A multi-chronometric investigation has been conducted on the ∼2.0-km-diameter Holleford impact structure of Ontario, Canada. In situ triple quadrupole laser ablation−inductively coupled−mass spectrometry U-Pb and Rb-Sr geochronology, along with (U-Th)/He thermochronology, have been applied to multiple mineral phases from impact melt-bearing breccias and overlying sedimentary units. Impact-induced resetting is absent in all three isotopic systems. While Holleford’s small size resulted in insufficient heating to reset geochronometers during impact, our investigation has defined a more detailed pre- and post-impact geologic setting within the Precambrian basement and overlying Paleozoic lithologies. Target rock age determinations include those associated with the Proterozoic Frontenac Terrane. These are manifest as the Rigolet (1004 ± 5 Ma, U-Pb apatite dating) and Ottawan (1074 ± 12 Ma, Rb-Sr biotite dating) phases of the Grenville Orogeny. Pre-Grenville ages associated with the Penokean (1806 ± 46 Ma, apatite dating) and the Shawinigan (1184 ± 8 Ma, U-Pb titanite dating; 1134 ± 21 Ma, U-Pb zircon dating) orogenies are also retained. A Paleoproterozoic age records Superior Province tectonometamorphism (2421 ± 97 Ma, U-Pb zircon dating). Dated post-impact events include dolomitization associated with Silurian marine transgression (430 ± 14 Ma, U-Pb dolomite dating) and regional K-metasomatism of Mississippian age (346 ± 5 Ma, U-Pb titanite dating). Extremely young (U-Th)/He ages (27−3 Ma) were obtained from planar fractured and recrystallized apatite, which we interpret to be the result of impact-induced diffusion domain reduction. This, combined with low-temperature heating due to burial, significantly limited He retention. Stratigraphic constraints place the Holleford impact event at ca. 458 Ma, close to the Darriwilian−Sandbian boundary of the Ordovician. This age indicates that Holleford may be part of the Late Ordovician group of terrestrial impact craters related to L-chondrite parent breakup.
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