Symmetry-breaking Phase Transition Research Articles

The simplified energy landscape of the φ 4 model and the phase transition

The on-lattice φ 4 model is a paradigmatic example of a continuous real-variable model undergoing a continuous symmetry-breaking phase transition (SBPT). Here, we study the Z2 -symmetric mean-field case without the quadratic term in the local potential. We show that the Z2 -SBPT is not affected by the quadratic term and that the potential energy landscape is greatly simplified from a geometric–topological viewpoint. In particular, only three critical points exist to confront, with a number growing as eN (N is the number of degrees of freedom) of the model with a negative quadratic term. We focus on the properties of the equipotential surfaces with the aim to deepen the link between SBPTs and the essential properties of a potential that is capable of entailing them. The results are interpreted in view of of some recent achievements regarding rigorous necessary and sufficient conditions for a Z2 -SBPT.

Cosmic Strings from Thermal Inflation

Thermal inflation was proposed as a mechanism to dilute the density of cosmological moduli. Thermal inflation is driven by a complex scalar field possessing a large vacuum expectation value and a very flat potential, called a “flaton”. Such a model admits cosmic string solutions, and a network of such strings will inevitably form in the symmetry breaking phase transition at the end of the period of thermal inflation. We discuss the differences of these strings compared to the strings which form in the Abelian Higgs model. Specifically, we find that the upper bound on the symmetry breaking scale is parametrically lower than in the case of Abelian Higgs strings, and that the lower cutoff on the string loop distribution is determined by cusp annihilation rather than by gravitational radiation (for the value of the transition temperature proposed in the original work on thermal inflation).

Percolating cosmic string loops from evaporating primordial black holes

The Pulsar timing data from NANOGrav Collaboration has regenerated interest in the possibility of observing stochastic gravitational wave background arising from cosmic strings. Standard theory of formation of cosmic strings is based on a spontaneous symmetry breaking (SSB) phase transition in the early universe, with a string network forming via the so called Kibble mechanism. This string network rapidly evolves and reaches a scaling solution with a given spectrum of string loops and long strings at any given time. This scenario necessarily requires that the entire observable Universe goes through the SSB phase transition. This would not be possible, e.g., in models of low energy inflation, where the reheat temperature is much lower than the energy scale of cosmic strings. We point out a very different possibility, where a network of even high energy scale cosmic strings can form when the temperature of the Universe is much lower. We consider local heating of plasma in the early universe by evaporating primordial black holes (PBHs). It is known that for suitable masses of PBHs, Hawking radiation of evaporating primordial black holes may re-heat the surrounding plasma to high temperatures, restoring certain symmetries locally which are broken at the ambient temperature of the Universe at that stage. Expansion of the hot plasma cools it so that the locally restored symmetry is spontaneously broken again. If this SSB supports formation of cosmic strings, then string loops will form in this region around the PBH. Further, resulting temperature gradients lead to large pressure gradients such that plasma will develop radial flow with the string loops getting stretched as they get dragged by the flow. For a finite density of PBHs of suitable masses, one will get local hot spots, each one contributing to expanding cosmic string loops. For suitable PBH density, the loops from different regions may intersect. If that happens, then intercommutation of strings can lead to percolation, leading to the possibility of formation of infinite string network, even when the entire universe never goes through the respective SSB phase transition.

Electronic Raman response of a superconductor across a time reversal symmetry breaking phase transition

Electronic Raman response of a superconductor across a time reversal symmetry breaking phase transition

A High Working Temperature Multiferroic Induced by Inverse Temperature Symmetry Breaking.

Molecular-based multiferroic materials that possess ferroelectric and ferroelastic orders simultaneously have attracted tremendous attention for their potential applications in multiple-state memory devices, molecular switches, and information storage systems. However, it is still a great challenge to effectively construct novel molecular-based multiferroic materials with multifunctionalities. Generally, the structure of these materials possess high symmetry at high temperatures, while processing an obvious order-disorder or displacement-type ferroelastic or ferroelectric phase transition triggered by symmetry breaking during the cooling processes. Therefore, these materials can only function below the Curie temperature (Tc), the low of which is a severe impediment to their practical application. Despite great efforts to elevate Tc, designing single-phase crystalline materials that exhibit multiferroic orders above room temperature remains a challenge. Here, an inverse temperature symmetry-breaking phenomenon was achieved in [FPM][Fe3(μ3-O)(μ-O2CH)8] (FPM stands for 3-(3-formylamino-propyl)-3,4,5,6-tetrahydropyrimidin-1-ium, which acts as the counterions and the rotor component in the network), enabling a ferroelastoelectric phase at a temperature higher than Tc (365 K). Upon heating from room temperature, two-step distinct symmetry breaking with the mm2Fm species leads to the coexistence of ferroelasticity and ferroelectricity in the temperature interval of 365-426 K. In the first step, the FPM cations undergo a conformational flip-induced inverse temperature symmetry breaking; in the second step, a typical ordered-disordered motion-induced symmetry breaking phase transition can be observed, and the abnormal inverse temperature symmetry breaking is unprecedented. Except for the multistep ferroelectric and ferroelastic switching, this complex also exhibits fascinating nonlinear optical switching properties. These discoveries not only signify an important step in designing novel molecular-based multiferroic materials with high working temperatures, but also inspire their multifunctional applications such as multistep switches.

Probing exotic phases via stochastic gravitational wave spectra

Abstract Stochastic backgrounds of gravitational waves (GWs) from the pre-BBN era offer a unique opportunity to probe the universe beyond what has already been achieved with the Cosmic Microwave Background (CMB). If the source is short in duration, the low frequency tail of the resulting GW spectrum follows a universal frequency scaling dependent on the equation of state of the universe when modes enter the horizon. We demonstrate that the distortion of the equation of state due to massive particles becoming non-relativistic can lead to an observable dip in the GW spectrum. To illustrate this effect, we consider a first order chiral symmetry breaking phase transition in the weak-confined Standard Model (WCSM). The model features a large number of pions and mostly elementary fermions with masses just below the critical temperature for the phase transition. These states lead to a 20% dip in the GW power. We find potential sensitivity to the distortions in the spectrum to future GW detectors such as LISA, DECIGO, BBO, and μAres.

Gravitational Waves from Nnaturalness

We study the prospects for probing the Nnaturalness solution to the electroweak hierarchy problem with future gravitational wave observatories. Nnaturalness, in its simplest incarnation, predicts N copies of the Standard Model with varying Higgs mass parameters. We show that in certain parameter regions the scalar reheaton transfers a substantial energy density to the sector with the smallest positive Higgs squared mass while remaining consistent with bounds on additional effective relativistic species. In this sector, all six quarks are much lighter than the corresponding QCD confinement scale, allowing for the possibility of a first-order chiral symmetry-breaking phase transition and an associated stochastic gravitational wave signal. We consider several scenarios characterizing the strongly-coupled phase transition dynamics and estimate the gravitational wave spectrum for each. Pulsar timing arrays (SKA), spaced-based interferometers (BBO, Ultimate-DECIGO, μAres, asteroid ranging), and astrometric measurements (THEIA) all have the potential to explore new regions of Nnaturalness parameter space, complementing probes from next generation cosmic microwave background radiation experiments.

Plastic phase transitions in tris(hydroxymethyl)aminomethane perchlorate.

Organic crystal materials with metal-free feature and intrinsically low molecular mass are highly desirable for applications in flexible smart devices. Here, we reported a plastic crystal, tris(hydroxymethyl)aminomethane perchlorate (Tris-HClO4), which crystallizes in the R3̄ space group at room temperature and undergoes plastic phase transition at 369 K, showing a large entropy gain of 70.5 J mol-1 K-1, much higher than its fusion entropy gain (12.9 J mol-1 K-1). PXRD measurement indicates that it has cubic lattice symmetry in the high-temperature phase. Moreover, it exhibits excellent dielectric permittivity switching properties and robust cyclic stability. This work could be the pathway for chemical designing multifunctional switchable materials with the motive of combining the idea of symmetry breaking and plastic phase transition.

Time-reversal and parity-time symmetry breaking in non-Hermitian field theories.

We study time-reversal symmetry breaking in non-Hermitian fluctuating field theories with conserved dynamics, comprising the mesoscopic descriptions of a wide range of nonequilibrium phenomena. They exhibit continuous parity-time (PT) symmetry-breaking phase transitions to dynamical phases. For two concrete transition scenarios, exclusive to non-Hermitian dynamics, namely, oscillatory instabilities and critical exceptional points, a low-noise expansion exposes a pretransitional surge of the mesoscale (informatic) entropy production rate, inside the static phases. Its scaling in the susceptibility contrasts conventional critical points (such as second-order phase transitions), where the susceptibility also diverges, but the entropy production generally remains finite. The difference can be attributed to active fluctuations in the wavelengths that become unstable. For critical exceptional points, we identify the coupling of eigenmodes as the entropy-generating mechanism, causing a drastic noise amplification in the Goldstone mode.

Self-Organisation of Prediction Models.

Living organisms are active open systems far from thermodynamic equilibrium. The ability to behave actively corresponds to dynamical metastability: minor but supercritical internal or external effects may trigger major substantial actions such as gross mechanical motion, dissipating internally accumulated energy reserves. Gaining a selective advantage from the beneficial use of activity requires a consistent combination of sensual perception, memorised experience, statistical or causal prediction models, and the resulting favourable decisions on actions. This information processing chain originated from mere physical interaction processes prior to life, here denoted as structural information exchange. From there, the self-organised transition to symbolic information processing marks the beginning of life, evolving through the novel purposivity of trial-and-error feedback and the accumulation of symbolic information. The emergence of symbols and prediction models can be described as a ritualisation transition, a symmetry-breaking kinetic phase transition of the second kind previously known from behavioural biology. The related new symmetry is the neutrally stable arbitrariness, conventionality, or code invariance of symbols with respect to their meaning. The meaning of such symbols is given by the structural effect they ultimately unleash, directly or indirectly, by deciding on which actions to take. The early genetic code represents the first symbols. The genetically inherited symbolic information is the first prediction model for activities sufficient for survival under the condition of environmental continuity, sometimes understood as the "final causality" property of the model.

Rotational symmetry breaking in superconducting nickelate Nd0.8Sr0.2NiO2 films

The infinite-layer nickelates, isostructural to the high-Tc cuprate superconductors, have emerged as a promising platform to host unconventional superconductivity and stimulated growing interest in the condensed matter community. Despite considerable attention, the superconducting pairing symmetry of the nickelate superconductors, the fundamental characteristic of a superconducting state, is still under debate. Moreover, the strong electronic correlation in the nickelates may give rise to a rich phase diagram, where the underlying interplay between the superconductivity and other emerging quantum states with broken symmetry is awaiting exploration. Here, we study the angular dependence of the transport properties of the infinite-layer nickelate Nd0.8Sr0.2NiO2 superconducting films with Corbino-disk configuration. The azimuthal angular dependence of the magnetoresistance (R(φ)) manifests the rotational symmetry breaking from isotropy to four-fold (C4) anisotropy with increasing magnetic field, revealing a symmetry-breaking phase transition. Approaching the low-temperature and large-magnetic-field regime, an additional two-fold (C2) symmetric component in the R(φ) curves and an anomalous upturn of the temperature-dependent critical field are observed simultaneously, suggesting the emergence of an exotic electronic phase. Our work uncovers the evolution of the quantum states with different rotational symmetries in nickelate superconductors and provides deep insight into their global phase diagram.

Critical behavior in a chiral molecular model.

Understanding the condensed-phase behavior of chiral molecules is important in biology as well as in a range of technological applications, such as the manufacture of pharmaceuticals. Here, we use molecular dynamics simulations to study a chiral four-site molecular model that exhibits a second-order symmetry-breaking phase transition from a supercritical racemic liquid into subcritical D-rich and L-rich liquids. We determine the infinite-size critical temperature using the fourth-order Binder cumulant, and we show that the finite-size scaling behavior of the order parameter is compatible with the 3D Ising universality class. We also study the spontaneous D-rich to L-rich transition at a slightly subcritical temperature of T = 0.985Tc, and our findings indicate that the free energy barrier for this transformation increases with system size as N2/3, where N is the number of molecules, consistent with a surface-dominated phenomenon. The critical behavior observed herein suggests a mechanism for chirality selection in which a liquid of chiral molecules spontaneously forms a phase enriched in one of the two enantiomers as the temperature is lowered below the critical point. Furthermore, the increasing free energy barrier with system size indicates that fluctuations between the L-rich and D-rich phases are suppressed as the size of the system increases, trapping it in one of the two enantiomerically enriched phases. Such a process could provide the basis for an alternative explanation for the origin of biological homochirality. We also conjecture the possibility of observing nucleation at subcritical temperatures under the action of a suitable chiral external field.

A solvable model for symmetry-breaking phase transitions

Analytically solvable models are benchmarks in studies of phase transitions and pattern-forming bifurcations. Such models are known for phase transitions of the second kind in uniform media, but not for localized states (solitons), as integrable equations which produce solitons do not admit intrinsic transitions in them. We introduce a solvable model for symmetry-breaking phase transitions of both the first and second kinds (alias sub- and supercritical bifurcations) for solitons pinned to a combined linear-nonlinear double-well potential, represented by a symmetric pair of delta-functions. Both self-focusing and defocusing signs of the nonlinearity are considered. In the former case, exact solutions are produced for symmetric and asymmetric solitons. The solutions explicitly demonstrate a switch between the symmetry-breaking transitions of the first and second kinds (i.e., sub- and supercritical bifurcations, respectively). In the self-defocusing model, the solution demonstrates the transition of the second kind which breaks antisymmetry of the first excited state.

Molecule–plasmon–photon hybridization and applications

We study a potential hybrid quantum system with a plasmonic nanocavity coupled to a vibrating mode of a single molecule and another optical cavity mode. To explore some important and valuable applications in quantum physics, we discuss and evaluate several different applications with respect to the plasmon-mediated quantum interface, the plasmon-assisted engineering of two-mode continuous-variable entanglement, and pursuing an indirect and ultrastrong molecule–photon cooperativity. In addition, governed by the relation of symmetry breaking and quantum phase transitions (QPTs),single-molecule-induced QPTs are also studied in this tripartite hybrid quantum system. This theoretical study strongly supports potential applications of this hybrid system in the field of quantum information processing. It is believed that our investigation of molecule–plasmon–photon hybridization can not only open a new avenue toward quantum manipulation, but also provide a fresh and reliable platform to carry out many applications with high efficiency.

One-dimensional Townes solitons in dual-core systems with localized coupling.

The recent creation of Townes solitons (TSs) in binary Bose-Einstein condensates and experimental demonstration of spontaneous symmetry breaking (SSB) in solitons propagating in dual-core optical fibers has drawn renewed interest in the TS and SSB phenomenology in these and other settings. In particular, stabilization of TSs, which are always unstable in free space, is a relevant problem with various ramifications. We introduce a system which admits exact solutions for both TSs and SSB of solitons. It is based on a dual-core waveguide with quintic self-focusing and fused (localized) coupling between the cores. The respective system of coupled nonlinear Schrödinger equationsgives rise to exact solutions for full families of symmetric and asymmetric solitons, which are produced by the supercritical SSB bifurcation (i.e., the symmetry-breaking phase transition of the second kind). Stability boundaries of asymmetric solitons are identified by dint of numerical methods. Unstable solitons spontaneously transform into robust moderately asymmetric breathers or strongly asymmetric states with small intrinsic oscillations. The setup can be used in the design of photonic devices operating in coupling and switching regimes.

Higher-form subsystem symmetry breaking: Subdimensional criticality and fracton phase transitions

Subsystem symmetry has emerged as a powerful organizing principle for unconventional quantum phases of matter, most prominently fracton topological orders. Here, we focus on a special subclass of such symmetries, known as higher-form subsystem symmetries, which allow us to adapt tools from the study of conventional topological phases to the fracton setting. We demonstrate that certain transitions out of familiar fracton phases, including the X-cube model, can be understood in terms of the spontaneous breaking of higher-form subsystem symmetries. We find simple pictures for these seemingly complicated fracton topological phase transitions by relating them in an exact manner, via gauging, to spontaneous higher-form subsystem symmetry breaking phase transitions of decoupled stacks of lower-dimensional models. We harness this perspective to construct a sequence of unconventional subdimensional critical points in two and three spatial dimensions based on the stacking and gauging of canonical models with higher-form symmetry. Through numerous examples, we illustrate the ubiquity of coupled layer constructions in theories with higher-form subsystem symmetries.

Comprehensive AbInitio Investigation of the Phase Diagram of Quasi-One-Dimensional Molecular Solids.

An abinitio investigation of the family of molecular compounds TM_{2}X is conducted, where TM is either TMTSF or TMTTF and X takes centrosymmetric monovalent anions. By deriving the extended Hubbard-type Hamiltonians from first-principles band calculations and evaluating not only the intermolecular transfer integrals but also the Coulomb parameters, we discuss their material dependence in the unified phase diagram. Furthermore, we apply the many-variable variational MonteCarlo method to accurately determine the symmetry-breaking phase transitions, and show the development of the charge and spin orderings. We show that the material-dependent parameter can be taken as the correlation effect, represented by the value of the screened on-site Coulomb interaction U relative to the intrachain transfer integrals, for the comprehensive understanding of the spin and charge ordering in this system.

Spectral signatures of symmetry-breaking dynamical phase transitions.

Large deviation theory provides the framework to study the probability of rare fluctuations of time-averaged observables, opening new avenues of research in nonequilibrium physics. Some of the most appealing results within this context are dynamical phase transitions (DPTs), which might occur at the level of trajectories in order to maximize the probability of sustaining a rare event. While macroscopic fluctuation theory has underpinned much recent progress on the understanding of symmetry-breaking DPTs in driven diffusive systems, their microscopic characterization is still challenging. In this work we shed light on the general spectral mechanism giving rise to continuous DPTs not only for driven diffusive systems, but for any jump process in which a discrete Z_{n} symmetry is broken. By means of a symmetry-aided spectral analysis of the Doob-transformed dynamics, we provide the conditions whereby symmetry-breaking DPTs might emerge and how the different dynamical phases arise from the specific structure of the degenerate eigenvectors. In particular, we show explicitly how all symmetry-breaking features are encoded in the subleading eigenvectors of the degenerate subspace. Moreover, by partitioning configuration space into equivalence classes according to a proper order parameter, we achieve a substantial dimensional reduction which allows for the quantitative characterization of the spectral fingerprints of DPTs. We illustrate our predictions in several paradigmatic many-body systems, including (1) the one-dimensional boundary-driven weakly asymmetric exclusion process (WASEP), which exhibits a particle-hole symmetry-breaking DPT for current fluctuations, (2) the three- and four-state Potts model for spin dynamics, which displays discrete rotational symmetry-breaking DPTs for energy fluctuations, and (3) the closed WASEP which presents a continuous symmetry-breaking DPT into a time-crystal phase characterized by a rotating condensate.

Inhomogeneous disordering at a photoinduced charge density wave transition

Symmetry-breaking phase transitions are ubiquitous in nature. The study of their dynamics in solids has often been performed using homogeneous order parameter theories. By microscopically modeling the photoinduced melting and recovery of a charge density wave, the authors instead show here that the transient dynamics can lead to disordered state, where the average order parameter is not representative of the atomic-scale configuration. This provides a possible minimal model description of the experimentally proposed inhomogeneous disordering pathway in photoinduced phase transitions.

Symmetry-breaking transitions in quiescent and moving solitons in fractional couplers.

We consider phase transitions, in the form of spontaneous symmetry breaking (SSB) bifurcations of solitons, in dual-core couplers with fractional diffraction and cubic self-focusing acting in each core, characterized by Lévy index α. The system represents linearly coupled optical waveguides with the fractional paraxial diffraction or group-velocity dispersion (the latter system was used in a recent experiment [Nat. Commun. 14, 222 (2023)10.1038/s41467-023-35892-8], which demonstrated the first observation of the wave propagation in an effectively fractional setup). By dint of numerical computations and variational approximation, we identify the SSB in the fractional coupler as the bifurcation of the subcritical type (i.e., the symmetry-breaking phase transition of the first kind), whose subcriticality becomes stronger with the increase of fractionality 2-α, in comparison with very weak subcriticality in the case of the nonfractional diffraction, α=2. In the Cauchy limit of α→1, it carries over into the extreme subcritical bifurcation, manifesting backward-going branches of asymmetric solitons which never turn forward. The analysis of the SSB bifurcation is extended for moving (tilted) solitons, which is a nontrivial problem because the fractional diffraction does not admit Galilean invariance. Collisions between moving solitons are studied too, featuring a two-soliton symmetry-breaking effect and merger of the solitons.