The X-ray diffraction method has been already established as one of the most effective nondestructive evaluation method of a stress in crystalline materials. Since white X-ray beam has a wide wavelength range, a diffraction angle has to fix during a measurement to obtain a lattice spacing using the Bragg’s low. Therefore, the white X-ray method has some different features from the characteristic X-ray method. For example, the information of lattice spacing of many lattice planes in a material can be obtained simultaneously on the same diffraction angle. Because all equipment are held fixed position during a measurement, it is advantageous to in-situ measurement under the special environment such as high temperature or high pressure. In the present review article, a brief history of development of the white X-ray method is covered and some factors related to the measurement accuracy is explained. Fundamentals of the measurement system using white X-ray and the energy dispersive method are presented. Applications of the method using white X-ray obtained from a rotating target type X-ray generator to the measurement of residual stress of a surface ground material and a coating material are described. Furthermore, applications of the method using high energy white X-ray generated in the synchrotron radiation facility SPring-8 to the measurement of internal strain of a material loaded by four-point bending and strain distribution in the vicinity of crack tip in a material introduced a fatigue crack are also described.