Sustainable Packaging Materials Research Articles

Survival models to estimate time to visible mold growth on new paper-based food-contact materials under varying environmental conditions

Effective packaging solutions are pivotal in addressing sustainability challenges associated with food consumption. Sustainable packaging must not only reduce ecological impact but also ensure food quality preservation, minimize the risk of foodborne diseases, and contribute to mitigating the accumulation of plastic waste. While paper-based food packaging is environmentally friendly, it is susceptible to mold growth when exposed to specific humidity and temperatures, potentially leading to spoilage and safety concerns. This study introduces an innovative modeling approach employing survival analysis to estimate time to visible mold growth on paper-based materials used in food-contact packaging under varying environmental conditions. The objective is to establish an alternative statistical framework for assessing the impact of relative humidity and temperature on mold proliferation. This approach is particularly relevant to novel sustainable packaging materials in the food industry, especially when dealing with censored data. Survival heatmaps are developed to simplify the visualization of spoilage likelihood, measured by time to visible growth at a given confidence level. Although the survival model is proposed for paper-based materials, there are no theoretical limitations to its extension for use with other materials within and beyond the food industry.

Improving the Physical and Mechanical Properties of Mycelium-Based Green Composites Using Paper Waste.

The growing demand for environmentally friendly and sustainable materials has led to the invention of innovative solutions aiming to reduce negative impacts on the environment. Mycelium-based green composites (MBCs) have become an alternative to traditional materials due to their biodegradability and various potential uses. Although MBCs are accepted as modern materials, there are concerns related to some of their physical and mechanical properties that might have limitations when they are used. This study investigates the effects of using paper waste to improve MBC properties. In this study, we investigated the physical and mechanical properties of MBCs produced from lignocellulosic materials (corn husk and sawdust) and mushroom mycelia of the genus Lentinus sajor-caju TBRC 6266, with varying amounts of paper waste added. Adding paper waste increases the density of MBCs. Incorporating 20% paper waste into corn husks led to the enhancement of the compression, bending, and impact strength of MBCs by over 20%. Additionally, it was also found that the MBCs produced from corn husk and 10% paper waste could help in reducing the amount of water absorbed into the material. Adding paper waste to sawdust did not improve MBC properties. At the same time, some properties of MBCs, such as low tensile strength and high shrinkage, might need to be further improved in the future to unlock their full potential, for which there are many interesting approaches. Moreover, the research findings presented in this publication provide a wealth of insightful information on the possibility of using paper waste to improve MBC performance and expand their suitability for a range of applications in sustainable packaging materials and various home decorative items. This innovative approach not only promotes the efficient utilization of lignocellulosic biomass but also contributes to the development of environmentally friendly and biodegradable alternatives to traditional materials.

Photochromic Responses and Stability of Functional Inks Applied on Sustainable Packaging Materials

Photochromism refers to a reversible colour change induced by the irradiation of photochromic materials with ultraviolet (UV) or visible light that reverts to the original colour after the light source is removed. This effect arises from chemical transformations between two isomers with different absorption spectra, involving processes like proton transfer, chemical-bond formation, and isomerisation. These photochromic inks, appearing as crystalline powders with micro-sized particles, require dissolution in a suitable matrix to achieve the colour change. Photochromic inks are used in security, as functional coatings for paper and packaging, in the fabric industry, and in other ways. This study examines the influence of varying concentrations of micro-sized photochromic pigments and different ink-coating thicknesses on the photochromic effect on sustainable paperboard substrates. Artificial ageing was performed to assess the photochromic response and lightfastness in relation to pigment concentration, ink-coating thickness, and the influence of the paperboard substrates. The results of this research could contribute to enhancing knowledge on employing photochromic inks for diverse packaging applications.

Exploring sustainable food packaging: Nanocellulose composite films with enhanced mechanical strength, antibacterial performance, and biodegradability

Food packaging films play a vital role in preserving and protecting food. However, due to their non-biodegradability, conventional packaging materials have led to significant environmental pollution. To overcome this hurdle, we have developed safe, innovative, sustainable and biodegradable packaging materials that can effectively extend the shelf life of food. In this study, two types of cellulose materials cellulose nanofibers (CNF) and carboxymethyl cellulose (CMC) with complementary roles were combined to prepare nanocellulose composite films with high transparency (90.3 %) of a certain thickness (30 ± 0.019 μm) by solution casting method, and their mechanical properties were further optimized by the addition of plasticizer-glycerol (Gly) and cross-linking agent-glutaraldehyde (GA), so as to maintain the strong tensile strength (≈112.60 MPa) and better malleability (4.12 %). In addition, we loaded the natural active agent tea polyphenols (TPs) with different concentrations to study the inhibition effect on E.coli and S.aureus and to simulate food packaging. Finally, we also found that the synthesized nanocellulose composite films can also achieve rapid degradation in a short time through soil burial, water flushing and immersion. The excellent performance demonstrated in this study provides reference value for further replacing petroleum-based materials with biomass materials in the field of food packaging.

A Novel Approach of Manufacturing Sustainable Seamless Jute Bags and Evaluation of Its Properties: A Comparative Study with Commercial Bags

ABSTRACT To reduce the adverse impact of synthetic bags on carbon footprints, greenhouse gases, and global warming, there is a rising demand for biodegradable and sustainable packaging material, especially for packing crops and food. Bags made from natural fibers are the finest alternative to synthetic ones. Jute is one of the most in-demand natural fibers in the packaging industry. Nevertheless, the traditional production method is more process-oriented, requiring more time and resulting in more expensive bags. Bowing problems induced by side seams cause sack bundles to roll during transport, which is also another issue. This study describes a unique process for producing seamless jute bags and sacks, eliminating the current processes in favor of fewer processes. A mechanical left-handed dobby loom with a cutting arrangement for separating the sacks produced continuous sack weaving. The tensile and seam strength of the produced sacks were evaluated and found to be comparable to those of commercially available sacks. In addition, one-way ANOVA and regression studies demonstrated the results significance. This developed method will increase productivity while reducing energy consumption, resulting in inexpensive packaging products and a solution to the transportation issue.

Utilization of tamarind kernel powder for the development of bioplastic films: production and characterization

This work highlights the production of tamarind kernel powder-based bioplastic films and their characterizations, which can be used as sustainable packaging materials.

The effect of glycerol and sago starch addition on the characteristics of bioplastic based on orange peel pectin

Sustainable food packaging materials have significant interest in addressing environmental issues by making renewable substitutes such as bioplastic based on pectin. Orange peel has a relatively high pectin content of 42.5%, which can be synthesized into bioplastic. Pectin-based bioplastic tend to have limitations in terms of mechanical and physical strength due to the hygroscopic nature of pectin. This study aims to determine the effect of adding glycerol and sago starch on the characteristics of orange peel pectin-based bioplastic. The casting method was used in the bioplasctic formulation using the variation of the pectin:starch ratio (75:25, 65:35, 55:45; and 50:50%) and glycerol composition (10, 20, 30, and 40%). Based on the results, the pectin obtained categorized as low methoxyl pectin and ester pectin. The characterizations of bioplastic achieved the maximum value of the tensile strength of bioplastic was 4.22 MPa, obtained by adding pectin:starch (50:50%) and 10% glycerol. The maximum value of the elongation properties at the break of bioplastic is 24%, obtained by adding the composition of pectin:starch (75:25%) and 40% glycerol. The more additions of the pectin:starch and glycerol composition result in higher water vapor evaporation rate. Hence, utilizing orange peel pectin-based bioplastic offers a sustainable solution by exploring repurposing waste to create bioplastic for food packaging, thereby contributing to environmental preservation.

Starch-based edible packaging: rheological, thermal, mechanical, microstructural, and barrier properties – a review

The microstructures of starch-based edible films are shown in the following micrographs. A well-defined distribution of edible oils and cellulose nanoparticles on the starch surface can be clearly visualized.

Sustainable packaging materials for fermented probiotic dairy or non-dairy food and beverage products: challenges and innovations.

The food and beverage packaging industry has experienced remarkable growth in recent years. Particularly the requirement for appropriate packaging materials used for the sale of fermented products is boosted due to the rising acceptance of economical functional foods available to consumers on the shelves of their local supermarkets. The most popular nutraceutical foods with increased sales include natural yogurts, probiotic-rich milk, kefir, and other fermented food and beverage products. These items have mainly been produced from dairy-based or non-dairy raw materials to provide several product options for most consumers, including vegan and lactose-intolerant populations. Therefore, there is a need for an evaluation of the potential developments and prospects that characterize the growth of the food packaging industry in the global market. The article is based on a review of information from published research, encompassing current trends, emerging technologies, challenges, innovations, and sustainability initiatives for food industry packaging.

Sustainable lignin nanoparticles from coconut fiber waste for enhancing multifunctional properties of macroalgae biofilms

Multifunctional and sustainable packaging biofilms felicitous to changeable conditions are in large demand as substitutes to petroleum-derived synthetic films. Macroalgae with noticeable film-formation, abundant, low-cost, and edible properties is a promising bioresource for sustainable and eco-friendly packaging materials. However, the poor hydrophobicity and mechanical properties of sustainable macroalgae biofilms seriously impede their practical applications. Herein, lignin nanoparticles (LNPs) produced by a sustainable approach from black liquor of coconut fiber waste were incorporated in the macroalgae matrix to improve the water tolerance and mechanical characteristics of the biofilms. The effect of different LNPs loadings on the performance of biofilms, such as physical, morphological, surface roughness, structural, water resistance, mechanical, and thermal behaviors, were systematically evaluated and found to be considerably improved. Biofilm with 6 % LNPs presented the optimum enhancement in most ultimate performances. The optimized biofilm exhibited great hydrophobic features with a water contact angle of over 100° and high enhancement in the tensile strength of >60 %. This study proposes a facile and sustainable approach for designing and developing LNPs-macroalgae biofilms with excellent and multifunctional properties for sustainable high-performance packaging materials.

Gelatin films reinforced by tannin-nanocellulose microgel with improved mechanical and barrier properties for sustainable active food packaging

In this study, reactive tannin-nanocellulose (TANC) microgels, prepared using dialdehyde nanocellulose and tannin through the condensation reaction, were incorporated into gelatin matrix to fabricate GE-TANC films for the potential application as active food packaging materials. AFM, FT-IR, XRD, and TG analysis were employed for characterization of TANCs and the composite films. AFM images and FT-IR analysis confirmed the successful crosslinking of nanocellulose with tannin. Their surface hydrophilicity, UV-blocking capability, antioxidant activity and mechanical properties were measured to investigate the impact of TANC microgels on the film properties. The tannin-containing films displayed excellent antioxidant and UV-blocking properties, maximally scavenging 79% of DPPH free radicals and absorbing 98% of ultraviolet light. The surface hydrophilicity, water vapor transmission rate (WVTR) and water solubility of the composite films decreased compared to those of the neat gelatin film, resulting from the formation of more chemical and physical crosslinkings within the film. The tensile strength tripled from 40 MPa to 108 MPa, and the elongation at break increased from 3.87% to 6.28% with only 5% of TANC2. The GE-TANC films in this work demonstrated high mechanical properties, oxidation and UV resistance, and thus have a prospective application as the sustainable active food packaging materials.

Evaluation of a Fish Gelatin-Based Edible Film Incorporated with Ficus carica L. Leaf Extract as Active Packaging.

The significant concerns associated with the widespread use of petroleum-based plastic materials have prompted substantial research on and development of active food packaging materials. Even though fish gelatin-based films are appealing as active food packaging materials, they present practical production challenges. Therefore, this study aimed to develop an edible film using Ficus carica L. leaf extract (FLE), as it is affordable, accessible, and has superoxide anion radical scavenging action. This edible film was produced by adding FLE to mackerel skin gelatin at varied concentrations (2.5-10% w/w). The results showed that adding FLE to gelatin films significantly affected the tensile strength (TS), elongation at break (EAB), transmittance and transparency, solubility, water vapor permeability (WVP), antioxidant activity, and antibacterial activity. Among all the samples, the most promising result was obtained for the edible film with FLE 10%, resulting in TS, EAB, solubility, WVP, antioxidant activity, and antibacterial activity against S. aureus and E. coli results of 2.74 MPa, 372.82%, 36.20%, 3.96 × 10-11 g/msPa, 45.49%, 27.27 mm, and 25.10 mm, respectively. The study's overall findings showed that fish gelatin-based films incorporated with FLE are promising eco-friendly, biodegradable, and sustainable active packaging materials.

Facile fabrication of arecanut palm sheath based robust hydrophobic cellulose nanopapers via self-assembly of ZnO nanoflakes and its shelf-life prediction for sustainable packaging applications

Cellulose nanofibers have been extracted from arecanut palm sheath fibers via mild oxalic acid hydrolysis coupled with steam explosion technique. Cellulose nanofibers with diameter of 20.23 nm were obtained from arecanut palm sheath fibers. A series of robust hydrophobic cellulose nanopapers were fabricated by combining the synergistic effect of surface roughness induced by the successful deposition of zinc oxide (ZnO) nanoflakes and stearic acid modification via a simple and cost-effective method. In this work, agro-waste arecanut palm sheath was employed as a novel source for the extraction of cellulose nanofibers. 2 wt% of ZnO nanoflakes and 1 M concentration of stearic acid were used to fabricate mechanically robust hydrophobic cellulose nanopapers with a water contact angle (WCA) of 134°. During the deposition of zinc oxide nanoflakes on the CNP for inducing surface roughness, a hydrogen bonding interaction is formed between the hydroxyl groups of cellulose nanofibers and the zinc oxide nanoflakes. When this surface roughened CNP was dipped in stearic acid solution. The hydroxyl groups in zinc oxide nanoflakes undergoes esterification reaction with carboxyl groups in stearic acid solution forming an insoluble stearate layer and thus inducing hydrophobicity on CNP. The fabricated hydrophobic cellulose nanopaper displayed a tensile strength of 22.4 MPa and better UV blocking ability which is highly desirable for the sustainable packaging material in the current scenario. Furthermore, the service life of the pristine and modified cellulose nanopapers was predicted using the Arrhenius equation based on the tensile properties obtained during the accelerated ageing studies. The outcome of this study would be broadening the potential applications of hydrophobic and mechanically robust cellulose nanopapers in sustainable packaging applications.

Construction of carboxymethyl chitosan/PVA/chitin nanowhiskers multicomponent film activated with Cotylelobium lanceolatum phenolics and in situ SeNP for enhanced packaging application

This work focused on the construction of bioactive packaging films based on carboxymethyl chitosan and poly(vinyl alcohol) (CMP) as polymeric matrix and fortified with chitin nanowhiskers, Cotylelobium lanceolatum phenolic extract (CL) and in situ synthesized nano selenium. Extensive morphological, microstructural, physical and mechanical analysis revealed that the nanofillers were well-dispersed and integrated into CMP matrix. Incorporation of the extract and nano selenium produced excellent UV blocking properties without seriously compromising the transparency of the composite (CMP/CNW/CLNS1) film. Moreover, blending of CMP with the filler materials significantly elevated (p < 0.05) the surface hydrophobicity (WCA by 35.4°), water barrier (by 53.86 %), tensile strength (from 29.35 to 33.09 MPa), elongation at break (from 64.28 to 96.48 %), and thermal properties of the resultant CMP/CNW/CLNS1 film, with concomitant reduction in water solubility and swellability. Furthermore, the CMP/CNW/CLNS films exhibited remarkable improvement in antioxidant properties. When used for packaging of peeled fresh garlic cloves, the CMP/CNW/CLNS1 film pouch, not the plain CMP or CMP/CNW film pouches, inhibited weight loss, oxidative browning, and the emergence of black mold on the packaged cloves. The developed CMP/CNW/CLNS1 film demonstrated enhanced capacity to safeguard the quality of packaged food and improved shelf life. Therefore, the present study suggests that incorporation of CNW/CLNS into carboxymethyl chitosan/PVA films is a suitable and facile strategy for the fabrication of films with improved mechanical, physico-chemical and functional properties with great potential for application as a sustainable active packaging material in the food industry.

Novel applications of black pepper essential oil as an antioxidant agent in sodium caseinate and chitosan based active edible films

In the current study, sodium caseinate and chitosan-based composite edible films were developed with the incorporation of black pepper (Piper nigrum) essential oil (BPO) in various concentrations (0.05, 0.1 and 0.15 %) for potential food packaging applications. The chemical composition of BPO was determined using GCMS and the major compound detected were β-caryophyllene, limonene, β-phellandren, pinene, copaene and α-humulene. The addition of BPO resulted in an increase in the thickness, EAB, WVP, moisture content and swelling index values of the films; however, the TS and water solubility decreased. The inclusion of BPO led to a substantial enhancement in the DPPH and ABTS radical scavenging capabilities of the edible films. SEM micrographs demonstrated intermolecular interaction between BPO, sodium caseinate, and chitosan. FTIR spectra confirmed the interaction of the functional groups of the polymers and BPO. The incorporation of the BPO increased the crystallinity of the films. Moreover, the thermal analysis including TGA, DSC and DTG demonstrated an increase in the thermal stability of the edible films with the addition of the BPO. These findings demonstrated that sodium caseinate and chitosan composite based edible films loaded with BPO can be used as sustainable active food packaging material.

Recent Recycling Innovations to Facilitate Sustainable Packaging Materials: A Review

Packaging materials play a significant role in the meat, fish, and seafood, pharmaceutical, beverages, and electronics industries. These materials protect the contents during handling and transportation from damage, contamination, and loss of quality, thus enhancing the shelf life of the products being packaged. Several materials, like paper and cardboard, plastics, metals, and glass, have been widely used. However, the vast consumption of these materials leads to high waste generation due to increasing demands globally. This article considers some aspects of recycling waste packaging materials, the need for recycling in terms of environmental impacts, and the energy-saving and economic benefits. It also provides some highlights on the sustainability of the processes of recycling and how the government and public can influence recycling operations. The impact of the COVID-19 pandemic on packaging systems and solid waste management is also highlighted. This study also provides a short note on the possible future methods to be adopted in the recycling process of waste packaging materials.

Rice straw-based sustainable food packaging material with improved strength and barrier properties: Development and characterization

Sustainable food packaging paper with high barrier and strength properties was developed with rice straw nanocellulose materials. Pulping and bleaching of rice straw were performed using an organosolv pulping and DED (D: chlorine dioxide bleaching; E: sodium hydroxide extraction) bleaching sequence. Bleached rice straw pulp was refined to 90°SR using a laboratory Valley beater. The laboratory handsheets were prepared using pulp slurry at 40°SR and 90°SR. The handsheets of cellulose nanofibrils (CNFs) made of highly refined pulp (90°SR) were surface sized using alkyl ketene dimer (AKD) wax to increase the barrier properties of paper for selective food packaging applications. The paper samples were tested for mechanical, optical, surface, and barrier properties, including tensile index, burst index, tearing index, bending stiffness, elongation, porosity, apparent density, opacity, Cobb value, water vapor transmission rate (WVTR), oil and grease resistance, and contact angle. The refined pulp (90°SR) was analyzed using field-emission scanning electron microscopy (FE-SEM), and it was observed that the morphology of the developed fibers changes to the nanoscale (&lt;100 nm) for at least one dimension. The particle size distribution of the refined pulp using DLS analyzer also confirmed the cellulose fibers to near nanoscale. It was concluded that nanofibers were formed by a high degree of the mechanical pulp refining process and found to be much more economical than alternative processes in this direction. The sample handsheets of CNFs showed good strength and barrier properties. The barrier properties further increased when surface sizing was done using low-cost, nontoxic, and biodegradable AKD wax.

Silver Bionanocomposites as Active Food Packaging: Recent Advances &amp; Future Trends Tackling the Food Waste Crisis

Food waste is a pressing global challenge leading to over $1 trillion lost annually and contributing up to 10% of global greenhouse gas emissions. Extensive study has been directed toward the use of active biodegradable packaging materials to improve food quality, minimize plastic use, and encourage sustainable packaging technology development. However, this has been achieved with limited success, which can mainly be attributed to poor material properties and high production costs. In the recent literature, the integration of silver nanoparticles (AgNPs) has shown to improve the properties of biopolymer, prompting the development of bionanocomposites. Furthermore, the antibacterial properties of AgNPs against foodborne pathogens leads towards food shelf-life improvement and provides a route towards reducing food waste. However, few reviews have analyzed AgNPs holistically throughout a portfolio of biopolymers from an industrial perspective. Hence, this review critically analyses the antibacterial, barrier, mechanical, thermal, and water resistance properties of AgNP-based bionanocomposites. These advanced materials are also discussed in terms of food packaging applications and assessed in terms of their performance in enhancing food shelf-life. Finally, the current barriers towards the commercialization of AgNP bionanocomposites are critically discussed to provide an industrial action plan towards the development of sustainable packaging materials to reduce food waste.

Potato Starch Based Paper Coatings For Sustainable Packaging Applications

As global environmental concerns continue to rise, there is an urgent need for sustainable alternatives in the packaging industry to reduce the environmental impact of traditional packaging materials. This research explores the potential of potato starch-based coatings as an eco-friendly alternative for paper-based packaging applications. The study investigates the feasibility of using locally sourced potato starch to create biodegradable and cost-effective coatings for paper packaging. In this research, a simple and accessible method is employed to extract and process potato starch. The extracted starch is then used to develop paper coatings through a straightforward application process. The study examines the physical properties of these coatings, such as their tensile strength, oil resistance and water resistance. These properties are crucial for ensuring the durability and functionality of the packaging material. Preliminary findings indicate that potato starch-based paper coatings exhibit promising adhesive properties and reasonable resistance to moisture, making them suitable for a variety of packaging applications. This research provides valuable insights into the potential of potato starch-based coatings as a sustainable alternative for paper packaging. The findings could have far-reaching implications for the packaging industry, offering a greener and more environmentally responsible solution to meet the growing demand for sustainable packaging materials.

Robust, biodegradable and flame-retardant nanocomposite films based on TEMPO-oxidized cellulose nanofibers and hydroxyapatite nanowires

Flammability is a fatal drawback for sustainable packaging materials made from cellulose and its derivatives. Incorporating inorganic nanomaterials is a viable approach to improve the fire-resistant property. However, due to the aggregation of inorganic fillers and weak interactions between components, incorporating inorganic nanomaterials always had an adverse impact on the mechanical properties and optical transparency of cellulose-based nanocomposites. Herein, we presented a robust, biodegradable, and flame-retardant nanocomposite film composed of TEMPO-oxidized cellulose nanofibers (TOCNFs) and inorganic hydroxyapatite nanowires (HNWs). Both TOCNFs and HNWs possessed one-dimensional microstructure and could form unique organic-inorganic networks microstructure. The organic-inorganic networks interact through physical intertwinement and multiple chemical bonds, endowing nanocomposite film with outstanding mechanical properties. This nanocomposite film showed a tensile strength of 223.68 MPa and Young's modulus of 9.18 GPa, which were superior to most reported cellulose-based nanocomposite. Furthermore, this nanocomposite film demonstrated exceptional thermal stability and flame-retardant feature attributed to the inorganic framework formed by HNWs. This nanocomposite film also possessed a high optical transmittance even when HNWs content reached 30 % and could be decomposed quickly in soil. By employing organic-inorganic interpenetrating network structure design and multiple bonding interaction, cellulose-based nanocomposites can overcome inherent limitations and attain desirable comprehensive properties.