Textile Finishing Research Articles

The Applications of Microencapsulation in Different textile Finishing

The Applications of Microencapsulation in Different textile Finishing

Domesticating Colour in the Early Modern Age: Dyeing Wool in Black in Portugal

Mastering a colour—as such, its ‘domestication’—involves a weft of technological and symbolic relationships encompassed in the human ability to reproduce a visible colour using the techniques of textile dyeing. The Regimento dos panos or Regimento dos trapeiros (‘regulation of fabrics’ or ‘regulation of drapers’), published in 1573 and expanded in 1690, is a document made up of 107 chapters aiming to standardise the various stages of the production chain of woollen goods in Portugal. In the sections relating to the finishing of fabrics, the regulation carefully details the dyeing of the colour black. The main aim of this text is to discuss the four recipes presented in that document. The system presupposed a phase exogenous to the rules, since the fabrics had to be previously dyed blue (‘celestial blues’) by means of successive immersions of the cloth in a vat with indigo. The dyeing itself was achieved by mixing mordants and auxiliaries (alum, tartar, iron sulphate, and tannins) with a red dye (madder). The main conclusion is that the formulae presented do not constitute, in their general principles, a characteristic Portuguese methodology. In addition, the article includes an inventory of the raw materials used for dyeing in the Early Modern Age, produced, through a qualitative method, through cross-reference with other manuscript and printed sources, as well as an interpretation of their social and economic importance, and a systematisation of the types of Portuguese wools.

Study on the Modification and Properties of Silk Sericin Protein/Nano-Titanium Dioxide Composite for Textile Applications

Abstract Silk sericin protein is a natural high-molecular-weight compound that contains eighteen types of amino acids. It is non-toxic, biodegradable, and biocompatible, with simple preparation methods and low cost. It finds widespread application in functional clothing, medical and pharmaceutical fields, tissue engineering, and more. Nano-titanium dioxide, on the other hand, possesses non-toxic, self-cleaning, antibacterial, and deodorizing properties. To develop multifunctional textiles with deodorization, UV protection, and good thermal and mechanical properties, this study utilized a compounding method to modify citric acid-pre-treated cotton fabrics through a two-dipping and two-padding process using a blend finishing solution of silk sericin protein and nano-titanium dioxide. Observations of the microstructure before and after fabric finishing, along with evaluations of deodorization, UV protection, and thermal properties, revealed that controlling the proportion of the silk sericin protein/nano-titanium dioxide blend finishing solution can result in a smooth surface of the modified cotton fabric. This modification not only enhances the fabric’s UV protection and tensile strength but also improves its thermal properties while imparting certain deodorization capabilities. Comprehensive analysis concludes that using silk sericin protein and nano-titanium dioxide for modifying cotton fabric to prepare multifunctional textiles with deodorization, UV protection, and good thermal and mechanical performance is feasibly viable.

Natural dyeing and anti bacterial finishing of cotton fabric with extracts from Justicia schimperiana leaf extract: a step towards sustainable dyeing and finishing

ABSTRACT The use of non-toxic and eco-friendly natural dyes on textiles has received much attention due to the increased environmental awareness to avoid some hazardous synthetic dyes. In the present study, an eco-friendly approach was developed to impart colour and antibacterial properties to cotton fabrics dyed with Justicia schimperiana leaf extract as a non-toxic natural colourant. The solvent method of extraction and exhaust dyeing method was used for this study. Copper sulphate, ferrous sulphate, and alum were applied in a simultaneous -mordanting process as a mordanting agent. The effects of shade percentage, dyeing temperature, and dyeing time on the obtained colour strength of the fabrics were investigated. Optimisation of dyeing conditions was carried out using Box Behnken design of expert software. An optimum level of 3. 28 colour strength (K/S) was observed in the sample treated with a shade percentage of 50 (% o.w.f), 72 °C dyeing temperature, and 45 minutes of dyeing time. Antibacterial properties of treated fabrics were evaluated against common pathogenic bacteria, Staphylococcus aureus (Gram-positive) and Escherichia coli (Gram-negative). The results indicated the treated fabrics possessed desirable antibacterial properties. The washing and rubbing fastness of the dyed fabrics were also reported.

Eco-friendly and sustainable application of gardenia yellow extraction as natural dye source for dyeing and bio-functional finishing of cotton fabric

Eco-friendly and sustainable application of gardenia yellow extraction as natural dye source for dyeing and bio-functional finishing of cotton fabric

Sustainable Dyeing of Wool and Silk with Conocarpus erectus L. Leaf Extract for the Development of Functional Textiles

Natural dyes derived from plants offer a sustainable alternative to synthetic dyes for textile coloration. This study examined the extraction of natural dyes from Conocarpus erectus L. leaves and their application on wool and silk fabrics. Aqueous extraction in an alkaline medium was used to obtain dyes from raw leaves, which were then applied to pre-mordanted silk and wool fabrics by applying the ultrasonic-assisted exhaust dyeing method. The dyed fabrics were evaluated for color strength (K/S) and CIELAB color coordinates. The color fastness (washing, rubbing, and light), ultraviolet protection factor, mosquito repellency, and antibacterial activity were established using standard testing protocols. The surface morphologies of silk and wool were examined using scanning electron microscopy. Interestingly, the dyed fabrics displayed good color strength and color fastness properties. Moreover, the dyed wool samples revealed satisfactory antibacterial activity against Gram-negative (E. coli) and Gram-positive (S. aureus) in both qualitative and quantitative assessment methods, good ultraviolet protection in terms of UPF, and good mosquito repellency against Aedes aegypti. This study for the first time presented the application of a medicinal plant (Conocarpus erectus L.) in the field of textile dyeing and finishing. Hence, the use of Conocarpus erectus L. leaf dyes offers significant results on wool and silk fabrics and contributes to sustainable functional textile production.

Advancing Antimicrobial Textiles: A Comprehensive Study on Combating ESKAPE Pathogens and Ensuring User Safety.

Antibiotic-resistant bacteria, ESKAPE pathogens, present a significant and alarming threat to public health and healthcare systems. This study addresses the urgent need to combat antimicrobial resistance by exploring alternative ways to reduce the health and cost implications of infections caused by these pathogens. To disrupt their transmission, integrating antimicrobial textiles into personal protective equipment (PPE) is an encouraging avenue. Nevertheless, ensuring the effectiveness and safety of these textiles remains a persistent challenge. To achieve this, we conduct a comprehensive study that systematically compares the effectiveness and potential toxicity of five commonly used antimicrobial agents. To guide decision making, a MULTIMOORA method is employed to select and rank the optimal antimicrobial textile finishes. Through this approach, we determine that silver nitrate is the most suitable choice, while a methoxy-terminated quaternary ammonium compound is deemed less favorable in meeting the desired criteria. The findings of this study offer valuable insights and guidelines for the development of antimicrobial textiles that effectively address the requirements of effectiveness, safety, and durability. Implementing these research outcomes within the textile industry can significantly enhance protection against microbial infections, contribute to the improvement of public health, and mitigate the spread of infectious diseases.

Synthesis of novel azo pyrazole disperse dyes for dyeing and antibacterial finishing of PET fabric under supercritical carbon dioxide

Supercritical carbon dioxide (scCO2) has been suggested as a good substitution to environmentally harmful water-based tincturing. The present study describes the successful synthesis of some biologically active dispersion tinctures for supercritical carbon dioxide tincturing of polyester fabric. The coupling of 1-cyanoacetylpiperidine (1) with the diazonium salt of aryl amine derivatives (2a–d) produced 1-((aryldiazenyl) cyanoacetyl piperidines (3a–d). To create the derivatives of 4-(phenyldiazenyl)-5-(piperidin-1-yl)-1H-pyrazol-3-amine (5a), the propane nitriles (3a–d) were condensed with hydrazine hydrate. However, the unexpected 3-aminopyrazol-5-ol yellow–red dispersion dyes (4a–d) were identified as the reaction results. The MS, IR, and NMR spectra were used to describe the novel dyes, and the results exactly matched the suggested structures. The antibacterial test, which was conducted using the AATCC method, revealed that some of the compounds (3a–d) and (4a–d) had impressive antibacterial capabilities against the researched +ve and gram −ve bacteria. For eight dyestuffs, the dyeability, color strength, and color fastness of the tincturing process were evaluated. The evaluation focused on determining color uptake using a gauge for color strength (K/S). All dyes displayed excellent rubbing, washing, and light fastness (color change and staining grade of 4–5).

Agricultural waste Ipomoea batatas leaves for low-temperature dyeing and functional finishing of polyester fabrics

The increasing focus on eco-friendly textiles and cleaner production manufacturing techniques have made natural pigments for coloring and enhancing the functionality of textiles become a popular trend. This research aimed to extract plant pigment from bio-waste Ipomoea batatas leaves and utilize it for dyeing and functional decoration of polyester fabric at low temperature. The study optimized the parameters for pigment extraction and fabric dyeing and also investigated the stability of the pigment solution. The finding indicated that strong acids and bases, intense light, high temperatures, and oxidants have a greater impact on pigment stability. Observation and analysis using SEM, bio-optical microscope, FTIR, and UV–vis–NIR absorption spectroscopy revealed that chlorophyll pigment entered into the interior of polyester molecular chains through hydrophobic end intercalation and was retained by the physical forces, enabling low-temperature coloring and functional finishing of polyester fabrics. As a result, the polyester fabrics dyed with natural pigment exhibited excellent resistance to rubbing, washing, saliva, and perspiration (rated at level 4 or higher), except for the average light fastness (only grade 4). Additionally, the dyed polyester fabrics demonstrated outstanding UV resistance (UPF of 33.57 for raw polyester and 120.77 for pre-mordant dyed polyester) and antibacterial properties (raw polyester agar plates showed bacterial growth, while the colored polyester agar plates had almost no bacterial growth). Even after 10 wash cycles, the dyed polyester fabrics maintained their UV protection and antibacterial properties. This research is expected to provide a new approach to the valuable utilization of agricultural residues in the textile industry.

Role of transition metals in coinage metal nanoclusters for the remediation of toxic dyes in aqueous systems.

A difficult issue in chemistry and materials science is to create metal compounds with well-defined components. Metal nanoclusters, particularly those of coinage groups (Cu, Ag, and Au), have received considerable research interest in recent years owing to the availability of atomic-level precision via joint experimental and theoretical methods, thus revealing the mechanisms in diverse nano-catalysts and functional materials. The textile sector significantly contributes to wastewater containing pollutants such as dyes and chemical substances. Textile and fabric manufacturing account for about 7 × 105 tons of wastewater annually. Approximately one thousand tons of dyes used in textile processing and finishing has been recorded as being discharged into natural streams and water bodies. Owing to the widespread environmental concerns, research has been conducted to develop absorbents that are capable of removing contaminants and heavy metals from water bodies using low-cost technology. Considering this idea, we reviewed coinage metal nanoclusters for azo and cationic dye degradation. Fluorometric and colorimetric techniques are used for dye degradation using coinage metal nanoclusters. Few reports are available on dye degradation using silver nanoclusters; and some of them are discussed in detailed herein to demonstrate the synergistic effect of gold and silver in dye degradation. Mostly, the Rhodamine B dye is degraded using coinage metals. Silver nanoclusters take less time for degradation than gold and copper nanoclusters. Mostly, H2O2 is used for degradation in gold nanoclusters. Still, all coinage metal nanoclusters have been used for the degradation due to suitable HOMO-LUMO gap, and the adsorption of a dye onto the surface of the catalyst results in the exchange of electrons and holes, which leads to the oxidation and reduction of the adsorbed dye molecule. Compared to other coinage metal nanoclusters, Ag/g-C3N4 nanoclusters displayed an excellent degradation rate constant with the dye Rhodamine B (0.0332 min-1). The behavior of doping transition metals in coinage metal nanoclusters is also reviewed herein. In addition, we discuss the mechanistic grounds for degradation, the fate of metal nanoclusters, anti-bacterial activity of nanoclusters, toxicity of dyes, and sensing of dyes.

One pot application of a green chemistry-based finish for cotton fabric, providing hydrophobic, flame retardant, and antimicrobial properties.

Fluorinated and formaldehyde-based compounds impart excellent hydrophobicity and flame-retardant properties to cotton fabrics. However, they come with various health and environmental risks. A novel hydrophobic, flame retardant, and antimicrobial finishing agent free from fluorine and formaldehyde was synthesized. The diammonium phosphate octadecyl citrate (DAPOC) was synthesized by using stearic acid (octadecanoic acid), citric acid (propane-1,2,3-tricarboxylic acid), and diammonium hydrogen phosphate. It was grafted onto the cotton fabrics by employing the conventional pad-dry-cure method. The results indicated that this newly developed finish could be chemically bonded to cotton fabrics through C-O-C covalent bonds. The contact angle of the cotton fabric finished with a 12% concentration of the finishing agent reached 151.9°. Additionally, the finished cotton fabrics displayed evident flame-retardant properties. After undergoing 20 laundering cycles, DAPOC maintained strong hydrophobic and flame-retardant characteristics, demonstrating its durability. The chemical structure of DAPOC was verified by nuclear magnetic resonance spectroscopy (1H-NMR). The thermogravimetric analysis confirmed the flame-retardant nature of the treated cotton fabric samples. Scanning electron microscopy (SEM), Energy dispersive X-ray analysis (EDX), and Fourier-transform infrared spectroscopy (FTIR) results demonstrated the successful grafting of the newly created finish onto the cotton fiber. X-ray diffraction (XRD) spectra depicted that the crystalline structure of finished cotton fabric remained mostly unaltered. Furthermore, the finished cotton fabric exhibited commendable antimicrobial properties due to the inclusion of citric acid.

Multipurpose pigment printing and functional finishing of cellulosic fabrics

AbstractFunctional fabrics that are economical and environmentally friendly are desired for many applications. Here in, individual inclusion of different additives, such as softeners, polyurethane, polyethylene glycol (PEG‐600) and benzophenone in suitable pigment printing formulation were applied to various cellulose containing fabrics, using flat screen and microwave curing methods. The imparted multifunctional and performance finishes to cellulosic fabrics namely ultraviolet (UV) protection, antibacterial, anti‐crease, and softening were evaluated. The developed functional properties and the depth of the pigment prints produced are governed by the nature of the substrate, concentration/location/distribution in addition to fixation of the added active compounds and pigment colourants. The surface alteration, morphological modifications, and immobilisation of the certain active components onto the printed substrates have been confirmed by scanning electron microscopy and energy‐dispersive X‐ray spectroscopy analysis for selected samples.

Sustainable Dyeing and Functional Finishing of Cotton Fabric by Rosa canina Extracts

This paper presents a comprehensive study on a novel ultrasound-assisted extraction process for Rosa canina, utilizing both dry and fresh fruits, and explores the potential application of Rosa canina extraction as a natural dye and functional agent for cotton fabrics. The ultrasound-assisted extraction employed different solvents, including distilled water, methanol, and a water/methanol mixture (50/50% v/v), conducted at 60 °C for 60 min. The extracted compounds were characterized through ultraviolet–visible (UV-Vis) spectroscopy and high-performance liquid chromatography with ultraviolet spectroscopy (HPLC-UV) analysis to assess the chemical composition. Textile applications were then performed using bio-mordant chitosan in a pre-mordanting process, and the treated cotton fabrics underwent analysis for surface chemistry and chemical composition using Fourier-transform infrared spectroscopy (FTIR). Untreated and treated fabrics, both with and without mordant, were evaluated for their UV protection and antibacterial properties. Color measurements and dyeability properties of the extractions were also assessed. Furthermore, waste solutions from textile applications were analyzed by UV-Vis spectroscopy to investigate the potential transfer of active compounds to the fabrics. Results indicate that Rosa canina, as a plant-based extract, holds significant potential for sustainable dyeing and functional finishing of cotton fabrics.

Novel enrichment in biobased monomers of waterborne polyurethane dispersions as a textile finishing agent for poly-cotton fabrics

This study introduces a novel biobased textile finishing agent synthesized as waterborne polyurethane dispersions (FCCB-WPUDs), utilizing bio-based monomers like fenugreek oil-based polyol, corn oil-derived emulsifier, and cellulose acetate butyrate (CAB) chain extender. The FCCB-WPUDs were prepared through the prepolymer polymerization method and characterized using FTIR, TGA, DMA, SEM, DLS, and swelling tests. Their application to poly-cotton fabrics significantly improved various fabric properties. The enhancements included increased washing fastness (from 3/4 ± 0.01 to 4 ± 0.02 for dyed and 3 ± 0.02 to 4/5 ± 0.02 for printed fabrics), rubbing fastness (from 3 ± 0.02 to 4/5 ± 0.03 for dyed and 4 ± 0.02 to 4/5 ± 0.03 for printed fabrics), and perspiration fastness (from 3 ± 0.02 to 4 ± 0.03 for acidic dyed and 3/4 ± 0.02 to 4 ± 0.02 for alkaline printed fabrics). Additionally, tear strengths improved significantly (from 13.66 ± 0.04 N/m to 20.53 ± 0.06 N/m for warp dyed and 10.85 ± 0.06 N/m to 15.14 ± 0.06 N/m for warp printed fabrics), along with tensile strengths (from 327 ± 5.38 N/m to 361 ± 3.26 N/m for warp dyed and 357 ± 5.34 N/m to 449 ± 4.90 N/m for warp printed fabrics). These improvements correlated with increasing CAB moles as a chain extender. This research presents a cost-effective and simple biobased method for textile finishing, offering an alternative to petrochemical-based monomers in conventional WPUD preparation.

Comparison of conventional and digital lectures and examinations with respect to the conditions after COVID-19 period – an example for a bachelor lecture on textile finishing

Due to the appearance of COVID-19, many lectures and examinations at universities are forced to digital formats. In the first post-pandemic semester again, the change from digital to conventional lectures was demanded. By this background the question arises, what is the better format for lecture and exam – digital or conventional? This question is discussed on the example of a bachelor lecture on textile finishing for the time period from 2019 to 2023. The combination of digital lecture and digital exam leads to strong participation numbers and by this to more successfully passing students. If the exam is done as conventional written text, the influence if the lecture is digital or conventional is weak. Also, the numbers of passing students or the finally achieved mark are mainly not dependent on the type of lecture format. Finally, it can be state that a digital lecture is more successful if there are also digital parts in the examination. Also, the return to conventional lectures and exams after the pandemic period is possible without influencing the student performance compared to pre-pandemic situation.

Altered Properties: Introducing a Novel Circular Cellulose–Based Binder for Printing Textile Finishes

Altered Properties: Introducing a Novel Circular Cellulose–Based Binder for Printing Textile Finishes

Eco-friendly fire-retardant finishing of cotton fabric with mixture of ammonium sulfamate and sodium Stannate with and without zinc acetate as external reagent

Eco-friendly fire-retardant finishing of cotton fabric with mixture of ammonium sulfamate and sodium Stannate with and without zinc acetate as external reagent

Evaluation of solanum tuberosum potato peel waste for use as an eco-friendly antibacterial finish for cotton fabrics

Purpose This study aims to investigate the potential use of potato peel extracts as antibacterial finishes for cotton fabrics against Staphylococcus aureus and Escherichia coli. Potato peels are abundant as waste and provide a natural, cheaper and sustainable alternative means of preventing the spread of bacterial infections on cotton fabric. Design/methodology/approach This research included the characterization of potato peel extracts, application of the extract onto cotton fabric and efficacy testing of the treated cotton fabric against bacteria. Phytochemical screening, agar well diffusion antibacterial test, minimum inhibitory concentration and Fourier transform infrared (FTIR) tests were used to characterize the extract. Antibacterial efficacy of the treated fabric was determined qualitatively using the disc diffusion assay and quantitatively using the bacteria reduction test. Findings Phytochemical screening confirmed the presence of several secondary metabolites including phenols and flavonoids. Antibacterial tests revealed a positive response in Escherichia coli and Staphylococcus aureus with a zone of inhibition of 6.50 mm and 5.60 mm, respectively. Additional peaks on the FTIR spectroscopy confirmed the presence of potato peel extract on the treated cotton fabric. The treated cotton fabrics showed efficacy against Staphylococcus aureus and Escherichia coli up to 20 washes. Originality/value This study introduced the application of potato peel extracts onto cotton fabrics and assessment of the antibacterial properties before and after washing. Results of this study suggest that potato peel extracts can be used as an organic eco-friendly antibacterial finish for cotton fabrics.

An eco-friendly technique for shrink-resist finishing of dyed wool via combined use of hydrolase and cyclamate

Savinase 16L as a type of mature protease for shrink-resist finishing can effectively hydrolyze wool scales, but it is also easy to penetrate into the cell membrane complex (CMC) layer, even easily causing undesired fiber damages. In this study, Savinase 16L was combinedly used with a protective agent of cyclamate, achieving an increase in the size of enzyme protein molecules through the intermolecular forces. This combined operation was intended to make it difficult for protease to enter the CMC layer, conferring protease a more concentrated actions towards wool scales. Meanwhile, a commercial keratinase was applied for wool pretreatment to loosen the structural integrity by hydrolyzing the disulfide bonds in wool scales. The combination use of hydrolase (20 U/mL of keratinase, and 6.5 U/mL protease) and 10 g/L cyclamate endowed the dyed wool fabric with encouraging shrink-resist property, achieving a felting shrinkage of 5.4% ± 0.55% with an acceptable strength loss of 12.3% ± 1.2%. More importantly, color hue of the wool fabric almost did not change compared with to that with chlorination method. As an eco-friendly and energy-saving strategy, it provides an efficient alternative for shrink-resist finishing of white and dyed wool fabrics, and expands the application of biotechnology in wool industry.

Flame retardant textile finishing: thermal analysis and dermal security

Many flame retardants (FRs) are brominated, and many of them are considered toxic, persistent and/or bio accumulative. A switch to non-halogenated alternatives for textile finishing is considered beneficial, but there is little knowledge about their environmental impact, their health risks during the production process and those in their final use. A conventional and an alternative FR (based on dialkyl phosphono carboxylic acid amine and ammonium sulfamate; urea and organophosphonate PO(OH)2-R-PO(OH)2, respectively) were applied to cotton fabrics that could be in touch with the skin in their final use. Burning and thermal behaviors and dermal toxicity when exposed to skin rubbing are evaluated. Fabrics treated show that both FR products act as FRs. The increase in the thermal stability of the tissue that causes an increase in the decomposition temperature is a relevant effect associated with the application of the conventional FR in the tissue, while the most important effect of the alternative FR lies in the increase of the residue at 600°C, associated with the generation of fewer volatiles, which has an impact on the intensity of combustion. The study of the dermal toxic potential of FR-treated cotton bed sheets showed that the two tested products do not penetrate into the skin when applied under the conditions used and were safe when in contact with the skin. Moreover, the alternative FR seems to be safer when in contact with the skin considering also its higher concentration in the textile.