Swelling Characteristics Research Articles

Temporal effect and evolution mechanism of sand-bentonite mixture liner swelling under the influence of sand and diesel

To elucidate the time-dependent swelling behavior of landfill sand-bentonite mixture liners under the effect of organic pollutants, an no loading swelling ratio test was conducted on mixtures with varying sand and diesel content. The evolution characteristics of the swelling time curve morphology were investigated. The micro-mechanisms underlying the swelling time effect evolution were explored. The results indicated that the sand-diesel interaction significantly altered the swelling time curve morphological characteristics of the mixture. As the sand content increased, the swelling coefficient at the stable state decreased. However, during the rapid swell phase, diesel-contaminated mixed soil does not exhibit the increase-then-decrease pattern in swell coefficient seen in unpolluted mixed soil. The duration of both the slow swelling phase and the time to reach a stable state were longer. Mechanistic analysis revealed that cation exchange capacity is insufficient to effectively analyze the evolution characteristics of the swelling time curve. Instead, the initial swelling potential of bentonite is the true indicator of the mixture’s swelling properties. The particle size distribution influences the changes in the swelling coefficient during the rapid swelling phase, but diesel alters the particle size distribution, mitigating its impact. The oil sealing effect within intra-aggregate and inter-aggregate pores not only weakened the swelling characteristics of the mixture at all stages but also increased the permeability resistance, thereby reducing the duration of the rapid swelling phase and extending the slow swelling and stable swelling phases.

Swelling characteristics of montmorillonite mineral particles in Gaomiaozi bentonite

Highly compacted bentonite is an ideal back-filling (buffer) material for the deep geological disposal of high-level radioactive waste. Montmorillonite is the main constituent mineral of it. The nanoscopic swelling characteristic of montmorillonite mineral particles greatly influences the macroscopic buffering performance of highly compacted bentonite blocks. Firstly, the montmorillonite suspension liquid was exfoliated by freeze-thaw cycles, the appropriate mineral particles were selected by atomic force microscope (AFM) for making colloidal probes. Then, the swelling pressure between mineral particles was measured by AFM, investigating the effects of interlayer distance, layer number, temperature, and interlayer cation type on the nanoscale swelling pressure. The experimental results showed that the swelling pressure of montmorillonite mineral particles peaks at about 0.7–0.8 nm interlayer distance. The swelling pressure of mineral particles with more layers is smaller. The higher the ambient temperature, the greater the swelling pressure. The swelling pressure of Ca-montmorillonite is significantly larger than that of Na-montmorillonite. The Laird model has a relatively good applicability with the interlayer distance of 0.6–1.2 nm; the DLVO theory has a good applicability with the interlayer distance greater than 1.5 nm. Finally, a predictive model was developed for the swelling pressure of nanoscopic mineral particles considering the effect of layer number. The research results provide data support and theoretical support for swelling pressure generation and cross-scale transmission mechanism of highly compacted bentonite hydration.

Comparison of thermal, rheological properties of Finnish Pinus sp. and Brazilian Eucalyptus sp. black liquors and their impact on recovery units

Black liquor (BL) is the major bioproduct and biomass fuel in pulp mill processes. However, the high viscosity of BL makes it a challenging material to work with, resulting in issues with evaporators and heat exchangers during its transport and processing. The thermal and rheological properties of BLs from Pinus sp. (PBL) and Eucalyptus sp. (EBL) were studied. FTIR spectra revealed the presence of the characteristic functional groups and the chemical composition in liquors. TGA/DTG curves showed three characteristic degradation stages related to evaporation of water, pyrolysis of organic groups, and condensation of char. Rheologically, liquors are classified as non-Newtonian and with comportment pseudoplastic. Their rheological dynamic shear properties included a linear viscoelastic region up to 1% shear strain, while frequency sweeps showed that storage modulus (Gʹ) > loss modulus (Gʹʹ), thus confirming the solid-like behavior of both BLs. The rheological study demonstrated that increasing the temperature and oscillatory deformations of PBL and EBL decreased their degree of viscoelasticity, which could favor their pumping and handling within the pulp mill, as well as the droplet formation and swelling characteristics in the recovery furnace.

Preparation of potato granules powder by low temperature ultrafine grinding and its effect on the texture of bread

AbstractIn this article, low temperature ultrafine grinding and other three kind of crushing methods were used to prepare potato granules powder. And the swelling power and solubility, water‐holding capacity, gelatinization characteristics, particle size, and chromaticity of different particle size levels of potato granules powder were determined. The experimental results showed that the potato granules powder prepared by low temperature ultrafine grinding had the highest solubility and swelling power, and the highest degree of pre‐gelatinization; With the increase in the addition of potato powder, the water absorption of the dough increased, and been more rheological. The volume of bread gradually decreases and the firmness increases. With the decrease of potato granules powder size, the water absorption of dough decreases and the bread hardness increases. In this experiment, when the grain size of potato powder was 200 mesh and the addition amount was 2%, the sensory score was the highest and the taste was the best. The result provides theoretical and practical basis for the production of potato bread and the comprehensive utilization of potato resources.Practical applicationsThe present study demonstrates the effective preparation of potato whole powder particles through low temperature ultrafine grinding. Comparative analysis with shear grinding, ball grinding, and room temperature grinding reveals that low temperature ultrafine grinding yields superior solubility, swelling, and gelatinization characteristics. Furthermore, incorporating 200 mesh fine potato powder in bread formulation significantly enhances dough rheological properties and water absorption while improving bread hardness and flavor. The findings offer a solid theoretical and practical foundation for the production of potato bread and the comprehensive utilization of potato resources.

Mechanical and in vitro study of 3D printed silk fibroin and bone-based composites biomaterials for bone implant application.

When treating orthopaedic damage or illness and accidental fracture, bone grafting remains the gold standard of treatment. In cases where this approach does not seem achievable, bone tissue engineering can offer scaffolding as a substitute. Defective and fractured bone tissue is extracted and substituted with porous scaffold structures to aid in the process of tissue regeneration. 3D bioprinting has demonstrated enormous promise in recent years for producing scaffold structures with the necessary capabilities. In order to create composite biomaterial inks for 3D bioprinting, three different materials were combined such as silk fibroin, bone particles, and synthetic biopolymer poly (ε-caprolactone) (PCL). These biomaterials were used to fabricate the two composites scaffolds such as: silk fibroin + bovine bone (SFB) and silk fibroin + bovine bone + Polycaprolactone (SFBP). The biomechanical, structural, and biological elements of the manufactured composite scaffolds were characterized in order to determine their suitability as a possible biomaterial for the production of bone tissue. The in vitro bioactivity of the two composite scaffolds was assessed in the simulated body fluids, and the swelling and degradation characteristics of the two developed scaffolds were analyzed separately over time. The results showed that the mechanical durability of the composite scaffolds was enhanced by the bovine bone particles, up to a specific concentration in the silk fibroin matrix. Furthermore, the incorporation of bone particles improved the bioactive composite scaffolds' capacity to generate hydroxyapatite in vitro. The combined findings show that the two 3D printed bio-composites scaffolds have the required mechanical strength and may be applied to regeneration of bone tissue and restoration, since they resemble the characteristics of native bone.

Synthesis and characterization of SiO2 nanoparticles reinforced 3D printable gelatin/PVA/guar gum/ hydroxypropyl methylcellulose-based biocomposite hydrogel

Biocomposite-based hydrogels have engrossed snowballing devotion due to their hydrophilic, biodegradability, and biocompatibility properties. 3D printing of biocomposite-based hydrogels has emerged in numerous fields, such as pharmaceutical, biomedical, and food engineering, as it involves fabricating complex and customized geometrical components. The present works focus on developing new 3D printable biocomposite hydrogels using gelatin, polyvinyl alcohol, guar gum, and hydroxypropyl methylcellulose (HMC). Hydroxyapatite (HAp) and SiO2 nanoparticles are used as supplemental materials to tailor the properties of hydrogels. The composition has been optimized for enhanced printability through rheological characterization. The developed hydrogel, chemically cross-linked with glyoxal, has been assessed for its static and dynamic mechanical properties, swelling, thermal stability, and degradation characteristics. By incorporating supplements such as HAp, HMC, and SiO2 into the gelatin/polyvinyl alcohol (PVA)/guar gum hydrogel, a compressive and tensile strength of 4.64 MPa, and 71.76 kPa was achieved with better recovery efficiency under cyclic compression and tensile tests. The highest storage modulus of 0.6 MPa at 100 Hz was noticed. A sorbing capacity of 208.98 % was perceived in 70 h. The hydrogel demonstrated quick creep recovery and stress relaxation properties with faster degradation behavior than the PVA hydrogel. Based on the outcomes attained in the present study, it is inferred that the reported biocomposite hydrogels are promising materials for pharmaceutical and biomedical applications.

Evaluation and prediction of swelling properties of bentonite under the action of salt solution

Bentonite demonstrates exceptional water absorption and expansion characteristics, along with a high degree of impermeability. The expansion characteristics of bentonite buffer materials are influenced by the underground aqueous solutions containing various base ions. In this paper, the swelling characteristics of bentonite with different dry densities under the action of different base ions and different concentrations of aqueous solution were studied by indoor limited expansion rate and swelling force tests. And the swelling characteristics of bentonite under the action of salt solution were predicted by Back Propagation Neural Network (BPNN). The findings demonstrated that: The swelling process of bentonite can be categorized into four distinct stages: initial swelling, rapid expansion, gradual enlargement, and stable volumetric increase. The expansion rate of bentonite is influenced by the dry density, as well as the type and concentration of the solution. The influence of various solutions on the expansion rate of bentonite follows the order: NaCl < CaCl2 ≈ MgCl2 < KCl. The type and concentration of the solution, as well as the initial dry density of the sample, exert significant influence on the swelling force of bentonite. The swelling characteristics of bentonite are accurately predicted by BPNN. The findings of this study offer valuable insights for the scientific utilization and rational disposal of bentonite in engineering applications.

Assessment of the Swelling Behavior of NaOH-Contaminated Red Earth in the Visakhapatnam Region of India Using X-ray Diffraction Analysis

Research on the impact of alkali contamination on the swelling behavior of red earth in the Visakhapatnam region has been notably limited. Therefore, this study aims to investigate the effects of alkali (NaOH) contamination on the swelling characteristics of the region’s red earth. The red earth of this region was found to be a well-graded sandy soil with 81% sand and 18% fines. X-ray diffraction studies showed that this region’s red earth mainly consists of quartz, kaolinite, and hematite. The soil is inherently non-swelling. However, the free swell tests showed considerable swell under contamination of NaOH solutions of various normalities (0.05, 0.1, 1, 2, and 4N). One-dimensional consolidation tests have shown that the swell increased with the concentration of the NaOH solution and with the duration of the interaction. Red earth exhibited 'an equilibrium swelling' of 5.6, 10, 15, 17, and 20% when contaminated with 0.05, 0.1, 1, 2, and 4N NaOH solutions, respectively. XRD studies revealed that the red earth sample contaminated with even 0.05N NaOH solution and cured for 56 days exhibited the formation of zeolites analcime and natrolite. Silicate minerals like paragonite and ussingite were also formed along with the zeolites. N-A-S-H compounds, hydrosodalites, and zeolites like super hydrated natrolite, zeolite SSZ16, and zeolite ZK-14 were formed at higher normalities of NaOH after a curing period of 56 days, which caused increased swell. The research demonstrated that the formation of zeolites resulting from the alkali contamination led to swelling in the red earth.

A novel coupled hydrothermal–mechanical model and numerical analysis of unsaturated bentonite considering the influence of salt ions

The quantitative research on swelling properties of bentonite considering the influence of salt ions under the effect of hydrothermo-mechanical coupling is relatively weak. Based on a calculation model for the swelling characteristics of bentonite from a fractal perspective, this work proposes a novel coupled multifield control equation for unsaturated bentonite considering the influence of salt ions. The numericalization of the coupling control equation was completed by secondary development of a numerical analysis platform. The new theoretical model’s dependability and validity were validated by comparing it to experimental data. The evolution of the related-field quantities under the multifield coupled effect in salt-bearing environments was obtained, and the effect of salt ion concentration was analyzed. The calculation showed that the temperature of bentonite changed periodically with changing ambient temperature. Temperature gradient induces migratory movement of water from high to low temperature regions. The hollow axisymmetric soil sample gradually saturated from outside to inside with increasing water injection rate at the outer cylindrical surface. The swelling pressure of bentonite will increase with an increase in water content, whereas the presence of salt ions weakened the swelling behavior. Temperature and relative humidity were less affected by salt ion concentration.

The Effect of Whey Protein Concentrate Addition on the Gel Properties of Potato Starch and the Quality of Vermicelli

T he quality of vermicelli was deemed dependent on gel characteristics. Alum was traditionally employed to modify gel characteristics for quality enhancement in potato vermicelli products. In this study, whey protein was added to boost the gel characteristics of potato starch, with the goal of improving vermicelli quality. It was observed that the peak viscosity, G', G", swelling characteristics, and dehydration of the potato starch gel were significantly reduced with the addition of whey protein. At the same time, a more continuous and dense honeycomb porous structure was gradually formed in the gel network with whey protein, facilitating a more compact potato starch gel network. The tight accumulation of the potato starch gel network was facilitated by this change. Significant increases were observed in the hardness, cooking loss, and water holding capacity of the vermicelli with the addition of whey protein. The swelling characteristics of the vermicelli gradually decreased, leading to a milky yellow color. When the whey protein addition was 4%, the textural and sensory characteristics of the vermicelli were found to be comparable to those of alum-treated vermicelli in overall sensory scores. It was demonstrated in this study that the gel characteristics of potato starch could be enhanced by whey protein, thereby improving the quality of vermicelli.

From biopolymer matrix to medicine: the drug delivery dynamics of amoxicillin-loaded PVA/SA/ZnONPs hydrogels

This research presents a comprehensive study of Polyvinyl alcohol/Sodium alginate/Zinc oxide nanoparticles (PVA/SA/ZnONPs) and PVA/SA/ZnONPs/Amoxicillin (AMX) hydrogels, demonstrating their potential for various biomedical applications. A comparative analysis of their swelling behavior, in vitro biodegradation, antibacterial properties, and drug release profiles was performed. The hydrogels demonstrated distinct swelling characteristics, with the PVA/SA/ZnONPs/AMX hydrogel showing a higher initial swelling ratio. This behavior, likely due to the increased hydrophilicity from AMX, subsequently decreased over time, indicating AMX release into the environment. The biodegradation study highlighted a faster degradation rate for the PVA/SA/ZnONPs/AMX hydrogel, suggesting its suitability for applications requiring rapid degradation, such as drug delivery systems. Regarding antibacterial properties, the PVA/SA/ZnONPs/AMX hydrogel showed significant antibacterial activity against both Escherichia coli and Staphylococcus aureus, making it a strong candidate for biomedical applications necessitating antibacterial activity. Additionally, the drug release study presented a gradual and controlled release of AMX from the hydrogels over time, demonstrating their potential for sustained drug delivery applications. This research underscores the potential of PVA/SA/ZnONPs/AMX hydrogel, particularly for biomedical applications, especially in wound healing and drug delivery domains, given its potent antibacterial properties and controlled drug release behavior.

Volume changes and consolidation of expansive subgrades under short- and long-term effects of freeze–thaw cycles

ABSTRACT Pavements and light structures constructed on expansive subgrade layers have experienced severe damage due to volume changes. These layers have been exposed to climatic changes such as freeze–thaw (FT) cycles. Accurate estimation of design parameters regarding heave/settlement is essential for sustainable performance. This work study the instantaneous and long-term effects of successive FT-cycles on the volume stability, swelling, and compressibility characteristics of natural and lime-treated expansive subgrades. Volume changes were traced during successive 15FT cycles. Swelling and consolidation characteristics were studied immediately after FT-cycles. The long-term effect of FT was tested at different recovery periods around year. FT-cycles significantly affects volume changes and compressibility, this effect is proportional to soil type and limited up to a certain number of FT-cycles. During the long-term recovery, a considerable part of underwent deformation is a permanent and not recovered, even after year the soil still memorizes this effect. Due to the propagated cracks, the plastic deformation increased with increase in FT-cycles.

Migration characteristics and geohazards risk analysis of swelling clay in clayey silt hydrate sediments

The safe and long-term hydrate production in loose clayey silt sediments with high clay content is one of the research priorities, in which the fines migration is one of the key factors. The characteristics of montmorillonite swelling and dispersion make its migration behavior more challenging, which causes the evolution of reservoir seepage properties and potential geohazards risk cannot be predict. The migration behavior of montmorillonite induced by pore water was investigated, and discusses its potential impact on the geomechanical properties of the reservoir. The results show that the combined effects of montmorillonite swelling, which creates favorable conditions for blockage, and migration, which exacerbates permeability decline, make montmorillonite have a much greater effect on seepage characteristics in clayey silt sediments than illite. Higher montmorillonite content and low salinity increase the particle concentration in the pore water, which creates a source of particles for blockage. The low reynolds number indicates that the particles mainly detach from the pore wall with rolling in laminar flow and the lifting force can be neglected. As a result of this combined effect, the montmorillonite is more likely to readsorb and block the pore throat with bridging. This work will help to understand the migration behavior of montmorillonite in clayey silt formations with low permeability, which needs to be paid attention to when formulating gas production schemes and safety control strategies.

Effect of lipase addition on inhibition of starch retrogradation in rice

We investigated whether the production of the free fatty acids (FFAs) by the addition of lipase during rice cooking inhibits starch retrogradation, and to examine whether proteins are involved in this process. Rice milled with milling ratios of 90%, 80%, 70%, and 60% and alkaline-soaked raw rice (AS) were prepared to obtain samples with different protein content. The protein content decreased from 8.24% to 5.83% as the milling ratio decreased from 90% to 60%, and AS contains 4.58% of protein. The prepared rice was cooked with and without lipase, and then treated with two freeze-thaw cycles to accelerate starch retrogradation. The addition of lipase increased the FFAs content and the peroxide value form 1.65 meq/kg to 4.75 meq/kg and decreased the free thiol (SH) content in cooked rice. The degree of swelling was reduced by 0.14 during cooking with the addition of lipase in cooked rice with a milling ratio of 90%. The degree of starch retrogradation (Dr) tended to increase as the milling ratios decreased from 90% to 60% and AS showed Dr similar to milling ratio of 60%. The degree of amylose-lipid complexes formation, which is involved in the inhibition of starch retrogradation, did not change with or without lipase, suggesting that the inhibitory effect of lipase became smaller as protein decreased. These results suggest that the FFAs produced by lipase converted the free SH of the protein into disulfide bonds, which altered the swelling characteristics of the starch and eventually inhibited the starch retrogradation.

Swelling characteristics of compacted graphene-modified GMZ bentonite infiltrated with NaCl solution

Swelling characteristics of compacted graphene-modified GMZ bentonite infiltrated with NaCl solution

Chitosan-based buccal mucoadhesive bilayer tablets enhance the bioavailability of tizanidine hydrochloride by bypassing the first-pass metabolism

Tizanidine hydrochloride (TZN) is an antimuscarinic agent used in the treatment of pain-related spasms, multiple sclerosis, and stroke-related spasticity. It has low oral bioavailability (40 %) due to excessive first-pass metabolism in the liver. The aim of this project was to enhance the systemic bioavailability of TZN by developing buccal mucoadhesive bilayer tablet formulations using chitosan salts with molecular weights of 136 kDa (7 cP) and 169 kDa (10 cP). Structural characterisation of chitosans and their salts was performed by FTIR, 1H NMR, DSC, TGA, and XRD analyses. Soluble chitosan salts, chitosan glutamate and chitosan chloride, for the adhesive layer, and insoluble ethyl cellulose for the impermeable backing layer were selected as polymers to fabricate the buccal tablets by direct compression method. The tablets containing TZN demonstrated high swelling and good mucoadhesion characteristics as well as released all the drug within 8 h. While TC10, formulated with 10 cP chitosan chloride, showed the highest swelling properties, TG10, prepared with 10 cP chitosan glutamate, exhibited the highest mucoadhesion. Chitosan glutamate tablets (TG7 and TG10) demonstrated better mucoadhesive characteristics and stability than chitosan chloride ones (TC7 and TC10) in the buccal medium based on the results of swelling and drug release studies. The permeability studies performed by Franz diffusion cell demonstrated that the amount of TZN passing through the bovine buccal mucosa was between 13.4 and 14.4 %. Stability studies conducted at 5 ± 2 °C, 25 ± 2 °C and 40 ± 2 °C for 6 months showed that no changes in the content uniformity and pH were observed. The in vivo comparative bioavailability studies in female New Zealand rabbits were performed and TZN-containing buccal mucoadhesive bilayer tablets fabricated with both chloride (TC10) and glutamate (TG10) salts of chitosan demonstrated three times higher bioavailability than the commercial TZN product (Sirdalud® oral tablet) administered by the gastrointestinal route.

Ocean waves in the southwestern Atlantic Ocean: An evaluation of global wave models

AbstractIn situ wave observations are essential for implementing coastal management strategies, designing coastal and offshore structures and understanding many processes related to sedimentology and marine biology. Despite their importance, these observations are rather scarce in the coastal areas of southeastern South America. Moreover, the existing observations are discontinuous, with several gaps and no simultaneity. Today, global wave models have improved their performance by providing reliable wave parameters with high resolution and coverage even at near‐shore areas. In this work, wave parameters from five global models were compared with significant wave heights (HS), peak periods (T) and propagation direction at nine sites located at the Southwestern South Atlantic Ocean. The global products used were WAVERYS (Global Reanalysis Wav 001 032), IOWAGA (WAVEWATCH III Hindcast – WW3 – Global grid – CFSR), ERA5 (ECMWF reanalysis), NOAA WW3 – 30‐year Hindcast Phase 2 and NCEP/EMC Operational global wave model GFS – Wave. Mean arithmetic error (Bias), root mean square deviation, scatter index and the Pearson linear correlation coefficient (r) were assessed at each location where wave observations were available. The best agreements for HS were obtained at the deepest sites located farther from the coast. Lower statistical metrics were achieved at coastal sites where the bathymetry is roughly represented by the global models. The calculated correlation coefficients were found to be lower for T than for HS. Overall, T was slightly underestimated by global models. Wave propagation directions were excellently represented by global models at offshore sites. The WAVERYS model is the global product that best represents the wave parameters in the study area, probably due to its higher spatial resolution (0.2°) and more realistic atmospheric forcing (ERA5). In addition, it satisfactorily represents the temporal variability of HS in open water as well as swell characteristics at the outer the Río de la Plata.

Synthesis of carboxymethyl chitosan–guar gum–poly(vinylpyrrolidone) ternary blended hydrogels with antibacterial/anticancer efficacy and drug delivery applications

Biopolymers have the utmost significance in biomedical applications and blending synthetic polymers has shown favorable characteristics versus individual counterparts. The utilization of the blends can be restricted through the use of toxic chemical agents such as initiators or crosslinkers. In this regard, a chemical agent-free ionizing irradiation is a beneficial alternative for preparing the hydrogels for biomedical applications. In this study, carboxymethyl chitosan (CM-CS), guar gum (GG), and poly(vinylpyrrolidone) (PVP) based ternary blends (TB) were crosslinked using various doses of ionizing irradiation to fabricate hydrogels. The prepared hydrogels were characterized for physicochemical properties, swelling analysis, biological assays, and drug delivery applications. Swelling analysis in distilled water revealed that the hydrogels exhibit excellent swelling characteristics. An in vitro cytocompatibility assay showed that the hydrogels have greater than 90% cell viability for the human epithelial cell line and a decreasing cell viability trend for the human alveolar adenocarcinoma cell line. In addition, the prepared hydrogels possessed excellent antibacterial characteristics against gram-positive Staphylococcus aureus (S. aureus) and gram-negative Escherichia coli (E. coli). Finally, the release studies of anti-inflammatory Quercus acutissima (QA) loaded hydrogels exhibited more than 80% release in phosphate-buffered saline (pH = 7.4). These findings suggest that TB hydrogels can be used as suitable carrier media for different release systems and biomedical applications.

Bioengineering solutions for expansive soil stabilization using waste materials: An experimental evaluation

Municipal solid waste incineration ash is the outcome/product of bioengineering science. The incineration or burning of municipal solid waste (MSW) reduces the volume of this biomass by 90%, and the residual ash can be used in several applications. In this study, the potential of municipal solid waste incineration (MSWI) ash and calcium carbide residue (CCR) waste for stabilization of expansive soil has been experimentally evaluated. The abnormal shrink–swell characteristics of expansive soils pose several problems for civil engineering structures when these soils are used for construction in their original form. The study presents an experimental set-up to determine the best combination of additives to achieve the most favorable technical characteristics of expansive soil for civil engineering activities. The percentage of expansive soil has been kept fixed at 60% of the total weight of the mix for varying ratios of stabilizing agents. The optimization of the stabilizing materials is based on the highest strength parameters of the mix achieved for a particular ratio of additives and soil. The two stabilizing agents are waste materials, and their disposal through landfilling has become costly due to a scarcity of space and handling mechanisms. The values of strength parameters, unconfined compressive strength (UCS), and split tensile strength (STS) of a treated mix are found to be highest for a unique combination of 60% lime stabilized expansive soil and 20% MSWI ash and an equal quantity (20%) of CCR. The cumulative effect of adding the best mix of additives to soil and curing time depicts an improvement of 526.03% in UCS and 463.41% in STS of the mix compared to one day and 28 days of curing time. There is scope for further study, such as adding some fibers to the finalized mix to reinforce the soil mix.

Amine functionalised graphene embedded polyvinyl alcohol (PVA) and PVA-chitosan hydrogel composites

A novel amine-functionalized graphene oxide (AFG) doped polyvinyl alcohol (PVA)/chitosan (PVA-Ch) composite film was developed using an eco-synthesis approach, eliminating the need for halogenated compounds. The resulting AFG-doped PVA/Chitosan (PVA-Ch/AFG) polymer film exhibited promising properties for controlled delivery and biosensing applications. The investigation included assessing the swelling behaviour, dissolution percent, gel fraction, and mechanical properties of the polymer film. The swelling characteristics of PVA-Ch and PVA-Ch/AFG were found to be pH and temperature-dependent across various pH ranges (3, 5, 7, and 9). Interestingly, PVA-Ch/AFG demonstrated a stable swelling pattern at pH 5 and 7, unaffected by changes in chitosan concentration, indicating enhanced stability compared to PVA-Ch. The study also explored the use of PVA-Ch/AFG in a drug delivery system, revealing controlled release of the model antibiotic amphicillin, emphasizing its potential in medical applications. Furthermore, the eco-friendly synthesis route underscored the safety of PVA-Ch/AFG for use in food and medical applications. Biocompatibility assessments, including biodegradability studies and cytotoxicity tests on fibroblasts (3T3 cells), confirmed the safety profile of PVA-Ch/AFG. In conclusion, the study suggests that PVA-Ch/AFG holds promise for bio-sensing applications, offering a flexible and colorimetric platform capable of encapsulating, adsorbing, and desorbing biomolecules such as drugs and sensing compounds.