Synthetic Fibers Research Articles

Design of experiments investigation into the production of all cellulose composites using regenerated cellulosic textiles

All cellulose composites (ACCs) can be produced from native and man-made cellulosic fibres; use of the latter provides an additional application for waste-derived regenerated fibers. ACCs were prepared using an ionic liquid dissolution method, utilizing a regenerated cellulose (Tencel) textile, with and without an interleaf cellulosic film. A design of experiments methodology was applied to explore process-property relationships; concentration of the ionic liquid and the processing time and temperature were investigated. It was found that the film remained in-between the textile layers, rather than penetrating the fiber assembly, in contrast to our previous work on cotton-based ACCs. This is due to the structural differences between Tencel and cotton fabric. A multi-response optimization was conducted through a central composite face centered strategy, which captured the film system more strongly. Optimized processing conditions were identified, yielding a Young’s modulus and strain-to-failure of 5.3 GPa and 3.5% respectively, validated through in-lab samples.

Displaced thinned single-mode fiber Mach-Zehnder interferometer tested for temperature and curvature applications

This article explains the features and qualities of employing a thinned manufacturing fiber to assemble a Mach-Zehnder interferometer (MZI) for detecting two physical variables: temperature and curvature. The MZI comprises a filter by splicing core-offset sections of a thinned fiber (TF) cladding diameter of 80 μm in an SMF-TF-SMF configuration. The TF splices act as the arms of the MZI, while the mismatch diameter sections serve as optical fiber couplers. The optical spectrum analyzer (OSA) detects the transmitted light and analyzes its optical transmission characteristics, showing 11 peaks of modal interferences into the longitude region. As a result of the experimental arrangement, the curvature and temperature sensitivities are 0.49 nm/m−1, 0.01 nm/°C, and 0.09 nm/°C for temperatures of 0–60 °C and 70–130 °C, respectively. The proposed sensor has potential advantages for measuring refractive index, pH, torsion, curvature, and temperature.

General ventilation filters: what acoustic characteristics?

In the field of general ventilation, air filters are widely used, and introduced in ventilation ductworks, or air-handling units. These filters are passed through by air flow and noise. However, their characteristics of sound attenuation and sound generation are very poorly known, used and tested. This presentation reports a study done in collaboration with French air filtering manufacturers members of CETIAT. More than thirteen 592x592 mm filters representing four different types of air filters commercially available have been tested in laboratory, to characterise the insertion loss and the noise generation. Those types of filters are mini pleated (50 & 100 mm thickness), V-bank, bags and pleated, with different materials such as glass fiber and synthetic fiber. In addition, the effect of the dust loading has been investigated the sound characteristics as well as the influence of a series installation of a prefilter and a filter. These experimental data will be helpful for acoustic studies of ventilation networks. Some results about sound absorption can be related to the characteristics of the filters, thickness or shape but also to the loading and the use in series, whereas no obvious relation can be found for sound generation.

Sandwich structures in bio-composite material for sustainable acoustic solutions

The use of bio-based materials in acoustic applications has gained a lot of attention recently as a functional and environmentally friendly alternative for synthetic materials. This is because conventional synthetic fibers have a significant impact on the environment and the health risks of people. The focus is now on developing composite systems that minimize environmental harm by using energy and materials more efficiently, and by substituting synthetic or petroleum-based materials with more sustainable options, such as natural fibers. These natural fibers are favoured for their biodegradability, sustainability, and widespread availability, earning them the label of "green materials." Thus, this paper aims to investigate the soundproofing capabilities of a novel sandwich structure composed of hemp fibers and bio-epoxy resin, aiming to broaden the application field of natural fiber composite materials.

Experimental study on the acoustic properties of monofilament fabrics

The traditional machining perforated sound absorption structure has high processing cost and inconvenient installation and disassembly, so that how to efficiently and economically manufacture submillimeter micropores still remains a challenge. In this study, a kind of flexible microporous sound absorbing material was obtained by weaving a polymer artificial fiber covered with ethylene polyester fiber, and the relationship between the sound absorption performance of the curtain and the porosity of the pass and fabric was obtained through the finite element simulation model and impedance tube experiment. The mechanism parameters of wide-band flexible microporous material with high sound absorption performance are obtained, which guide the design of a kind of sound absorption material with lower production cost and easy installation and disassembly.

Photodegradation Pathways of Aliphatic Polyamide through Conical Intersection between Ground and Excited States.

Time-dependent density functional theory studies were performed to investigate the photochemistry properties of the widely used aliphatic polyamide (APA), alias nylon, under ultraviolet radiation with N-ethylacetamide (NEA) being the model molecule. The characteristics of the transition molecular orbitals for the low-order excited states (ESs) of NEA were clarified, and the ES geometries related to the transition worthy of study were optimized. Our research proved that there is a conical intersection between the ground and excited states featured by the transition from the lone pair orbital to the σ antibonding orbital on the C-N bond within the peptide group or the N-C bond adjacent to the carbonyl group, and the C-N or N-C bond has the probability to be disrupted after internal conversion. These original quantum chemistry discoveries depict the C-N and N-C bond cleavage scheme that initiates the primary and secondary paths in the scission processes of the APA chain, respectively, which is helpful for giving new insight into the overall photodissociation mechanism of APA and designing advanced polyamide-based synthetic fibers.

Use of magnetic fields to impact glass-transition and crystallization during manufacturing of ZBLAN optical fibers

ZBLAN (ZrF4-BaF2-LaF3-AlF3-NaF) is the most stable glass among the Heavy Metal Fluoride (HMF) family and has a wide range of applications in medical industry, telecommunication, IR transmission, among others. But, due to crystal formation while manufacturing of ZBLAN fiber its theoretical minimum loss has not been achieved yet. Some techniques such as high cooling rate and microgravity conditions have been utilized to reduce the crystal formation but are challenging to implement during manufacturing of these fibers. Alternatively, magnetic field (MF), also a body force like gravity, is expected to influence the crystal formation mechanism and glass kinetics. In this work, ZBLAN glass is processed under magnetic fields of various intensities while simulating fiber drawing manufacturing process conditions. Then, the processed ZBLAN is analyzed using Differential Scanning Calorimetry (DSC) at varying scanning rates. Various glass kinetics parameters such as activation energy, fragility, and preferred crystallization mechanism in terms of Avrami parameter (n) have been analyzed. The glass transition temperature (Tg) increases for a given sample as scanning rate (β) increases. Samples processed under varying magnetic fields, at the same scanning rate, displayed higher glass transition temperatures. Also, when the magnetic field increases, the activation energy required for glass transition decreases, and the fragility index (m) decreases. There is also a preference for surface crystallization over volume crystallization. These results encourage application of magnetic fields for reducing crystal formation while processing ZBLAN glass.

High-performance magnetic artificial silk fibers produced by a scalable and eco-friendly production method

Flexible magnetic materials have great potential for biomedical and soft robotics applications, but they need to be mechanically robust. An extraordinary material from a mechanical point of view is spider silk. Recently, methods for producing artificial spider silk fibers in a scalable and all-aqueous-based process have been developed. If endowed with magnetic properties, such biomimetic artificial spider silk fibers would be excellent candidates for making magnetic actuators. In this study, we introduce magnetic artificial spider silk fibers, comprising magnetite nanoparticles coated with meso-2,3-dimercaptosuccinic acid. The composite fibers can be produced in large quantities, employing an environmentally friendly wet-spinning process. The nanoparticles were found to be uniformly dispersed in the protein matrix even at high concentrations (up to 20% w/w magnetite), and the fibers were superparamagnetic at room temperature. This enabled external magnetic field control of fiber movement, rendering the material suitable for actuation applications. Notably, the fibers exhibited superior mechanical properties and actuation stresses compared to conventional fiber-based magnetic actuators. Moreover, the fibers developed herein could be used to create macroscopic systems with self-recovery shapes, underscoring their potential in soft robotics applications.

Micro-plastics in soil environment: A review

Environmental scientists and other stakeholders have paid serious attention to soil pollution by microplastics in the last ten years. In soils, the microplastic particles act as a vector for the toxic persistent organic pollutants and potentially toxic metals that are easily sorbed by plants and enter the food chain. Microplastics are emerging as persistent terrestrial pollutants due to mismanagement and indiscriminate use. Microplastic contaminants affect the physicochemical characteristics of the soil as well as the feeding patterns of the soil biota. Sewage sludge, bio waste compost additions, plastic mulching, wastewater irrigation, landfill leachate, and air deposition are the causes of microplastics in soils. The amount of microplastics particles per kilogram of soil ranged from zero to thirteen thousand pieces. There are 523 times as many microplastic particles in the soil as there are in the ocean. Plant growth and seed germination are slowed down by the microplastic in the soil. Microplastics also affect the soil's enzymatic activities. The environmental sources of microplastic include plastic pellets, city dust, abrasion of road markings, tires, synthetic textiles, personal care products, and cosmetics. Human consumption through food can have a variety of harmful effects, including cytotoxicity, immunotoxicity, pulmonary toxicity, and reproductive toxicity. The current study describes the origins, distribution, and effects of microplastics on plants, soil biota, and human health in the soil environment. Bangladesh J. Nuclear Agric, 38(1): 1-19, 2024

Characterization and life cycle assessment of alkali treated abaca fibers: the effect of reusing sodium hydroxide

The increasing demand for natural fibers, driven by their advantageous attributes such as low density, sustainability, and high specific strength, has promoted the adoption of sustainable alternatives in composites. Although alkali treatments are known to improve fiber properties, they entail challenges regarding NaOH consumption and environmental impact, making it necessary to explore cleaner production strategies. This study evaluated the effects of implementing a circular economy approach through the recirculation of an NaOH solution on the treatment of abaca fibers. The fiber properties were assessed using thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and tensile strength testing, along with an evaluation of the carbon footprint through a life cycle assessment. New life cycle inventories were developed to reflect the NaOH recirculation process. Comparative analyses were conducted using polypropylene fibers. The findings indicate that the recirculation of the NaOH solution remains effective for up to eight cycles, producing consistent TGA, SEM, and tensile strength results while achieving a 25 % reduction in the carbon footprint compared to conventional treatment. Additionally, this study highlights the environmental advantages of abaca over synthetic fibers, with increased tensile strength (8–46 %) and carbon footprint reduction (55–86 %) compared to polypropylene fibers. These results highlight the potential of abaca fibers to contribute to the circular economy, enhance resource efficiency, and mitigate climate change.

Environmental behaviour of synthetic and natural fibre reinforced composites: A review

There has been an increasing interest in natural fibre-reinforced composites as viable alternatives to typical synthetic fibre composites as a result of increased environmental consciousness, which has led to the quest for materials that are more sustainable. This review paper aims to provide a comprehensive evaluation of the environmental performance of both natural and synthetic fibre-reinforced composites by summarizing relevant information. The article begins by discussing the advantages of natural fibres. These advantages include the fact that natural fibres are eco-friendly, Natural fibre composites demonstrate a significantly reduced carbon footprint and energy usage over their entire life cycle when compared to their glass fibre-reinforced counterparts. Furthermore, the biodegradability of natural fibres provides the opportunity for end-of-life recycling or disposal options that are more ecologically benign than those for synthetic fibre composites. This is because natural fibres are biodegradable and the research acknowledges that various factors, such as the specific fibre and matrix used, and the manufacturing procedures employed, can influence the environmental performance of natural fibre composites. Additionally, further research and development to optimize their performance and ensure their widespread adoption as sustainable alternatives to traditional composite materials. Natural fibre-reinforced composites are more environmentally friendly than traditional composite materials.

From waste to advanced resource: Techno-economic and life cycle assessment behind the integration of polyester recycling and glucose production to valorize fast fashion garments

This work demonstrates the technical, economical, and environmental viability of integrating enzymatic hydrolysis, mechanical refining, and total chlorine-free (TCF) bleaching processes for industrial-scale production of glucose from textile waste. The process features an innovative mechanical refining pretreatment coupled with TCF oxidation of dyes to achieve over 90% improvement in enzymatic hydrolysis yields of cotton textile waste while also promoting the purification and recycling of synthetic fibers. A comprehensive techno-economic analysis was performed based on a 14,000 bone dry tons (BD tons) annual glucose production line, utilizing both 100% cotton and cotton/polyester blends, reveals capital investments ranging from USD 5.6 to 7.9 million, with manufacturing costs per ton of glucose varying between USD 215 and USD 475, depending on the textile blend used. The cotton/polyester 50/50 blend scenario had the lowest minimum selling price (USD 290 per ton of glucose) due to the revenue from the unhydrolyzed synthetic fibers, which are a valuable and key co-product. A sensitivity analysis highlights the significant influence of recycled polyester content and market prices on the economics. Additionally, a life cycle assessment was performed to compare the carbon footprint of the four scenarios. In contrast to other existing pretreatments that can contribute to up to 70% of the emissions in enzymatic hydrolysis of textiles, the mechanical refining pretreatment can contribute as low as 10% of the total emissions in the process proposed in this work. While certain challenges remain, such as the development of a robust supply chain model, the conversion pathway shown in this work for upcycling cotton textile waste into value-added chemicals represents a promising opportunity to combat textile landfilling and foster the circular economy within the industry.

Thermal Performance Of Termite Mold Bricks Reinforced With Empty Fruit Bunch Spikelet And Coconut Fibers

The use of natural fibers to enhance the thermal properties of earth bricks has become increasingly popular. This study investigates the thermal performance of termite mold soil (TMS) reinforced with two types of fibers: coconut fibers (CF) and empty fruit bunch spikelet fibers (EFBSF). Various fiber compositions (0%, 0.5%, 1%, 1.5%, 2%, and 2.5%) were combined with sodium hydroxide (NaOH) treatments at concentrations of 1%, 2%, 3%, and 4%. Laboratory results reveal that TMS exhibits promising physical properties, including a moisture content of 23.64%, a maximum dry density of 1.63 g/cm³, and a plasticity index of 20%, indicating its structural stability and suitability for earth block production. The study also analyzes the chemical properties of EFBSF and CF fibers, noting that CF has a higher holocellulose content (88.0%) compared to EFBSF (33.5%), which impacts moisture retention and structural integrity. Thermal analysis demonstrates that incorporating these natural fibers significantly enhances the thermal performance of TMS. With a 2.5% fiber content, CF reduces thermal effusivity from 1771.43 J/m²Ks^1/2 to 1079.39 J/m²Ks^1/2 and thermal conductivity from 0.86 W/mK to 0.38 W/mK, making it particularly effective in improving insulation in hot conditions. EFBSF also lowers thermal effusivity and conductivity, but to a lesser extent than CF. Additionally, the presence of these fibers reduces volumetric calorific capacity, with CF showing a more pronounced effect. Overall, TMS reinforced with coconut fibers, especially at 1% NaOH and 2.5% fiber content, offers the best thermal performance, suggesting its potential for sustainable construction. This research promotes the use of locally sourced, natural fibers in earth block manufacturing, contributing to the development of more energy-efficient and environmentally friendly building materials.

Hyperthermia and biological investigation of a novel magnetic nanobiocomposite based on acacia gum-silk fibroin hydrogel embedded with poly vinyl alcohol

The design and synthesis of biocompatible nanostructures for biomedical applications are considered vital challenges. Herein, a nanobiocomposite based on acacia hydrogel, natural silk fibroin protein, and synthetic protein fibers of polyvinyl alcohol was fabricated and magnetized with iron oxide nanoparticles (Fe3O4 MNPs). The structural properties of the hybrid nanobiocomposite were investigated by essential analyses such as Fourier Transform Infrared Spectrometer (FTIR), Field emission scanning electron microscopy (FE-SEM), and X-ray powder diffraction)XRD(analyses, Thermogravimetric and Differential thermogravimetric analysis (TGA-DTG), Vibrating-sample magnetometry (VSM), and Energy Dispersive X-Ray Analysis (EDX). The biological activities and functional properties of the prepared magnetic nanobiocomposite were studied. Results proved that this nanobiocomposite is non-toxic to the healthy HEK293T cell line. In addition, the synthesized nanobiocomposite showed an approximately 22 % reduction in cell viability of BT549 cells after 72 h. All results confirmed the anti-cancer properties of nanobiocomposite against breast cancer cell lines. Therefore, the prepared nanobiocomposite is an excellent material that can use for in-vivo application. Finally, the hyperthermia application was evaluated for this nanobiocomposite. The SAR was measured 93.08 (W/g) at 100 kHz.

Important Practical Conditions for Getting the High-Quality Foam Concretes

Introduction. The most important reasons justifying the relevance of the research on the practical methods of reducing the consumption of materials in construction industry have been distinguished. The priorities of the Russian Federation referring to the foam concrete technology have been outlined. The level of reliability of the Internet resources describing properties of the dispersedly reinforced foam concretes has been briefly evaluated. The aim of the study is to establish the relationships between the individual properties of fiber, its quantity to the mass of cement ratio, and the most important operational properties of foam concrete manufactured using a single-stage technology.Materials and methods. The types and properties of raw materials used in the experimental research, the methods for controlling the properties of mixes and hardened foam concretes have been defined.Results. The relationship between the speed of phase transition of the viscoplastic properties of the foam concrete mixes into the elastic ones and the possibility of getting a high-quality structure of the hardened foam concrete have been briefly theoretically justified. The physical reasons influencing the direction and speed of forming the raw material dispersed particle clusters in the structure of the interpore partitions of foam concrete mixes have been revealed, which are the important factors to be considered in practice to get the high-strength foam concretes. Depending on the fiber concentration in the concrete mixture composition, the specifics of the fiber physical nature influence on the speed of phase transition from viscoplastic to elastic state have been established. It has been proved that the synergetic effect of dispersed reinforcement is achieved when fiber concentration is enough to provide the significant acceleration of the phase transition. New experimental data on the influence of the individual properties of fiber on the rheological and physico-mechanical properties of D500 foam concrete has been obtained.Discussion and Conclusion. The scientific explanation of the reasons for emergence of the electret effect on the surface of synthetic fiber has been given. It has been revealed that the discovered effect is induced by the specifics of the foam concrete mixture preparation using a single-stage technology. The most important practical conditions due to be met to get the high-strength foam concrete have been determined.

Development of Natural Fiber Reinforced Polymer Matrix Composites: A Critical Review

AbstractFiber reinforced composites are made by reinforcing fibers in a polymeric matrix and shaping them to fit. Natural fibers, on the other hand, such as jute sisal, hemp, flax etc. are increasingly commonly utilized as reinforcements and perform similarly to artificial fibers. Man‐made fibers like as carbon, glass, and kevlar are utilized as reinforcements in the start and have shown to be the best in terms of characteristics, reinforcing capacity, and usefulness. Research investigations also show that when man‐made and natural reinforcements are combined in a hybrid form, the composite characteristics increase significantly. The composite material obtains all of the better qualities of individual fibers as a result of this combination, and when the composite is subjected to varying loads, each fiber gives its own maximal resistance. The chemical and physical properties are further enhanced by including particular reinforcements into polymer matrix composites, which provide whole new features (which has transformed the aerospace, marine, defence, and automobile industry). As a result, the composite would be better in all attributes. The current study provides a thorough examination of the different challenges concerning the synthesis and mechanical characterization of natural fiber reinforces hybrid polymer composites. Future difficulties, as well as areas of use for polymer matrix composites, have been investigated that may aid in the elimination of plastic waste and the reduction of environmental pollution.

A Critical Review on Polymer Composites Reinforced with Artificial Fibers using Fused Deposition Modelling

The practical application of Additive Manufacturing (AM) technology expands constantly in the automotive, aerospace, and biomedical sectors, among others. Additive manufacturing technology has been categorized by ASTM into seven groups according to the type of material and process used to fabricate the parts. Intellectual property rights of manufacturer restrict the users to process few materials in a machine. Nevertheless, compared to extrusion or injection molding, the mechanical strength and robustness of three dimensional (3D) printed items are significantly lower. First, some researchers have looked into optimizing process factors such build orientation, layer height, infill density, and air gap with the purpose of enhancing the mechanical properties. Secondly, altering the material with reinforcement improves mechanical properties compared with un-reinforced material. Fusion Deposition Modelling (FDM) technology based on 3D printer retains a market share of 40% globally. This article reviews the mechanical performance of FDM feed stock filament of thermo-plastic polymers ABS/PLA/PP with a reinforcement of CF/CNF/CNT/JFRT/CPT. The researchers reported improvements in mechanical characteristics such as strength, strain failure rate, and Young's modulus.

A sustainable recycling process and its life cycle assessment for valorising post-consumer textile materials for thermal insulation applications.

The textile industry along with construction, electronics and plastic generate huge amounts of waste posing challenges to the adoption of the circular economy. This research presents a sustainable and low-cost recycling technology for conversion of post-consumer textile (denim) wastes to useful insulation materials. To accomplish the objective, nonwoven materials were produced using varying proportions of post-consumer recycled denim (r-denim) fibre and hollow polyester (PET) fibre using different punch densities in the needle punching process. Kowalski, Cornell and Vining mixture design, a special type of design of experiments, was adopted to develop the samples. Developed nonwoven materials were characterised for thermal resistance and tensile properties. The results show that nonwoven materials containing the minimum proportion (20%) of r-denim fibres exhibited the highest thermal resistance (0.131 W-1m2K). However, by adjusting the process parameter of the nonwovens, that is, the punch density, the same thermal resistance (0.131 W-1m2K) is also achieved even with 39% r-denim fibres. Additionally, the nonwovens produced from this blend proportion (r-denim:PET = 39:61) demonstrate a reasonable strength of 2.43 cN/tex. Environmental benefits of the developed r-denim/PET nonwovens have been evaluated by the life cycle assessment approach. Results show that the use of ~40% r-denim fibre has reduced the environmental burden significantly. Therefore, the nonwoven materials produced from post-consumer textile wastes hold tremendous potential as an alternative to synthetic fibres in thermal insulation applications. This recycling approach has immense potential to contribute to the efficient utilisation of post-consumer textile waste materials paving the way for environmental sustainability.

Mechanical properties of seaweed/banana fiber/hBN filled epoxy composites using Box–Behnken method

Natural particulate reinforced polymer (NPRP) composites are developed to replace synthetic fibers, aiming to reduce costs and environmental impact. Industries such as automotive, electronics, construction and aerospace are turning to filler-reinforced polymer composites and natural bio-fibers to enhance structural properties and develop eco-friendly products. This article presents research on epoxy-based composites fortified with natural and ceramic micro-sized fillers, including seaweed filler (SF), banana fiber (BF) and hexagonal boron nitride (hBN), fabricated using the hand layup technique. Through experiments, the effect of filler loading on the enhancement of mechanical properties such as tensile strength (TS), toughness (T), Young's modulus (YM), resilience (R) and yield strength (YS) of multiphase hybrid composites is investigated. Incorporating mixtures of ceramic filler and natural fillers into the epoxy matrix improves mechanical properties. The results demonstrated that the interlaced composites achieved optimum mechanical properties for S6 sample, including a TS of 24.85 MPa, T of 25.47 MJ/m3, YM of 7.15 GPa, R of 0.698 MJ/m3 and YS of 3.34 MPa. In comparison with S11 samples, the mechanical properties such as TS, T, YM, R and YS of the S6 composite sample are increased by 110.95%, 57.8%, 450%, 501.7% and 292.9%, respectively. The tensile fracture's scanning electron images reveal a homogenous surface with the formation of a fractured surface and defects. Statistical analysis at a 96% confidence level revealed the significance of the interaction between natural and ceramic micro particulate on the TS of the developed interlaced composite material, with a p-value of 0.007.

Mechanical Properties and Flammability Analysis of Wood Fiber Filled Polylactic Acid (PLA) Composites Using Additive Manufacturing

ABSTRACT Natural fibers, such as wood fibers, can substitute for synthetic fibers in various applications due to their low environmental impact, cost-effectiveness, and outstanding mechanical properties as rapid-growing materials and renewable resources. This paper aims to investigate the mechanical properties of 20% wood fiber as a reinforcement material in polylactic acid (PLA) using an additive manufacturing approach. The samples were fabricated using 3D printing techniques. The relevant parameters included the orientation of printing in X, Y, and Z directions, with the percentage of infill set to be 100%. The findings indicated that bio-composites and their adopted printing orientations confirmed the significant effects on the mechanical properties. Pure PLA possessed superior properties in all directions compared to wood/PLA. The highest values were 50.33 MPa for tensile strength and 94.36 MPa for flexural strength, both achieved in Y orientations. However, composites showed an improvement in tensile and flexural moduli in X orientation with 1395.40 MPa, and 2937.72 MPa for Young and flexural modulus, respectively. In the flammability test, wood/PLA bio-composites were ignited easily with reduced smoke production compared to the neat PLA. Wood/PLA bio-composites exhibited high stiffness, and their mechanical properties were influenced by many factors, such as percentage of weight fraction, wood type, and printing orientations.