Terrigenous Sediment Input Research Articles

OSL and radiocarbon dating of core TBF-1 on the outer shelf of the East China Sea and implications for late Quaternary stratigraphic correlation

It is crucial to establish a robust chronology for understanding late Quaternary sedimentation processes and environment changes in response to sea-level fluctuation on shelves. The shelf of the East China Sea (ECS) is featured by huge terrigenous sediment input and striking land -sea interaction during the late Quaternary. However, there remains controversy in chronostratigraphic rebuilding of transgression and regression deposits during eustatic-glacial cycles, mainly due to a lack of reliable dating data. In this study, an extensive comparison of 17 optically stimulated luminescence (OSL) and 15 AMS 14C ages from core TBF-1 (upper 40 m) provides a constraint in chronostratigraphic reconstruction since Marine Isotope Stage (MIS) 5. OSL ages range from 9.5 ± 0.7 to 67.3 ± 4.8 ka at depths from 2.00 to 28.00 m, while 14C ages range from 6645 to 41435 cal a BP at depths from 0.02 to 17.52 m. Regression analysis demonstrates a high level of agreement between OSL and 14C ages, with r2 values of 0.91 and 0.90, respectively. For Holocene sediments (U1), both OSL and 14C methods are applicable in tidal sand ridges, however, it should be noted that 14C ages may exhibit a young bias of up to 3 ka. For pre-Holocene sediments (U6-U2), OSL ages are robust within saturation limitation of OSL signal (De up to ca. 166 Gy), cross-checked by feldspar post-IR IRSL (pIRIR) dating protocol. Nevertheless, the shell 14C ages (11620 and 10390 cal a BP at depths of 13.95–14.56 m) in Last Glacial Maximum (LGM) fluvial sediments of U2 are significantly underestimated, because of their susceptibility to recrystallization and overgrowth, resulting in carbon exchange with environment. While the peaty layer's14C age in deltaic deposition (17.50 m, U5) was determined to be 36420 cal a BP, coincided with OSL age of 39.6 ± 3.9 ka. The chronostratigraphy since MIS 5 for core TBF-1 exhibits a significant correlation with previously published cores SFK-1, DZQ4, and DH02, on the ECS outer shelf. Through the evaluation of those underestimated 14C ages and saturated OSL ages, we re-elucidated the primary sedimentary facies and their respective formation periods. This sedimentary stratigraphic illustration exhibits significant consistency with eustatic-glacial cycles. The renewed chronological framework for ECS shelf allows better correlation between the late Quaternary sedimentary evolution and the land-sea interaction on open shelves dominated by siliciclastic sedimentation.

Nonnegligible contribution of terrigenous sediment inputs from local small watersheds to west regions of the Pearl River Estuary, northern South China Sea shelf

As a crucial “sink” for terrigenous material entering the ocean, provenance of sediments within the coastal zone and continental shelf sea regions holds significant scientific importance in the investigation of global material cycling. Environmental magnetism was proved as an effective and rapid approach for sediment source identification. Detail and systematic magnetic measurements were performed for surface sediment samples collected from the mega Pearl River, local small rivers (Tan, Moyang and Jian rivers) of west Guangdong, coastal zone (CZ) and continental shelf (CS) to analyze the contribution of local small watersheds to marine sediments. The results indicate that detrital river input magnetite and hematite are coexisted in both CZ and CS sediments. Compared to CZ sediments, relatively higher concentration of hematite and finer grain size of magnetite are appeared at CS sediments. By comparing of magnetic parameters, it was inferred that magnetic minerals from the Pearl and Tan rivers are transported and deposited on the coastal zone by Guangdong longshore current. Meanwhile, sediment magnetic parameters in the Moyang and Jian Rivers are similar to the CS sediments, implying the two rivers-sourced materials were directly transported and deposited at the CS due to their narrow and restricted estuaries, and/or the CS preserves the residual deposits from the two rivers formed during the Last Glacial. Except for the Pearl River, sources of local small rivers significantly contribute to marine sediments at the coastal zone and continental shelf.

Mapping benthic sediment types and composition in a turbid Jamaican bay using hydroacoustic data and different spatially explicit interpolation techniques

Hydroacoustic sensors are better suited for mapping shallow turbid coastal waters, but surveys must take place along transects, necessitating the interpolation of processed, large, spatially dependent hydroacoustic datasets to produce continuous maps. The aim of this study was to evaluate the performance of interpolation techniques that can handle data obtained from a hydroacoustic survey (covering 23 km2) conducted in 2016 in a shallow bay in southwestern Jamaica. Independent data or a 5-fold cross validation were used to compare the accuracies of continuous maps of benthic sediment percentage composition and submerged aquatic vegetation cover (SAV), interpolated from the survey data using random forest (RF) regression (RFr), RFr kriging (RFrk) and Ensemble Machine Learning (EML) with rotated/oblique coordinates. Categorical/thematic maps of sediment types interpolated using RF (RFc) and EML classifiers and a spatial Markov chain model with indicator kriging predictor/simulation (Mc-IK) were also compared. RFr, RFc, RFrk and EML covariates included coordinates and auxiliary data. The following maps were more accurate than corresponding interpolated maps: EML - mud, sand, silt, clay and SAV; RFr - loss on ignition [LOI]; RFrk - calcium carbonate; Mc-IK – sediment types with 3 and 4 classes. The Mc-IK maps were also the most suitable maps for assessing spatial and quantitative changes. The predominant substrate type in the bay was muddy sand covering 15.7 km2. The highest percentage composition of mud, silt, clay, and organic matter [LOI] was found close to the mouth of the Black River where sandy mud was found, indicating a high input of terrigenous sediment. Calcium carbonate composition showed an opposite spatial trend and was positively associated with higher SAV percentage cover. The bay is now part of a protected area, as such, these maps will be used as a baseline to gauge the impact of increased protection/management on benthic dynamics.

Provenance and transport mechanism of gravity core sediments in the deep-water area of the Qiongdongnan Basin, northern South China Sea

Reconstructing the role of provenance and transport mechanism of sediments deposited in deep-water environments is often complex because of myriad of factors such as variability in sediment sources, tectonics, bottom morphology, climatic changes and sea level fluctuations as well as current regime. The South China Sea (SCS) is situated at the tectonic intersection of the Pacific, Eurasian, and Indo-Australian plates, and provides an excellent natural laboratory for understanding source-to-sink transport processes of fluvial sediments. The Qiongdongnan Basin (QDNB) is located in the northern part of the SCS, and the deep-water area (>300 m) of the QDNB has a good hydrocarbon source and hydrocarbon accumulation conditions with a tremendous thickness since the late Miocene-Quaternary. However, the complex sources and transport mechanisms of sediments in the QDNB are undefined. In previous study QDNB may have a major provenance or a mixture of sources. In this paper, the sediments of two cores from the deep-water area of QDNB have been analyzed using several sedimentological and geochemical approaches, including measurements of grain size distribution(433 samples), the occurrence of minerals, and trace element geochemistry(37 samples)as well as strontium and neodymium isotopes(20 samples).The granularity analysis results first show that the 19S37 core can be divided into three stages while the 19S40 core is divided into two stages by clear vertical variations in grain size characteristics. Chlorite (62.0%) and Muscovite (33.6%) appear to be the predominant minerals in the 19S37 core, while the mineral assemblage of sediments from 19S40 mainly consists of kaolinite (37.4%), muscovite (29.2%) and chlorite (27.1%). The primitive mantle standardization curves and chondrite standardized distribution patterns of 19S37 and 19S40 are consistent and display enrichments in Th, U, Pb, and Nd and depletions in Ba, Nb, Sr, and Eu. In addition, the content of Sr fluctuates greatly with depth, which should reflect the influences of sea level changes and the relative proportion of various provenance components. The 143Nd/144Nd ratios and εNd values of the sediments from 19S37 are higher than those of the sediments from 19S40, and all the εNd values show narrow variations and range from −10.085 to −11.080. We conclude that the sediments of the deep-water area in the upper Pleistocene-Holocene were mainly from the sources of the Red River, Taiwan, Pearl River, Hainan Island, and Vietnam. The transport mechanism of the sediments from Hainan Island can be explained by the short distance between the source region and the sedimentary site, while the large amounts of terrigenous sediment inputs derived from the Red River and advantageous morphology make the Red River the largest sediment source to cores 19S37 and 19S40. The transport distance and amount of Deep Water Current could be even more powerful to make Taiwan be the second largest source of modern sediments in QDNB.

The influence of submarine canyons-related processes on recent benthic foraminiferal distribution, Espírito Santo Basin, Southeastern Brazil

The complex topography of submarine canyons may result in different composition of benthic foraminifera assemblages. To understand how trophic, hydrological and sedimentological conditions in submarine canyons can influence the distribution of benthic foraminifera, and to use this information to corroborate paleoenvironmental interpretations for the Holocene, we investigated recent benthic foraminiferal assemblages (total fauna >63 μm) and sedimentological data in two canyons (CANWN and CAND) in the Espírito Santo Basin (ESB) between 18°20′ and 21°20′ S. Surface sediment samples (0–2 cm) were collected inside the canyons (150 to 1300 m water depth) and in shelf-slope adjacent transects (50 to 1300 m water depth). The density, taxonomic diversity, and assemblage composition of benthic foraminifera change with depth and location. The distinct ecological preferences of the most abundant taxa allowed us to recognize five benthic foraminiferal groups. Three groups (V, III, and I) are present in different bathymetric sectors; Group V: outer shelf (50 m), Group III: upper, and middle – lower slope (150 to 400 m), and Group I: middle – lower slope (1000 to 1300 m). Groups II and IV show no characteristic bathymetric distribution and are present only in CAND and in CANWN, respectively. Group V consists of Hanzawaia boueana, Peneroplis planatus, and Quinqueloculina lamarckiana; Group III is dominated by Globocassidulina rossensis and Trifarina spp.; Group I consists of Globocassidulina crassa, Bolivina lowmani, Gavelinopsis versiformis, Alabaminella weddellensis, and Epistominella exigua. The main species in Group II (CAND, 150, 1000 to 1300 m) are Trifarina angulosa, Globocassidulina subglobosa, and Discorbis vilardeboanus. Group IV (middle – lower CANWN, 1000 to 1300 m), consists mainly of agglutinated species Glomospira charoides, Rhabdammina abyssorum, and Psammosphaera fusca. Our data suggest that the quantity (and quality) of food supply, hydrodynamic conditions and sediment properties are the main drivers controlling the bathymetric distribution of benthic foraminiferal assemblages in both canyons. The middle – lower CANNW revealed unstable trophic conditions, related to terrigenous sediment input due to turbidity currents. In CAND, the foraminiferal assemblages ecology indicated sufficient organic matter supply that favors species establishment and diversity, indicating a more productive and less unstable environment than in CANWN.

Seismic stratigraphy and development of a modern isolated carbonate platform (Xuande Atoll) in the South China Sea

Xuande Atoll is an isolated carbonate platform that has developed since the early Miocene. This study conducted high-resolution seismic surveys and shallow drilling to understand its internal structure and development. Five seismic sequences were observed (from bottom to top): SQ1 (early Miocene), SQ2 (middle Miocene), SQ3 (late Miocene), SQ4 (Pliocene), and SQ5 (Quaternary). The seismic data indicated that the platform formation started in the early Miocene and flourished during the early and middle Miocene. The platform shrank before the isolated platform formed in the middle Miocene. The final shrinking stage occurred in the southern and western parts of the platform at the end of the Miocene, which may reflect rapid tectonic subsidence and increased terrigenous sediment inputs owing to the formation of the semi-marginal sea. The peri-platform contains a falling sea-level sequence that was dominated by mass wasting deposits.

New insights on the Late Quaternary evolution of Abrolhos reefs, Eastern Brazilian Shelf

The Abrolhos shelf, in the eastern Brazilian margin, encompasses the largest reef province in the South Atlantic, characterised by low coral diversity and a high level of endemism. Knowledge gaps about how the Abrolhos coastal reefs evolved, during the post LGM and MIS 6/MIS 5, favoured a paradigm that is revisited in the light of new data. Here, new data from two new, long boreholes (20 and 50 m-long) are presented in order to investigate and provide new insights into the evolution of two shallow reefs on the Abrolhos Shelf during the late Pleistocene and Holocene epochs. Results show that Holocene and Pleistocene reefs grew on highly turbid waters with a significant terrigenous sediment input. Corals and CCA assemblages were identified as main framework builders of Abrolhos inner-shelf reefs since the Pleistocene. No clear shallowing upward sequence of reef builders was observed, which differs from other reef sequences all over the world. In terms of Holocene reef growth, Pedra Grande and Coroa Vermelha reefs turned on roughly coevally at different depths and with different coral assemblages. Pedra Grande reef started growing circa 6.8 kyr BP in a water depth approximately 10 m deeper than Coroa Vermelha, which started growing around 6.4 kyr BP, but Coroa Vermelha turned off at around 4 kyr BP, while Pedra Grande kept growing until around 1.2 kyr BP. This novel reef stratigraphy data provided a new insight on the evolution of the Abrolhos coastal reefs, showing that different environmental and topographic controls could have acted spatially in different ways. Coroa Vermelha reef seems to have started its growth as a result of a topographic high control. Pedra Grande reef seems to be connected to a broader submerged reef setting and started to grow in deeper water depths. The presence of three reef arcs in Abrolhos is proposed, including a submerged reef arc.

Orbital-scale cyclicity and organic matter production in a Permian shallow mixed carbonate-siliciclastic system: Paraná Basin, Brazil

Mixed deposition in shallow seas is highly sensitive to climate variations and sea-level changes, which are the primary controls of high-frequency cycles in the stratigraphic record. The widespread Lower Permian mixed carbonate-siliciclastic succession of the Paraná Basin is composed of rhythmic organic-rich shale interbedded with dolostone. The strata are organized into several orders of magnitude of superimposed asymmetrical and symmetrical facies stacking patterns that developed in a broad epeiric sea, which extended over 106 km2 of Permian Gondwanan land. Detailed sedimentological and stratal stacking analysis allow the hierarchical organization to be identified in large-scale, medium-scale, small-scale, and elementary stacking patterns. The high-frequency depositional cycles compose four 3rd-order sequences. They comprise gray to black shale, marls, and peloidal to micritic dolostone. Due to the shallow water setting, the minimal available accommodation is responsible for the reduced cycle thickness and the overall mixed succession. The rhythmic deposits host highly productive hydrocarbon source rocks. Two widespread, thicker intervals of bituminous shale that develop during 3rd-order sequence transgression events are highly organic-rich oil shale (27 wt%). In addition, thin black shale laminae, which are interbedded with dolostone in high-frequency stacking patterns, are also rich in organic carbon (2–8 wt%). The alternation of high carbonate content and organic matter production was controlled by wet‒dry seasons and was related to total solar radiation maxima and minima. The total solar radiation maxima are translated into elevated carbonate precipitation due to shallower and hypersaline conditions. Total solar radiation minima induce freshwater discharge in shallow and hypersaline environments during wet stages, resulting in water column stratification. The occurrence of kerogen types III and IV, a high gammacerane index, variable Pr/Ph ratios, and C35 homohopane indices indicate this condition. In addition, the input of nutrient-rich terrigenous sediments favor algal blooms, enhancing anoxia in the bottom water, which is responsible for the organic-rich shale facies, as indicated by kerogen types I and II, high hydrogen index values, high C27/C29 sterane ratios, and higher β-carotane values. Based on the hierarchical organization and previous U–Pb SHRIMP zircon ages of volcanic ash layers, it is possible to correlate the observed succession with the global sea-level curve. A time span of 8.0 Ma is assessed for the Irati Sea, with an average of 2.7 Ma for the large-scale cycles. Furthermore, the high-frequency patterns that are compatible with the precession and eccentricity of the short (±100 ka) and major (±400 ka) periodicities of the Earth's orbit are estimated to be 26.6 ka, 135.5 ka, and 400 ka. The high-frequency cycles of organic-rich shales and carbonate that are deposited over thousands of years under long-term sea-level changes and are correlated along the basin suggest climatic control driven by the Earth's orbital perturbation, which is possible in the Milankovitch frequency band.

Paleoenvironmental changes recorded at a late Maastrichtian marine succession of northern South America

One of the major environmental and biotic turnovers of the Phanerozoic occurred at the Cretaceous-Paleogene (K-Pg) boundary, being the focus of countless scientific studies that addressed the timing, causes and consequences of this global event. Paleoenvironmental conditions that preceded the K-Pg boundary, however, have been less studied, especially at low latitudes. In order to help reconstructing late Maastrichtian marine environments along the equatorial South American margin, we apply micropaleontological and geochemical techniques to a stratigraphic core that recovered the Colón Formation in northern Colombia. Low abundance foraminiferal assemblages were overall dominated by benthic taxa (Maastrichtian local biozones Siphogenerinoides bramletti and Ammobaculites colombiana), and the planktonic species Guembelitria cretacea. Ostracod assemblages were mainly composed of the genera Veenia, Cytherella, Paracypris, and Cythereis. Calcareous nannofossils were typical of Upper Cretaceous low-latitude successions, with low abundance and diversity assemblages dominated by Micula staurophora, Kamptnerius magnificus and Cervisiella operculata. Sediment elemental ratios (Zr/Rb, Fe/Ca and Sr/Ba), as well foraminiferal, ostracod and nannofossils assemblages, indicate a shallowing upward trend, characterized by a transition from inner platform settings to sublittoral conditions. Input of terrigenous sediments and weathering intensity also increased upward in the section, probably related to the uplift pulses of the Andean orogeny. Proportions of benthic infauna, as well the V/Cr ratio and the distribution of redox-sensitive trace metals (Ni, Cu) along the core, mostly indicate suboxic bottom water conditions in the Colón Formation.

Interannual Variations of D14CTOC and Elemental Contents in the Laminated Sediments of the Santa Barbara Basin During the Past 200 Years

A 51-cm core (SBB-8-2012) from the depo-center of Santa Barbara Basin (SBB), California has been dated by 210Pb dating and varve counting, spanning a depositional history during 1815-2011 CE. A total of 89 AMS 14C measurements on samples from 66 horizons, including animal cartilage, shell and total organic carbon (TOC) in the sediments show apparent 14C ages between 500 and 4000 yr BP. Among these AMS dates, D14C values measured in 78 samples from 62 horizons vary in the range of -64.3‰ to -383.8‰. The 14CTOC ages much older than predicted from our sedimentation model are influenced by the input of terrigenous sediments, changes in ocean circulation, biological input and carbon remineralization. Three strong old 14CTOC excursions at 1964~69, 1884~87 and 1819~21 CE indicate higher old carbon input caused by some unusual events (e.g., oil spill, flood event and earthquake). On multi-decadal timescales, the D14CTOC shifts in three zones were mainly caused by changes in fossil carbon emission from the seafloor, fraction of marine productivity to terrigenous input of organic carbon (OC) and the atmospheric nuclear bomb testing input of 14C into the SBB. On interannual to decadal timescales, variations of D14CTOC correspond to El Niño-Southern Oscillation effects. During the La Niña period, stronger upwelling and northerly California Current bring nutrient-enriched water into SBB and lead to higher productivity hence more marine OC with higher D14CTOC. In addition, reduced terrigenous input of OC with lower D14C under less coastal rainfall during La Niña could further elevate the D14CTOC. Lower scanning XRF (K+Ti)/2 (indicating lower terrigenous input), higher scanning XRF Sr/Ti as well as acid-leachable elements (reflecting higher biogenic components), and higher D14CTOC occur during La Niña. During the El Niño period, the phenomena are opposite. Spectrum analyses of the Southern Oscillation Index (SOI) and the D14CTOC as well as the comparison of SOI and SBB-8-2012 records support our scenarios.

Sea level change and Kuroshio intrusion dominated Taiwan sediment source-to-sink processes in the northeastern South China Sea over the past 244 kyrs

The terrigenous sediment source-to-sink processes in continental margins are determined by complex interactions among climate, sediment discharge, sea level and oceanic circulations on various temporal and spatial scales. The northeastern South China Sea (NSCS) margin is a natural laboratory to catch a glimpse of these processes due to large amounts of terrigenous sediment inputs and continuous sedimentations during the late Quaternary. Based on a 35 m-long sedimentary sequence (core MD12-3429) retrieved from the NSCS upper continental slope, we distinguished sediment sources based on geochemical compositions, and then linked sedimentary responses to sea level change and Kuroshio intrusion over the past 244 kyrs via various sedimentary records including mass accumulation rates (MAR), foraminifera data, grain-size end-member modeling (EMM) and spectral analysis. Geochemical proxies including major element ratios and fractionation parameters of rare earth elements suggest that the detrital sediment in the core was derived primarily from the Taiwan. The MAR of terrigenous sediment yields an average 9.6 g/cm2/kyr, and high MAR values are both observed in glacial and interglacial intervals. The results of EMM reveal three end-members with dominant modal grain sizes of 6.6 μm (EM1), 26.3 μm (EM2) and 49 μm (EM3), respectively. The temporal variations of the finest end-member (EM1) and the coarsest end-member (EM3) demonstrate clearly glacial-interglacial cyclicity, and the spectral analysis indicates the dominance of 100-kyr eccentricity, which suggests that sea level changes are the first-order control for the NSCS continental margin sedimentation. In addition, the temporal variations in hydrodynamic sensitive component (EM2) and its MAR display gradually increasing trends with weakening East Asian monsoon. Combing with modern observation and modeling results, we suggest that enhanced Kuroshio intrusion might account for the transport of Taiwan-derived sediment during the late Quaternary. As indicated by a 31 kyr periodicity in EM2, we infer that the development of El Niño-like condition strengthened the intrusion of oligotrophic Kuroshio from the Luzon Strait, resulting in the obvious increase of Taiwan terrigenous MAR but decreases of the primary productivity in the northeastern South China Sea. This study provides deep insight into the complex terrigenous sediment source-to-sink processes in a fast-changing marginal sea environment during the late Quaternary.

Revisit the Sedimentary Stratigraphic Evolution and Environmental Changes on the Outer Shelf of the East China Sea Since MIS 5

The East China Sea (ECS) is featured by the broad continental shelf, huge terrigenous sediment input and striking river-sea interaction during the Quaternary. Despite the numerous studies, mostly on the delta, coastal and inner shelf areas, the late Quaternary stratigraphy and sedimentary environment on the mid-outer ECS shelf were poorly documented. In particular, it is still controversial in issues such as the recognition of marine transgression deposits in the interglacial period and the occurrence and ages of deposits in the glacial period. This study presents new data of high-resolution seismic reflection profiles and collective evidences from lithology, microfossil assemblages and geochronology of borehole SFK-1 on the ECS outer shelf, aiming to revisit the sedimentary stratigraphic evolution and environmental changes since the Marine Isotopic Stage 5 (MIS 5). Sixty-one ages were obtained by radiocarbon and Optical Stimulation Luminescence (OSL), providing robust constraints on the chronostratigraphy. Three marine regression/transgression cycles were identified, which primarily constrained the sedimentary environmental evolution over the past 100 kyrs. Although the strong river-sea interaction accompanied with sea level fluctuations characterized the late Quaternary depositional environment on the shelf, this study clearly identified the stratigraphic boundaries between MIS 1 and MIS 5, and confirmed the tide-influenced fluvial deposition formed during the Last Glacial Maximum on the outer shelf. We infer that tidal forcing significantly superimposed its influence on sea level change and thus formed the most striking feature on the late Quaternary stratigraphy of the open ECS shelf. With the combination of a large number of absolute depositional ages with high-resolution core records, the major findings of this study may allow better understanding of the Quaternary sedimentary evolution and river-sea interaction on open shelves dominated by siliciclastic sedimentation.

Organic carbon burial in Mediterranean sapropels intensified during Green Sahara Periods since 3.2 Myr ago

Dark organic-rich layers (sapropels) have accumulated in Mediterranean sediments since the Miocene due to deep-sea dysoxia and enhanced carbon burial at times of intensified North African run-off during Green Sahara Periods (GSPs). The existence of orbital precession-dominated Saharan aridity/humidity cycles is well known, but lack of long-term, high-resolution records hinders understanding of their relationship with environmental evolution. Here we present continuous, high-resolution geochemical and environmental magnetic records for the Eastern Mediterranean spanning the past 5.2 million years, which reveal that organic burial intensified 3.2 Myr ago. We deduce that fluvial terrigenous sediment inputs during GSPs doubled abruptly at this time, whereas monsoon run-off intensity remained relatively constant. We hypothesize that increased sediment mobilization resulted from an abrupt non-linear North African landscape response associated with a major increase in arid:humid contrasts between GSPs and intervening dry periods. The timing strongly suggests a link to the onset of intensified northern hemisphere glaciation.

Sedimentation in the adjacencies of a southwestern Atlantic giant carbonate ridge

Although carbonate mounds have been investigated for 100 years, few studies focus on the giant variety. The Alpha Crucis Carbonate Ridge (ACCR), a ~17 x 12-km ring-shaped ridge formed by hundreds of mounded structures, located between the 300 and 800-m isobaths and reaching a maximum height of 340 meters above the adjacent seafloor, is the first giant carbonate mounded feature described for the SW Atlantic margin. This study provides the first multiproxy approach to investigate sediments covering the ACCR and its adjacencies. Most of the area is located under the Intermediate Western Boundary Current (IWBC) flow, which carries the nutrient-rich Antarctic Intermediate Water (AAIW). Radiocarbon aging shows pronounced differences for the shallow layers (MIS3 for the top of the mounds and late Holocene for the adjacencies). Grain size data indicate the prevalence of sandy fractions on top of the mounds and muddy sediments in the adjacent areas. Fe/Ca and Ti/Ca proxies allowed for identifying mainly biogenic sedimentation in the area. However, the input of allochthonous terrigenous sediment is necessary for mound buildup, and values of Fe and Ti collected on the top of the mounds are significant. End-Members distributions and metal concentrations also allowed for recognition of distinct sources of sediment. εNd and Ln(Fe/K) indicated two primary terrigenous sources, the Precambrian rocks of the Brazilian shield (Cabo Frio end-member) and the multiple lithologies drained by the Rio de la Plata basin. Redox condition proxies indicated that the area is submitted to oxic conditions, probably reflecting the action of the IWBC. This work provides the first insight into an integrated grain-size and geochemical characterization of the Alpha Crucis Carbonate Ridge (southwestern Atlantic margin).

Controls on Terrigenous Detritus Deposition and Oceanography Changes in the Central Okhotsk Sea Over the Past 1550 ka

The Okhotsk Sea, which connects the high latitude Asian continent and the North Pacific, plays an important role in modern and past climate changes due to seasonal sea ice coverage and as a precursor of the North Pacific Intermediate Water. The long-term glacial-interglacial changes of sea ice coverage and its impacts on terrigenous transport and surface primary productivity in the Okhotsk Sea remain, however, not well constrained. Base on the paleomagnetic, rock magnetic, micropaleontological (diatom), and geochemical studies of the marine sediment core MD01-2414 (53°11.77′N, 149°34.80′E, water depth: 1,123 m) taken in the central Okhotsk Sea, we reconstruct the terrigenous sediment transport and paleoceanographic variations during the past 1550 thousand years (kyr). Seventeen geomagnetic excursions are identified from the paleomagnetic directional record. Close to the bottom of the core, an excursion was observed, which is proposed to be the Gilsa event ∼1550 thousand years ago (ka). During glacial intervals, our records reveal a wide extension of sea ice coverage and low marine productivity. We observed ice-rafted debris from mountain icebergs composed of coarse and high magnetic terrigenous detritus which were derived from the Kamchatka Peninsula to the central Okhotsk basin. Still during glacial intervals, the initiation (i.e., at ∼900 ka) of the Mid-Pleistocene Transition marks the changes to even lower marine productivity, suggesting that sea-ice coverage became larger during the last 900 ka. During interglacial intervals, the central Okhotsk Sea was either devoid of sea-ice or the ice was at best seasonal; resulting in high marine productivity. The weaker formation of Okhotsk Sea Intermediate Water, lower ventilation, and microbial degradation of organic matter depleted the oxygen concentration in the bottom water and created a reduced environment condition in the sea basin. The freshwater supplied by snow or glacier melting from Siberia and Kamchatka delivered fine grain sediments to the Okhotsk Sea. During the stronger interglacial intervals after the Mid-Brunhes Transition (i.e., Marine Isotope Stages 1, 5e, 9, and 11), strong freshwater discharges from Amur River drainage area are in association with intensified East Asian Summer Monsoon. This process may have enhanced the input of fine-grained terrigenous sediments to the central Okhotsk Sea.

Response of Terrigenous Sediment Input to Sea Level Change and East Asian Monsoon Evolution Since 30kyr in the Southwestern Taiwan Basin

Response of Terrigenous Sediment Input to Sea Level Change and East Asian Monsoon Evolution Since 30kyr in the Southwestern Taiwan Basin

Late Holocene Paleonvironmental Evolution of Two Coastal Lakes in Mediterranean Chile and Its Implications for Conservation Planning

Paleolimnological reconstructions from the mid and high latitudes in the Southern Hemisphere are still relatively scarce. Anthropogenic impacts have evidenced trophic state changes and an increase in cyanobacterial blooms in the lacustrine system of San Pedro de la Paz in the last decades. Here, we reconstructed primary production and sedimentological changes spanning the past 2500 years in two coastal lakes in Mediterranean Chile. A multiproxy approach including sedimentological, biogenic silica, carbon and nitrogen isotopes and fossil pigments analysis in sediment cores was performed in Laguna Grande (LGSP) and Laguna Chica de San Pedro (LCSP). A marked change in the sedimentology of the lakes, likely related to the terrigenous sediment inputs derived by a transition from an arid condition in the mid-Holocene to a more humid condition in the late Holocene that favoured arboreal forest establishment at 100 BC–AD 150. A period of low primary production was identified between 850 to 1050 AC for LCSP, suggesting moist and cold conditions that were possibly related to La Niña events. In recent decades, there have been increases in primary production, probably resulting from anthropogenic disturbances. These likely include the clearance of native vegetation, the introduction of exotic tree species, and urbanisation, which in turn, resulted in nutrient inputs and hence eutrophication. We conclude that an integrated management program for both lakes is urgently needed.

A Plio-Pleistocene (c. 0–4 Ma) cyclostratigraphy for IODP Site U1478 (Mozambique Channel, SW Indian Ocean): Exploring an offshore record of paleoclimate and ecosystem variability in SE Africa

The paleoclimate and ecosystem variability in Africa during the Plio/Pleistocene has received considerable attention due to its potential links to hominid evolution. However, the reconstruction of this variability hinges critically upon highly temporally resolved proxy data from continuous, well-dated sediment archives. In light of these requirements we use a new XRF core-scanning record from International Ocean Discovery Program (IODP) Site U1478 off the Limpopo River mouth (Mozambique Channel, SW Indian Ocean) spanning the past c. 4 Ma to identify the climate variability in SE Africa. Our results show that the elemental distribution in the Site U1478 cores is mainly controlled by the rate of terrigenous input and – to a lesser extent – by bottom-current transport and post-depositional processes such as propagation of paleoredox boundaries and diagenesis across some intervals. The log(Ti/Ca) ratio, which is used as a tracer of terrigenous sediment input, shows quasi-cyclical variability across the entire record that closely matches the periods of orbital parameters. However, the cyclical behaviour of the log(Ti/Ca) signal varies through time, with the uppermost 106 m of the sequence (0–1.07 Ma) displaying a mix of precession and obliquity signals, the intervals 106–223 m (1.07–2.80 Ma) and 240–257 m (3.68–4.05 Ma) being dominated by precession, and the interval 223–240 m (2.80–3.68 Ma) being controlled by eccentricity. To refine the available chronology for Site U1478, which is based on shipboard biostratigraphic and paleomagnetic data, we have tuned the log(Ti/Ca) record to the LR04 benthic oxygen isotope record, summer insolation at 25° S, and orbital eccentricity depending on the dominant cyclicities in the XRF dataset across individual time intervals. The resulting chronology enables us to evaluate the XRF data as well as the previously available shipboard sedimentological and geochemical datasets within a regional and global climatic context. This allows the connection of a c. 7-m-thick contourite deposit and a prominent paleoredox boundary to hydroclimate and ocean-circulation changes during the early Pleistocene and across the Mid-Pleistocene Transition, respectively. Moreover, a decoupling of the log(Ti/Ca) and the log(Ti/K) records, with the latter indicating the degree of sediment weathering, from 3.2 to 2.8 Ma points to an increased delivery of highly weathered sediments to Site U1478. We attribute this to temporarily wetter and warmer conditions in the catchment of the Limpopo River and/or a change in the sediment source, perhaps associated with the tectonically driven enlargement of the Zambezi River catchment during the late Pliocene/early Pleistocene.

Molecular Geochemistry of the Dispersed Organic Matter in the Late Cenozoic Sediments of the Laptev Sea Continental Margin and Adjacent Part of the Arctic Ocean

Abstract ––The main factors controlling the bulk sedimentation in the Siberian segment of the Lomonosov Ridge (axial part and western slope) and the Laptev Sea continental margin during the late Cenozoic were studied using a complex of geomorphological, lithological, and organic geochemical data. Samples for the study were collected during the cruises of R/V Akademik Fedorov in 2005 and 2007 and nuclear icebreaker Rossiya in 2007. Analysis of the group and molecular composition of the dispersed organic matter (DOM) in bottom sediments has shown that the input of terrigenous sediments enriched in the products of abrasion of lithified rocks determines sedimentation process on the continental slope of the Laptev Sea and in the Amundsen Basin. The individual characteristics of the DOM of the late Cenozoic sediments from the Lomonosov Ridge reflect the wide diversity of sedimentary sources and depositional environments. Subaqueous erosion of edaphogenic products and pre-Holocene sediments plays an important part in sedimentation together with terrigenous flow and ice transport.

A Multi‐Proxy Approach to Unravel Late Pleistocene Sediment Flux and Bottom Water Conditions in the Western South Atlantic Ocean

AbstractMagnetic signals in deep‐sea sediments have the potential to unravel past continental environmental changes, via changes in primary terrigenous magnetic supply, but also record past marine environmental conditions, via in situ formation of secondary magnetic minerals, particularly when complemented by independent proxies. By combining environmagnetic, geochemical, and siliciclastic grain size data, we investigated marine sediment core GL‐1090 (24.92°S, 42.51°W, 2,225 m water depth) aiming to unravel changes in terrigenous sediment input and bottom water conditions during the last ∼184 ka at the western South Atlantic middepth. The Al/Si, Fe/κ and siliciclastic grain size data show that terrigenous sediments at this core location derived from the Plata River (southeastern South America). This material was transported northwards by the Brazilian Coastal Current and their delivery to our core site was modulated by sea‐level oscillations. Periods of low sea‐level were characterized by the input of coarser and more abundant terrigenous sediments. Environmagnetic parameters indicate significant downcore variations in the magnetic domain state, which we interpret as changes in the content of biogenic magnetite following glacial‐interglacial cycles. Coeval negative excursions in magnetic grain size and benthic δ13C suggests that concentrations of single domain magnetite (possibly magnetotactic bacterial magnetite) vary in response to middepth water ventilation. We suggest that reduced ventilation in the middepth western South Atlantic bottom waters during peak glaciations triggered a decrease in the production of biogenic magnetite. Peak glaciations were, in turn, linked with increases in the residence time of North Atlantic Deep Water (or its glacial counterpart).