Voltage stability condition, reliability and service quality are the important parameters of a distribution system which need to be satisfied from the customer point of view.To measure voltage stability of distribution network a voltage stability index is presented in this paper. Voltage stability improvement of network is facilated by network reconfiguration and voltage stability level is quantified by voltage stability index. Network reconfiguration is a process which alters the feeder topological structure by changing the open/close status of the sectionalizing (normally closed) and ties switches (normally open) in the system. In this work, a two stage search of switching option i.e. local search and global search is implemented to achieve desired network configuration. A multilayer ANN model with Error Back Propagation Learning (EBPL) algorithm is simulated for global search to obtained optimal set of candidate switching. The proposed scheme is tested on an 11 kV practical radial distribution system consisting of 52 buses. After reconfiguration, better voltage stable condition of the system is attained. Active power loss of the system is reduced from 0.854 MW to 0.485 MW and reactive power loss of the system is reduced from 0.355MVar to 0.199MVar after achieving optimal configuration.