Nanotube Suspensions Research Articles

Voltammetric Assessment of Paracetamol on a CuONPs – MWCNTs Modified Glassy Carbon Electrode

In this work, an electrochemical sensor using differential pulse voltammetric method for the assessment of antipyretic and analgesic drug, paracetamol was developed. The CuO nanoparticles were synthesized and characterized. A glassy carbon electrode (GCE) fabricated with the suspension of CuO nanoparticles (CuONPs) and multi-walled carbon nanotubes (MWCNTs) were used. The fabricated electrode was characterized using Potassium ferricyanide as a redox probe, which showed increase in the electro active area in the modified electrode. The modified electrode showed improved anodic peak current enhancement in phosphate buffer solution. The consequence of pH of supporting electrolyte and amount of nanoparticles suspension were investigated at a physiological pH of 7.4. Using differential pulse voltammetry, the fabricated electrode showed linear dynamic range from 9 to 160 nM of paracetamol concentration. From the calibration plot, the computed detection limit was 5.06nM and quantification limit was16.88 nM. The developed method was checked for its reproducibility and assay during a day and intraday as well and the results were good with permitted range of errors. The developed process was fruitfully applied to detect paracetamol in pharmaceutical formulations.

Adjusting Paper Device Properties for Bioelectrochemical Analysis and 3D Cell Culture

Context- Paper is an innovative material for cell culture due to its biocompatibility, its inert chemical properties and its low-cost. Paper is already used in many biomedical applications such as immunoassays and, more recently, as affordable electrochemical sensors. In this context, tuning the properties of paper devices can achieve better, more efficient and user-friendly assays for biomedical applications. Here, and by modifying the electrochemical properties of paper electrochemical devices, it is possible to create electrodes that can detect neurotransmitters, a critical type of biomolecules involved in neuronal communication. Dopamine is a neurotransmitter involved in reward and addiction and a molecule of considerable scientific interest. Dopamine is secreted in the brain by dopaminergic neurons. However, the fine chemical mechanisms of neuron networks are still obscure. Being able to spatially measure dopamine secretion, in response to activation of precise neuronal regions in a unique system, can lead to a better understanding of neuronal dynamics, as well as their response to drug alterations. Proposing a research model describing neuronal chemical function in a network will therefore help shining light on their mechanisms and testing new neuropharmacological solutions. Developing new tools for the analytical electrochemistry of the brain will make quantitative neuro-analysis more accessible, thus paving the way for a better understanding of the chemical mechanisms of the brain. Tuning paper electrode for neurochemical analysis- Conductive inks, i.e. conductive polymer poly(3,4-ethylenedioxythiophene): poly(styrene sulfonate) (PEDOT:PSS) and carbon nanotubes (CNT) suspensions, were used to improve the detection of dopamine at paper-based electrodes. The physical and chemical properties of different preparations and mixtures of inks were considered. Solvent secondary doping, a common technique for PEDOT-PSS based electrode, was used to improve the electrical properties of the electrodes. Ferrocyanide electroanalysis was used to benchmark 10 different electrode preparations, revealing that combining CNT and PEDOT-PSS improves the electroactivity of the surface of the sensor. Interestingly, it was found that CNT has a doping effect on PEDOT-PSS, leading to improved electrochemical properties. Finally, these electrodes were tested for dopamine detection. It was found that combining PEDOT-PSS and CNT in the surface layer of ink deposited on the paper electrode allows for lower capacitance, higher anodic current as well as better fouling resistance. Figure 1 presents a CV voltammogram for Dopamine obtained with a paper electrode. Overall, this strategy improves the sensitivity of the assay. Growing neurons on paper- Paper-based devices can also be used for cell culture. Cell on paper constructs are 3D cell culture models that are more suitable to study cell in a biomimetic 3D environment, thus better recapitulating their functions and biology. By carefully modifying the surface of the paper devices, it is possible to adjust their biocompatible properties to ameliorate the survival rate of cell culture on paper. This opens the possibility to achieve neuronal cell culture on paper. We will present different paper preparations compatible with murine dopaminergic maintenance. The neurons were maintained alive for several days of culture. We were able to effectively observe and study neurons in a 3D paper environment and quantify the growth of their processes. Figure 1 : Electrochemical detection of Dopamine for 20 cycles. Working electrode is a paper electrode with PEDOT:PSS and CNT conductive inks, shown on the right, scale is 1 cm. The reference electrode is an Ag/AgCl electrode, and the counter electrode is a platinum electrode. Scan rate is 0.02 Vs-1. Figure 1

Surface engineering of carbon nanotube-carbon fiber networks for enhanced strength in additive manufacturing of nylon composites

This work quantifies the impact of chemical functionalization of carbon nanotubes and carbon fibres on the interfacial shear strength, tensile and interlaminar shear strength properties of additively manufactured nylon composites. The surface chemistry of functionalized carbon materials was evaluated through infrared spectroscopy, energy-dispersive X-ray spectroscopy, and X-ray photoelectron spectroscopy. Single carbon fibre was dip-coated in a suspension of nanotubes and embedded into a nylon matrix. The fibres were pulled out to measure the interfacial shear strength, and the fibres with attached neat, carboxylated, and silanized nanotubes increased it by up to 67 %, 112 %, and 216 %, respectively. Composite samples were manufactured using a novel hybrid additive manufacturing method, which was able to deposit nylon layers and a suspension containing carbon reinforcement. The use of chemically functionalized nanotubes in the suspension led to carbon layers that improved tensile strength by 49 % and tensile modulus by 126 % over neat nylon. Functionalization of carbon reinforcement increased the interlaminar shear strength by up to 63 %. Overall, this paper demonstrates the importance of chemical modification in composite materials containing a large interface area of carbon materials.

Boosting electrochemical performance of single-walled carbon nanotube three-dimensional architectures through appropriate selection of organic dispersant

The choice of organic dispersant in the fabrication of 3D carbon nanotube architectures affects their macroscopic properties. Binder-free papers (referred to as buckypapers, BPs) consisting of single-walled nanotubes (SWCNTs) fabricated by vacuum filtration of nanotube suspensions in isopropanol, ethanol, benzoic acid dissolved in ethanol and lemon oil show a work of adhesion of water that varies from 25.7 to 112.2 mJ·m−2. Bulk electrical resistivity also changes significantly from 145 to 1010 mΩ cm. Raman and FTIR spectra of pristine SWCNTs and BPs show evidence of permanent adsorption of organic molecules on SWCNTs. Heterogeneous electron transfer (HET) standard rate constants, k0, for ferro/ferricyanide and hexaammineruthenium(II)/(III) redox probes estimated from cyclic voltammetry measurements on BP electrodes vary from 12.6×10−4cms−1 to 32.7×10−4cms−1 and 12.8×10−4cms−1 to 26.0×10−4cms−1, respectively, depending on the dispersant used. Calculations using the Gerischer-Marcus model show that molecules adsorbed act as electron donors that boost HET kinetics and cause a shift in the reaction half-wave potential. The level of doping of nanotubes depends on the dipole moment of the dispersant molecules and proton affinity. Thus, the electrocatalytic activity of three-dimensional architectures composed of nanotubes can be adjusted by selecting an appropriate dispersant.

Dispersion quality of aqueously dispersed MWCNT affected by step sonication process and its impact on mechanical strength of cement paste: A comparison between polycarboxylate based high range water reducers and air entraining agent

It has been widely reported that the application of high-level ultrasonic energy during dispersion process of carbon nanotube causes damage on the carbon nanotube and reduces its mechanical performance. However, if the amount of ultrasonic energy is insufficient, the quality of carbon nanotube dispersion becomes poorer so that the effect caused by carbon nanotube reinforcement is minimized. In this work, the step sonication process, which divides a prolonged sonication into a few separate cycles while maintaining the same level of ultrasonic energy, is applied since this process can improve dispersion of carbon nanotube without causing serious damage. Commercially available polycarboxylate ester, polycarboxylate, and air entraining agent were used as dispersing agents. The effect caused by step sonication and type of dispersing agent on dispersion quality of multi-walled carbon nanotube was evaluated, and their impacts on mechanical strength development of cement paste were analyzed. According to the experimental results, step sonication process improved the quality of multi-walled carbon nanotube dispersion when polycarboxylate ester and polycarboxylate were used. Step sonication process was found to be more effective for multi-walled carbon nanotube suspension with higher concentration. Among all dispersing agents, air entraining agent was found to be the best dispersing agent showing 2 times higher UV absorption peak than polycarboxylate and polycarboxylate ester, but the application of air entraining agent caused 40–65% reduction in compressive strength due to the air entrainment. It was also found that dispersion quality of multi-walled carbon nanotube affected flexural strength more significantly than compressive strength.

Sensitive Voltammetric Detection of Acetaminophen on CuONPs-MWCNTs Modified Glassy Carbon Electrode with Enhancement Effect of Anionic Surfactant

In the present work, a voltammetric method using differential pulse voltammetric technique for the assessment of antipyretic and analgesic drug, acetaminophen was developed. The CuO nanoparticles were prepared and characterized. A glassy carbon electrode (GCE) fabricated with the suspension of CuO nanoparticles (CuONPs) and multi-walled carbon nanotubes (MWCNTs) were used. The modified electrode showed improved anodic peak current by introducing an anionic surfactant sodium dodecyl sulphate in phosphate buffer solution. The consequence of pH of supporting electrolyte, amount of nanoparticles suspension and surfactant concentration was investigated at a physiological pH of 7.4. Using differential pulse voltammetry, the fabricated electrode showed linear dynamic range from 9 to 160 nM of acetaminophen concentration. From the calibration plot, the computed detection limit was 5.06 nM and quantification limit was 16.88 nM. The developed method was checked for its reproducibility and assay during a day and intraday as well. The developed process was fruitfully applied to detect acetaminophen in pediatric oral suspensions administered to infants.

Analysis of fluid flow and heat transfer in CNT-infused spiraling disk

This study investigates the fluid flow and heat transfer characteristics influenced by the thermophysical properties of carbon nanotube suspension in engine oil over a stretching-spiraling disk. The surface comprises Homan stagnation point flow impinging normal to a rotating, radially stretching disk, which gives velocity a form of logarithmic spiral. Similarity ansatz transformed coupled nonlinear differential equation system is derived and solved numerically using MATLAB’s bvp4c collocation method. Numerical and asymptotic solutions are also obtained against the controlled parameters via graphical representations and tabular data. Findings indicate that the magnetic field enhances temperature distribution while reducing the velocity field. At the same time, stretching increases radial velocity but decreases azimuthal velocity and temperature profiles, regardless of carbon nanotube type. The asymptotic values of skin friction decline with an increase in the spiralisng angle and in the absence of a magnetic field for both SWCNTs and MWCNTs cases.

Retraction Note: Thermodynamic effect in Darchy–Forchheimer nanofluid flow of a single-wall carbon nanotube/multi-wall carbon nanotube suspension due to a stretching/shrinking rotating disk: Buongiorno two-phase model

Retraction Note: Thermodynamic effect in Darchy–Forchheimer nanofluid flow of a single-wall carbon nanotube/multi-wall carbon nanotube suspension due to a stretching/shrinking rotating disk: Buongiorno two-phase model

Impact of length and radius of carbon nanotubes on flow and heat transfer in converging and diverging channels with entropy generation

This research examines the complex interplay between the carbon nanotubes' length and radius and how that affects flow patterns, heat transfer properties, and entropy creation in both convergent and divergent channels. Our research elucidates the mechanisms at play by revealing a crucial link between carbon nanotube dimensions and the efficacy of heat transfer processes. In particular, carbon nanotubes with a longer length have better heat transmission properties, while carbon nanotubes with a smaller radius generate less entropy. From microfluidics to energy-efficient materials, these results show significant promise for optimizing thermal systems and improving performance. This research looks on the differences between the thermal transports of single- and multi-walled carbon nanotubes in water. Thermo physical characteristics of carbon nanoparticles are one of a kind and essential for this purpose. The fluid is assumed to be incompressible and to flow steadily a two-dimensional plane. The effects of thermal radiation on the heat transfer of a water-based fluid in convergent and divergent channels with decreasing and expanding walls have been studied. In order to quickly sketch the equations, the RK-4 method with shooting approach is used, and similarity transformation is employed to reduce their dimensionality. The key factors influencing hydrothermal performance have been visualized through the use of graphs. The production numbers of entropy are also shown and explained at length. The obtained data supports the reliability of the approach used. Surface heat transport was found to be negatively impacted by elongation. Colloidal single-walled carbon nanotube (SWCNT) suspensions in water had higher thermal conductivity than water itself.

Heat transfer analysis of single-walled carbon nanotubes in Ellis's fluid model: Comparative study of uniform and non-uniform channels

BackgroundThe essential features of nanoparticles in nanofluids play a vital role in nanotechnology. The nanosized particles of carbon are known as carbon nanotubes (CNTs). The properties of CNT like thermal and electrical conductivity, lightweight, flexibility, and mechanical strength support its applications in the medical field i.e., diagnostic and therapeutic agents (drugs, antibodies, biosensors, vaccines etc.). These are not only excellent vehicles for drug delivery and gene therapies but also useful in biosensor diagnostic, enantiomer separation of chiral drugs, tissue regeneration, extraction, and analysis of pollutants and drugs. ObjectiveThe focus of this research work is to open the essential features of peristaltic transport of Ellis nanofluid through uniform and non-uniform channels with suspension of single-walled carbon nanotubes (SWCNT). The consideration of blood flow with SWCNT under the effects of heat generation and electroosmosis is one of the key factors of this investigation. MethodThe complexity of the system is reduced with the implementation of the concepts of longer wavelength and lower Reynolds number. The governing two-dimensional equations are simplified by introducing dimensionless variables and parameters. The mathematical tool “MATHEMATICA 13.3” is used to compute the exact solution and graphical demonstration of velocity, temperature, heat transfer rate, and streamlines. Computational resultsIt is noticed that velocity, temperature, and heat transfer rate are prominent in non-uniform channels as compared to uniform channels. Similarly, the size and number of boluses during the trapping phenomenon increase or decrease quickly in non-uniform channels. The volumetric addition of SWCNT diminishes the velocity and temperature while the heat transfer rate is enhanced in both channels but in the nonuniform channel effects are more prominent. ApplicationsThis study explores the applications of SWCNT in medical fields like angiography, angioplasty, and cancer therapy. NoveltyThe present study is new and has never been addressed before.

Surface-anchored carbon nanomaterials for antimicrobial surfaces.

Carbon nanomaterials (CNMs) are known for their antimicrobial (antibacterial and antiviral) activity when dispersed in a liquid, but whether this can be transferred to the surface of common materials has rarely been investigated. We have compared two typical CNMs (double-walled carbon nanotubes and few-layer graphene) in their non-oxidised and oxidised forms in terms of their antibacterial (Pseudomonas aeruginosa and Staphylococcus aureus) and antiviral (SARS-CoV2) activities after anchoring them onto the surface of silicone. We propose a very simple and effective protocol using the air-brush spray deposition method to entrap CNMs on the surfaces of two different silicone materials and demonstrate that the nanomaterials are anchored within the polymer while still being in contact with bacteria. We also investigated their antiviral activity against SARS-COV2 after deposition on standard surgical respiratory masks. Our results show that while suspensions of double-walled carbon nanotubes had a moderate effect on P. aeruginosa, this was not transferred after anchoring them to the surface of silicone. In contrast, graphene oxide showed a very strong antibacterial effect on P. aeruginosa and oxidised double-walled carbon nanotubes on S. aureus only when anchored to the surface. No significant antiviral activity was observed. This work paves the way for new antibacterial surfaces based on CNMs.

Textile‐Based Stretchable Supercapacitors with Liquid Metal Current Collectors

AbstractStretchable supercapacitors (SCs) have attracted attention as energy storage devices for wearable electronics due to their excellent power performance, low heat generation, and ease of integration into clothing. This paper presents a stretchable SC composed of liquid metal current collectors on textile substrates. For the liquid metal and textile‐based supercapacitors (LM/Tex SCs), the wetting characteristics and electrical resistance of the liquid metal on different types of textile substrates are investigated. The wettability of the carbon nanotube suspension for an electrochemically active material is also affected by the chemical and structural properties of the textile substrates. The intrinsically stretchable LM/Tex SCs are fabricated by sandwiching a soft gel electrolyte layer between the two liquid metal and textile‐based electrodes. The optimized SCs based on the polyester/neoprene textile exhibit a high areal capacitance of 527.8 mF cm−2 and maintain more than 90% of their initial capacitance after 1000 repetitive stretching cycles. Finally, it is demonstrated that the LM/Tex SC is readily integrated into a shirt and reliably supplies electrical energy to light up a light‐emitting diode even under human motion.

Building Three-Dimensional Network Structures of Silicon–Graphite/Carbon Nanotube Composite Anode for High-Energy Lithium-Ion Batteries

As the increasing demand for high-energy-density lithium-ion batteries (LIBs), silicon-based anodes have become an excellent alternative to conventional graphite anodes owing to their high theoretical capacities. In this study, a three-dimensional (3D) electric network structure was developed using an aqueous carbon nanotube (CNT) suspension to improve the specific capacity and cyclability of Si–graphite electrodes. Field-emission scanning electron microscopy demonstrated that longer single-walled CNTs (SWCNTs) effectively covered and interconnected the entire surface of the Si and graphite particles, thereby providing electric conduction networks and facile access to Li ions in the electrode and structural strength with flexibility. As a result, 3D networks structure of Si–graphite/SWCNTs (Si-G-SW) exhibited the highest specific capacity (829.7 mAh g−1 at 0.1 A g−1), rate capability, and cycle stability (>79% after 100 cycles). We expect this robust 3D network electrode system to provide a new route for high-energy-density LIB anodes.

Orientational Transitions in Magnetically Compensated Liquid-Crystal Suspensions of Ferromagnetic Carbon Nanotubes

Purpose of research is to study the influence of ferromagnetic carbon nanotubes on orientational transitions in magnetically compensated liquid-crystal suspensions.Methods. The problem was solved in the framework of the continuum theory. By minimizing the Helmholtz free energy functional, a system of Lagrange-Euler equations is obtained that determines the equilibrium dependences of the orientation angles of liquid crystal and impurity ferromagnetic carbon nanotubes directors, as well as the concentration distributions of the dispersed phase of the suspension as a function of the transverse coordinate, material parameters, and magnetic field strength.Results. It is shown that in the presence of an external magnetic field, a liquid-crystal suspension of ferromagnetic carbon nanotubes can be in a non-uniform phase (angular phase) and two uniform phases (planar and homeotropic phases). Expressions for the threshold fields of transitions between coexisting orientational phases are obtained analytically as functions of the material parameters of the composite. Diagrams of the orientational phases of the suspension are plotted.Conclusion. As a result of the research, it was shown that the addition of low concentrations of ferromagnetic carbon nanotubes can significantly reduce the threshold of the magnetic Fréedericksz transition compared to a pure liquid crystal, which is important for various technical applications. The obtained analytical formulas for the threshold fields of transitions between different orientational phases can be used to determine the anchoring energy and material parameters of suspensions of ferromagnetic carbon nanotubes in a liquid crystal.

Impact of thermal radiation and internal heat generation on Casson nano-fluid flowing by a curved stretchable surface with suspension of carbon nanotubes (CNTs)

The function of present work is to inspect heat transmission of radiative nanofluid in regard to boundary layer description. Carbon nanotubes (CNTs) dependent fluid is being evaluated and it flows overtop a curved stretching surface. Special features, like thermal radiation and internal heat generation, which corresponds to heat transmission along the flow have been incorporated. Dual nature of carbon nanotubes, that is, single walled carbon nanotubes (SWCNTs) as well as multiple walled carbon nanotubes (MWCNTs) together with blood (base fluid) have been utilized for the composition of nanofluid. The rheological properties of blood have been captured using Casson fluid model. Appropriate transformations have been applied to reduce the modeled system of nonlinear partial differential equations into a system of ordinary differential equations (ODEs). To achieve the desired numerical solution of obtained system of ODEs, NDSolve technique is employed using Mathematica. Numerous parameters appearing in governing equations, exert influence on focused physical quantities. Graphs have been engaged to capture these variations for both SWCNTs and MWCNTs. Likewise, numeric charts have been displayed to investigate impressions on skin friction coefficient and Nusselt number for distinct parameters.

Study of thermal convection in chemically reactive carbon nanotube suspension saturated in anisotropic porous enclosure

This study aims to investigate the influence of chemical reactions and anisotropic porous material on the convective instability, heat and mass transfer rate of water-based carbon nanotube suspension. Flow governing dynamics are modeled using the modified Brinkman–Buongiorno model. The effects of pertinent flow characterizing parameters such as chemical reaction parameter, porosity parameter, mechanical anisotropy parameter and thermal anisotropy parameter on the threshold of convection, heat and mass transport rate are discussed and compared for three types of enclosures: shallow, square and tall. The study concludes that nanoliquid suspended with single-walled carbon nanotubes has higher heat and mass transfer capability than the multi-walled carbon nanotubes when saturated in a tall porous enclosure and also tall enclosure allows the convection to set in earlier. Anisotropic effect and destructive chemical reaction delay the starting of convection. Further, it is observed that the heat transfer rate decreases with the chemical reaction parameter.

The linear and non-linear study of effect of rotation and internal heat source/sink on Bénard convection

The primary objective of this study is to investigate non-linear Bénard convection in a single-walled carbon nanotube suspension saturated in a rotating porous medium with an internal heat sink/source. The modified Buongiorno model is utilized to formulate the governing equations for the flow. Both linear and weak non-linear stability analyses are conducted in this investigation. The linear stability analysis employs the truncated Fourier series transformation, while the weakly non-linear stability analysis utilizes the Lorenz model, assuming weak thermophoresis, porous friction, and small-scale convective motion. The cubic Ginzburg–Landau equation is formulated and subsequently solved to derive the expression for the amplitude. The influence of various parameters, such as the Taylor number, heat sink/source parameter, and viscosity parameter, is discussed in relation to the threshold criteria of convection, as well as heat and mass transport rates. Based on the linear stability analysis, it is determined that the introduction of a rotating frame of reference delays the initiation of convection, whereas the energy supplied to the system accelerates the onset of convection. The heat transfer rate increases by when the nanofluidic system is placed in the rotating frame of reference under the presence of an internal heat source.

Cation Adsorption in TiO2 Nanotubes: Implication for Water Decontamination.

TiO2 nanotubes constitute very promising nanomaterials for water decontamination by the removal of cations. We combined a range of experimental techniques from structural analyses to measurements of the properties of aqueous suspensions of nanotubes, with (i) continuous solvent modeling and (ii) quantum DFT-based simulations to assess the adsorption of Cs+ on TiO2 nanotubes and to predict the separation of metal ions. The methodology is set to be operable under realistic conditions, which, in this case, include the presence of CO2 that needs to be treated as a substantial contaminant, both in experiments and in models. The mesoscopic model, based on the Poisson-Boltzmann equation and surface adsorption equilibrium, predicts that H+ ions are the charge-determining species, while Cs+ ions are in the diffuse layer of the outer surface with a significant contribution only at high concentrations and high pH. The effect of the size of nanotubes in terms of the polydispersity and the distribution of the inner and outer radii is shown to be a third-order effect that is very small when the nanotube layer is not very thick (ranging from 1 to 2 nm). Besides, DFT-based molecular dynamics simulations demonstrate that, for protonation, the one-site and successive association assumption is correct, while, for Cs+ adsorption, the size of the cation is important and the adsorption sites should be carefully defined.

Influence of Single-Wall Carbon Nanotube Suspension on the Mechanical Properties of Polymeric Films and Electrospun Scaffolds.

Carbon nanotubes (CNTs) are used in applications ranging from electrical engineering to medical device manufacturing. It is well known that the addition of nanotubes can influence the mechanical properties of various industrial materials, including plastics. Electrospinning is a popular method for fabricating nanomaterials, widely suggested for polymer scaffold manufacturing. In this study, we aimed to describe the influence of single-walled carbon nanotube (SWCNT) suspensions on polymeric poured films and electrospun scaffolds and to investigate their structural and mechanical properties obtained from various compositions. To obtain films and electrospun scaffolds of 8 mm diameter, we used poly-ε-caprolactone (PCL) and poly(cyclohexene carbonate) (PCHC) solutions containing several mass fractions of SWCNT. The samples were characterized using tensile tests, atomic force and scanning electronic microscopy (AFM and SEM). All the studied SWCNT concentrations were shown to decrease the extensibility and strength of electrospun scaffolds, so SWCNT use was considered unsuitable for this technique. The 0.01% mass fraction of SWCNT in PCL films increased the polymer strength, while fractions of 0.03% and more significantly decreased the polymer strength and extensibility compared to the undoped polymer. The PHCH polymeric films showed a similar behavior with an extremum at 0.02% concentration for strength at break.

Influence of carbon nanotube suspensions on the structural, optical, and electrical properties of grown ZnO nanorods

Influence of carbon nanotube suspensions on the structural, optical, and electrical properties of grown ZnO nanorods