We have imaged thick (3.0–5.0 km) sub-trappean Gondwana sediments deposited in a typical rift-environment of the south Rewa basin in Central India masked by the Deccan basalts. The basalts intrude through the basin forming several dykes, sills, and other intrusions along with large-scale undulations of the basement showing complex geology and tectonic settings due to Late Cretaceous volcanism (∼65 Ma). To delineate complex subsurface geological structures and understand the tectonic settings, we use long-offset seismic reflection data along the N-S trending 127 km Kuvari-Shahdol profile of the basin. The conventional stack and pre-stack time migration techniques fail to image the complex subsurface structures dominated by steeply dipping faults. The steeply dipping faults with small-scale structures are influenced by strong lateral and vertical velocity variations that cause problems in imaging the basin. Hence, a robust tomographic inversion with pre-stack depth migration technique is adopted to image fine-scale subtle subsurface geological structures with smooth velocity variations. The tomographic velocity model and pre-stack depth migration seismic image could decipher basaltic trap thickness, numerous dyke intrusions, alternate horsts and grabens with deposition of thick hydrocarbon-bearing sub-trappean Gondwana rocks along with the basement configuration. The deep basinal faults with highly distorted basement structures represent the intense tectonic activity of this Gondwana rift-basin. The deep-seated hydrocarbon reservoir is discovered with an excellent trapping mechanism forming both pre-rift and syn-rift settings of the rift-basin. The seismic image is further constrained and corroborated by the inversion of residual Bouguer gravity anomaly data to obtain corresponding density model derived from tomographic velocity model. The large basement faults, horsts and grabens, several intrusives like dyke, sill, laccolith, and thick sub-trappean Gondwana formations with Deccan trap cover indicate complex geology and tectonic settings of south Rewa basin forming the Late Cretaceous Volcanic Province of India.