System-environment Interaction Research Articles

A quantum algorithm for evolving open quantum dynamics on quantum computing devices

Designing quantum algorithms for simulating quantum systems has seen enormous progress, yet few studies have been done to develop quantum algorithms for open quantum dynamics despite its importance in modeling the system-environment interaction found in most realistic physical models. In this work we propose and demonstrate a general quantum algorithm to evolve open quantum dynamics on quantum computing devices. The Kraus operators governing the time evolution can be converted into unitary matrices with minimal dilation guaranteed by the Sz.-Nagy theorem. This allows the evolution of the initial state through unitary quantum gates, while using significantly less resource than required by the conventional Stinespring dilation. We demonstrate the algorithm on an amplitude damping channel using the IBM Qiskit quantum simulator and the IBM Q 5 Tenerife quantum device. The proposed algorithm does not require particular models of dynamics or decomposition of the quantum channel, and thus can be easily generalized to other open quantum dynamical models.

Generating Kerr nonlinearity with an engineered non-Markovian environment**Project supported by the National Key Research and Development Program of China (Grant No. 2017YFA0304503) and the National Natural Science Foundation of China (Grant Nos. 11835011, 11574353, 11734018, and 11674360).

Kerr nonlinearity is an important resource for creating squeezing and entanglement in quantum technology. Here we propose a scheme for generating Kerr nonlinearity originated from an engineered non-Markovian environment, which is different from the previous efforts using nonlinear media or quantum systems with special energy structures. In the present work, the generation of Kerr nonlinearity depends on the system–environment interaction time, the energy spectrum of the environment, and the system–environment coupling strength, regardless of the environmental initial state. The scheme can be realized in systems originally containing no Kerr interaction, such as superconducting circuit systems, optomechanical systems, and cavity arrays connected by transmission lines.

Anti-Zeno-based dynamical control of the unfolding of quantum Darwinism

We combine the collisional picture for open system dynamics and the control of the rate of decoherence provided by the quantum (anti-)Zeno effect to illustrate the temporal unfolding of the redundant encoding of information into a multipartite environment that is at the basis of Quantum Darwinism, and to control it. The rate at which such encoding occurs can be enhanced or suppressed by tuning the dynamical conditions of system-environment interaction in a suitable and remarkably simple manner. This would help the design of a new generation of quantum experiments addressing the elusive phenomenology of Quantum Darwinism and thus its characterization.

Coherence-based measurement of non-Markovian dynamics in an open quantum system

We present a theoretical scheme and its experimental proof of principle for an open quantum system undergoing Markovian and non-Markovian evolutions. We exhibit these two regimes by diagnosing them with the relative entropy of coherence of two polarization qubits playing the roles of system and ancilla. These are initially prepared in a polarization maximally entangled state of a photon pair produced by spontaneous parametric down-conversion. We induce Markovian and non-Markovian regimes in the system's dynamics with the help of two auxiliary qubits, experimentally implemented by optical paths in a layout of Sagnac and Mach-Zehnder interferometers. We replicate system-environment interactions by means of an amplitude damping channel and a suitably designed inversion of it. In our scheme, one needs only two experimentally accessible parameters to achieve Markovian and non-Markovian regimes.

Quantum algorithm for the simulation of open-system dynamics and thermalization

The quantum open-system simulation is an important category of quantum simulation. By simulating the thermalisation process at the zero temperature, we can solve the ground-state problem of quantum systems. To realise the open-system evolution on the quantum computer, we need to encode the environment using qubits. However, usually the environment is much larger than the system, i.e. numerous qubits are required if the environment is directly encoded. In this paper, we propose a way to simulate open-system dynamics by reproducing reservoir correlation functions using a minimised Hilbert space. In this way, we only need a small number of qubits to represent the environment. To simulate the $n$-th-order expansion of the time-convolutionless master equation by reproducing up to $n$-time correlation functions, the number of qubits representing the environment is $\sim \lfloor \frac{n}{2} \rfloor \log_2(N_\omega N_\beta)$. Here, $N_\omega$ is the number of frequencies in the discretised environment spectrum, and $N_\beta$ is the number of terms in the system-environment interaction. By reproducing two-time correlation functions, i.e. taking $n = 2$, we can simulate the Markovian quantum master equation. In our algorithm, the environment on the quantum computer could be even smaller than the system.

Gaussian Thermal Operations and The Limits of Algorithmic Cooling.

The study of thermal operations allows one to investigate the ultimate possibilities of quantum states and of nanoscale thermal machines. Whilst fairly general, these results typically do not apply to continuous variable systems and do not take into account that, in many practically relevant settings, system-environment interactions are effectively bilinear. Here we tackle these issues by focusing on Gaussian quantum states and channels. We provide a complete characterization of the most general Gaussian thermal operation acting on an arbitrary number of bosonic modes, which turn out to be all embeddable in a Markovian dynamics, and derive necessary and sufficient conditions for state transformations under such operations in the single-mode case, encompassing states with nonzero coherence in the energy eigenbasis (i.e., squeezed states). Our analysis leads to a no-go result for the technologically relevant task of algorithmic cooling: We show that it is impossible to reduce the entropy of a system coupled to a Gaussian environment below its own or the environmental temperature, by means of a sequence of Gaussian thermal operations interspersed by arbitrary (even non-Gaussian) unitaries. These findings establish fundamental constraints on the usefulness of Gaussian resources for quantum thermodynamic processes.

Master-equation approach to the three-state open Majorana model

The three-state Majorana model in the presence of dissipation is considered. Different models of system-environment interaction are explored, ranging from situation where dissipation is the main effect to regimes where dephasing is mainly produced. It is shown that the detrimental effects of the noise are stronger in the presence of dissipation than in the presence of dephasing. The role of temperature is also discussed.

Quantum Markovian master equations: Resonance theory shows validity for all time scales

Quantum systems coupled to environments exhibit intricate dynamics. The master equation gives a Markov approximation of the dynamics, allowing for analytic and numerical treatments. It is ubiquitous in theoretical and applied quantum sciences. The accuracy of the master equation approximation was so far proven for small values of the system–environment interaction coupling strength λ, under the additional constraint that time t must not exceed an upper bound, λ2t≤ constant. Here, we show that the Markov approximation is valid for fixed small coupling strength and for all times. We also construct a new approximate Markovian dynamics – a completely positive, trace preserving semigroup – which is asymptotically in time exact, to all orders in the coupling.

A new approach to study the Zeno effect for a macroscopic quantum system under frequent interactions with a harmonic environment

Quantum Zeno and anti-Zeno behaviors of a two-level macroscopic quantum system in interaction with a harmonic environment are studied using the perturbation theory. The system-environment interactions are applied in a successive and step-by-step way. A new expression for the probability of surviving the macrosystem in its initial state, after the Nth interaction step, is derived through a different method of calculation. It is shown that multiple transitions between Zeno and anti-Zeno behaviors can be found in our approach. We have shown that in addition to the environmental parameters like the Ohmicity, the macroscopic trait of the system also has a notable effect on the decay rate Γ(τ). Moreover, we have investigated how the decay rate Γ(τ) varies as the parameter of the macroscopicity of the system tilde{{boldsymbol{h}}} changes continuously in a given domain.

Precise determination of excitation energies in condensed-phase molecular systems based on exciton-polariton measurements

The precise determination of the excitation energies in condensed-phase molecular systems is important for understanding system-environment interactions as well as for the prerequisite input data of theoretical models used to study the dynamics of the system. The excitation energies are usually determined by fitting of the measured optical spectra that contain broad and unresolved peaks as a result of the thermally random dynamics of the environment. Herein, we propose a method for precise energy determination by strongly coupling the molecular system to an optical cavity and measuring the energy of the resulting polariton. The effect of thermal fluctuations induced by the environment on the polariton is also investigated, from which a power scaling law relating the polariton's linewidth to the number of molecules is obtained. The power exponent gives important information about the environmental dynamics.

Thermodynamics of Weakly Coherent Collisional Models.

We introduce the idea of weakly coherent collisional models, where the elements of an environment interacting with a system of interest are prepared in states that are approximately thermal but have an amount of coherence proportional to a short system-environment interaction time in a scenario akin to well-known collisional models. We show that, in the continuous-time limit, the model allows for a clear formulation of the first and second laws of thermodynamics, which are modified to include a nontrivial contribution related to quantum coherence. Remarkably, we derive a bound showing that the degree of such coherence in the state of the elements of the environment represents a resource, which can be consumed to convert heat into an ordered (unitarylike) energy term in the system, even though no work is performed in the global dynamics. Our results therefore represent an instance where thermodynamics can be extended beyond thermal systems, opening the way for combining classical and quantum resources.

Non-Markovianity in experimentally simulated quantum channels: Role of counterrotating-wave terms

We experimentally investigate the non-Markovianity problems in a quantum channel implemented by an all-optical setup. The quantum channel simulates the dynamics of a two-level (qubit) system surrounded by bosonic modes, with the system-environment interaction treated without applying the rotating-wave approximation (RWA). Therefore, it allows us to demonstrate the important role of counterrotating-wave terms in influencing the memory effects of the environment. The experimental and theoretical results are in good agreement and show quite different behaviors of the non-Markovianity measure between RWA and non-RWA channels. One can find the nonmonotonic dependence of the non-Markovianity measure on the coupling and detuning parameters in the non-RWA case, which is attributed to the competing mechanisms caused by the counterrotating-wave terms. We emphasize that the non-RWA channel provides a more clear description of the open-system dynamics and the counterrotating-wave terms are indispensable in the study of non-Markovianity.

Energy transfer times in fluorographene-based biomimetic light harvesting antennae

It has been demonstrated earlier that graphene-like defects on fluorographene can act as molecules in biomimetic molecular light-harvesting antennae. In competition with radiative and non-radiative losses, transfer time of excitations in an antenna measures its performance. We report on the optimal conditions for excitation energy transfer in artificial antennae built from selected types of fluorographene defects. The excitation transfer dynamics is calculated based on the Frenkel exciton model using hierarchical equations of motion for different values of temperature, system-environment reorganization energy and bath correlation time to study a possible range of parameters pertaining to the fluorographene material. We also study possible energy funnelling in the third dimension for two parallel fluorographene sheets with defects. We conclude that the strength of system-environment interaction is more important for the efficient energy funnelling in our proposed material than a precise control over the structure of artificial antennae.

A quantum mechanical approach towards the calculation of transition probabilities between DNA codons

The role of quantum tunneling in altering the structure of nucleotides to each other and causing a mutational event in DNA has been a topic of debate for years. Here, we introduce a new quantum mechanical approach for analyzing a typical point-mutation in DNA strands. Assuming each codon as a base state, a superposition of codon states could provide a physical description for a set of codons encoding the same amino acid and there are transition amplitudes between them. We choose the amino acids Phe and Ile as our understudy bio-systems which are encoded by two and three codons, respectively. We treat them as large quantum systems and use double- and triple-well potential models to study the fundamental behaviors of them in interaction with a harmonic environment. We use the perturbation theory to calculate the transition probabilities between the codons which encoding the same amino acid and determine the transition rates of some point mutations. Moreover, we evaluate the quantum biological channel capacity for these transitions to show that the channel capacity depends on the system–environment interaction via the dissipation factor Γ. The obtained results demonstrate that the tunneling rate is under the control of capacity of the corresponding biological channel. In other words, the reduction in quantum channel capacity prevents the quantum tunneling rate to be increased.

Preferred states of open electronic systems

System-environment interaction may introduce dynamic destruction of quantum coherence, resulting in a special representation named as pointer states. In this work, pointer states of an open electronic system are studied. The decoherence effect is taken into account through two different ways which are Büttiker's virtual probe model and strong electron-phonon interaction in the polaron picture. The pointer states of the system with different coupling strength are investigated. The pointer states are identified by tracking the eigenstates of the density matrix in real-time propagation. It is found that the pointer states can emerge for arbitrary coupling strength. And the pointer states deform to the eigenstates of the system in the strong coupling limit, which indicates the vanish of quantumness in the strong coupling limit.

Spin Polarization Oscillations and Coherence Time in the Random Interaction Approach

We study the time evolution of the survival probability and the spin polarization of a dissipative nondegenerate two-level system in the presence of a magnetic field in the Faraday configuration. We apply the Extended Gaussian Orthogonal Ensemble approach to model the stochastic system-environment interaction and calculate the survival and spin polarization to first and second order of the interaction picture. We present also the time evolution of the thermal average of these quantities as functions of the temperature, the magnetic field, and the energy-levels density, for ρ(ϵ)∝ϵs, in the subohmic, ohmic, and superohmic dissipation forms. We show that the behavior of the spin polarization calculated here agrees rather well with the time evolution of spin polarization observed and calculated, recently, for the electron-nucleus dynamics of Ga centers in dilute (Ga,N)As semiconductors.

Collisional unfolding of quantum Darwinism

We examine the emergence of objectivity via quantum Darwinism through the use of a collision model, i.e. where the dynamics is modeled through sequences of unitary interactions between the system and the individual constituents of the environment, termed "ancillas". By exploiting versatility of this framework, we show that one can transition from a "Darwinistic" to an "encoding" environment by simply tuning their interaction. Furthermore we establish that in order for a setting to exhibit quantum Darwinism we require a mutual decoherence to occur between the system and environmental ancillas, thus showing that system decoherence alone is not sufficient. Finally, we demonstrate that the observation of quantum Darwinism is sensitive to a non-uniform system-environment interaction.

Classicality First: Why Zurek’s Existential Interpretation of Quantum Mechanics Implies Copenhagen

Most interpretations of Quantum Mechanics alternative to Copenhagen interpretation try to avoid the dualistic flavor of the latter. One of the basic goals of the former is to avoid the ad hoc introduction of observers and observations as an inevitable presupposition of physics. Non-Copenhagen interpretations usually trust in decoherence as a necessary mechanism to obtain a well-defined, observer-free transition from a unitary quantum description of the universe to classicality. Even though decoherence does not solve the problem of the definite outcomes, it helps to explain why we do not observe superpositions and, according to Zurek’s existential interpretation, why a specific preferred basis emerges through system–environment interactions. The aim of this paper is to show why such interpretation ends up begging the question and provides little progress in understanding the quantum-to-classical transition; the ultimate reason being that preferred bases always correlate to human observation. Benefitting from the technical discussion, some remarks will be offered in the last section regarding the role of classical observations as a necessary condition to make workable the formalism of Quantum Mechanics and scientific activity itself.

Energy Transfer in the Light-Harvesting Complexes of Purple Bacteria**Supported by the Research Start-up Foundation for Talents of Northwest A&F University of China under Grant Nos. Z111021106 and Z111021307

In this paper, we use a nonlinear decohering quantum model to study the initial step of photosynthesis which is an ultrafast transfer process of absorption the sunlight by light-harvesting complexes and electronic excitation transfer to the reaction center (RC). In this decohering model, the Hamiltonian of the system commutes with the system-environment interaction. We take B850 ring of light-harvesting complex II (LH-II) in purple bacteria as an example to calculate the efficiency of the energy transfer as a function of time. We find that the environmental noise can make the LH-II have stable energy transfer efficiency over a long time. This is to say that the environmental noise which is the decohering source has advantage of the energy transfer in the process of photosynthesis.

System-environment correlations and Markovian embedding of quantum non-Markovian dynamics

We study the dynamics of a quantum system whose interaction with an environment is described by a collision model, i.e. the open dynamics is modelled through sequences of unitary interactions between the system and the individual constituents of the environment, termed "ancillas", which are subsequently traced out. In this setting non-Markovianity is introduced by allowing for additional unitary interactions between the ancillas. For this model, we identify the relevant system-environment correlations that lead to a non-Markovian evolution. Through an equivalent picture of the open dynamics, we introduce the notion of "memory depth" where these correlations are established between the system and a suitably sized memory rendering the overall system+memory evolution Markovian. We extend our analysis to show that while most system-environment correlations are irrelevant for the dynamical characterization of the process, they generally play an important role in the thermodynamic description. Finally, we show that under an energy-preserving system-environment interaction, a non-monotonic time behaviour of the heat flux serves as an indicator of non-Markovian behaviour.