It is necessary to maintain safe, efficient, and compatible energy storage systems to meet the high demand for electric vehicles (EVs). Lithium manganese nickel cobalt (NMC) and lithium ferro phosphate (LFP) batteries are the most commonly used lithium batteries in EVs. It is imperative to note that batteries are classified according to their electrochemical performance. A number of factors play a crucial role in determining how efficiently batteries can be used. These factors include the cell temperature, energy density, self-discharge, current limits, aging, and performance measurements. This paper offers a proposed electrothermal model for comparison between LFP and NMC batteries. This model demonstrates the different behaviors according to their application in EVs. This is carried out through studies of state of charge (SoC), state of health (SoH), thermal runaway, self-discharge, and remaining useful life (RUL) in EVs. According to numerical analysis, this paper examines how these different types of batteries behave in EVs to assist in the selection of the most suitable battery taking into account the operating temperature and discharge current using a helpful thermoelectric model reflecting battery safety and life span effectively. Using MATLAB Simulink, the data selected in the electrothermal model are combined from a number of references that are incorporated into lookup tables that affect the change in values in the electrothermal model. The cells are implemented in an EV system using a current test to examine the measured current that goes in and comes out of the battery cells during charging and discharging processes taking into account motoring and regenerative braking for a specified drive cycle time and a number of discharging cycles. It was found that LFP batteries have better stability for open circuit voltages of 3.34 volts over a wide range of conducted temperatures. NMC batteries, on the other hand, exhibit some open circuit voltage variation of 0.053 volts over the temperature range used. Furthermore, the self-discharging current of LFP batteries was about 12 times lower than that of NMC batteries. Compared to LFP batteries, NMC batteries have a higher energy density per unit of mass of 150%, which reflects their greater discharge range. As a result of temperature effects, it has been revealed that LFP batteries are about two times more stable during discharging than NMC batteries, particularly at higher temperatures, such as 45 degrees.
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