With advances in research on hypersonic vehicles, the precise simulation of the effects of thermochemical non-equilibrium has become increasingly important in their design. In light of this, this study explores the influence of high-temperature thermochemical non-equilibrium on the characteristics of the flow field around the hypersonic wings of an aircraft. We initially conducted a numerical simulation by using the model of flow through a cylinder to validate the accuracy and reliability of an 11-species gas model in representing high-enthalpy flow fields. Subsequently, a systematic analysis was conducted on the impact of thermochemical nonequilibrium effects on the temperature, pressure, and enthalpy distribution in the flow field around a symmetric diamond wing under different Mach numbers and angles of attack. The research results indicated that the deeper reason behind the differing thermochemical nonequilibrium effects in the flow field at various Mach numbers lies in the distinct distribution of enthalpy of the air components at different locations, which provided a new perspective for understanding flow field variations from the standpoint of enthalpy. It is disclosed that the thermochemical non-equilibrium significantly altered the characteristics of the flow field, particularly at high Mach numbers and angles of attack, with a significant impact on the aerodynamic parameters of both the windward and the leeward sides of the wing. Through explaining the mechanisms of thermochemical non-equilibrium under flow fields with different structures, this study provides a theoretical foundations for and a fresh perspective on the design of hypersonic vehicles.