Ancient architectures are not only valuable for their historical significance but also represent the scientific and technological advancements of human civilization over thousands years. Protecting these cultural relics is crucial for preserving human history, culture, and scientific values. However, ancient architecture is vulnerable to natural aggressions such as fires, lightning strikes, earthquakes, floods, biological threats, and ultraviolet rays over time. Additionally, while the electrification and information technology bring great convenience to daily life, the accompanying electromagnetic pollution, continuous vibration, and noise pollution also pose significant threats to the lifespan of ancient architecture. This review describes the progress made in the field of materials for ancient architecture protection to combat these threats. The protection research includes flame retardant materials, anti-biological attack materials, anti-aging materials, and vibration and noise reduction materials. The review also analyzes the mechanism of the role of materials for ancient architecture protection and the mechanism of performance enhancement. Finally, the review points out the key scientific and technological bottlenecks that need to be urgently addressed. This paper may be an important guide for subsequent research on materials for the conservation of ancient architectures.
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