A linear Boltzmann model is used for studying a condensation{evaporation prob- lem in a bounded domain. First the time asymptotic limit is derived, which solves the associated stationary problem. Then the Milne problem is discussed for the boundary layer. Finally a fluid approximation is obtained in the small mean free path limit with initial and boundary layers of zeroth order. Introduction. The kinetic description of a rareed gas can be given through the Boltzmann equation for the density function f(t;x;v) of particles with velocity v at position x and time t. A coarser theory consists of describing the gas as a continuous fluid with local density (t;x), velocity u(t;x), and temperature T (t;x) satisfying the Euler or Navier{Stokes equations. In the limit of small mean free path, the fluid dynamic equations may be derived from the Boltzmann equation through either a Hilbert or Chapman{Enskog expansion; see, e.g., (2, 8, 9, 12). However, the fluid dynamic limits fail near shocks and for general indata near spatial or temporal boundaries. Among the many studies of the boundary layer structure let us mention the following. In (3), the steady nonlinear Boltzmann equation for a gas with zero bulk velocity between two plates at two dierent temperatures is solved for a small mean free path, using a Chapman{Enskog expansion between the two plates. Here the fluid part of the solution contains Fourier's law for heat conduction which can be made to satisfy dierent temperature values at the two plates. This is why the boundary layer terms only need to be of rst order with respect to the mean free path. An analogous study also including the initial layer is performed in (16) for the linear semiconductor case where further references in the eld may also be found. For more results in the area see also (5, 10, 13, 19). The present paper addresses the added presence of condensation{evaporation on the boundary. In this context a formal analysis and numerical computations are carried out in (17, 18) for a rareed gas with varying temperatures and condensation{ evaporation on the boundaries. On the basis of the linearized Boltzmann equation for hard sphere molecules, zeroth-order boundary layer terms are needed for solving the problem. Our paper considers the same problem for a rareed solute in a solvent gas, and with varying temperatures on the boundary. The linear Boltzmann equation is used as a model for the solute. We prove that a fluid approximation in the interior together with initial and boundary layer structures are available to describe the solute