Surficial Soil Research Articles

Fine-scale surficial soil moisture mapping using UAS-based L-band remote sensing in a mixed oak-grassland landscape

Soil moisture maps provide quantitative information that, along with climate and energy balance, is critical to integrate with hydrologic processes for characterizing landscape conditions. However, soil moisture maps are difficult to produce for natural landscapes because of vegetation cover and complex topography. Satellite-based L-band microwave sensors are commonly used to develop spatial soil moisture data products, but most existing L-band satellites provide only coarse scale (one to tens of kilometers grid size), information that is unsuitable for measuring soil moisture variation at hillslope or watershed-scales. L-band sensors are typically deployed on satellite platforms and aircraft but have been too large to deploy on small uncrewed aircraft systems (UAS). There is a need for greater spatial resolution and development of effective measures of soil moisture across a variety of natural vegetation types. To address these challenges, a novel UAS-based L-band radiometer system was evaluated that has recently been tested in agricultural settings. In this study, L-band UAS was used to map soil moisture at 3–50-m (m) resolution in a 13 square kilometer (km2) mixed grassland-forested landscape in Sonoma County, California. The results represent the first application of this technology in a natural landscape with complex topography and vegetation. The L-band inversion of the radiative transfer model produced soil moisture maps with an average unbiased root mean squared error (ubRMSE) of 0.07 m3/m3 and a bias of 0.02 m3/m3. Improved fine-scale soil moisture maps developed using UAS-based systems may be used to help inform wildfire risk, improve hydrologic models, streamflow forecasting, and early detection of landslides.

Kinetic Analysis of Rainfall-Induced Landslides in May 2022 in Wuping, Fujian, SE China

In the context of global climate change, shallow landslides induced by strong typhoons and the ensuing rainstorms have increased significantly in China’s eastern coastal areas. On 27 May 2022, more than 700 liquefied landslides were induced by the rain gush in Wuping County, Longyan City, Fujian Province, SE China. In light of their widespread occurrence and the severe damage caused, detailed field investigations, UAV surveys, trench observations, in situ tests, and numerical simulation are conducted in this work. The cascading landslides are classified as channelized landslides and hillslope landslides. Long-term rainfall, the influence of vegetation roots under wind load, and differences in the strength and structure of surficial soil are the dominant controlling factors. The sliding surface is localized to be the interface at a depth of 1–1.5 m between the fully weathered granite and the strongly weathered granite. Kinetic analysis of a channelized landslide shows that it is characterized by short runout, rapid velocity, and strong impact energy. The maximum velocity, impact energy, and impact force of the Laifu landslide are 29 m/s, 4221.35 J, and 2110 kPa. Effective excavation is usually impossible in this context. This work highlights the escalating issue of shallow landslides in eastern China’s coastal areas, exacerbated by climate change and extreme weather events like typhoons. By conducting comprehensive investigations and analyses, the research identifies key factors influencing landslide occurrence, such as rainfall patterns and soil characteristics. Understanding the dynamics and impact of these landslides is vital for improving risk assessment, developing effective early warning systems, and informing land management policies in this region. Further exploration concerning hydro-meteorological hazard early warning should be encouraged in this region.

Multi-omics inhalation toxicity assessment of urban soil dusts contaminated by multiple legacy sources of lead (Pb)

Although animal studies have evaluated lead (Pb) toxicity, they are limited to soluble forms, such as Pb-acetate, which do not reflect the range found in the exposome. Recent studies on Pb speciation of residential soils in urban areas revealed that the initial Pb sources are not persistent and are extensively repartitioned into adsorbed forms of Pb rather than insoluble phosphates. We investigated the inhalation and neurological toxicity of dusts generated from a surficial soil sample collected from a residential site with an exposomic mixture of various Pb species, both adsorbed phases (Fe and Mn oxide, humate bound Pb) and mineral phases (Pb hydroxycarbonate, pyromorphite, galena). Mice inhaled East Chicago dust (ECD) generated from a composite soil sample for 4 h/day, 7 days/week, for 4 weeks. Mice were necropsied immediately, 1, 14 and 30 days post exposure to evaluate both toxicity and recovery. Exposure to ECD caused changes in memory and spatial learning in the Morris Water Maze test. RNAseq analysis of the hippocampus region revealed multiple differentially expressed genes and impacts on pathways involved in ion channel complexes, and neuron-to-neuron synapse. Metabolomics analysis of plasma highlighted significant alterations in metabolic processes immediately after exposure that resolved after 14 days of rest.

Predicting unsaturated soil strength of coarse-grained soils for mobility assessments

Accurately estimating surficial soil moisture and strength is integral to determining vehicle mobility and is especially important over large spatial extents at fine resolutions. While methods exist to estimate soil strength across landscapes, they are empirical and rely on class average soil behavior. The Strength of Surficial Soils (STRESS) model was developed to estimate moisture-variable soil strength with a physics-based approach. However, there is a lack of field data from a diverse landscape to evaluate the STRESS model. To test the STRESS model, a field study was conducted in northern Colorado. Soil moisture and strength were measured on 10 dates. Data from the surficial layer (0–5 cm) were used to test the STRESS model and determine if soil strength trends could be estimated from topographical and soil textural differences. High variability was observed in soil strength measurements stemming from fine-scale terrain features and user variability. Observations show lower soil strengths for greater soil moistures, steeper slopes, higher vegetation, and lower soil fines content. STRESS estimated rating cone index values with a mean relative error of 37.5 %, while a pre-existing model had a mean relative error of 47.4 %. The STRESS model outperforms the current RCI prediction method, but uncertainty remains large.

Raman spectroscopic quantification of graphene oxide in soil: Transport, surficial enrichment and environmental effects

The transport and retention data in environmental media are indispensable for the hazard evaluations of graphene materials. Due to the complexity of soil, the transport of graphene is hard to quantify without isotope labeling. Herein, we developed 2D Raman mapping as a label-free technique to quantify graphene oxide (GO) in soil. After pre-treatment by hydrazine hydrate to quench its fluorescence, the quantification of GO in soil was achieved in the range of 0.1–1000 mg/L by measuring the average G-band intensity. In column transport experiment, the transport and retention of GO in soil depended on the solution chemistry. Lower pH and higher ionic strength hindered the transport of GO. In particular, Ca2+ showed the most obvious retardation on the transport of GO. GO enriched in the surficial soil layer by several folds of the initial concentrations, and higher GO concentration led to more surficial enrichment. The sowing manner of seeds affected the soil enrichment of GO, too. The surficial enrichment of GO reduced its direct contact with seedling roots, resulting in the alleviation of GO toxicity. Our results provided a facile method to study the environmental behaviors of graphene and highlighted the crucial impacts of environmental media on the graphene toxicity.

HOTSED: A new integrated model for assessing potential hotspots of sediment sources and related sediment dynamics at watershed scale

In this paper we introduce HOTSED, a novel, innovative GIS-based model designed for assessing potential hotspots of sediment dynamics at watershed scale. HOTSED integrates geomorphic spatial information with both structural and functional properties of connectivity. HOTSED provides a single and intuitive output that depicts the location of sediment source hotspots. Moreover, it enables the identification of “relative hazard” classes for sediment production and related effects. The general methodological framework is based on the initial elaboration of an Inventory Map (IM) of sediment-related landforms and processes, along with the implementation of a corresponding database. Subsequently, we used data stored in the IM to estimate the geomorphic Potential of Sediment Sources (PSS) through a relative scoring system. Furthermore, we computed Structural Sediment Connectivity (STC) and the Potential for Sediment Transport (PST) by combining terrain and hydrological parameters, vegetation roughness, and rainfall erosivity. Afterwards, PSS, STC, and PST components are integrated through a raster-based calculation method yielding the HOTSED model. We tested the HOTSED procedure in the upper Val d’Arda-Mignano watershed, which is a representative geomorphologically highly active Mediterranean area of the Northern Apennines (Italy). Through photointerpretation, terrain analysis, and fieldwork, we mapped sediment-related geomorphic features for a total of 4640 ha including: badlands and gullies (0.26%), rill-interrill erosion (15.03%), fluvial erosion (0.03%), landslides (70.06%), litho-structural erosional systems (0.87%), slope deposits (12.56%), and alluvial deposits (1.19%). HOTSED revealed hotspots with a very high hazard potential located near main channels or upstream of the reservoir. These areas are often linked with active landslides highly connected to the drainage system and frequently associated with other processes like bank erosion or surficial soil erosion. The model also highlighted linear hotspots corresponding to drainages flowing alongside or intersecting complex geomorphic systems such as landslides. Furthermore, HOTSED identified areas where sediments are stored in depositional landforms, exhibiting a low hazard potential, considering both low geomorphic potential and sediment connectivity. Our conceptual model is generally applicable but proves to be particularly effective in areas characterized by complex and polygenetic geomorphic systems, such as the Northern Apennines. HOTSED offers a valuable tool for watershed authorities to support sustainable watershed and reservoir management.

The Effect of Deposited Particulate Matter on the Mobility of Contaminants in the Surficial Soils of Flin Flon, Manitoba, Canada

The Effect of Deposited Particulate Matter on the Mobility of Contaminants in the Surficial Soils of Flin Flon, Manitoba, Canada

Differential effects on soil water repellency of Eucalyptus and Pinus plantations replacing natural pastures

ABSTRACT Land-use changes from native pastures to forest plantations in humid temperate areas have raised concerns about their potential impact on the environment. This study aimed to assess the effects of such changes on soil water properties, focusing on the impact of the forest species planted and their relationship with changes in soil C content. Specifically, we aimed to identify the development of surficial soil hydrophobicity and changes in soil water holding capacity. A long-term forest experiment with variable planting densities (816, 1111, and 2066 trees ha -1 ) of Eucalyptus grandis Hill ex Maiden and Pinus taeda L. was established in 2004 on native pasture vegetation. Undisturbed soil samples (0.00-0.03 m soil layer) were extracted from the experiment and surrounding pastures and soil water repellency was determined by the water drop penetration time (WDPT) method at three soil matric potential levels (SMP). Bootstrapping was used to test if the sample size was sufficient to obtain robust results. Replacing native pastures with forest plantations significantly increased surficial soil hydrophobicity, which was more pronounced under Eucalyptus grandis than under Pinus taeda. Soil water repellency increased with decreasing SMP, particularly in land-uses that generated higher initial hydrophobicity. Additionally, the soils under forest cover had less water retention capacity than those under pastures at each SMP, with larger differences when the soil was dried to more negative SMP. More research is necessary to determine if soil alterations from converting native pastures to forest plantations in temperate climates will lead to a significant decrease in soil water holding capacity and an increase in hydrophobicity at deeper depths.

Exploring landscape and geologic controls on spatial patterning of streambank groundwater discharge in a mixed land use watershed

AbstractPreferential groundwater discharge features along stream corridors are ecologically important at local and stream network scales, yet we lack quantification of the multiscale controls on the spatial patterning of groundwater discharge. Here we identify physical attributes that best explain variation in the presence and lateral extent of preferential groundwater discharges along two 5th order streams, the Housatonic and Farmington Rivers, and 32 1st to 4th order reaches across the Farmington River network. We mapped locations of preferential groundwater discharge exposed along streambanks using handheld thermal infrared cameras paired with high‐resolution topographic and land use land cover datasets, surficial soil characteristic maps, and depth‐to‐bedrock geophysical measurements. The unconfined Housatonic River, MA, USA (12 km) had fewer discharge locations and less lateral extent (41 discharge locations with 38 m of active discharge/km of river) compared to the partially confined Farmington River, CT, USA (26 km; 169 discharge locations with 129 m of active discharge/km of river). Using a moving window analysis, we found along both rivers that discharge was more likely to occur where bank slopes were steeper, floodplain extent was narrower, and degree of confinement was higher. Along the Farmington River, groundwater discharge was more likely to occur where saturated hydraulic conductivity was higher and depth‐to‐bedrock was shallower. Among the 32 stream reaches surveyed (33.2 km of total stream length) within the Farmington River watershed, preferential discharge was observed in all but two stream reaches, varied from 0 to 25% of lateral extent along stream banks (mean = 6%), and was more likely to occur where stream reach slopes were steep, saturated hydraulic conductivity was high, and watershed urbanization was low. Our results show that, though both surface (e.g., topographic, land use land cover) and subsurface (e.g., soil characteristics, bedrock depth) factors control the prevalence of streambank preferential groundwater discharge, the dominant controls vary across valley settings and stream sizes.

Heavy metals concentration in soils across the conterminous USA: Spatial prediction, model uncertainty, and influencing factors

Assessment and proper management of sites contaminated with heavy metals require precise information on the spatial distribution of these metals. This study aimed to predict and map the distribution of Cd, Cu, Ni, Pb, and Zn across the conterminous USA using point observations, environmental variables, and Histogram-based Gradient Boosting (HGB) modeling. Over 9180 surficial soil observations from the Soil Geochemistry Spatial Database (SGSD) (n = 1150), the Geochemical and Mineralogical Survey of Soils (GMSS) (n = 4857), and the Holmgren Dataset (HD) (n = 3400), and 28 covariates (100 m × 100 m grid) representing climate, topography, vegetation, soils, and anthropic activity were compiled. Model performance was evaluated on 20 % of the data not used in calibration using the coefficient of determination (R2), concordance correlation coefficient (ρc), and root mean square error (RMSE) indices. Uncertainty of predictions was calculated as the difference between the estimated 95 and 5 % quantiles provided by HGB. The model explained up to 50 % of the variance in the data with RMSE ranging between 0.16 (mg kg−1) for Cu and 23.4 (mg kg−1) for Zn, respectively. Likewise, ρc ranged between 0.55 (Cu) and 0.68 (Zn), respectively, and Zn had the highest R2 (0.50) among all predictions. We observed high Pb concentrations near urban areas. Peak concentrations of all studied metals were found in the Lower Mississippi River Valley. Cu, Ni, and Zn concentrations were higher on the West Coast; Cd concentrations were higher in the central USA. Clay, pH, potential evapotranspiration, temperature, and precipitation were among the model's top five important covariates for spatial predictions of heavy metals. The combined use of point observations and environmental covariates coupled with machine learning provided a reliable prediction of heavy metals distribution in the soils of the conterminous USA. The updated maps could support environmental assessments, monitoring, and decision-making with this methodology applicable to other soil databases, worldwide.

Visible and near-infrared spectral results of Chang’E-5 surficial and subsurface soils

Aims. Studies on high-resolution and high-precision laboratory reflectance spectra of the Moon have historically been restricted to the analysis of old Apollo samples (>3.0 Ga). In contrast, studies of young lunar soils have exclusively relied on the analysis of remote sensing spectra. In this study, we present the results of a laboratory spectral investigation of young lunar soils (~2.0 Ga) obtained by the Chang’E-5 (CE-5) mission. Methods. We analyzed surficial and subsurface soils collected through scooped and drilled sampling methods. The laboratory reflectance spectra of the CE-5 soils were compared with those of Apollo soils and orbital spectra. Two methods were employed for maturity inversion. The relationship between the UV-vis color and TiO2 content of young basalts was also investigated. Results. The CE-5 samples exhibit much fresher spectral features, including higher reflectance, deeper absorption depths, and a smaller visible and near-infrared continuum slope (VNCS), compared to pristine regolith. The subsurface soils sampled from a depth of approximately 10 cm exhibit a slightly fresher spectral feature compared to the surficial soils. Our comparison revealed a rapid rate of space weathering at the lunar surface compared to the vertical overturn. Compared to older iron-rich soils, the CE-5 soils have a larger reflectance but similar UV-vis ratios. The UV-vis ratio alone could not accurately predict the TiO2 content of all mare basalts. The CE-5 samples provide a new ground truth for estimating the TiO2 content of young lunar basalts, which have the largest uncertainty in TiO2 content, as estimated from spectral parameters. We find that the samples returned by the CE-5 mission represent disturbed soils and that they exhibit significantly fresher characteristics compared to pristine regolith, a fact that should be kept in mind when using samples as ground truth for remote sensing research.

The use of a geogrid – geotextile geo-composite to improve soft soils for construction works at a facility expansion site in Western Canada

Soft soils pose several challenges for construction works – from site accessibility and trafficability challenges, to earthworks, foundation design and other related challenges. This paper presents the use of a geocomposite reinforcement material to improve site accessibility and trafficability for a facility expansion project at a manufacturing and processing site in Western Canada. The soil stratigraphy at the site consisted of approximately 0.1 m to 0.8 m layer of organic topsoil (peat moss), underlain by soft lacustrine clay that extended up to depths of 11.5 m to 14.6 m below the ground surface. The soft surficial soils at the site made it challenging, or impossible in some areas, for the field investigation and construction equipment and crew to access the proposed construction areas. There was a high risk of equipment getting stuck or falling over in various areas, which had reportedly occurred during previous works on the site. To create a suitable working and trafficable surface for the required construction works, the geo-composite reinforcement material was placed directly on top of the stripped subgrade, followed by a 300 mm layer of compacted well-graded pit run. The use of the geo-composite reinforcement material helped to create the required stable working surface for equipment and crew to complete the construction of the facility expansion.

Metal toxin threat in wildland fires determined by geology and fire severity

Accentuated by climate change, catastrophic wildfires are a growing, distributed global public health risk from inhalation of smoke and dust. Underrecognized, however, are the health threats arising from fire-altered toxic metals natural to soils and plants. Here, we demonstrate that high temperatures during California wildfires catalyzed widespread transformation of chromium to its carcinogenic form in soil and ash, as hexavalent chromium, particularly in areas with metal-rich geologies (e.g., serpentinite). In wildfire ash, we observed dangerous levels (327-13,100 µg kg−1) of reactive hexavalent chromium in wind-dispersible particulates. Relatively dry post-fire weather contributed to the persistence of elevated hexavalent chromium in surficial soil layers for up to ten months post-fire. The geographic distribution of metal-rich soils and fire incidents illustrate the broad global threat of wildfire smoke- and dust-born metals to populations. Our findings provide new insights into why wildfire smoke exposure appears to be more hazardous to humans than pollution from other sources.

Geophysical research on the interplays between soil–rock variability and hydrogeological structures: a case study

Understanding the spatial variations in soil–rock profiles is crucial for identifying weathered rock layers and mapping geological structures, particularly in the complex feldspar-rich granitic terrain of Penang Island, Malaysia. This study employs a combination of electrical resistivity and seismic refraction tomographic techniques, along with borehole lithological data, in three distinct areas on the island. Its goal is to provide insights into surficial and subsurface soil–rock characteristics and water-bearing structures within the North Penang Pluton (including a part of the Sungai Ara axis) for sustainable groundwater development, addressing the needs of the region's growing population. The research identifies three distinct geological units at the near-surface: residual soils, highly to moderately weathered/fractured granitic layers and fresh bedrock, each with its hydrogeological properties. Promisingly, the weathered layers offer significant groundwater development potential, with deep weathered and potentially fractured zones exceeding depths of 30 m in the study area. These findings have substantial implications for sustainable groundwater development, especially in tropical hard-rock terrains. In addition, the study underscores the limitations of small geophysical spacings when probing deeper groundwater resources. This knowledge is essential for informed decision-making in water resource management and infrastructure development, addressing the ongoing global challenge of ensuring access to clean water resources amid population growth.

Effects of dissolved organic carbon on potentially toxic element desorption in stormwater bioretention systems

Stormwater runoff contains dissolved organic carbon (DOC) and potentially toxic elements (PTEs). Interactions between DOC and PTEs can impact PTE speciation and mobility, but are not fully understood. Soil samples were collected from a vegetated bioretention bed to investigate the effects of DOC (0, 15, and 50 mg-C/L) on the desorption of 10 PTEs captured by the soil media: Mn, Fe, Co, Cu, Zn, As, Cd, Sn, Sb, and Pb. In the absence of DOC, the desorbed PTE concentration from bioretention media into the aqueous phase ranking was as follows: Fe > Mn ∼ Zn > Cu > Pb > Sb > As > Co > Sn ∼ Cd. Increased DOC concentrations resulted in a reduction of the soil-water distribution coefficient (Kd) values. The greatest shift in Kd was observed for Cu and lowest for Sb. The PTE sorption capacities were lower for surficial soil samples (lower Kd) compared to the deep soil samples. Overall, the desorbed PTE (average midchannel 55.7 μg/g) fraction accounted for <1.1 % of the total extracted PTEs (5364 μg/g), and while this is a small percentage of the total, this is the fraction that is mobile. The extracted PTE fractions revealed that DOC reduced the organic matter-bound and carbonate-bound fractions. The PTE desorption trends suggest that reducing DOC in stormwater runoff could be an effective measure to mitigate the release of PTEs into the environment.

AN INTEGRATED GEOTECHNICAL INVESTIGATION FOR STRUCTURAL FOUNDATION SUITABILITY ACROSS NIGER RIVER, NORTH CENTRAL NIGERIA

- The need to assess the suitability of foundation soil for oil and gas installations, such as pipeline, stations, and all other ancillary facilities, necessitated this study across the Niger River of north central Nigeria. A total of 17 boreholes and cone penetration tests were conducted. Samples were recovered from the boreholes and tested in the laboratory to obtain soil parameters. The investigation revealed that the subsurface is essentially composed of FINE SAND/SAND and CLAY. The FINE SAND is largely the superficial soil except in BH1 where CLAY is the superficial soil. The FINE SAND is loose at the top becoming medium dense and clayey at the base as it grades into CLAY. It has a greyish colour, with moisture content between 6% and 29% and bulk unit weight between 15.17 kN/m3 and 21.76 kN/m3 . The CLAY underlies the FINE/SAND and SAND. It is generally greyish in colour, with moisture content between 12% and 29% and bulk unit weight between 15.17 kN/m3 and 21.30 kN/m3 and an average strength of 156 kN/m2 except where it is the surficial soil and soft (strength &lt; 25 kN/m2 ). Oversize materials were not encountered during the investigation and as such shall not pose any risk to horizontal directional drilling operation. However, on the Island, within the FINE SAND, bed of gravel occurs in BH8 and BH9. In terms of plasticity, due to saturation, the soils are not expected to swell. Nevertheless, it is advisable to add polymers to the drilling mud to prevent transfer of water from the drilling fluid into the soil as a precaution for clayey soils at the entry and exit points and on the Island. Most of the soil contains fines less than 30% and therefore, specific measures may be employed to improve borehole stability during drilling and installation.

Role of hydrophobic sand particle granularity on water droplet post-impact dynamics

This paper investigates, experimentally and theoretically, the effects of sand particle size and hydrophobicity of a water drop impacting horizontal and inclined surfaces within a context of post-wildfire mudflow precursors. Although previous research established that wildfires often turn hillslope surficial soil hydrophobic, little research shows how wildfire-altered soil surfaces affect raindrops' impact behavior. Specific findings point to a significant effect of sand type on the drop impact dynamics. After spreading, the drop gathers back more on finer than coarser hydrophobic sands due to the substrate air-entrapped grooves, as in the Cassie-Baxter model, leading to drop retraction, rebound, splash, and fragmentation into droplets. The results indicate that if the hillslope dominant median grain size is fine, alteration to hydrophobicity would multifold enhance drop downhill mobility. In contrast, coarse sand surfaces exhibit minimal effects on drop mobility after hydrophobization. In addition, the paper proposes a modified Tang et al. model for the maximum spread factor as a function of the median grain size and hydrophobicity. This research offers essential findings from the perspective of the previous limiting understanding that only drop infiltration prevents erosion in hydrophilic slopes.

How geoecological components of a terroir can be altered by spatial changes of vineyards – A case study from Eger Wine District (Hungary)

Terroir is a concept referring interactions of natural (topography, lithology, climate, soil etc.) and human (economic conditions, traditions, cultivation practices, etc.) factors; therefore, terroir is spatially delimited and subjected to environmental, socio-economic, and temporal changes. The geoecological background of wine districts are considered more stable among them, but, because of its natural diversity and the spatial changes of production sites, changes in abiotic terroir components might occur too. In this study the spatial changes of grape production sites in Eger Wine District (Hungary) across two and a half centuries (1784 to 2018), and their consequences on the composition of the geoecological factors (lithology, topography, soil characteristics) were analyzed. Modernization of cultivation, urbanization and increase of built-up areas around the central settlement resulted in decreased concentration, i.e. increased spatial dispersion to more remote vineyards further from Eger. It also has consequences on the lithological and topographical composition of the production sites. Besides the slightly increasing extent of vineyards (from 5346 ha to 7413 ha) we found a distinct decrease of vineyards at higher elevations and a substantial increase at lower elevations. Distribution according to slope gradient changed also remarkably, with the share of vineyards on &lt;5 % slopes from 38 % to 65 %. These changes resulted in transformations of pedological characteristics according to the comparison of vineyard’s extent with soil map data: vineyards shifted to slightly acidic, more fertile (i.e. deeper soil layer with higher organic carbon content) soils. The share of vineyards with different lithology and parent material also changed: loose, calcareous Tertiary sediments decreased almost to half, and the share of vineyards over acidic volcanics and their weathered regoliths almost doubled. Comparing these two dominant lithological types and soil profiles derived from them, different pedological characters and taxonomic status were found (Phaeozems and Vertisols). However, comparison of these two lithological types based on main topsoil characteristics (pH, SOC, carbonates, depth of fertile soil layer, N, P, K content) according to 25 randomly chosen surficial soil samples at production sites, showed no significant differences.. In the case of this particular wine district, spatial changes of the production sites affected mostly the distribution by elevation, by slope gradient, but did not alter significantly the surface soil character of the terroir.

Assessing mercury pollution at a primary ore site with both ancient and industrial mining and smelting activities

The Minamata Convention on Mercury has mandated a renewed global effort to tackle Hg pollution. The present study evaluates Hg pollution at a primary Hg production site exploited since the Qin Dynasty (200s BC), with intensive industrial scale production over the past four decades. This single location accounts for over 95% total Hg production in China in recent years. To assess the environmental risk and effectiveness of recently implemented control measures, we collected 90 soil samples, 60 plant tissue samples, 47 sediment samples, and 47 river water samples from the site and its vicinity. A site-specific conceptual site model was established based on the sources, migration transformation pathways of Hg pollutant and its exposure scenarios. The maximum soil Hg concentration reached 10,451 mg kg−1, posing a high health and ecological risk. Vegetable and crop Hg concentrations outside the site reached 0.23 mg kg−1 in rice grains and 4.24 mg kg−1 in green onion. The highest health risk, with a hazard quotient of 130.66, was observed in the Ore Storage Site, which reduced to 17.14 when Hg bioavailability was considered. Risk control measures implemented in recent years included a stormwater collection system and capping of the tailing pond area with clean imported soil. These measures were generally successful; however, Hg in the tailings were found to be contaminating the imported surficial soil due to rainfall saturation and upward migration, suggesting a need for long-term post remedial site monitoring and maintenance. We also found that mining and smelting activities have contaminated a 6 km stretch of a nearby river, with sediment Hg concentrations reaching 2819 mg kg−1, and water column concentrations reaching 193.21 ng L−1. The sediment and water concentrations are highly correlated (R2 = 0.78), suggesting that, with risk control measures in place, a reservoir of Hg in polluted river sediment is now driving pollution in the water column. This work demonstrates that primary Hg mining has caused widespread and serious soil and water pollution. Risk control measures can reduce human health and ecological risks, but robust monitoring and maintenance are required for remediation to be effective in the long-term.

Urban stream restorations increase floodplain soil carbon and nutrient retention along a chronosequence

Stream restoration is a common management practice to meet regulatory or voluntary efforts to improve water quality via nutrient and carbon (C) retention, including in the Chesapeake Bay watershed. However, most restoration projects have few quantifiable measures of project success, no standard metrics, and rarely collect pre-restoration data. Storage of nutrients, such as phosphorus (P) and nitrogen (N), in floodplain soils of restored streams can act as an easily quantifiable indicator of restoration success, particularly when the project goals include improved water quality. To determine how floodplains of restored streams change in their P and C storage as time since restoration increases, floodplain surficial soil samples (10 cm depth) were collected from 18 streams in the urbanized Piedmont region of northern Virginia, representing a chronosequence of time (1–10+ yrs.) since restoration as well as unrestored streams with high impervious surface cover (ISC) and unrestored streams with low ISC. The samples were analyzed for total carbon (TC), total nitrogen (TN) and total phosphorus (TP) storage, whereas C turnover rate and equilibrium phosphorus concentration (EPC0) were measured as metrics of C and P loss. These metrics were compared to time since restoration and potential environmental drivers, including soil moisture, pH, median particle size (D50), organic matter content (OM), and bioavailable P, iron (Fe), and aluminum (Al). These stream restorations demonstrated increasing nutrient storage for TC, TN, and TP along the chronosequence to values greater than both unrestored or reference streams, as well as decreasing C turnover and no significant changes in EPC0. Soil wetness and OM, key drivers in nutrient retention, also increased as restoration projects aged increasing C, N, and P storage. Overall, stream restoration did improve soil C, N, and P retention in floodplains as compared to unrestored sites and exceeded those of low ISC ‘reference’ sites.