Today, the use of environmentally friendly materials is becoming increasingly important. The construction of energy-saving buildings with enclosing structures made of insulated profiled timber, is one of the most promising areas in low-rise construction.Materials having minimum negative impact on the environment during their operation, include new construction insulation materials based on peat-vermiculite granules. The paper studies the main physical properties of wooden exterior walls made of profiled timber, in which peat vermiculite is used as insulation, thermal conductivity of which ranges from 0.05 to 0.06 W/(m·K). For this purpose, numerical simulation is performed for the heat-mass transfer in wooden enclosing structures made of insulated timber with three different connector options.The temperature and heat flow distributions are obtained as a result of modeling stationary thermal conductivity processes in timber structures. It is shown that plywood connectors do not affect the thickness temperature distribution in wooden walls with peat-vermiculite insulation. An increase in thermal conductivity of insulation has no significant effect on the temperature difference along the connector axis or outside the region of its temperature influence.It is found that the thickness of the peat-vermiculite insulation layer should be at least 0.176 m to ensure the compliance with the main requirements for thermal protection properties of enclosing structures in the climatic conditions of Tomsk. The greatest heat loss with a minimum insulation thickness is observed for the wall made of profiled insulated timber with T-shaped connectors. A high-strength timber with the additional central lamella has the best thermal protection with the lowest insulation thickness.