than the other two. It is believed that the prepared materials and the proposed strategy would contribute to future advances in single-fluorophore-based multicolor emissive materials.

Synthesis and Comprehensive Studies of Be‐IV‐N2 (IV=Si, Ge): Solving the Mystery of Wurtzite‐Type Pmc21 Structures

AbstractThe research for wurtzite‐type ternary nitride semiconductors containing earth abundant elements with a stoichiometry of 1 : 1 : 2 was focused on metals like Mg or Zn, so far. The vast majority of these Grimm–Sommerfeld analogue compounds crystallize in the β‐NaFeO2 structure, although a second arrangement in space group Pmc21 is predicted to be a viable alternative. Despite extensive theoretical and experimental studies, this structure has so far remained undiscovered. Herein, we report on BeGeN2 in a Pmc21 structure, synthesized from Be3N2 and Ge3N4 using a high‐pressure high‐temperature approach at 6 GPa and 800 °C. The compound was characterized by powder X‐ray diffraction (PXRD), solid state nuclear magnetic resonance (NMR), Raman and energy dispersive X‐ray (EDX) spectroscopy, temperature‐dependent PXRD, second harmonic generation (SHG) and UV/Vis measurements and in addition also compared to its lighter homologue BeSiN2 in all mentioned analytic techniques. The synthesis and investigation of both the first beryllium germanium nitride and the first ternary wurtzite‐type nitride crystallizing in space group Pmc21 open the door to a new field of research on wurtzite‐type related structures.

Ab initio study of Z(N) = 6 magicity

Abstract The existence of magic numbers of protons and neutrons in nuclei is essential for understanding nuclear structure and fundamental nuclear forces. Over decades, researchers have conducted theoretical and experimental studies on the new magic number { $Z(N) = 6$}, focusing on observables such as radii, binding energy, electromagnetic transition, and nucleon separation energies. We perform the {\it ab initio} no-core shell model calculations for the occupation numbers of {the lowest} single particle states in {the ground states of} {$Z(N)=6$ and $Z(N)=8$ isotopes (isotones)}. Our calculations do not support {$Z(N)=6$} as a magic number over a span of atomic numbers. However, $^{14}$C and $^{14}$O exhibit the characteristics of double-magic nuclei.

Boosting the Stability of Subnanometer Pt Catalysts by the Presence of Framework Indium(III) Sites in Zeolite.

Subnanometer metal clusters show advantages over conventional metal nanoparticles in numerous catalytic reactions owing to their high percentage of exposed surface sites, abundance of under-coordinated metal sites and unique electronic structures. However, the applications of subnanometer metal clusters in high-temperature catalytic reactions (>600 °C) are still hindered, because of their low stability under harsh reaction conditions. In this work, we have developed a zeolite-confined bimetallic PtIn catalyst with exceptionally high stability against sintering. A combination of experimental and theoretical studies shows that the isolated framework In(III) species serve as the anchoring sites for Pt species, precluding the migration and sintering of Pt species in the oxidative atmosphere at ≥650 °C. The catalyst comprising subnanometer PtIn clusters exhibits long-term stability of >1000 h during a cyclic reaction-regeneration test for ethane dehydrogenation reaction.

Theoretical study of adsorption of gas (CO, CO2, NH3) by metal (Au, Ag, Cu)-doped single-layer WS2.

The adsorptions of gas (CO, CO2, NH3) by metal (Au, Ag, Cu)-doped single layer WS2 are studied by density functional theory. The doping of metal atoms makes WS2 behave as n-type semiconductors. The final adsorption sites for CO, CO2, and NH3 are close to the atomic sites of the doped metal. The adsorptions of CO and NH3 gases on Cu/WS2, Ag/WS2, and Au/WS2 are dominated by chemisorption. The doped metal atoms enhance the hybridization of the substrate with the gas molecular orbitals, which contributes to the charge transfer and enhances the adsorption of the gas with the material surface. The adsorptions of CO and NH3 on Cu/WS2 and Ag/WS2 allow favorable desorption in a short time after heating. The single-layer Cu/WS2 is proved to have the potential to be used as a reliable recyclable sensor for CO. This work provides a theoretical basis for developing high-performance WS2-based gas sensors. In this paper, the adsorption energy, electronic structure, charge transfer, and recovery time of CO, CO2, and NH3 in the doped system have been investigated based on the CASTEP code of density functional theory. The exchange correlation function used is the Perdew-Burke-Ernzerhof (PBE) generalized gradient approximation (GGA). The TS (Tkatchenko-Scheffler) dispersion correction method was used to involve the effects of van der Waals interaction on the adsorption energies for all adsorption system. The ultrasoft pseudopotentials are chosen and the plane-wave cut-off energies are set to 500eV. The k-point mesh generated by the Monkhorst package scheme is used to perform the numerical integration of the Brillouin zone and 5 × 5 × 1k-point grid is used. The tolerances of total energy convergence, maximum ionic force, ionic displacement, and stress component are 1.0 × 10-5eV/atom, 0.03eV/Å, 0.001Å, and 0.05 GPa, respectively.

The Role of Print Media in Shaping Public Health Outcomes: A Comprehensive Review

This theoretical study investigates how health-related material in print media affects public health by synthesising current data to grasp its influence in determining public health results. Even with the digital revolution, print media including newspapers, periodicals, and pamphlets remains a major source of information. Key topics include the spread of health information, the way health concerns are framed, and the impact on public perspective and behaviour are underlined in the review. Research show that print media may influence health policy debate, increase knowledge of health concerns, and encourage good practices. Still, these results are much influenced by the accuracy, bias, and depth of the material. Print media's health-related material reflects more general social, economic, and political settings, therefore impacting its presentation and reception. Moreover, the different degrees of media literacy among the people help to control the influence of such material. The evaluation also covers ethical obligations of print media in health communication as well as the possibility of false information. This study offers a complete framework for comprehending the intricate interaction between print media and public health by combining theoretical viewpoints from psychology, public health, and communication studies. The results underline the importance of planned, evidence-based health communication in print media to improve its favourable influence on public health outcomes.

Emergence of high-mass stars in complex fiber networks (EMERGE). IV. Environmental dependence of the fiber widths

Despite their variety of scales throughout the interstellar medium, filaments in nearby low-mass clouds appear to have a characteristic width of sim 0.1 pc from the analysis of Herschel observations. The validity and origin of this characteristic width, however, has been a matter of intense discussions during the last decade. We made use of the EMERGE Early ALMA Survey comprising seven targets among low- (OMC-4 South, NGC 2023), intermediate- (OMC-2, OMC-3, LDN 1641N), and high-mass (OMC-1, Flame Nebula) star-forming regions in Orion, which include different physical conditions, star formation histories, mass, and density regimes. All targets were homogeneously surveyed at high-spatial resolution (4.5 or sim 2000 au) in N$_2$H$^+$ (1$-$0) using a dedicated series of ALMA+IRAM-30m observations, and previous works identified a total of 152 fibers throughout this sample. Here, we aim to characterise the variation in the fiber widths under the different conditions explored by this survey. We characterised the column density and temperature radial profiles of fibers using the automatic fitting routine FilChap, and systematically quantified its main physical properties (i.e. peak column density, width, and temperature gradient). The Orion fibers show a departure from the isothermal condition with significant outward temperature gradients with $ T_ K > 30$ K pc$^ $. The presence of such temperature gradients suggests a change in the equation of state for fibers. By fitting their radial profiles, we report a median full width at half maximum ($FWHM$) of $ 0.05$ pc for the Orion fibers, with a corresponding median aspect ratio of $ Along with their median, the $FWHM$ values for individual cuts are consistently below the proposed characteristic width of 0.1 pc. More relevantly, we observe a systematic variation in these fiber $FWHM$ between different regions in our sample. We also find a direct inverse dependence of the fiber $FWHM$ on their central column density, $N_0$, above $ $ cm$^ $, which agrees with the expected $N_0-FWHM$ anti-correlation predicted in previous theoretical studies. Our homogeneous analysis returns the first observational evidence of an intrinsic and systematic variation in the fiber widths across different star-forming regions. While sharing comparable mass, length, and kinematic properties in all of our targets, fibers appear to adjust their $FWHM$ to their density and to the pressure in their host environment.