Tephra Deposits Research Articles

Chironomidae responses to volcanic ash fall: a case study from Northern Patagonia for consideration in paleolimnological reconstructions

ABSTRACT Lacustrine environments from Northern Patagonia are exposed to volcanic events from the Southern Volcanic Zone. Chironomid larvae are an important paleo-proxy because, in addition to their environmental sensitivity, their chitinous cephalic capsules are well preserved in lacustrine sediments, allowing their recovery and identification. We analysed the effects of a recent volcanic eruption (Puyehue-Cordón Caulle Volcanic Complex 2011) on the chironomid community based on their cephalic remains accumulated following the ash deposition process. Two pulses of ash deposition were distinguished: a first stage comprising the immediate coarse ash fall and a delayed finer volcanic deposition. An abrupt decline in chironomid taxa and their densities were noted during the first coarse pulse, followed by an attempt of community recovery through the second finer pulse, characterised by main taxa turnover, observing an alternative community functional structure. Based on these results and comparing with past volcanic depositions, we observed different chironomid responses according to their particular ecological habits, and we noted possible percolation effects, mainly in coarse tephras, and probably a delayed record of very low abundance taxa. Our results suggest caution in analysing chironomid assemblages within and adjacent to tephra deposition as local volcanic eruption could affect chironomid community with possible consequences on paleoreconstructions.

The post-2016 long-lasting Vulcanian activity of Sabancaya volcano (Peru) and associated aeolian remobilisation of volcanic ash

The characterisation of tephra deposits resulting from almost simultaneous sedimentation and wind remobilisation is complex, and multidisciplinary strategies are required in order to accurately constrain associated processes and eruptive parameters. We present a multifaceted study that aims to characterise the recent eruptive activity and the subsequent aeolian remobilisation of tephra deposits at Sabancaya volcano (Peru), which started erupting in November 2016 with frequent and relatively small explosions (plume heights <6 km above the vent). First, we estimated the bulk volume of tephra deposit produced between November 2016 and August 2018 at 0.04 ± 0.02 km3, and the dense rock equivalent (DRE) volume at 0.02 ± 0.01 km3. This corresponds to a tephra production rate of 1.1 ± 0.5 × 10−3 km3 DRE per month. Second, continuous sampling in a dedicated tephra collector network between April 2018 and November 2019 allowed estimation of the tephra volume at 2.3 ± 1.1 × 10−5 km3 DRE per month, indicating a significant decrease in the mass eruption rate since 2018. Third, by characterising the pulsatory activity through the repose interval between explosions and magma characteristics, Sabancaya's activity was classified as Vulcanian. Finally, aeolian remobilisation phenomena were studied using high-resolution videos, measurements of the airborne concentration of particulate matter with a diameter of ≤10 μm (PM10) and particle physical characterisation. Subtle morphological differences are identified between remobilised particles and those in primary deposits, and we found that particles moving at ground level and above 1.5 m have grainsizes transportable by saltation and suspension, respectively.

The cenozoic marine tephra record in Indian Ocean deep drill sites

Provenance studies of widely distributed tephra deposits are important to deduce systematic changes in the source, size, distribution, and temporal variation of regional explosive volcanism. Long-term deep ocean drilling sedimentary records are particularly useful for these kind of studies. In this study, we establish a robust tephrochronostratigraphy for 235 primary marine tephra layers collected during International Ocean Discovery Program Expeditions 353, 354, and 362, complemented by older drill cores from Deep Sea Drilling Program and Ocean Drilling Program Legs 22, 119, 120, 121, and 183. We infer at least two major phases of highly explosive arc volcanism during the Early Miocene to Pleistocene, as well as three episodes related to explosive ocean island volcanism located in the Kerguelen plateau, the Broken Ridge, and close to Réunion reaching back to the Paleogene.Twenty-two widespread arc-derived tephra layers from individual eruptions can be correlated by geochemical fingerprinting between multiple holes. These provide nine Quaternary and 13 Neogene temporal tie points in the sedimentary sequence including four new UPb zircon ages. Provenance analysis of the marine tephra layers, which is based on glass composition, assign eleven of these layers to a Toba-like source, ranging from 24 Ma to 75 ka, with the youngest correlative being Young Toba Tuff. Based on distribution pattern, thickness decay, and compositional evidence another eleven tephra layers can be assigned to a northern Sumatran Arc or to an Andaman Arc provenance. First-order minimum eruptive volume estimates for the Neogene tephra layers imply eruptive magnitudes ranging from M = 6.5 to M = 7.5, proving a continuous history of large explosive eruptions from the Sumatran/Andaman Arc since the Neogene, as previously known from the Quaternary. Plain language summaryKnowing the origin of large volcanic eruptions is important to deduce systematic changes in the source, size, distribution, and changes of regional explosive volcanism. In this study we use widely dispersed marine volcanic deposits in the Indian Ocean, so-called marine tephra layers, to reconstruct the history of a) Sumatran highly explosive eruptions over the last 24 Ma, and b) ocean island volcanism frequently observed in the Indian Ocean. The marine deposits are often the only evidence of major eruptions in the past because respective volcanic edifices and terrestrial deposits are often destroyed by subsequent eruptions, eroded or overlain by younger deposits. Deep ocean drilling provides the unique possibility to overcome these problems by recovering long, tephra-bearing marine sediment sequences in the drill cores. We present the results for 235 primary marine tephra layers that have been collected during eight deep drilling campaigns in the Indian Ocean. Twenty-two widespread connections of arc-derived tephra layers are established by comparing distinctive geochemical fingerprints of the tephras between multiple locations. These provide nine Quaternary and 13 Neogene temporal tie points in the sedimentary sequence. The origin of these marine tephra layers is determined based on the unique glass compositions of individual volcanoes and eruptions, assigning 11 of these layers to a Toba-Caldera-like source ranging from 24 Ma to 75 ka, with the youngest correlative being the iconic Young Toba Tuff. Another eleven tephra layers can be assigned to a northern Sumatran Arc or to an Andaman Arc provenance.Our record demonstrates a continuous history of large explosive eruptions from the Sumatran/Andaman Arc since the Neogene. We additionally infer (1) at least two major phases of highly explosive arc volcanism from the Sumatra-Andamen volcanic chain during Early Miocene to Pleistocene times, and (2) three episodes related to explosive ocean island volcanism found in the Kerguelen plateau, the Broken Ridge, and close to Réunion.

Analysis of magma flux and eruption intensity during the 2021 explosive activity at La Soufrière, St Vincent, West Indies

Abstract Real-time Seismic Amplitude Measurement signals and eruption cloud height measurements were used to estimate peak intensities of 40 explosive events during the 8–22 April 2021 activity of La Soufrière volcano. We estimated magma supply rates and erupted volumes in each explosion, characterized uncertainty by stochastic modelling and identified four eruptive stages. Stage 1 included an intense period of 9.5 hours with 11 explosive events with peak eruption intensity between 2000 and 4000 m 3 s −1 and magma supply rate reaching 828 m 3 s −1 . Twelve high-intensity explosions ( c. 4000 m 3 s −1 ) occurred in Stage 2 with average magma supply rate of 251 m 3 s −1 . Stage 3 involved both declining intensity and magma supply rate and lengthening repose periods between explosions. Stage 4 involved three much weaker explosions. The total erupted volume of magma is estimated at 38.5 × 10 6 m 3 (90% credible interval: [22.0 .. 61.9] × 10 6 m 3 ) consistent with independent estimates from analysis of tephra deposits and volcano subsidence sourced at c. 6 km depth. The 150-fold increase in magma supply rate, from the preceding effusive phase to Stage 1 of the explosive phase, is attributed to replacement of very high-viscosity degassed magma occupying the shallow conduit system with new, lower-viscosity, volatile-rich magma from the magma chamber.

Reconstructing tephra fall deposits via ensemble-based data assimilation techniques

Abstract. In recent years, there has been a growing interest in ensemble approaches for modelling the atmospheric transport of volcanic aerosol, ash, and lapilli (tephra). The development of such techniques enables the exploration of novel methods for incorporating real observations into tephra dispersal models. However, traditional data assimilation algorithms, including ensemble Kalman filter (EnKF) methods, can yield suboptimal state estimates for positive-definite variables such as those related to volcanic aerosols and tephra deposits. This study proposes two new ensemble-based data assimilation techniques for semi-positive-definite variables with highly skewed uncertainty distributions, including aerosol concentrations and tephra deposit mass loading: the Gaussian with non-negative constraints (GNC) and gamma inverse-gamma (GIG) methods. The proposed methods are applied to reconstruct the tephra fallout deposit resulting from the 2015 Calbuco eruption using an ensemble of 256 runs performed with the FALL3D dispersal model. An assessment of the methodologies is conducted considering two independent datasets of deposit thickness measurements: an assimilation dataset and a validation dataset. Different evaluation metrics (e.g. RMSE, MBE, and SMAPE) are computed for the validation dataset, and the results are compared to two references: the ensemble prior mean and the EnKF analysis. Results show that the assimilation leads to a significant improvement over the first-guess results obtained from the simple ensemble forecast. The evidence from this study suggests that the GNC method was the most skilful approach and represents a promising alternative for assimilation of volcanic fallout data. The spatial distributions of the tephra fallout deposit thickness and volume according to the GNC analysis are in good agreement with estimations based on field measurements and isopach maps reported in previous studies. On the other hand, although it is an interesting approach, the GIG method failed to improve the EnKF analysis.

Characteristics of particulate matter during New Year's eve fireworks and Taal volcano ashfall in Metro Manila on January 2020

In this study, we describe the chemical and physical characteristics of two air pollution events in the first half of January 2020 in Metro Manila, Philippines, namely the New Year's eve fireworks and the Taal volcano ashfall. During the New Year's eve fireworks, PM2.5 concentration and most of the chemical components increased three-fold. However, we found disproportionately higher increases for certain metallic components typically used as pyrotechnic propellant and/or colorant for blue, white, and green light: Fe(5-fold), Cr(5-fold), Cu(8-fold), Ni(9-fold), V(10-fold), Ti(11-fold), and Ba(34-fold). These results provide insights for health assessments and legislation related to fireworks emissions. On January 12, 2020, the Taal volcano eruption caused much concern in Metro Manila as visible tephra deposits were observed. There was only a slight increase (8%) in PM2.5 concentration and its components related to basaltic ash. The low PM2.5 concentration was mainly due to the inhibited intrusion of ash into the stable nocturnal boundary layer. In addition, the detection of lightning in the plume and umbrella region showed size segregation of ash particles. The WRF-Chem model was able to capture the distribution of both tephra advection and fallout, a first for Taal volcano, making it possible for use in the future ashfall forecasting.

Eruptive history of Mt. Fuji over the past 8000 years based on integrated records of lacustrine and terrestrial tephra sequences and radiocarbon dating

Reliable records of past volcanic activities are essential for assessing future eruption probabilities and establishing effective volcanic disaster mitigation plans. We integrated the lacustrine and terrestrial sequences of tephra deposits at the northeastern foot of Mt. Fuji based on high-resolution radiocarbon (14C) dating to elucidate its eruptive history over the past 8000 years. Accurate chronologies of 29 tephra layers in the Lake Yamanaka sediments (core YA-1) were determined using the age-depth model of the 14C of bulk organic matter after variability correction of lake reservoir ages. The following ages were compared to those of major tephra deposits in the proximal trench section (MF20-01) and in the literature. From ∼7300 to ∼3200 cal yr BP, four tephra layers in core YA-1 (i.e., YA-T1, 2, 7, and 10) were likely correlated with the scoria fall deposits S-3, 5, 6, and 10 respectively, as reported in the outcrops near the lake. The core also features six undetected eruptions from ∼5050 to ∼3900 cal yr BP, demonstrating the advantages of lake sediments proximal to the volcano in identifying previously undetected eruptions. After ∼3200 cal yr BP, five tephra layers in core YA-1, ranging from ∼2900 to ∼1600 cal yr BP (YA-T11, 12, 14, 20, and 22), showed similar age ranges as the major tephra layers in MF20-01 (IY5, 8, 11, 25, and 26), with identical lithological characteristics and stratigraphic orders. This suggests that the tephra sequence in the trench section positively reflects the major eruptive events over the past 2900 years, providing a basis for the comprehensive reconstruction of volcanic eruption histories in the region.

Historical explosive activity of Mount Melbourne Volcanic Field (Antarctica) revealed by englacial tephra deposits

Five tephra layers named BRH1 to 5 were sampled in an ice cliff located on the north-eastern flank of Mount Melbourne (northern Victoria Land, Antarctica). The texture, componentry, mineralogy, and major and trace element compositions of glass shards have been used to characterize these layers. These properties suggest that they are primary fall deposits produced from discrete eruptions that experienced varying degrees of magma/water interaction. The major and trace element glass shard analyses on single glass shards indicate that Mount Melbourne Volcanic Field is the source of these tephra layers and the geochemical diversity highlights that the eruptions were fed by compositionally diverse melts that are interpreted to be from a complex magma system with a mafic melt remobilizing more evolved trachy-andesitic to trachytic magma pockets. Geochemical compositions, along with textural and mineralogical data, have allowed correlations between two of the englacial tephra and distal cryptotephra from Mount Melbourne, recovered within a marine sediment core in the Edisto Inlet (~ 280 km northeast of Mount Melbourne), and constrain the age of these englacial tephra layers to between the third and the fourth century CE. This work provides new evidence of the intense historical explosive activity of the Mount Melbourne Volcanic Field and better constrains the rates of volcanism in northern Victoria Land. These data grant new clues on the eruptive dynamics and tephra dispersal, and considerably expand the geochemical (major and trace elements) dataset available for the Mount Melbourne Volcanic Field. In the future, this will facilitate the precise identification of tephra layers from this volcanic source and will help define the temporal and spatial correlation between Antarctic records using tephra layers. Finally, this work also yields new valuable time-stratigraphic marker horizons for future dating, synchronization, and correlations of different palaeoenvironmental and palaeoclimatic records across large regions of Antarctica.

Tephra sedimentation and grainsize associated with pulsatory activity: the 2021 Tajogaite eruption of Cumbre Vieja (La Palma, Canary Islands, Spain)

Long-lasting eruptions are of complex characterization and are typically associated with challenging risk assessment and crisis management due to the usual occurrence of multiple interacting hazards evolving at different temporal and spatial scales (e.g., lava, tephra, and gas). The 2021 Tajogaite eruption of Cumbre Vieja (La Palma) demonstrated how even hybrid events that are mostly effusive can be associated with widespread and impacting tephra deposits as a result of a complex interplay among gas flux, conduit geometry, and magma feeding rate. In this novel study, direct observations, syn-eruptive and post-eruptive sampling, and statistical analysis of pulsatory activity have been combined to provide new insights into eruption dynamics. They show how rapid gas segregation and high magma ascent rate modulated the gas flux at multiple vents, resulting in short-time fluctuations among the different explosive styles (ash-poor gas puffing, Strombolian, violent Strombolian, and lava fountaining) and unsteady tephra ground accumulation. Various size-selective sedimentation processes were also observed, including particle aggregation and ash fingers, which have impacted the overall tephra dispersal. In fact, even though both local and total grainsize distributions of selected layers, units, and of the whole tephra blanket are unimodal with a low fine-ash content, grainsize analysis of 154 samples suggests no correlation of particles &amp;lt;63 μm with distance from vents. Our analyses demonstrate the need to include a detailed characterization of all products of hybrid eruptions for a comprehensive interpretation of eruptive dynamics and to use multiple classification strategies that can capture eruptive styles at different temporal scales.

Ultra-distal tephra deposits and Bayesian modelling constrain a variable marine radiocarbon offset in Placentia Bay, Newfoundland

Abstract. Radiocarbon dating marine sediments is complicated by the strongly heterogeneous age of ocean waters. Tephrochronology provides a well-established method to constrain the age of local radiocarbon reservoirs and more accurately calibrate dates. Numerous ultra-distal cryptotephra deposits (non-visible volcanic ash more than 3000 km from source) have been identified in peatlands and lake sediments across north-eastern North America and correlated with volcanic arcs in the Pacific north-west. Previously, however, these isochrons have not been identified in sediments from the north-west Atlantic Ocean. In this study, we report the presence of two ultra-distal cryptotephra deposits; Mazama Ash and White River Ash eastern lobe (WRAe), in Placentia Bay, North Atlantic Ocean. We use these well-dated isochrons to constrain the local marine radiocarbon reservoir offset (ΔR) and develop a robust Bayesian age–depth model with a ΔR that varies through time. Our results indicate that the marine radiocarbon offset in Placentia Bay was -126±151 years (relative to the Marine20 calibration curve) at the time of Mazama Ash deposition (7572 ± 18 yr BP) and −396 ± 144 years at the time of WRAe deposition (1098–1097 yr BP). Changes in ΔR appear to coincide with inferred shifts in relative influences of the inner Labrador Current and the Slopewater Current in the bay. An important conclusion is that single-offset models of ΔR are easiest to apply and often hard to disprove. However, such models may oversimplify reservoir effects in a core, even over relatively short timescales. Acknowledging potentially varying offsets is critical when ocean circulation and ventilation characteristics have differed over time. The addition of tephra isochrons permits the calculation of semi-independent reservoir corrections and verification of the single ΔR model.

A guide to assess distance from ecological baselines and change over time in palaeoecological records

Palaeoecology provides critical data for establishing ecological ‘baselines’, which can guide restoration efforts and be used to assess ecosystem change. However, statistical analyses can be challenging because of the large number of methods available for establishing palaeoecological baselines combined with a lack of practical guidance, particularly around quantifying baselines that include natural variability. We contribute one solution by providing guidance and an R package baselines for using palaeoecological data to (i) define baselines and (ii) test for change over time that incorporates variability. These methods provide an alternative to single-taxon analyses and allow ecosystem complexity to be captured. We use published pollen records as case studies to demonstrate how to establish vegetation baselines for seven localities in New Zealand where relatively recent (c. 1280 AD) and near-simultaneous human settlement across the country allows background environmental disturbance in the pre-human era to be distinguished from anthropogenic disturbance. We present methods for calculating distance from initial sample, distance from baseline in ordination space, allowing incorporation of ecosystem variability, and analysis of rates of change over time using principal curves. We found conventional and Bayesian ordination methods yielded similar results and were effective at identifying change following human settlement, despite the potential for a positive mean-variance relationship to confound results. Principal response curves were most sensitive to a known period of vegetation disturbance caused by volcanic eruptions at two sites with tephra deposits. Our proposed methods, case study and R package baselines are designed to provide a suite of tools to encourage and enable palaeoecological data to be used by palaeoecologists to assess trajectories and change over time, and monitor whether historical management actions have facilitated a change in direction towards a desired baseline state.

An integrated proximal-distal radiocarbon dating approach provides improved age constraints for a key Holocene tephra isochron

Volcanic ash (tephra) horizons are an essential tool for the spatial and temporal correlation of many natural archives. However, tephrochronology is accompanied by age uncertainties that often limit its capacity to effectively constrain age models. This is particularly problematic for paleoseismology in complex tectonic settings such as New Zealand, where the accuracy and precision of earthquake ages is important for interpreting past fault interactions and earthquake sequences. We use the widespread Waimihia tephra, erupted at ∼3.4 ka from Taupō volcano, as a case study for generating improved age constraints for Holocene tephra isochrons. Our dating strategy minimizes uncertainties by (i) conducting detailed assessments to identify the most reliable dateable material, (ii) using precise AMS dating techniques, and (iii) constructing Bayesian age models. By applying consistent procedures to date tephra deposits at proximal, onshore distal and offshore distal locations, we also facilitate the detection of any geographic radiocarbon bias. Based on high agreement between the independently derived tephra ages from each location, we demonstrate no offsets in radiocarbon results between proximal and distal deposits, precluding bias from near-vent magmatic degassing. Our integrated age model exploits the benefits of each individual dating approach and uses the full suite of 42 new radiocarbon dates to yield an age of 3574–3478 cal yr BP (highest 95% range) for the Waimihia eruption. Compared to previous estimates, this older and more precise age has implications for refining existing paleoearthquake correlations and other chronologies that rely on the Waimihia isochron to provide age control. We recommend applying this multi-location approach to existing tephrochronologies where possible, to achieve more accurate and precise eruption age estimates that allow for the detection of radiocarbon bias.

A palaeoecological study investigating the impacts of multiple tephra depositions on a lacustrine ecosystem in Northeast China, using diatoms as environmental indicators

Tephra layers are common in lake sediments and although they have often been used as chronological controls, few studies have investigated the impacts of past tephra depositions on lake ecosystems (Tephropalaeoecology). For the first time we systematically assess how different types of tephra layers vary in their ecological impact on the same lacustrine system. We use a diatom-based tephropalaeoecological approach to infer the impacts of five tephra deposits on Lake Sihailongwan, a well-studied volcanic lake in Northeast China, over the past 30,000 years. The five tephra layers (including two micro-tephras) have varying thicknesses and were deposited in time periods with different climatic conditions. Changes in diatom communities and chrysophyte-cyst concentrations between pre- and post-tephra samples were used to infer changes in lake conditions and highlight the importance of lake background conditions in mediating the impact of tephra. While the two micro-tephra layers did not cause observable changes, the three thicker tephras induced pronounced changes in lake conditions and thus diatom communities. The two thick tephras deposited in more eutrophic and warmer lake conditions caused larger responses from diatoms. We argue that water-column phosphorus decreased due to reduced sediment–water-phosphorus loading as thick tephra layers formed an impermeable layer at the lake bottom. This is supported by a decrease in total diatom concentration and a decline in high phosphorus-requiring taxa such as Discostella stelligeroides and Stephanodiscus minutulus as well as modern limnological observations which showed that groundwater influxes from the lake bottom are the main source of nutrients to the lake. By contrast, the thick tephra deposited in more oligotrophic and colder lake conditions caused less conspicuous changes. When the lake was already low in phosphorus, diatoms did not respond to a further decline in phosphorus but rather responded to the minor increase in silica from the dissolution of tephra particles in the water column. This was inferred from the slight increases in overall diatom concentration and opportunistic taxa such as Pantocsekiella comensis f. minima. Diatom analysis of the post-tephra sediments above the three thick tephras showed that the aquatic ecosystem did not completely recover, indicating the long-lasting effects of these thick tephras and shifts to new lake-ecosystem equilibria.

The influence of burial rate on variability in tephra thickness and grain size distribution in Iceland

We explore whether the rate at which a tephra deposit is buried influences the variability (thickness and grain size distribution) within the tephra layer subsequently preserved within the stratigraphic record. This has important implications for understanding how processes of soil formation interact with the creation of a volcanic record. To assess the relationship between soil formation and the preservation of tephra layers, the thickness and grain size distribution of the Katla 1918 tephra in Iceland and the rate at which it was buried (inferred from the thickness of the overlying soil) was measured 1620 times at six locations. Tephra layer thickness does not correlate with rate of burial, but the proportion of original deposit retained does, and variations in grain size distribution are correlated with burial rate. Our results indicate that whilst medium term (i.e. years-decades) burial processes may contribute less to tephra layer variability than environmental processes operating immediately after deposition, rapid burial facilitates better preservation of the original fallout characteristics with important implications for the accurate reconstruction of past volcanic eruptions based on tephra layer characteristics. There are two key implications: firstly, sites need to be chosen where surface characteristics minimise the initial alterations of tephra deposits, and secondly sites with rapid burial will produce the best quality data, although workable data can be gathered elsewhere if areas of uncertainty are acknowledged.

Island ecosystem responses to the Kuwae eruption and precipitation change over the last 1600 years, Efate, Vanuatu

IntroductionIslands of the Southwest Pacific are exposed to geologic and climate-related disturbances that occur on a range of timescales and which probably affect, to varying degrees, their terrestrial ecosystems. Over the past ∼1100 years we know of two major events in the region: the Kuwae eruption which is thought to have occurred ∼500 cal. years BP and a shift to drier conditions which began ∼1100 cal. years BP.MethodsWe investigated terrestrial and lacustrine ecosystem responses to these events and also to a changing fire regime, likely human-caused, using a multi-proxy (C/N, charcoal, chironomids, pollen, and tephra) record from Lake Emaotul, Efate, Vanuatu.ResultsTephra from the Kuwae eruption was found across a 6 cm layer which our age-depth model suggests was deposited 650–510 cal. years BP (95% confidence). Forest and chironomid community turnover increased during the wet-dry shift 1100–1000 cal. years BP; subsequently, chironomid turnover rates decreased again within &amp;lt;135 years and vegetation had partially (but not fully) recovered after ∼80 years. Following Kuwae volcanic tephra deposition, vegetation turnover increased again, reflecting a reduction in small trees and shrubs and an increase in grasses. Subsequently, the forest vegetation did not regain its previous composition, whereas chironomid community composition remained fairly stable before and after tephra deposition. Within the last ∼90 years, enhanced local burning drove another increase in vegetation turnover.DiscussionTerrestrial and freshwater ecosystems in Efate are sensitive to changes in hydroclimate, volcanism, and anthropogenic fires, although to different degrees; while recent human impacts are often obvious, volcanic eruptions and climatic shifts have also structured Pacific-island ecosystems and will continue to do so.

Volcanic, tectonic and climate controls on lacustrine sedimentary supplies over the last millenia in NE Chilean Patagonia (Lake Esponja, Aysen, 45°S)

The environmental variability of Northern Chilean Patagonia during the last millennia is evaluated using a multi-proxy analysis of sediment cores from Lake Esponja (45°S 72°W) to decipher if the sediment deposition is controlled by volcanic eruptions, landslides induced by earthquake or heavy rainfall. The lake is located in a glacio-tectonic valley in Patagonia. The organic-rich clayey silt sediment with low biogenic silica content was analysed for grain size, magnetic susceptibility, organic matter, biogenic silica content and diatom assemblages, mineralogy (X-ray diffraction), organic (IRMS C and N analyses) and inorganic (XRF core-scanner) geochemistry and glass shard major composition (Microprobe, SEM). The combination of 210Pb, 137Cs, 14C and tephrochronology indicates an averaged accumulation rate of 0.4 mm/year, leading to a record of ~3.5 kyr within 154 cm. The sedimentary geochemistry records changes in volcanic supplies, diatom productivity and detrital inputs. The sediments were interrupted by millimetric to centimetric layers corresponding to tephra deposition related to explosive eruptions of nearby volcanoes Macá, Melimoyu and Hudson. Concerning the diatoms, the dominant planktonic species (80–150 cm) are replaced by benthic species in a transition interval (55–80 cm) and then by Surirella spp. in the upper core. This last genus indicates a closure of the basin ~2 ka ago, probably related to an uplift linked to a rejuvenation of the Mañihuales fault. This local change could reflect regional tectonic instability. Indeed, a partial earthquake rupture occurred around ~AD100 along the southern part of the Valdivia segment, recorded as a mass transport deposit in Aysén fjord sedimentation. The fine detrital input varies over time with more variable Si/Al values in the lower part of the LEs14 core than in the upper 80 cm. The higher values may reflect wetter conditions, leading to an higher lake level and more turbid conditions in agreement with changes in diatom assemblages.

Release of tephra-hosted iron during early diagenesis fingerprinted by iron isotopes

The micronutrient iron (Fe) plays a fundamental role controlling primary productivity in the upper ocean, with volcanic eruptions and deposition of airborne volcanic material (termed tephra) a potential source of Fe. Here, we investigate the geochemical and Fe isotopic (δ56Fe) composition of tephra layers, sediments, and mixed tephra-sediment samples from the Integrated Ocean Drilling Program (IODP) Hole 1396C, located offshore the volcanically active island of Montserrat in the Lesser Antilles, Caribbean Sea. We find that buried tephras, which have experienced diagenesis, exhibit lighter δ56Fe (relative to standard IRMM-524a) compositions (down to −0.26 ± 0.04‰, 2SD) than fresh tephra deposited in Montserrat (δ56Fe = 0.02 ± 0.02‰, 2SD). Such negative values suggest that isotopically heavier Fe has been lost from the originally deposited material. Using multivariate statistical modelling and mass balance constraints, we identify the outward Fe flux (with calculated δ56Fe of 0.21 ± 0.31‰, 2SD, n = 12) during non-reductive dissolution of tephra as the likely cause of the retention of these light δ56Fe compositions. Due to the widespread nature of tephra deposition, tephra diagenesis may provide an important source of isotopically heavy dissolved Fe (dFe) to the oceans. This process contrasts with more commonly considered reductive dissolution processes, which provide a source of dFe enriched in light isotopes to the oceans.

Postglacial vegetation and fire history with a high-resolution analysis of tephra impacts, High Cascade Range, Oregon, USA

The postglacial history of vegetation, wildfire, and climate in the Cascade Range (Oregon) is only partly understood. This study uses high-resolution macroscopic charcoal and pollen analysis from a 13-m, 14,500 years sediment record from Gold Lake, located in a montane forest, to reconstruct forest vegetation and fire history. The occurrence of three tephra layers, including a 78-cm airfall Mazama tephra, as well as highly laminated segments, allows one to study tephra impacts on vegetation at a fine temporal resolution. From the Late Glacial through the Younger Dryas, pollen spectra vary little. The early Holocene is marked by a sudden increase in Pseudotsuga, indicating warmer conditions, while the late Holocene is marked by increasing Tsuga heterophylla and Tsuga mertensiana, indicating the onset of moist conditions in the region. High-resolution charcoal data show periods of large peaks during the Late Glacial, pre-, and post-Mazama eruption and since 4 ka (thousands of years before present). Low fire during the early Holocene is unexpected, given regional evidence of warmer and drier summers, but it may be the result of fuel limitation. After the Mazama tephra deposition (7.63 ka), the non-arboreal pollen composition was changed, with some taxa disappearing or reduced in abundance for 300 years. Arboreal taxa were little affected by the tephra, showing only a 20% increase in Pinus pollen and no discernible impact on the pollen accumulation rate (PAR).In contrast, the Mazama tephra was followed by ca. 70 years of very low charcoal input, followed by a large peak, consistent with the burial of surface fuels and decades of fuel accumulation. There was also increased fire frequency and peak magnitude at 1.5 ka, followed by very little fire after 0.4 ka, consistent with the current old-growth forest surrounding the lake. This detailed and high-resolution record adds significantly to understanding the impacts of climate change and the singular effect of the Mazama eruption, impacting watershed vegetation, and fire for centuries but with minimal impact on the regional forest composition.

Volcaniclastic sedimentation in a closed, marginal rift basin: the case of the Melka Kunture area (upper Awash, Ethiopia)

Abstract The upper Awash runs across a volcano-sedimentary succession dated from the Early to Middle Pleistocene and located on the western margin of the northern portion of the Main Ethiopian Rift. The succession lies above Late Miocene to Pliocene lava flows, domes and large volume ignimbrites. The succession formed within a fluvial system that developed within transversal rift faults. The stratigraphy consists of primary volcanic deposits interbedded with reworked sediments emplaced in a low-energy floodplain developed in a subsiding area. The lower part of the volcaniclastic sequence is dominated by a 1.2 Ma old, low aspect ratio, pyroclastic density current deposit (Kella ignimbrite). This eruption was followed by an eruptive stasis and reorganization of the drainage system. Tephra deposition in the floodplain climaxed again between 0.9 and 0.7 Ma and was associated with extensive tephra reworking. Sedimentation rates significantly decreased after 0.6 myr ago, probably owing to declining volcanic activity. Dynamic interaction between tectonics and volcanic activity created a complex sedimentary environment preserving numerous artefacts (lithic tools), animal and hominin remains. Stratigraphic correlation is based on the interpretation of the basin evolution and has relevance for the reconstruction of the palaeoenvironment and the interpretation of the palaeontological and archaeological data.

CHEMICAL AND TEXTURAL STUDIES OF THE YOUNGEST PYROCLASTIC DEPOSITS AT MT. SEMINUNG (SOUTH SUMATRA, INDONESIA): A WINDOW FOR UNDERSTANDING THE EXPLOSIVE BEHAVIOR OF A POST-CALDERA VOLCANO

The youngest tephra deposits of Seminung Volcano in South Sumatra, Indonesia, was studied by addressing the stratigraphy (field data), componentry, petrography, glass and mineral compositions, and textural analysis of vesicles to interpret the magmatic system and eruption dynamics. Based on the componentry and grain size characteristics, the section is divided into three different units: (1) massive block and ash, (2) interbedded ash and lapilli, and (3) massive lapilli. All units include grey pumice (GP), brown pumice (BP), and scoria (SC) as the main juvenile types, while porphyritic lava occurs as the non-juvenile phase (lithics). Noteworthy, minor banded pumice (BaP) can be observed in all units, and accretionary lapilli (AL) is exclusive in the interbedded ash and lapilli unit. The similarity in mineralogy and the linear correlation of all major elements of glass compositions suggest that grey and brown pumice originated from the same shallow, biotite-bearing more silicic magma (64.5-74.9 wt. % ), while scoria originates from the deeper, biotite-free less silicic magma (62.1-69.2 wt. % ). The fact that grey pumice shows higher silica content and pheno-bubble fraction with lower phenocryst content than brown pumice suggests the rough stratification of the more silicic magma reservoir. Furthermore, the more silicic magma was likely intruded by the deeper less silicic magma, as indicated by the bimodal distribution of anorthite (An#) in grey and brown pumices (i.e. the peak of the high anorthite content is similar to that of scoria). Thus, the accumulation of pheno-bubble and magmatic recharge were likely responsible for triggering the eruption. Finally, the fact that juvenile clasts from units 2 and 3 had the highest matrix-vesicle number density (MVND) implies that the eruption intensity reached its peak towards the final eruption stage.