Taking the Co68.7Fe4Ni1B13Si11Mo2.3 glass-coated amorphous microwire as the research object, the mechanical properties of the amorphous wire were tested through biaxial tensile experiments, and the fracture deformation process of the amorphous wire was analyzed. Based on the experimental data, the finite element method was used The simulation software ABAQUS numerically simulates the tensile deformation of the amorphous wire, and the fracture relationship between the glass cladding layer and the core wire, and further reveals the tensile deformation fracture behavior of the amorphous wire was analyzed. The experimental results indicate that the fabricated microwires exhibit good tensile properties, and the maximum tensile breaking strength can reach 2918MPa; the fracture of the amorphous wire is a typical brittle fracture, and there is no obvious yield phenomenon. The tensile mechanics simulation results of the amorphous wire are consistent with the experimental results. The glass cladding layer breaks before the core wire, and the stress transfer effect in the amorphous wire is good. The model fracture is consistent with the fracture morphology of the amorphous wire. These results show that the amorphous wire exhibits good tensile properties and stress transmission capabilities, confirming the huge application potential of amorphous wire materials in sensor applications and functional composite materials.