Swelling Of Clay Minerals Research Articles

Influence of water soaking on swelling and microcharacteristics of coal

AbstractImproving the coal seam permeability is an important measure for increasing the coal bed methane (CBM) production and preventing gas disasters. Hydraulic technologies are effective ways of improving coal seam permeability. However, hydraulic technologies can also cause water to enter the coal seam, allowing the coal seam to soak for a long time. In this study, to obtain the influence of water soaking on the microscopic characteristics of coal, X‐ray diffraction (XRD), scanning electron microscopy (SEM), free swelling ratio tests, and low‐temperature nitrogen adsorption tests (LT‐NATs) were conducted. The mineral compositions of raw coal samples, the variation regularities of micromorphologies, and pore characteristics of the samples with different soaking times were obtained. The results showed that the coal samples contained about 8.5% clay minerals, of which 71% were illite/smectite mixed‐layer. Expansions of different sizes in the areas where the surface of the soaked coal samples contained clay minerals were observed, and the swelling was also observed macroscopically. The swelling not only led to an increase in the coal sample volume but also led to a decrease in pore volume. This change was magnified with the increase in soaking time (within 30 days). The cumulative pore volume of the samples soaked for 30 days was 0.00681 cm3/g. This was a reduction of 29.9% compared to the unsoaked samples. Moreover, the pore volumes show a logarithmic dependence on soaking time. This study provides evidence that the coal containing clay minerals will swell obviously when soaked in water, and the hydration swelling of clay minerals has a great influence on the swelling of coal. This swelling would lead to a decrease in the pore volume and the efficiency of CBM transport, thus affecting the effect of hydraulic measures.

Study on salt precipitation induced by formation brine flow and its effect on a high-salinity tight gas reservoir

For the tight gas reservoir with high salinity formation water, the flow of formation brine may cause salt precipitation and thus promote scale formation. Salt deposition and the accompanying scale formation as well as swelling and shrinkage of clay minerals may cause blockage of the pore and throats, which will significantly reduce permeability and the subsequent gas production rate. In this study, the influence of salt precipitation/dissolution on the physical properties of a tight gas reservoir is studied. Core analyses, core flooding tests, core evaporation tests, and microscopic visual flooding inspections are carried out on core samples extracted from the Shahejie Formation. To simulate the depletion production process in the subsurface, brine flow characteristics are studied by core flooding tests with pressure reduction at a formation temperature of 115 °C and with the change of pressure ranging from 30 to 1 MPa. The potential changes in physical properties including permeability, porosity, pore radius, pore size distribution, and surface area are analyzed by core evaporation tests. To show the brine flow and geometry of salt deposits in the pore structure, visual brine flooding is observed under high magnification microscope. Photos of the pore structure at different stages of salt precipitation are recorded. The results reveal that salt dissolution/precipitation has a significant impact on flow-through characteristics, and it can be divided into three stages during the depletion process. The damage of salt to the core permeability could reach more than 90%, and it increases gradually with the reduction of porosity and initial permeability and the increase of specific area. The maximum formation damage caused by salt precipitation is realized when the salt crystal size and pore throat diameter are close in size. The semi-empirical Carman-Kozeny equation together with porosity and grain diameter is used to estimate the permeability after precipitation.

Modelling Hydration Swelling and Weakening of Montmorillonite Particles in Mudstone

It is of paramount importance to understand the hydration swelling and weakening properties of clay minerals, such as montmorillonite, to determine their mechanical responses during deep underground argillaceous engineering. In this study, the mineral components and microscopic structure of mudstone were characterised using X-ray powder diffraction and field-emission scanning electron microscopy. Experimental schemes were devised to determine the properties of mudstone under the influence of underground water and stress; these involved compacting montmorillonite particles with various water contents and conducting uniaxial compression tests. Experimental results demonstrated that compaction stress changes the microscopic structure of the montmorillonite matrix and affects its properties, and stress independency was found at particular water and stress conditions. Two equations were then obtained to describe the swelling and weakening properties of the montmorillonite matrix based on the discrete element method; further, the hydration swelling equation represents the linear decrease in the density of the montmorillonite matrix with an increase in the water content. It was also determined that the water dependency of uniaxial compressive strength can be described by negative quartic equations, and the uniaxial compressive strength of the montmorillonite matrix is just 0.04 MPa with a water content of 0.6. The experimental results are in good agreement with the calculated solutions and provide an important experimental basis to the understanding of the mechanical properties of montmorillonite-rich mudstones under the influence of underground water and stress.

Use of low-mineralized water for displacing oil from clay productive field formations

The X-ray structural analysis of clay cement composition in the Jurassic sediments of the Shaim oil and gas region of Western Siberia carried out before and after the experiments identified that qualitative and quantitative clay cement composition does not change, i.e. water of the aquifer interacting with the fine rock component does not affect the injection process. Slight swelling of clay minerals does not decrease permeability due to the small amount of minerals with a moving crystal lattice. It was established that formation water does not cause swelling of clay rocks, i.e. it does not have a negative effect on the injection process. Decreasing permeability is due to the deposition of salts clogging filtration channels.

Numerical Simulations of Fracture Propagation in Jointed Shale Reservoirs under CO2 Fracturing

Water-based hydraulic fracturing for the exploitation of shale gas reservoirs may be limited by two main factors: (1) water pollution and chemical pollution after the injection process and (2) permeability decrease due to clay mineral swelling upon contact with the injection water. Besides, shale rock nearly always contains fractures and fissures due to geological processes such as deposition and folding. Based on the above, a damage-based coupled model of rock deformation and gas flow is used to simulate the fracturing process in jointed shale wells with CO2 fracturing. We validate our model by comparing the simulation results with theoretical solutions. The research results show that the continuous main fractures are formed along the direction of the maximum principal stress, whilst hydraulic fractures tend to propagate along the preexisting joints due to the lower strength of the joints. The main failure type is tensile damage destruction among these specimens. The preexisting joints can aggravate the damage of the numerical specimens; the seepage areas of the layered jointed sample, vertical jointed sample, and orthogonal jointed sample are increased by 32.5%, 29.16%, and 35.05%, respectively, at time t=39 s compared with the intact sample. The preexisting horizontal joints or vertical joints promote the propagation of hydraulic fractures in the horizontal direction or vertical direction but restrain the expansion of hydraulic fractures in the vertical or horizontal direction.

Crystal structure model development for soil clay minerals – II. Quantification and characterization of hydroxy-interlayered smectite (HIS) using the Rietveld refinement technique

The acidic weathering process of soils is a worldwide problem. In this process, Al3+ is dissolved from silicates and intercalated into swellable clay minerals by replacing exchangeable cations such as Na+ or Ca2+. Al3+ polymerizes in the interlayer regions of the clay minerals to form fixed oligomers, which significantly reduces the clay minerals swellability and cation exchange, and hence, the soil fertility. The layer silicates with fixed (Al) oligomers in the interlayer are known as hydroxy-interlayered minerals, such as hydroxy-interlayered smectite (HIS), or hydroxy-interlayered vermiculite (HIV). These phases have been recognized for many years, but it is still problematic to adequately characterize the details of their structure and to determine their proportion in soils, based on X-ray diffraction (XRD), which is the most common method for mineral quantification. In the present study, two crystal structure models are used to allow characterization and quantitative determination of HIS in artificial and natural soils, using the Rietveld refinement technique based on XRD. Both models are identical regarding the 2:1 layer and the description of the hydroxy-interlayering, but differ in the effect imposed by environmental conditions. The first model describes the smectite in the ethylene glycol saturated state (≈17 Å), commonly used by clay scientists as a diagnostic intercalate for swellable smectitic or vermiculitic layers in pure smectite or vermiculite or interstratifications. The second model describes the smectite in the air-dried (AD) state including the collapsed state (≈10 Å), one-water layer state (≈12.5 Å), and two-water layer state (≈15 Å). Both models are used to fit XRD patterns obtained from samples with preferred orientation and from XRD random powder specimens, each including structural disorder effects. The models provide plausible refinement results with respect to crystallographic parameters and quantitative proportions. The degree of hydroxy-interlayering gives an estimate of how many exchangeable cations of the smectite were replaced by fixed Al oligomers that inhibit expandability. This value corresponds to calculated values within a range of precision of ≤15% mol/mol. Physical mixtures of HIS with clinochlore, muscovite, quartz, and albite were quantified using the proposed crystal structure model. Results showed that the HIS model delivers reliable quantification results (deviations from actual values ≤3% w/w) which may be applied also for natural soil.

Swelling of clay minerals and its effect on coal permeability and gas production: A case study of southern Qinshui Basin, China

AbstractThe permeability damage of high‐rank coal reservoirs is the main factor affecting the development of coalbed methane (CBM) in the late production stage. Coal core samples from southern Qinshui Basin were saturated with actual formation water, 1/2 salinity formation water, and distilled water to study the swelling of clay minerals. Then, the mechanism of permeability change caused by water sensitivity and its effect on gas production was discussed. The results show that the permeability decrease caused by flow velocity sensitivity did not occur during the water sensitivity experiments. The permeability damage caused by water sensitivity is mainly the static damage from swelling of clay minerals, especially illite/smectite mixed clays and chlorite. During the process of CBM development, the water sensitivity of coal reservoirs will lead to the sharp increase of Na+ concentration and a decrease of Mg2+ concentration in the produced water. Meanwhile, the clay minerals swell due to the adsorption of more Mg2+ and Ca2+, decreasing the reservoir permeability and gas production rate.

Molecular Dynamics Simulation of Hydration and Swelling of Mixed-Layer Clays in the Presence of Carbon Dioxide

Swelling of clay minerals is an important phenomenon that is relevant to many problems in geoscience, oil and gas reservoirs, geophysics, and engineering. The phenomenon is even more complex when c...

Swelling of clay minerals: dual characteristics of K+ ions and exploration of critical influencing factors.

Clay swelling occurs frequently and is closely relevant to a number of engineering and industrial processes, while the underlying mechanisms remain elusive. In this study, K+-bearing clay systems with different charge amounts and charge locations have been simulated by molecular dynamics, showing that swelling is unfavorable for lower charge amounts (1.00 and 1.25 e uc-1) while it relies on charge locations for higher charge amounts (1.50 and 1.75 e uc-1): inhibited when tetrahedrally charged and favored when octahedrally charged. Accordingly, K+ shows dual characteristics and is not always a swelling inhibitor as generally thought. The various influencing factors are inspected and only the hydration effect interprets satisfactorily the swelling behaviors for all K+-bearing clay systems. The critical role of hydration effect during clay swelling is corroborated by the results of residence time, distribution of interlayer water and divergent swelling behaviors from Na+-bearing clay systems. Although water participates in a wide spectrum of physical and chemical processes, hydration is not necessarily among the most important influencing factors. Hydration effect has been evidenced as critical for clay swelling, and the results provide new insights into unraveling the complex swelling processes and resolving the associated engineering and industrial problems.

How Effective Is Carbon Dioxide as an Alternative Fracturing Fluid?

Summary Massive hydraulic fracturing requires an enormous consumption of water and introduces many potential environmental issues. In addition, water-based fluid tends to be trapped in formations, reducing oil/gas-phase relative permeability, and causes clay-mineral swelling, which lowers absolute permeability. Carbon dioxide (CO2) is seen as a promising alternative working fluid that poses no formation-damage risk, and it can stimulate more-complex and extensive fracture networks. However, very little, if any, extant research has quantitatively analyzed the effectiveness of CO2 fracturing, except for some qualitative fracturing experiments that are based on acoustic emissions. In this study, we systematically examine water and CO2 fracturing, and compare their performance on the basis of a rigorously coupled geomechanics and a fluid-heat-flow model. Parameters investigated include fluid viscosity, compressibility, in-situ stress, and rock permeability, illustrating how they affect breakdown pressure (BP) and leakoff, as well as fracturing effectiveness. It is found that (1) CO2 has the potential to lower BP, benefiting the propagation of fractures; (2) water fracturing tends to create wider and longer tensile fractures compared with CO2 fracturing, thereby facilitating proppant transport and placement; (3) CO2 fracturing could dramatically enhance the complexity of artificial fracture networks even under high-stress-anisotropy conditions; (4) thickened CO2 tends to generate simpler fracture networks than does supercritical CO2 (SC-CO2), but still more-complex fracture networks than fresh water; and (5) the alternative fracturing scheme (i.e., SC-CO2 fracturing followed by thickened-CO2 fracturing) can readily create complex fracture networks and carry proppant to keep hydraulic fractures open. This study reveals that, for intact reservoirs, water-based fracturing can achieve better fracturing performance than CO2 fracturing; however, for naturally fractured reservoirs, CO2 fracturing can constitute an effective way to stimulate tight/shale oil/gas reservoirs, thereby improving oil/gas production.

Model development of permeability impairment due to clay swelling in porous media using micromodels

Swelling and displacement of clay minerals during drilling and production of oil and gas reservoirs are among the main mechanisms of formation damage. Most reservoirs contain clay minerals, either originally deposited during sedimentation phase, or precipitated from fluids flowing through matrix. Owing to the large specific surface area of clay particles, their swelling, detachment, and migrationmay lead to permeability impairment in porous media.Therefore, an accurate interpretation of the behaviour of clay particles in the porous media may enable us to prevent and possibly reverse the respective damage mechanisms. In this work, the pore-scale swelling behaviour of clays are studied using glass micro models as porous medium and Sodium bentonite as swelling clay. By image processing technique, effective porosity of model during low salinity water (LSW) flooding are estimated. The effect of different parameters such as porous medium aspect ratio and clay concentration on permeability impairment is studied. According to this study, besides higher clay concentrations, the permeability is also affected adversely by larger aspect ratio of pore bodies. Based on our experiments, a model is developed to estimate permeability impairment by clay swelling as a function of pore geometry and clay concentration.

Experimental study on the supercritical CO2 fracturing of shale considering anisotropic effects

Hydraulic fracturing using freshwater as fracturing fluid is regularly employed in commercial shale gas or oil production. Many problems are brought by the fracturing fluid of water, such as water shortages, swelling of clay mineral, and the pollution of flow-back water. Replacement of water by supercritical CO2 (SCCO2) in the hydraulic fracturing treatment of shale reservoir has meaningful potential for the improvement of gas production. Hydraulic fracturing experiments, under different injection rate and stress state, were carried out for studying the SC-CO2 fracturing of shale considering anisotropy effects. Anisotropy of shale has a significant impact on the mechanical behavior and fracture propagation of shale in the experiment. There shows a downward tendency for breakdown pressure with the increase of bedding plane angle in general. Higher injection rate can lead to the higher breakdown pressure, while higher deviator stress can lead to the lower breakdown pressure instead. In addition, three patterns of fracture propagation can be observed in the experiment, relative to the bedding structures of shale specimen, including propagating along, propagating across and arresting. The maximum values of fracture width during experiment in shale with different bedding plane angle ranges from 0.29 mm to 1.05 mm, while the final fracture width after the fracturing experiment is kept within the range of 0.01 mm–0.04 mm under the injection rate of 0.3 ml/s.

Deterioration of volcanic tuff rocks from Armenia: constraints on salt crystallization and hydric expansion

Volcanic tuffs are widely used in the Armenian architecture and represent building stones of the country’s most precious cultural heritage sites. For the very first time, extensive investigations regarding their chemical and mineralogical composition as well as the influence of petrophysical properties on their weathering behavior were realized. Different groups of tuff rocks could be identified, which differ greatly in their chroma, texture, their chemical and mineralogical composition, as well as their weathering behavior. At 30% porosity and 25% micropores, the tuff rocks show a sharp limit of changing water transport and retention behavior. Swellable clay minerals, the amount of micropores and the hygroscopic sorption value show a direct relation with the hydric expansion and proved to be reliable parameters for its estimation. Zeolite minerals proved to drastically increase the sorption values of the tuff rocks and are discussed as a cause for potential disjoining pressure. Furthermore, the application of the salt bursting test by European standard on these glass-rich volcanic tuff rocks is questioned, due to considerable different mineralogy and fabric in comparison to classic ash-rich tuffs.

Mechanical-Chemical-Mineralogical Controls on Permeability Evolution of Shale Fractures

We report experimental observations of permeation of CO2-rich aqueous fluids of varied acidic potential (pH) on three different shales to investigate mechanical, chemical, and mineralogical effects on fracture permeability evolution. Surface profilometry and SEM-EDS (scanning electron microscopy with energy-dispersive X-ray spectroscopy) methods are employed to quantify the evolution in both roughness on and chemical constituents within the fracture surface. Results indicate that, after 12 hours of fluid flow, fracture effective hydraulic apertures evolve distinctly under different combinations of shale mineralogy, effective stress, and fluid acidity. The evolution of roughness and transformation of chemical elements on the fracture surface are in accordance with the evolution of permeability. The experimental observations imply that (1) CO2-rich aqueous fluids have significant impact on the evolution of fracture permeability and may influence (and increase) shale gas production; (2) shale mineralogy, especially calcite mineral, decides the chemical reaction and permeability increasing when CO2-rich aqueous fluids flow through fractures by free-face dissolution effect; (3) clay mineral swelling reduces fracture aperture and additively calcite pressure solution removes the bridging asperities, which are the main reasons for fracture permeability decrease; (4) competition roles among clay mineral swelling, mineral pressure solution, and free-face dissolution determine how fracture permeability changes. Furthermore, a multiple parameter model is built to analyze effective hydraulic aperture evolution in considering above three mechanisms, which provide a reference to forecast fracture permeability evolution in shale formations.

Structure and hydraulic properties in soils under long-term irrigation with treated wastewater

Secondary treated wastewater, a commonly used water resource in agriculture in (semi-)arid areas, often contains salts, sodium, and organic matter which may affect soil structure and hydraulic properties. The main objective of this study was to jointly analyse the effects of long-term irrigation with treated wastewater on physicochemical soil characteristics, soil structure, and soil water dynamics in undisturbed soils. X-ray microtomography was used to determine changes in macro-porosity (> 19 μm), pore size distribution, and pore connectivity of a sandy clay loam and a loamy sand. Differences in the pore network among soils irrigated with treated wastewater, fresh water that replaced treated wastewater, and non-irrigated control plots could be explained by changes in textural composition, soil physicochemical parameters, and hydraulic properties. In this study we showed that irrigation led to the development of a connected macro-pore network, independent of the studied water quality. The leaching of silt and clay particles in the sandy soil due to treated wastewater irrigation resulted in an increase of pores < 130 μm. While this change in texture reduced water retention, the unsaturated hydraulic conductivity was diminished by physicochemical alteration, i.e. induced water repellency and clay mineral swelling. Overall, the fine textured sandy clay loam was much more resistant to soil alteration by treated wastewater irrigation than the loamy sand.

Molecular Dynamics Simulation of Hydration and Swelling of Mixed-Layer Clays

Swelling of clay minerals is important to a broad class of problems in science and engineering. While the problem has been extensively studied experimentally, past molecular modeling of the phenome...

Structures and fractal characteristics of pores in low volatile bituminous deformed coals by low-temperature N2 adsorption after different solvents treatments

Coal is a porous medium with fractal characteristics. With the removal of soluble fractions under solvent treatment, the structures and fractal characteristics of pores are bound to produce changes. Exampled by low volatile bituminous coals with different degrees of deformation from Huoerxinhe and Changcun coal mines in Qinshui basin, North China, the paper investigated on the changes of pore structure parameters and minerals compositions of coals before and after different solvents treatments, including tetrahydrofuran (THF), hydrochloric acid (HCl) and chlorine dioxide (ClO2). And Insight into the relationships between fractal dimensions and pore structure parameters and coal compositions were provided. Results show that: The shapes of N2 adsorption/desorption isotherms rarely change but their adsorption quantities differ sharply after different solvents treatments for coal with same deformation, indicating no change in pore type but a change in the number of pore in the same pore size. Compared to raw coals, with the removal of soluble fractions in coals pore volume (PV) and specific surface area (SSA) tend to ascend after THF extraction; changes in PV and SSA depend jointly on the dissolution of carbonate minerals and the swelling of clay minerals after HCl treatment; and the varieties of PV and SSA, to a great extent, are closely related to the swelling of clay minerals after ClO2 treatment. Pore structure fractal dimension (DA) and surface fractal dimension (DB) are obtained based on Frenkel-Halsey-Hill model. DA is mainly affected by the proportion of transitional pores and mesopores on PV; therefore, DA can be used to describe pore volumetric roughness of these transitional pores and mesopores. Meanwhile, DB is mainly influenced by the proportion of micropores on SSA; therefore, DB can be utilized to represent pore surface roughness of these micropores. As coal deformation increases, DA grows for raw coals and coals after extraction with THF; therefore, PV has a significant migration to the pores of small apertures causing the growing contribution of micropores to PV. However, DA declines for coals treated by HCl and ClO2, potentially because the welling of clay minerals blocks the pores of small apertures and increase the proportion of the pores of large apertures on PV. DB shows no clear trends with increasing coal deformation. A “reversed U-shaped” curve relationship is observed between moisture in coal and two fractal dimensions, which is due to the effect of water molecule interfacial tension. Ash correlates negatively with DA and positively with DB because of the various influences of minerals on pore homogeneity in pores of different apertures.

Effect of Water Saturation on Pressure-Dependent Permeability of Carboniferous Shale of the Qaidam Basin, China

Permeability is the most important parameter that describes gas flow characteristics in shale. Water saturation and effective pressure have a considerable effect on shale permeability. This paper presents the results of a laboratory study of the effects of water saturation and effective pressure on gas permeability in Carboniferous shales of the Qaidam Basin, China. The permeability of shale samples with varying water saturation (0–33 wt%) was measured at effective pressure of 6.9 to 27.59 MPa and at low mean pore pressure (< 6.89 MPa) at room temperature, using a pressure pulse decay permeameter. The results indicate that the water saturation and the effective pressure are the main factors affecting the shale permeability. Permeability of sample C034, which has a high clay content and is dominated by nanoscale slit-shaped pores, shows a large decrease (up to 90%) with increasing water saturation (from 0 to 31.7 wt%), depending on the effective pressure. A much larger permeability reduction with increasing water saturation fraction is associated with the swelling of clay minerals. For each sample with varying water saturation, our analyses revealed a consistent line relationship between log permeability and effective pressure variation. The impact of effective pressure on the measured permeability becomes more significant as water saturation increases. With increasing water saturation, the gas slippage factor decreases and calculated effective pore size increases, and gas–water flow in the shale samples occurs as channel flow. This study provides practical information for further studies of stress-dependent permeability of shale with water and the gas slippage effect in two-phase, gas–water flow.

Microscopic Mechanism of Clay Minerals on Reservoir Damage during Steam Injection in Unconsolidated Sandstone

In this work, the swelling, transformation, and dissolution of clay minerals after steam injection in heavy oil reservoir were investigated, and the damage mechanism of steam injection was discussed to research the microscopic mechanism of clay minerals on reservoir damage during steam injection in unconsolidated sandstone. The results show that the swelling of clay minerals increases with the increase of the pH of the brine and decreases with the increase of the salinity of the brine. As we all know, the swollen clay minerals are liable to fall from the inner wall of the pass, which may cause the blockage of reservoirs. What is more, the environment of high temperature and high pH would promote the transformation of the clay minerals. Montmorillonite can be transformed into illite and analcime, and kaolinite can be transformed—due to the water sensitivity of the clay mineral—to montmorillonite and analcime, whereas illite is relatively stable. For the movement of particles in the reservoir during the inj...

On the Prediction of Water Contents in Na-Saturated Dioctahedral Smectites

Properties of swellable clay minerals in technical and geotechnical applications as well as in geological systems are determined by their water content. Thereby, the water content depends on the structure and morphology of the smectites and available water while smectites are the most heterogeneous clay minerals. Here, first-principles calculations are combined with ab initio thermodynamics to systematically study the hydration states of Na-saturated dioctahedral smectites. Total energy calculations based on density functional theory are carried out for a series of montmorillonites and beidellites with varying layer charge (0.125 ≤ ξ ≤ 0.5) and increasing number of water molecules per unit cell. The thermodynamic ground state was then defined with the help of the grand canonical potential as a function of chemical potential of water, which is directly related to the experimental conditions of pressure and temperature. For the first time, p,T-phase diagrams of stable hydration states together with relative...