We report an exploration of liquid hydrogen (LH2) tank technology, determining if improving LH2 tank weight, multiplicity or shape enables more hydrogen to be stored on hydrogen vessels. The improvements investigated are well beyond the current LH2 technology state-of-the-art. The platform for this study is a monohull H2 Baseline research vessel powered 100% by hydrogen.Regarding weight reductions, we found that the research vessel does not benefit significantly from large weight reductions of the LH2 tanks. A 50% reduction in mass of the inner pressure vessel led to a 3.1% reduction in the total research vessel weight. Reducing the LH2 tank weight to the asymptotic limit of zero results in a 7.1% reduction in the overall research vessel weight. This maritime application, while benefitting from a reduction in LH2 tank weight, is not a strong driver for LH2 tank weight improvements.The two large LH2 tanks of the H2 Baseline Vessel can be replaced with a multitude of smaller LH2 tanks. In two Multiplicity design variants, the total amount of stored LH2 was ∼5–9% less than that of the H2 Baseline Vessel, which does not motivate conducting the needed R&D that would drive the technology to smaller high-performing LH2 tanks.We did find a significant benefit to improving the shape of LH2 tanks, towards prismatic tanks that would better match the vessel hullform. Considering a “Shape Variant” that included space-consuming features such as tank connection spaces, manifolding and ventilation, we found a 26% improvement in stored LH2 compared to the H2 Baseline Vessel. The large improvement in storage capacity could warrant further LH2 tank R&D that can enable high performing prismatic LH2 tanks, such as pressure vessel steel developments allowing for higher strength/ductility at 20 K, improved insulation systems, methods for efficiently building prismatic tanks with insulation systems fit for 20 K service and flare-less techniques for managing heat leak (venting).The results are reviewed considering the current regulatory restrictions as well as prevailing limitations in LH2 tank manufacturing.