Carbon nanorods exhibit excellent properties in mechanics, electricity, thermology and optics, and have broad application prospects in the frontier of the major areas. In this study, a self-assembly method was employed to synthesize carbon nanorods using sodium hyaluronate (SH) as the carbon source. Using the crystal structure of sodium chloride as a partitioning agent for carbon nanorods micelles. As prepared Samples were characterised and tested using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and Raman spectroscopy. The results demonstrated the successful preparation of SH @ NaCl carbon nanorods, with an average diameter and length of approximately 50 nm and 800 nm, respectively, and L/D ratio of 16. The present research strategy emphasises the significance of macromolecule @ salt self-assembly in the synthesis of carbon nanostructures of varying morphologies in different systems.