Temperature Dependence Research Articles

Synthesis and properties of 12442-family superconductor

We report a synthesis of two members of recently discovered high-temperature superconductors of 12442 family, with formula MCa2Fe4As4F2 (M=Rb,K) and transition temperatures of 32.7 and 34.6K, respectively. Quality of the samples was assessed using X-ray powder diffraction, superconducting transitions were identified through transport and magnetic experiments. The temperature dependence of the upper critical field and vortex activation energy was investigated under magnetic fields up to 19T. Two distinct thermally activated flux flow regimes were observed in both systems. Field dependences of activation energy U0(H) indicate a change in the properties of vortex matter in these regimes and distinctly different dissipation mechanisms, reminiscent of cuprate HTSC.

ABOUT ONE METHOD OF STUDYING THE COEFFICIENT OF THERMAL EXPANSION OF POLYMERS

The problem of studying the deformation response of film samples made of UV-curable polymers to temperature changes is considered. It is difficult to obtain massive samples of these polymers due to the peculiarities of their polymerization. This paper suggests a methodology for tests that allows us to determine the temperature dependence of the coefficient of linear thermal expansion (CTE) in a wide range, including the relaxation transition. As measuring equipment was used a dynamic mechanical analyzer TA Instruments Q800 DMA with liquid nitrogen cooling system GCA, which allows varying temperature and its rate of change in wide ranges, controlling and measuring forces and displacements with high accuracy. The proposed approaches are applicable to any film samples and provide an opportunity to establish functional dependences of CTE not only on temperature, but also on its rate of change. At the same time, in contrast to traditional methods, the described procedures allow obtaining correct data under the conditions of relaxation transitions taking into account the influence of the temperature change rate on these processes. Considerable attention is paid to calibrate the measuring equipment, in particular, the measurement and compensation of the temperature deformation of the tooling. The measurements results are compared with known literature sources, manufacturers data, the results of measurements of samples with known characteristics and with the results obtained on a horizontal dilatometer. It is shown that the proposed method of measurements is correct and has a number of advantages over traditional methods of research when working with film samples or in cases where it is necessary to take the effect of the rate of temperature change on CTE into account.

On the phase behaviors of CH4-CO2 binary clathrate hydrates: Equilibrium with aqueous phase.

We explore the solubilities of guest CH4 and/or CO2 in the aqueous state coexisting with the corresponding hydrate. The equilibrium conditions are estimated by calculating the chemical potentials of water and guest species in the hydrate on the basis of a statistical mechanical theory using pairwise intermolecular potentials. This requires the least computational cost while covering a wide range of temperature, pressure, and composition of guest species, even for the binary hydrate. The nonstoichiometric nature, one of the most important characters of hydrates, is invariably taken into account when evaluating its phase behaviors and the driving force for nucleation of hydrates. The two-phase equilibrium concerning CO2 hydrate is evaluated considering a low but finite value of CO2 solubility in water. It is found that the finite solubility gives rise to a small systematic deviation of the dissociation temperature of CO2 hydrate. The solubility of CO2 coexisting with fluid CO2 decreases with temperature but the opposite temperature dependence is obtained in the presence of hydrate, as in the case of CH4. This method is applied to CH4-CO2 binary hydrates of various guest compositions. We also find a significant difference in composition of guests among the phases involved in the equilibria.

Temperature dependence of thermal conductivity of proteins: Contributions of thermal expansion and Grüneisen parameter.

The thermal conductivity of many materials depends on temperature due to several factors, including variation of heat capacity with temperature, changes in vibrational dynamics with temperature, and change in volume with temperature. For proteins some, but not all, of these influences on the variation of thermal conductivity with temperature have been investigated in the past. In this study, we examine the influence of change in volume, and corresponding changes in vibrational dynamics, on the temperature dependence of the thermal conductivity. Using a measured value for the coefficient of thermal expansion and recently computed values for the Grüneisen parameter of proteins we find that the thermal conductivity increases with increasing temperature due to change in volume with temperature. We compare the impact of thermal expansion on the variation of the thermal conductivity with temperature found in this study with contributions of heat capacity and anharmonic coupling examined previously. Using values of thermal transport coefficients computed for proteins we also model heating of water in a protein solution following photoexcitation.

The effect of acceptor and donor doping on the electronic properties of the half-Heusler TiNiSn.

Optimizing the electronic transport properties of thermoelectric compounds is commonly achieved by either donor or acceptor atom doping to increase the conduction of the appropriate carrier type, electrons or holes, respectively. Enhancing carrier mobility and carrier concentration will both lead to optimized electronic properties. In this work the effect of various dopants on the electronic properties of TiNiSn was explored, by modeling the doping of an ideal compound on the Ti-sublattice with acceptor or donor elements. Using ab initio DFT calculations and a set of analytical expressions of transport properties, the temperature dependencies of the electronic properties were calculated, to examine possible n-type or p-type dopants to be used in further experimental studies.

Temperature Dependence of Coupling Loss between Polymer Optical Waveguides and SMF for Co-Packaging

Temperature Dependence of Coupling Loss between Polymer Optical Waveguides and SMF for Co-Packaging

Impact of nonextensivity on the transport coefficients of strongly interacting QCD matter

Abstract Tsallis nonextensive statistics is applied to study the transport coefficients of strongly interacting matter within the Polyakov chiral SU(3) quark mean field model (PCQMF). Nonextensivity is introduced within the PCQMF model through a dimensionless $q$ parameter to examine the viscous properties such as shear viscosity ($\eta$), bulk viscosity ($\zeta_b$), and conductive properties, including electrical conductivity ($\sigma_{el}$) and thermal conductivity ($\kappa$). Additionally, some key thermodynamic quantities relevant to the transport coefficients, like the speed of sound ($c_{sq}^2$) and specific heat at constant volume ($c_{vq}$), are calculated. The temperature dependence of the transport coefficients is explored through a kinetic theory approach with the relaxation time approximation. The results are compared to the extensive case where $q$ approaches 1. The nonextensive $q$ parameter is found to have a significant effect on all transport coefficients. We find that the nonextensive behaviour of the medium enhances both specific shear viscosity $\eta/s_q$ as well as conductive coefficients $\sigma_{el}/T$ and $\kappa/T^2$. In contrast, the normalised bulk viscosity $\zeta_b/s_q$ is found to decrease as the nonextensivity of the medium increases. We have also studied the transport coefficients for finite values of chemical potentials. The magnitude of $\eta$, $\sigma_{el}$, and $\kappa$ increases at lower temperatures while $\zeta$ is found to decrease for systems with non-zero chemical potential.

Multiscale modeling of short pulse laser induced amorphization of silicon

Silicon surface amorphization by short pulse laser irradiation is a phenomenon of high importance for device manufacturing and surface functionalization. To provide insights into the processes responsible for laser-induced amorphization, a multiscale computational study combining atomistic molecular dynamics simulations of nonequilibrium phase transformations with continuum-level modeling of laser-induced melting and resolidification is performed. Atomistic modeling provides the temperature dependence of the melting/solidification front velocity, predicts the conditions for the transformation of the undercooled liquid to the amorphous state, and enables the parametrization of the continuum model. Continuum modeling, performed for laser pulse durations from 30 ps to 1.5 ns, beam diameters from 5 to 70 μm, and wavelengths of 532, 355, and 1064 nm, reveals the existence of two threshold fluences for the generation and disappearance of an amorphous surface region, with the kinetically stable amorphous phase generated at fluences between the lower and upper thresholds. The existence of the two threshold fluences defines the spatial distribution of the amorphous phase within the laser spot irradiated by a pulse with a Gaussian spatial profile. Depending on the irradiation conditions, the formation of a central amorphous spot, an amorphous ring pattern, and the complete recovery of the crystalline structure are predicted in the simulations. The decrease in the pulse duration or spot diameter leads to an accelerated cooling at the crystal–liquid interface and contributes to the broadening of the range of fluences that produce the amorphous region at the center of the laser spot. The dependence of the amorphization conditions on laser fluence, pulse duration, wavelength, and spot diameter, revealed in the simulations, provides guidance for the development of new applications based on controlled, spatially resolved amorphization of the silicon surface.

Anisotropy of the zigzag order in the Kitaev honeycomb magnet α−RuBr3

Kitaev materials often order magnetically at low temperatures due to the presence of non-Kitaev interactions. Torque magnetometry is a very sensitive technique for probing the magnetic anisotropy, which is critical in understanding the magnetic ground state. In this paper, we report detailed single-crystal torque measurements in the proposed Kitaev candidate honeycomb magnet α−RuBr3, which displays zigzag order below 34 K. Based on angular-dependent torque studies in magnetic fields up to 16 T rotated in the plane normal to the honeycomb layers, we find an easy-plane anisotropy with a temperature dependence of the torque amplitude following closely the behavior of the powder magnetic susceptibility. The torque for the field rotated in the honeycomb plane has a clear sixfold periodicity with a sawtooth shape, reflecting the threefold symmetry of the crystal structure and stabilization of different zigzag domains depending on the field orientation, with a torque amplitude that follows an order parameter form inside the zigzag phase. By comparing experimental data with theoretical calculations we highlight the importance of relevant anisotropic interactions and the role of the competition between different zigzag domains in this candidate Kitaev magnet. Published by the American Physical Society 2024

Investigation into the impedance, dielectric behavior, and conductivity within p-silicon/n-nanocrystalline iron disilicide heterojunctions and equivalent circuit model in relation to temperature

The p-Si/n-nanocrystalline FeSi2 heterojunctions constructed through facing-targets sputtering were characterized for impedance under various frequencies and temperatures of between 160−400 K. Imaginary and real impedance plots for all temperatures demonstrated single semicircular arc with negative temperature dependency. From the arc, a circuit model equivalent to electrode resistance serially connected to several loops, each consisting of a parallel circuit comprising a resistance//constant phase element (Q), corresponding to the crystallite, crystallite boundary, and interface. All resistances increased with decreasing temperatures, while the Q values decreased but behaved as ideal capacitors for all temperatures. The dielectric constants versus increasing temperature demonstrated a linear increase. At 300 K and 1 MHz, the dielectric constant was 24.5 with 0.1 loss tangent, denoting its possible usage for filtration and storage. The alternating-current conductivities disclosed that direct-current conductivities increased as the temperature increased. The exponents from Jonscher's fit were 1 or less around 180 K and the values beyond 1 at higher temperatures, indicating the shift from long transitional transport to localized hopping transport. The activation energy based on conductivities was higher than the one based on relaxation times, implying that excess charge led to more energy requirements for transportation.

2,3-per-acylated α and β cyclodextrins as inducers of helical liquid crystalline phases

ABSTRACT For the first time, a comprehensive study of the mesomorphic, physical and orientation properties of helical mesophases induced by partially acylated cyclodextrins was carried out. Using polarisation microscopy, the formation of a helical mesophase was established when a nematic mixture of polar 4-alkoxy-4’-cyanobiphenyls (CB-2) was doped with chiral 2,3-per-acetylated and 2,3-per-propionylated α- and β-cyclodextrins. The clearance temperatures and helical pitch were measured. The high efficiency of helix twisting under the influence of these dopants and an increase in the orientational order parameter of the liquid crystal matrix were ascertained. Using Haller’s extrapolation method for approximation the temperature dependences of birefringence a decrease in inverse helix pitch (1/p) upon heating was shown to be due to a reduction in the LC order parameter. Quantum chemical simulation of the acetylated α- and β-cyclodextrins structure and their solvates with 4-pentyloxy-4’-cyanobiphenyl was performed, and their interaction energies and dipole moments were calculated. The formation of inclusion compounds of LC molecules into the internal cavity of acylated CDs was established. The higher interaction energy and helical twisting power, as well as the least destabilisation of the mesophase were shown to be observed for β-cyclodextrin derivatives.

The theoretical approach for description of magnetic properties and magnetocaloric effect in all-d-metal Heusler alloys Ni2−xCoxMn1.25Ti0.75

This paper investigates the influence of Co addition and atomic ordering on the magnetic and magnetocaloric properties of all-d-metal Heusler alloys Ni2−xCoxMn1.25Ti0.75, which exhibit a second-order magnetic phase transition. The modeling approach employed is based on the density functional theory and Monte Carlo method. The atomic ordering is considered with reference to the fully ordered structure, L21, and the partially ordered structure, B2. It is demonstrated that in both structures, the predominant magnetic state within the cubic austenitic phase is characterized by ferromagnetic ordering. An increase in the Co content results in the strengthening of the ferromagnetic exchange interactions between Mn, Ni, and Co, as well as an increase in the Curie temperature. For the ground state L21 structure, the largest Curie temperature values are observed, exceeding those of the B2 structure by almost 100 K. The temperature dependencies of the magnetization and magnetocaloric effect (ΔSmag) in magnetic fields up to 2 T are calculated using the Heisenberg Hamiltonian by the Monte Carlo method. The largest effect (ΔSmag≈1.4 J/kg K) is observed for the compound with x = 0.375 and B2 structure at temperature ≈150 K, whereas for L21-Ni1.5Co0.5Mn1.25Ti0.75 and B2-Ni1.25Co0.75Mn1.25Ti0.75, ΔSmag of 1.05 J/kgK appears in the vicinity of room temperature.

Ionic Conductivity Studies on Proton Conducting Solid Biopolymer Electrolyte Based on 2-Hydroxyethyl Cellulose (2HEC) Doped with Ammonium Chloride (NH4CL)

Solution casting techniques have been used to create a solid biopolymer electrolyte (SBEs) based on 2-hydroxyethyl cellulose (2HEC) doped with varying amounts of ammonium chloride (NH4Cl) to investigate the potential of NH4Cl in enhancing the ionic conductivity of SBE. Electrical impedance spectroscopy (EIS) was used to measure the impedance of the electrolytes between 50 Hz and 1 MHz in frequency. At room temperature, ionic conductivity was at its highest for 16% weight percent of NH4Cl which was 1.74 x 10-3 Scm-1. The temperature dependence data of 2HEC-NH4Cl SBEs abides Arrhenius behaviour. Complex electrical modulus and complex permittivity were used to assess the dielectric data for the sample at various temperatures.

Colossal magnetoresistance from spin-polarized polarons in an Ising system

Recent experiments suggest a new paradigm toward novel colossal magnetoresistance (CMR) in a family of materials EuM 2 X 2 (M = Cd, In, Zn; X = P, As), distinct from the traditional avenues involving Kondo–Ruderman–Kittel–Kasuya–Yosida crossovers, magnetic phase transitions with structural distortions, or topological phase transitions. Here, we use angle-resolved photoemission spectroscopy and density functional theory calculations to explore their origin, particularly focusing on EuCd 2 P 2 . While the low-energy spectral weight royally tracks that of the resistivity anomaly near the temperature with maximum magnetoresistance ( T MR ) as expected from transport-spectroscopy correspondence, the spectra are completely incoherent and strongly suppressed with no hint of a Landau quasiparticle. Using systematic material and temperature dependence investigation complemented by theory, we attribute this nonquasiparticle caricature to the strong presence of entangled magnetic and lattice interactions, a characteristic enabled by the p - f mixing. Given the known presence of ferromagnetic clusters, this naturally points to the origin of CMR being the scattering of spin-polarized polarons at the boundaries of ferromagnetic clusters. These results are not only illuminating to investigate the strong correlations and topology in EuCd 2 X 2 family, but, in a broader view, exemplify how multiple cooperative interactions can give rise to extraordinary behaviors in condensed matter systems.

Influence of a laser pulse on thermoelasticity with temperature dependence under the dual-phase-lag model using improved modified extended tanh function method

In this paper, the improved modified extended tanh function method (IMETFM) is introduced for analyzing the influence of laser pulse on a thermo-elastic with temperature-dependence under a dual phase lag model (DPL). Nonlinear thermo-elasticity examines cases in which a material’s response to changing thermal loads causes considerable changes in both its geometry and material properties. This field is crucial for effectively describing real-world phenomena, such as thermal stresses in large-scale structures, the behavior of materials at high temperatures, and the intricate interactions between mechanical and thermal fields. The proposed method generated a variety of exact solutions featuring distinct free parameters, including hyperbolic, rational, bright solitons, singular solitons, dark solitons, exponential, polynomial, and Jacobi elliptic solutions. Additionally, some of the results for displacement component, temperature, and stress tensor are presented through graphical illustrations.

Effect of temperature and frequency on the dielectric behaviour of cellulose nanocrystals

Nanocellulose is a promising material for advanced applications due to its renewable nature, non-toxicity, eco-friendliness, mechanical strength and other unique properties. This study investigates the dielectric properties of cellulose nanocrystals (CNCs) derived from wastepaper through acid hydrolysis, across a temperature range of 30°C to 100°C and a frequency range of 1 Hz to 10 MHz. Using theoretical models such as the modified Cole-Cole model, Jonscher's universal dielectric response (UDR) model and modified Kohlrausch-Williams-Watts (KWW) model, a detailed analysis is performed. The results indicate that the dielectric properties depend on temperature, with the frequency dispersion of the real (ε′) and imaginary parts (ε″) of the dielectric permittivity fitting the modified Cole-Cole equation. These values show an initial increase up to 70°C (ε′∼ 6000 and dielectric loss <1) followed by a decrease at higher temperatures, which is linked to the hydroxyl groups. A temperature dependence is also observed in space charge conductivity, free charge conductivity and relaxation time. Non-Debye type behaviour is attributed to asymmetrical features in the electric modulus spectra, as explained by the modified KWW model at various temperatures. The frequency variation of AC conductivity adheres to Jonscher’s power law and the temperature variation of the frequency exponent (0≤ s ≤1) indicates a correlated barrier hopping conduction mechanism for charge carriers. Overall, these findings highlight CNCs as excellent candidate for antistatic applications, demonstrating conductivity ranging from 10−5 to10−9 Scm−1. The results also suggest CNCs can be used in energy storage applications due to their outstanding dielectric properties and low dielectric loss (<1).

Absorption and diffusion process at the CO[formula omitted]-decane interface considering density fluctuations near the critical CO[formula omitted] point

The injection of CO2 into geological formations for storage and for efficiency enhancement of oil production is considered a promising technology. Fundamental is an understanding of the absorption and diffusion process at the CO2-decane interface and its pressure and temperature dependence when approaching the critical CO2 point (31 °C, 7.38 MPa).Based on a new conceptual model, which considers CO2 density fluctuations in the critical range, we were able to consistently explain the time dependence of the volume increase for the respective thermodynamic state. The experimental results confirm the new conceptual model that volume swelling in the non-critical pressure range (< 6 MPa) is a surface effect with limited penetration depth. In contrast, the volume increase in the critical pressure range (6 - 8 MPa) is caused by mixing of liquid CO2droplets and the oil phase, i.e. to a level increase of the liquid mixed phase. Our experimental contact angles confirm this. The measured minimum miscible pressures (MMP) are 5.6 and 6.5 MPa at 20 °C and 30 °C, respectively.The CO2 absorption process at the CO2-decane interface is studied independently with pressure decay experiments. Our model results show excellent agreement (relative error ≅ 1 %) with the experimental results for both the non-equilibrium and equilibrium model, and the early-time diffusion coefficient is 4.7±1.9×10−7m2/s, confirming a fast CO2 mass transfer process.

Temperature and Frequency-Dependent Dielectric Properties Prediction of Oxide Glasses by Machine Learning

The dielectric properties of oxide glasses are essential for telecommunications, where thermal and frequency stability of devices are crucial. However, predicting the temperature and frequency-dependent dielectric properties of glasses is complex using empirical models and computational methods. To address this challenge, machine learning (ML) models with descriptor sets in two different domains—the chemical composition domain and the element physical and chemical properties domain—were employed to predict the dielectric constant and loss of oxide glasses, along with their temperature and frequency dependencies. Additionally, Shapley additive explanations (SHAP) analysis was conducted to interpret the hidden relationships among the data. Compared to experimental values, the ML models perform well in terms of root mean square error (RMSE) and the coefficient of determination (R2). Moreover, the ML models using element physical and chemical properties descriptors demonstrate the potential to predict the dielectric properties of glasses with unknown components.

Effect on In3+ co-doping on photoluminescence and scintillation properties of LYSO:Ce crystal

In this work, a series of LYSO:0.03at.% Ce,xat.%In (x=0, 0.001, 0.005 and 0.01) crystals were successfully grown for the first time by the optical floating zone (FZ) method. The effect of In3+ co-doping on photoluminescence and scintillation properties of LYSO:Ce scintillation single crystal was investigated. It was found that at x = 0.001, the overall scintillation performance was optimized. This was attributed to the fact that In3+ co-doping reduces the concentration of Ce2 emission center and accelerates the photoluminescence decay time of Ce3+. The temperature dependence of photoluminescence of unco-doping and 0.001at.% In3+ co-doping samples was also investigated. Combined with density functional theory calculation, the phenomenon of In3+ co-doping leading to a decrease in quenching temperature of decay time was explained in terms of both crossover relaxation and introduction of impurity energy levels.

Study on the change of the oil-paper insulation’s AC conductivity characteristics based on dielectric response in frequency domain

Oil-immersed power equipment (transformers and high voltage bushings) are key components of power systems. Oil-paper insulation has endured complex and harsh operating conditions when used as a primary insulation system, so it is essential to determine the insulation state of oil-paper insulation system to ensure a stable operation for the power grid. The oil-paper insulation’s conductivity behavior can effectively characterize the degree of insulation deterioration. However, the relationship between the alternating current (AC) and direct current (DC) conductivity behavior for oil-paper insulation systems is still unclear in current research, resulting in limitations in the traditional evaluation model’s application. Therefore, this paper uses oil-paper insulation materials under different aging to carry out relevant research about the changing features of the complex AC conductivity under different test temperature environments. The influence of oil-paper insulation aging, test temperature, and excitation frequency on the complex AC conductivity is verified. Considering the correlation between low-frequency AC conductivity and DC conductivity, the frequency range of AC conductivity is extended by means of frequency temperature and conductance double translation. The temperature dependence of the AC conductivity behavior is defined over a wide frequency test range. The relaxation polarization process dominated the AC conductivity variation law is obtained. The impact of experimental temperature and insulation aging on the cumulative characteristic parameters of AC ionic mobility is clarified. This study theoretically corrects the traditional calculation model for AC conductivity of oil-paper insulation. The bias in conductivity calculations caused by only considering a single relaxation polarization process is eliminated. The conductivity model that can characterize multiple relaxation polarization processes in the dielectric is established. This model provides theoretical support for the later assessment of oil-paper insulation state depending on conductance behavior.