Electric vehicles (EV) are promising alternate fuel technologies to curtail vehicular emissions. A modeling framework in a hybrid electric vehicle system with a joint analysis of EV in powering and regenerative braking mode is introduced. Bidirectional DC–DC converters (BDC) are important for widespread voltage matching and effective for recovery of feedback energy. BDC connects the first voltage source (FVS) and second voltage source (SVS), and a DC-bus voltage at various levels is implemented. The main objectives of this work are coordinated control of the DC energy sources of various voltage levels, independent power flow between both the energy sources, and regulation of current flow from the DC-bus to the voltage sources. Optimization of the feedback control in the converter circuit of HEV is designed using an artificial neural network (ANN). Applicability of the EV in bidirectional power flow management is demonstrated. Furthermore, the dual-source low-voltage buck/boost mode enables independent power flow management between the two sources—FVS and SVS. In both modes of operation of the converter, drive performance with an ANN is compared with a conventional proportional–integral control. Simulations executed in MATLAB/Simulink demonstrate low steady-state error, peak overshoot, and settling time with the ANN controller.