Publisher Summary This chapter focuses on the problem of thermophoresis in gases taking into account a volatility of particle substance. The effect of volatility on thermophoresis is twofold—that is, the temperature distribution inside and outside the particle changes and the surrounding space fills with the vapor of the volatile substance leading to thermal diffusion in the mixture and an uncompensated transfer of momentum from gas molecules to the particle. At room temperature, the change in the temperature field is more essential for particles with low thermal conductivity. The fact that the experimentally obtained values of thermophoretic velocity significantly exceed the computed ones—by Epstein's formula—cannot be accounted for solely be the effect of volatility.
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