Synthetic Natural Gas Research Articles

Behavior of the Electricity and Gas Grids When Injecting Synthetic Natural Gas Produced with Electricity Surplus of Rooftop PVs

Distributed generation and sector coupling are key factors for economic decarbonization. Because gas networks have a large storage capacity, they have attracted the attention of power engineers to use them to increase the flexibility and security of supply in the presence of renewable and distributed energy resources. This paper makes the first attempt to integrate the electricity and gas systems to fill available gas storage facilities with synthetic natural gas on a large scale. This synthetic natural gas can then be used to operate gas turbines and to compensate for the fluctuating production of renewable energy sources. The LINK-holistic architecture, which integrates renewable and distributed energy resources, is used in this work. It facilitates sector coupling, which means power-to-gas and gas-to-power, throughout the entire power grid and at the customer level. This work is limited to investigating the power-to-gas process at the prosumer level. The electricity surplus of rooftop PVs is used to produce synthetic natural gas, fed into the gas grid after covering the local gas load. The behaviors of the electricity and gas grids are investigated. Results show that electricity prosumers may also become prosumers of synthetic natural gas. The current unidirectional gas grids should be upgraded with compressors at pressure reduction groups to turn them bidirectional, allowing synthetic natural gas storage in the existing large gas storage appliances after considering the pipes’ linepack effect. The proposed solution could make it possible to fill the underground storage plants in summer, when the electricity and synthetic natural gas production exceed electrical and gas demand, respectively.

CO2-free production of hydrogen via pyrolysis of natural gas: influence of non-methane hydrocarbons on product composition, methane conversion, hydrogen yield, and carbon capture

Methane pyrolysis represents a CO2-free hydrogen production route that enables simultaneous carbon capture. While the majority of previous studies in the field focus on pure CH4 as feed gas stream, commercial processes will typically rely on natural gas as feedstock that contains also non-methane hydrocarbons such as ethane, propane, and n-butane. Therefore, the present study evaluates how CH4 conversion, H2 selectivity, product composition, and solid carbon yield evolve when using either pure CH4 or synthetic natural gas (SNG) as feed gas stream for a thermal pyrolysis process in a lab-scale high-temperature reactor. For this, industrially viable conditions are applied, namely temperatures between 1000 °C and 1600 °C, residence times between 1 s and 7 s, and molar H2 dilution ratios between 1:1 and 4:1. Although the use of SNG results in slightly lower hydrocarbon conversions because the additional components in SNG result in a higher effective H2 dilution ratio compared to a CH4-only feed, the non-methane hydrocarbons in the SNG have a positive effect on both H2 selectivity and solid carbon yield. Taking existing mechanistic understanding into account, these positive effects are attributed to radicals formed from the non-methane hydrocarbons, which facilitate dehydrogenation steps from ethane to ethylene and hereby increase the relative amount of H2 originating from CH4. The introduction of a carbonaceous fixed bed further benefits the performance of the pyrolysis process and ultimately enables to capture more than 98% of carbon in its solid form under industrially viable process conditions.

Synthetic natural gas (SNG) production by biomass gasification with CO2 capture: Techno-economic and life cycle analysis (LCA)

The integration of renewables with CCUS technologies has the promising potential to deliver energy applications with overall negative CO2 emissions which would significantly contribute to the climate neutrality. Moreover, the renewable-based synthetic fuels are predicted to replace the conventional fossil fuels. The current work evaluates key techno-economic and environmental indicators for the SNG production from various renewable fuels (e.g., sawdust, residual wood, organic wastes, agricultural and urban wastes etc.) through gasification process fitted with decarbonization capability. The investigated plant capacity was set to 500 MWth SNG with 60 % CO2 capture rate of primary fuel (biomass). The overall concept was evaluated using various process engineering approaches e.g., reactor & process modelling and simulation, model validation, heat and power analysis, techno-economic assessment combined with detailed environmental impact by Life Cycle Analysis (LCA). The investigated design shows promising performance indicators such as high cumulative energy efficiency (69 %) and carbon conversion to SNG, almost zero plant specific CO2 emissions (3 kg/MWh) and overall negative carbon emissions (−457 kg/MWh) from the whole biomass chain. The SNG production cost is not yet fully competitive versus the EU natural gas prices (53 vs. 30–35 €/MWh) but it shows promising potential considering the trends of increasing fossil prices and CO2 emission tax.

Fine-tuning syngas composition using laser surface modified silver electrode for CO2 electroreduction

Electrochemical reduction of CO2 and H2O to synthesize gas (H2 and CO mixture) is of significant interest due to established industrial pathways to tune the H2 to CO composition to generate an array of valuable products including methanol, synthetic fuel, synthetic natural gas, and hydrogen. However, controlled H2:CO ratios are challenging on CO-active electrocatalysts like silver. We demonstrate that applying laser engineering to adjust the surface wetting state of a silver electrocatalyst with water contact angles θw ranging from 47° and 135°, H2:CO ratios can be tuned from 1 to 4 at modest potentials (−0.7 V versus RHE, RHE—reversible hydrogen electrode) with almost total unity Faradaic efficiency. Both hydrophilic (θw = 47°) and more hydrophobic (θw = 135°) samples showed an increasing H2:CO trend with rising potentials (0.7–1.2 V versus RHE) due to mass transport. Conversely, silver electrocatalyst with θw = 110° exhibited a constant H2:CO ratio of 4. This indicates catalyst wettability potentially affects *H and *HOCO intermediates’ adsorption, impacting H2:CO ratios. Our results show the feasibility of syngas composition control on silver catalysts via surface wettability, providing a simpler alternative to complex multicomponent electrocatalytic systems.

Footprint family of China's coal-based synthetic natural gas industry

China's increasing demand for natural gas and concerns related to energy security have expanded the coal-based synthetic natural gas (CBSNG) industry. The accompanying intensive environmental and economic impacts are evaluated based on static design or simulated data, but their industrialized performance at both the project-specific and national levels remains unclear. The objective of this study is to estimate an energy-water-pollutant-carbon-economic footprint family of China's CBSNG industry. To this end, a comprehensive accounting methodology for the multiple footprints of CBSNG was developed and the first-hand dynamic operation and economic data of four commercialized projects were surveyed. Accompanied by the technology learning curve, scenarios towards 2035 were designed to predict future trajectories of these footprints. The results show that the project-specific energy-water-pollutant-carbon footprints generally reduced by 10 to 30 % from 2020 to 2022, while the economic footprints increased slightly. The total energy-water-pollutant-carbon footprints, driven by scale expansion, increased by less than 10 % and the total economic footprint increased by over 30 %. They were predicted to approximately double by 2025 and increase fivefold by 2035, which suggests the deployment of green hydrogen and a circular economy, optimization of spatial layout, and fortification of separate statistics and economic policies for sustainability.

Establishment and evaluation of dynamic viscoelasticity constitutive model for asphalt mixtures based on PCA model: Utilizing coal-based synthetic natural gas slag and phosphogypsum whisker as substitute fillers

To promote the secondary utilization of solid waste in asphalt pavement and reduce resource waste and environmental damage, the fine solid waste powder from the secondary treatment of solid waste was used as a substitute filler to prepare asphalt mixtures. To more precisely characterize the effects of filler type and substitution ratio on the dynamic viscoelastic mechanical characteristics of asphalt mixtures, the dynamic modulus test was conducted on asphalt mixtures, while the dynamic modulus master curve of asphalt mixtures was established based on the time-temperature equivalent principle and the Sigmoidal function. The improved generalized Sigmoidal (IGS) model, five-parameter fractional Zener (FFZ) model, six-parameter fractional Zener (SFZ) model and ten-parameter fractional Zener (TFZ) model were used to construct the shrinkage frequency curves of different asphalt mixtures under different constitutive relationships, whereas the applicability of the constitutive models was further evaluated by the principal component analysis (PCA) model. The research results showed that the dynamic modulus and phase angle of the mixture exhibited a similar change rule with the variation of temperature and frequency, and the use of solid waste-based fillers could effectively reduce the effect of frequency variation on the viscoelasticity of the mixture. The dynamic modulus master curve constructed by Sigmoidal function could accurately describe the functional relationship between the dynamic modulus with loading frequency and temperature, and the variation trend of dynamic modulus in a wider frequency range was flattened with the increase in frequency, and this change rule was not affected by the substitution ratio of the filler, while the use of solid waste-based filler could reduce the dependence of the mixture on the temperature. Compared to several fractional constitutive models, the IGS model exhibited a higher fitting accuracy for the dynamic viscoelasticity of several mixtures, and with the use of solid waste-based fillers, the deviation of fitting curves gradually decreased. A comparative study showed that the fractional constitutive model was difficult to accurately describe the dynamic viscoelasticity of the mixture, and the IGS model was preferred to be recommended as a calculation model to investigate the constitutive relationship on the dynamic viscoelasticity of the mixture.

Kinetic Gas Hydrate Inhibition by Alternating Dipeptoids with Optimal Size and Shape N-Substituents.

Current commercial kinetic hydrate inhibitors (KHIs) are all based on water-soluble polymers with amphiphilic alkylamide or lactam groups. The size and shape of the hydrophobic moiety are known to be critical for optimum KHI performance. Proteins and peptides represent an environmentally friendly alternative, especially as bioengineering could be used to manufacture a product predetermined to have optimum KHI performance. Here, we explore a new series of polymers that are alternating dipeptoids where one of the peptide links originates from glycine. The dipeptoids contain n-propyl groups on the nitrogen atom and varying size and shape alkyl side chains on the neighboring carbon atom. Experiments were carried out in high-pressure steel rocking cells using the slow constant cooling (SCC) test method (1 °C/h) and a synthetic natural gas mixture. All the dipeptoids showed good KHI performance with the best result being for that with a glycine-N-propylleucine repeating unit (Poly iC4-Pr), which has pendant iso-butyl groups on the carbon atom. It exhibited the same KHI performance as poly(N-vinyl caprolactam). Dipeptoids with smaller or longer alkyl groups than iso-butyl gave worse performance. It is conjectured that the iso-butyl group is the optimal carbon length for this polymer class. In addition, the end-branching maximizes the van der Waals interaction with open cavities on growing hydrate particles, which must occur without loss of hydrogen-bonding from the neighboring peptide linkage for optimum KHI performance. Thus, the study provides further evidence for the premise that good KHI molecules must contain multiple amphiphilic groups (often as polymers) with optimal size and shape hydrophobic groups adjacent to strong hydrogen bonding groups. The solvent, n-butyl glycol ether, was shown to be a synergist for Poly iC4-Pr, lowering the onset temperature of hydrate formation in SSC tests relative to the polymer alone.

Techno-economic assessment of the Synthetic Natural Gas production using different electrolysis technologies and product applications

Power to Methane (PtM) systems are considered an attractive alternative for power generation, renewable sources’ potential harnessing, and atmospheric carbon dioxide (CO2) utilization. This study analyzes the potential use of Synthetic Natural Gas (SNG) for electrical power generation or its direct injection into the currently available Natural Gas Transportation infrastructure. A simulation approach using Aspen Plus v14 software was employed to assess various PtM configurations. Six different systems were analyzed for methanation processes, utilizing three types of electrolysis systems: Alkaline (AE), Proton Exchange Membrane (PEME), and Solid Oxide (SOE). Two primary methane applications were considered: integrated into a combined cycle for power generation and a standalone gas treatment stage for grid injection. As a result, the PEME-based system showed the highest generated-to-fed power ratio, larger than SOE (1.45% higher) and AE (20.66% higher). In addition, PEME technology reports the largest generation of SNG per power supply, exceeding 3.4% and 16.4% of those of SOE and AE, respectively. However, the SOE technology showed a larger efficiency than PEME technology by 8.2% and a PtM efficiency larger than PEME by 12.4%. Fixed capital investment for the PtM systems is around 8.6 and 13.9 million USD$, and their total earnings are between −8.2 and 20.9 thousand USD$ a year, depending on the electrolysis technology, methane application, and carbon credits scenario. According to these results, the PEME-based system is the most suitable option regarding technical and economic criteria.

Integrated CO2 capture and conversion into methanol units: Assessing techno-economic and environmental aspects compared to CO2 into SNG alternative

Using carbon dioxide (CO2) as a raw-material to produce value-added chemicals has a strategic role to play in the decarbonization of energy resources and the transition to a climate-neutral economy. E-methanol, Synthetic Natural Gas (SNG) and e-kerosene are one of the most promising pathways to convert CO2. In this context, the aim of this work is to propose an optimized and integrated CO2 to methanol process and then to compare it to the CO2 to SNG process from economic and environmental points of views. An optimized reactor configuration in the CO2 to methanol conversion unit has been successfully implemented in Aspen Plus® and leads to a thermal energy self-sufficiency of this unit. A heat integration with an advanced capture unit has been performed where 5 % of the heat requirement could be provided from the conversion unit while 95 % come from external steam source. Techno-economic assessment of the optimized process showed that methanol is more profitable when it is used as a raw material to synthetize other chemicals. As an energy carrier, SNG is more interesting. Compared to the reference scenario, a net CO2 emission reduction of 70 % in the CO2 to SNG route and of 60 % in the CO2 to methanol route were obtained. Concerning the fossil depletion impact, in both cases, a reduction of more than 60 % was noticed (ca. 75 % in CO2 to SNG route and 61 % in CO2 to methanol case).

Investigation of the kinetics of methanation of a post-coelectrolysis mixture on a Ni/CZP oxide catalyst

The use of synthetic natural gas (SNG) as a plug-and-play fuel coming from renewables can help to overcome the limitations given by the intermittency of renewable energy. A way to implement the production of SNG pass through the co-electrolysis of CO2 to a mixture of hydrogen, carbon monoxide and carbon dioxide, steam and small amounts of methane, followed by CO and CO2 methanation. The presence of different reactants and processes requires the comprehension and quantification of the kinetics of the reactions involved with the aim of optimizing methanation. In this work a kinetic model that considers both the direct CO2 methanation and the indirect RWGS + CO methanation pathways has been developed over a Ni(10 %wt)/Ce0.33Zr0.63Pr0.04O2. The kinetic study made it possible to understand the influence of the reactants and products on the reactions through the calculation of reaction rates. This allowed to test, by linearization, the models found in the literature and their adjustment permitted to calculate sixteen kinetic parameters (activation energies, heats of adsorption and pre-exponential factors) present in the rate laws of methanation of CO2, CO and the Reverse Water Gas Shift reaction. The models then made it possible to simulate the evolution of partial flow rates in an isothermal plug flow reactor and were compared to experimental data.

Enhanced CO2 methanation over LaNiO3/CeO2 derivative catalyst with high activity and stability

The conversion of CO2 into synthetic natural gas offers a promising approach for the long-term storage of renewable energy, addressing the challenge of its intermittent supply. This study successfully developed a catalyst comprised of LaNiO3 supported by CeO2, synthesized via a citric acid-aided impregnation method. This catalyst demonstrated efficiency and stability as a precursor for the CO2 methanation reaction. Upon reduction, it transforms into a Ni–La2O3/CeO2 configuration, featuring dispersed Ni nanoparticles. Characterization through hydrogen temperature-programmed reduction (H2-TPR) revealed that this catalyst exhibits enhanced reducibility and smaller particle sizes, which promote hydrogen activation at lower temperatures. X-ray photoelectron spectroscopy (XPS) analysis further clarified that the increased catalytic activity results from electron transfer interactions between Ni, CeO2, and La2O3. Moreover, the catalyst displayed an augmented count of weak to medium basic sites, which, along with improved hydrogen activation, elevated the CO2 conversion rate to 83.8% within the kinetic control region. The collaborative effect of Ni, La2O3, and CeO2 substantially outperformed the conventional Ni/CeO2 catalyst in CO2 methanation efficiency. Additionally, in-situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS) analysis revealed that the methanation process predominantly follows the HCOO* pathway. Notably, the LaNiO3/CeO2 catalyst exceeded the performance of Ni–La/CeO2 in CO2 adsorption, HCOO* intermediate decomposition, and CHO* conversion, significantly enhancing low-temperature methanation activity.

Synthetic natural gas in the private heating sector in Germany: match or mismatch between production costs and consumer willingness to pay?

BackgroundThe residential heating sector in many European countries requires a fundamental transformation if it is to become climate neutral. Besides the introduction of efficiency measures and updating heating systems, scholars and practitioners consider replacing fossil fuels in existing heating systems a viable approach. Drop-in renewable gases such as biomethane and synthetic natural gas (SNG) cause considerably fewer carbon dioxide (CO2) emissions than natural gas and can be used in natural gas boilers, the dominant heating system in many European countries. To move the ongoing debate around e-fuels forward, this study reports on a Discrete Choice Experiment with 512 respondents in Germany that analyzed consumer preferences and willingness to pay (WTP) for SNG. I build on these insights by comparing WTP to the production costs, making evidence-based decision-making possible.ResultsThe results show that consumers prefer renewable gases over natural gas. Comparing the two types of renewable gases, SNG and biomethane, reveals that consumers clearly favor the latter despite the criticism it has come under in the last 10–15 years. Consumers show a surprisingly high WTP for increasing shares of SNG, with premia of 40 to almost 70% over a natural gas-based tariff. Comparing production costs to the WTP reveals that only tariffs with small shares of SNG (5% and 10%) can be offered at cost-covering prices.ConclusionsGiven the urgent need for a fundamental transition of the residential heating sector, marketers and policymakers should consider carefully whether it is worth channeling a rather unknown and expensive product like SNG into the voluntary market for heating gas, especially as biomethane is already established in the market and clearly a cheaper and more popular alternative.

Co-feeding biomass and municipal solid waste for enhanced hydrogen and synthetic natural gas yields employing chemical looping process

Synthetic natural gas (SNG) is a promising alternative to conventional fossil natural gas. This study proposes a chemical looping hydrogen production (CLHP)-based route for SNG synthesis and elucidates the insights and necessities of appropriately co-feeding different types of feedstocks to maximize the yields of hydrogen and subsequent SNG. A study employing microalgae (MA) and refuse-derived fuel (RDF) as biomass and municipal solid waste representatives demonstrates that blending MA with RDF in a proportion of 40 %:60 % (0.4MA-0.6RDF) eradicates oxygen carrier splitting. This boosts fuel-to-hydrogen efficiency from 74.1 % to 77.8 %, as well as subsequent thermal and exergy efficiencies of SNG production from 59.07 % and 55.8 % to 61.3 % and 57.92 %, respectively, compared to the use of MA alone. Nonetheless, blending fuels does not yield substantial economic advantages, as evidenced by the levelized cost of SNG production using pure MA and the 0.4MA-0.6RDF blend remaining at approximately 0.63 USD/Nm3.

Integration of Chemical Looping Combustion to a Gasified Stream with Low Hydrogen Content

Global population growth requires the use of various natural resources to satisfy the basic needs of humanity. Fossil fuels are mainly used to produce electricity, transportation and the artificial air conditioning of habitats. Nevertheless, countries around the world are looking for alternative energy sources due to the decrease in the availability of these fuels and their high environmental impact. The mixture of hydrogen and carbon monoxide (H2 + CO), commonly called syngas, is a high-value feedstock for various industrial applications. By varying the composition of syngas, especially the H2/CO molar ratio, it can be used to produce methanol, fuels or synthetic natural gas. However, when this ratio is very low, the separation of this gas usually represents a great problem when making the energy balance, which is why it is proposed to adapt a combustion process in chemical cycles, taking advantage of the energy of this gas, reducing the energy impact of the process. During the present project, mass and energy balances were developed for combustion in chemical cycles, using ilmenite as a carrier, integrating heat exchangers to take advantage of the residual energy at the output of the process, to preheat the inlet current in the regenerator. Here, a comparative was made at different temperatures of the air stream and evaluating the mechanism of the ilmenite when a syngas stream is used as fuel.

Megawatts to methane – a deep drop in emissions reduction transition for existing regional gas-based ammonia plants

Synthetic ammonia production sustains food production for more than half of the world’s population. Many regional ammonia plants convert all ammonia to ammonium nitrate fertiliser. With these, all carbon in the feed ends up as carbon dioxide (CO2), with around 2 tonnes of CO2 released per tonne of ammonia produced using natural gas. Conveniently, ammonia plants produce a substantial pre-concentrated CO2 stream. Ammonia plants are high-capex, long-life assets that operate for 40+ years. With the energy transition, replacing such assets is very high cost and will dramatically impact the cost of food production. Further, green energy is highly variable, leading to the need for additional supply side assets to stabilise energy supply. This paper outlines a transition approach for a 30% CO2 reduction (also a 43% case) to extend the useful life of these assets while re-using much of the plant, with the ability to turn on/off the green energy with minimal disruption for stable operation. The example plant is based on a typical 750 tpd ammonia gas Steam Methane Reforming (SMR) plant. The approach considers adding and integrating green power and biogas into this plant to reduce net reportable CO2 emissions. Methanation of CO2 has been demonstrated in several projects and is considered key in developing a transition pathway for an existing gas-based plant, extending its operational life and flexibility to operate with varying degrees of variable green energy supply. Further, whilst Synthetic Natural Gas (SNG) is used in this case, the approach can be beneficially applied with methanol and other Power-to-X opportunities.

Experimental assessment of oxy-CO2 gasification strategy with woody biomass

This paper presents the results obtained during an extensive experimental campaign focused on analysing the application of Oxy-CO2 gasification technology to a small downdraft gasifier fed with woody biomass. Oxy-gasification enables the production of a nitrogen-free synthesis gas (syngas), which can be effectively employed in the synthesis of various high-value chemicals, including but not limited to synthetic natural gas (SNG), methanol (CH3OH), ammonia (NH3), hydrogen and more.The gasifier performances were analysed using different CO2/O2 ratios in the feed (between 1 and 3 kg/kg). The inlet biomass flow rate was approximately 12–18 kg/h, while the equivalence ratio ranged between 19 % and 26 %. The results show that the gasifier can produce a syngas flow rate in the range of 15–25 Nm3/h with a lower heating value (LHV) of between 8 and 10 MJ/Nm3 and a cold gas efficiency of up to 78 %. The operative behaviour of the gasification system is stable and simple to control.

Photocatalytic CO2 methanation over the Ni/SiO2 catalysts for performance enhancement

CO2 methanation produces synthetic natural gas, which reduces CO2 emission and generates sustainable energy. Exploring effective approach and developing high performance Ni catalysts are the main focus for the reaction. In this study, we report photocatalytic methanation over Ni/SiO2 catalysts. Through physicochemical properties of BET, XRD, H2-TPR and TEM, optical properties of UV–visual light absorbance and light-illuminated H2-TPR, and the performance of photocatalytic methanation, the structure-performance relationship is tentatively discussed. The strong absorbance of light, the small size of Ni nanoparticles and the strong metal-support interaction of the Ni/SiO2 catalysts, as well as the low activation energy of CH4 production, are correlated to the enhanced photocatalytic performance compared to the conventional catalytic performance. The photocatalytic pathway of methanation on Ni nanoparticles are suggested to understand the enhanced performance. The work demonstrates the higher photocatalytic methanation performance than conventional catalytic methanation, which is applicable for other reactions using photo-sensitive catalysts.

Life cycle assessment of synthetic natural gas production from captured cement’s CO2 and green H2

Research on the environmental benefits of carbon capture and utilization (CCU) in cement production so far, has predominantly emphasized energy efficiency enhancements and CO2 emission reductions at a CCU product level, neglecting broader environmental consequences for the sector. This research broadens this perspective by providing an extensive life cycle assessment (LCA) of a circular Portland cement (CPC) model. Synthesized methane is used as input fuel through green hydrogen and calcium-looping (CaL) post-combustion captured CO2 from cement flue gas. Comparative analysis with ordinary Portland cement (OPC) reveals significant reductions in climate change and fossil resource use environmental impact categories. However, trade-offs are evident in acidification, water use, and minerals and metals resource consumption. The electrolysis system is a critical contributor due to the high electricity demand for hydrogen production, and its environmental impact depends largely on the renewable electricity source. The wind-based electrolysis model yields the most favourable results, followed by mixed (50% solar – 50% wind) and solar scenarios. These findings offer valuable insights for the cement industry, supporting stakeholders decision making on the adoption of sustainable circular production methods.

Techno-economic and life cycle analysis of synthetic natural gas production from low-carbon H2 and point-source or atmospheric CO2 in the United States

Synthetic natural gas (SNG) is of great interest in reducing fossil energy consumption while maintaining compatibility with existing NG infrastructure and end-use applications equipment. SNG can be produced using clean H2 generated from renewable or nuclear energy and CO2 captured from stationary sources or the atmosphere. In this study, we develop an engineering process model of SNG production using Aspen Plus® and production scales reported by the industry. We examine the levelized cost and life cycle greenhouse gas (GHG) emissions of SNG production under various CO2 supply scenarios. Considering the higher cost of H2 transportation compared with CO2 transportation, we assume that CO2 feedstock is transported via pipeline to the H2 production location, which is collocated with the SNG plant. We also evaluate the cost of CO2 captured from the atmosphere, assuming the direct air capture process can occur near the SNG facility. Depending on the CO2 supply chain, the levelized cost of SNG is estimated to be in the range of $45–76 per million British thermal units (MMBtu) on a higher heating value (HHV) basis. The SNG production cost may be reduced to $27–57/MMBtu-HHV by applying a tax credit available in the United States for low-carbon H2 production (45 V). With a lower electricity price of 3ȼ/kWh for water electrolysis and accounting for a 45 V tax credit, the SNG cost reaches parity with the cost of fossil NG. Depending on the CO2 supply chain, SNG can reduce life cycle GHG emissions by 52–88 % compared with fossil NG.

Mechanical properties and microscopic characterization of coal-based synthetic natural gas slag as supplementary cementitious materials

This study investigated the feasibility of using coal-based synthetic natural gas slag (CSNGS) as supplementary cementitious materials in cement-based binders. The effects of different CSNGS/Cement ratios on the slump flow and mechanical strengths of paste and mortar were first analyzed. Subsequently, the mineralogy, morphology, and chemical structure of CSNGS-Cement paste were examined by means of XRD, SEM/EDS, FT-IR, and TG/DTG. The results showed that an appropriate incorporation of CSNGS contributed to the improvement of flowability due to the micro-filling effect. As the CSNGS proportion increased, the compressive strength decreased, while an appropriate amount of CSNGS was conducive to improving the flexural strength of mortar. The 28-day compressive strength of composite mortar reached over 89 % than that of the reference mortar under CSNGS within 0–30 %, possibly due to the increased contents of needle-like ettringite and C-A-S-H. Additionally, a formula considering the effective water absorption rate and pozzolanic activity of CSNGS was developed for predicting the compressive strength of CSNGS-cement mortar, demonstrating a good correlation coefficient (R2 > 0.93) between predicted and measured values. Overall, CSNGS proves to be a feasible supplementary cementitious material, offering a promising way for the effective utilization of CSNGS as well as the clean production of concrete.