Surfactant Sodium Dodecylbenzenesulfonate Research Articles

Stretchable and Flexible Painted Thermoelectric Generators on Japanese Paper Using Inks Dispersed with P- and N-Type Single-Walled Carbon Nanotubes.

As power sources for Internet-of-Things sensors, thermoelectric generators must exhibit compactness, flexibility, and low manufacturing costs. Stretchable and flexible painted thermoelectric generators were fabricated on Japanese paper using inks with dispersed p- and n-type single-walled carbon nanotubes (SWCNTs). The p- and n-type SWCNT inks were dispersed using the anionic surfactant of sodium dodecylbenzene sulfonate and the cationic surfactant of dimethyldioctadecylammonium chloride, respectively. The bundle diameters of the p- and n-type SWCNT layers painted on Japanese paper differed significantly; however, the crystallinities of both types of layers were almost the same. The thermoelectric properties of both types of layers exhibited mostly the same values at 30 °C; however, the properties, particularly the electrical conductivity, of the n-type layer increased linearly, and of the p-type layer decreased as the temperature increased. The p- and n-type SWCNT inks were used to paint striped patterns on Japanese paper. By folding at the boundaries of the patterns, painted generators can shrink and expand, even on curved surfaces. The painted generator (length: 145 mm, height: 13 mm) exhibited an output voltage of 10.4 mV and a maximum power of 0.21 μW with a temperature difference of 64 K at 120 °C on the hot side.

An Artificial Liquid–Liquid Phase Separation-Driven Silk Fibroin-Based Adhesive for Rapid Hemostasis and Wound Sealing

The powerful adhesion systems of marine organisms have inspired the development of artificial protein-based bioadhesives. However, achieving robust wet adhesion using artificial bioadhesives remains technically challenging because the key element of liquid–liquid phase separation (LLPS)-driven complex coacervation in natural adhesion systems is often ignored. In this study, mimicking the complex coacervation phenomenon of marine organisms, an artificial protein-based adhesive hydrogel (SFG hydrogel) was developed by adopting the LLPS-mediated coacervation of the natural protein silk fibroin (SF) and the anionic surfactant sodium dodecylbenzene sulfonate (SDBS). The assembled SF/SDBS complex coacervate enabled precise spatial positioning and easy self-adjustable deposition on irregular substrate surfaces, allowing for tight contact. Spontaneous liquid-to-solid maturation promoted the phase transition of the SF/SDBS complex coacervate to form the SFG hydrogel in situ, enhancing its bulk cohesiveness and interfacial adhesion. The formed SFG hydrogel exhibited intrinsic advantages as a new type of artificial protein-based adhesive, including good biocompatibility, robust wet adhesion, rapid blood-clotting capacity, and easy operation. In vitro and in vivo experiments demonstrated that the SFG hydrogel not only achieved instant and effective hemostatic sealing of tissue injuries but also promoted wound healing and tissue regeneration, thus advancing its clinical applications. Statement of significanceMarine mussels utilize the liquid–liquid phase separation (LLPS) strategy to induce the supramolecular assembly of mussel foot proteins, which plays a critical role in strong underwater adhesion of mussel foot proteins. Herein, an artificial protein-based adhesive hydrogel (named SFG hydrogel) was reported by adopting the LLPS-mediated coacervation of natural protein silk fibroin (SF) and anionic surfactant sodium dodecylbenzene sulfonate (SDBS). The assembled SFG hydrogel enabled the precise spatial positioning and easy self-adjustable deposition on substrate surfaces with irregularities, allowing tight interfacial adhesion and cohesiveness. The SFG hydrogel not only achieved instant and effective hemostatic sealing of tissue injuries but also promoted wound healing and tissue regeneration, exhibiting intrinsic advantages as a new type of artificial protein-based bioadhesives.

Sol–gel-stabilized CO2 foam for enhanced in-situ carbonation in foamed fly ash backfill materials

AbstractA novel highly stable aqueous foam was synthesized using CO2, sodium silicate (SS) and anionic surfactant of sodium dodecylbenzene sulfonate. The influence of CO2 foam on the mechanical properties and its underlying mechanisms of foamed backfill material was investigated. The experimental results revealed that the addition of CO2 and SS effectively reduced the drainage of the foam while strengthening the liquid film of the Plateau borders, which stabilizes the foam. The excellent stability is attributable to the gel network developed after SS exposed to CO2, that adhere to the foam surface. Furthermore, due to the interaction between encapsulated CO2 and hydration products, micro CaCO3 formed and filled the pore wall; thus, precast foam forms robust pore structures in the hardened foamed backfill.

Comparative Analysis of Hydrogel Adsorption/Desorption with and without Surfactants.

In this particular study, a hydrogel known as SAP-1 was synthesized through the grafting of acrylic acid-co-acrylamide onto pullulan, resulting in the creation of Pul-g-Poly (acrylic acid-co-acrylamide). Additionally, a sponge hydrogel named SAP-2 was prepared by incorporating the surfactant sodium dodecyl benzene sulfonate (SDBS) into the hydrogel through free radical solution polymerization. To gain further insight into the composition and properties of the hydrogels, various techniques, such as Fourier transform infrared spectroscopy, hydrogen nuclear magnetic resonance (1H NMR), atomic absorption spectroscopy, and field emission scanning electron microscopy (FE-SEM), were employed. Conversely, the absorption kinetics and the equilibrium capacities of the prepared hydrogels were investigated and analyzed. The outcomes of the investigation indicated that each of the synthesized hydrogels exhibited considerable efficacy as adsorbents for cadmium (II), copper (II), and nickel (II) ions. In particular, SAP-2 gel displayed a remarkable cadmium (II) ion absorption ability, with a rate of 190.72 mg/g. Following closely, SAP-1 gel demonstrated the ability to absorb cadmium (II) ions at a rate of 146.9 mg/g and copper (II) ions at a rate of 154 mg/g. Notably, SAP-2 hydrogel demonstrated the ability to repeat the adsorption-desorption cycles three times for cadmium (II) ions, resulting in absorption capacities of 190.72 mg/g, 100.43 mg/g, and 19.64 mg/g for the first, second, and third cycles, respectively. Thus, based on the abovementioned results, it can be concluded that all the synthesized hydrogels possess promising potential as suitable candidates for the adsorption and desorption of cadmium (II), copper (II), and nickel (II) ions.

Theoretical study on the influence of three different surfactants on the binding of laccase with bisphenol A

Laccase catalyzes the formation of phenoxyl radicals as an intermediate in Bisphenol A (BPA) degradation, and certain surfactants can affect the effectiveness of laccase in removing BPA from various effluents, yet the specific molecular details remain unclear. In this study, based on laccase and BPA complex, three surfactants, cetyltrimethylammonium bromide (CTAB), sodium dodecylbenzene sulfonate (SDBS), and TritonX-100 (TX-100), were introduced to construct four systems. We applied MD simulation along with MM-PBSA method to investigate the effects of different surfactants on the binding of laccase with BPA. During the MD simulations, these three surfactants enveloped the enzyme surface to varying degrees, causing the solvent to separate from parts of the laccase surface. The addition of CTAB and SDBS suppressed BPA degradation mainly by influencing the polar solvation free energy and van der Waals (vdW) interactions between laccase and BPA. In contrast, TX-100 promoted the degradation of BPA by reducing polar solvation free energy. This explains why in the laccase-BPA complex system the addition of a certain concentration of TX-100 resulted in a higher degradation rate compared to CTAB or SDBS. Our work clarifies the molecular mechanisms of the interaction between laccase and BPA under the influence of CTAB, SDBS, and TX-100 surfactants, and provides some guidance for laccase degradation of BPA.

Effects of sodium dodecylbenzene sulfonate (SDBS) on zebrafish (Danio rerio) gills and blood

ABSTRACT Sodium dodecylbenzene sulfonate (SDBS) is an important surfactant used as a cleaning agent and industrial additive to remove unwanted chemicals which have been detected in the aquatic environment. The aim of this study was to examine the toxicological potential of SDBS on the gills of adult male zebrafish (Danio rerio) exposed to this chemical. For the 96 hr acute exposure, fish were divided into three groups: control, 0.25 mg/L, and 0.5 mg/L of SDBS. After the experiment, morphophysiological analyses (gill histopathology and histochemistry), oxidative stress (determination of gill activities of superoxide dismutase (SOD) and catalase (CAT)), and hematological analyses (leukocyte differentiation) were conducted. Data demonstrated that SDBS at both tested concentrations altered the histopathological index and initiated circulatory disturbances, as well as adverse, progressive, and immunological changes in the gills. In the 0.5 mg/L group, SOD activity decreased significantly, but CAT activity was not altered. Prominent blood changes observed in this group were neutrophilia and lymphocytosis. The number of mucous and chloride cells increased significantly in both groups. Taken together, our findings demonstrated that exposure of D. rerio to SDBS, even for 96 hr, produced adverse morphological and hematological effects associated with a reduction in SOD activity. Our findings indicate that exposure of aquatic species to the anionic surfactant SDBS may lead to adverse consequences associated with oxidative stress. Therefore, this study highlights the risks that this substance may pose to aquatic ecosystems and emphasizes the need for further investigations and strict regulations on its disposal.

THE EFFECT OF PYROLYSIS DURATION ON THERMAL CONDUCTIVITY, STABILITY, AND VISCOSITY OF DISPERSED PCB-BASED PARTICLES IN THERMAL FLUID

Solid particles have a higher thermal conductivity compared to a fluid. Therefore, it is a common practice to disperse solid particles inside a base fluid to increase its thermal conductivity. The particle-dispersed fluid is called a thermal fluid. Thermal fluid, such as a coolant, is widely used as a heat transfer fluid. Several types of particles can be used to increase the thermal conductivity of the fluid, i.e., metallic particles, metal-oxide particles, or even carbon-based particles. In this research, a carbon-based particle was used as the dispersed particle. The particle was obtained by processing electronic waste, specifically Printed Circuit Board (PCB). The PCB was pyrolyzed for variable duration at 15, 30, and 45 minutes to increase the carbon content. After pyrolyzing, the particle was milled to reduce its size. Subsequently, the PCB particle was added to distilled water. Sodium Dodecylbenzene Sulfonate (SDBS) was added as a surfactant to increase fluid stability and prevent particle agglomeration. Thermal conductivity was improved by up to a 13% increase at the 15-minute pyrolysis. Adding SDBS surfactant also improves the thermal fluid's stability to -29,1 mV. The fluid's viscosity was slightly increased up to a maximum of 0.984 mPa.S.

Molecular dynamics models to investigate the diffusion behavior of emulsified asphalt

The utilization of emulsified asphalt is widespread in the recycling of asphalt pavement due to its eco-friendliness and energy efficiency. While numerous research studies have been conducted on the mixture design and strength assessment of emulsified asphalt, the mechanism by which it diffuses and adheres to the aggregate surface remains inadequately comprehended. This study developed molecular dynamics models to investigate the diffusion behavior of emulsified asphalt on the aggregate surface to clarify the role of emulsifier, water, and asphalt in the adsorption process from a molecular perspective. Interface models are established according to the diffusion state for interfacial adhesion evaluation. The results show that the movement of water molecules is the driving force for the entire emulsified asphalt to adsorb to the aggregate surface, whether the aggregate is silica or reclaimed asphalt pavement (RAP). Compared with anionic surfactant Sodium Dodecylbenzene Sulfonate (SDBS), cationic emulsifier Cetyltrimethylammonium Chloride (CTAC) has a better affinity, stronger adsorption, and higher interfacial adhesion energy with silica. Compared with RAP, emulsified asphalt is more readily adsorbed to the surface of silica. It is concluded that emulsifiers have two distribution conformations during the adsorption process, delamination, and aggregation, with delamination exhibiting stronger interface strength with silica than aggregation. When the emulsified asphalt spreads on the RAP surface, the penetration of water molecules into the aged asphalt layer in the RAP structure reduces the structure's water resistance. These results can provide a molecular perspective for understanding the internal structure of emulsified cold recycle mixture (ECRM) and link the adsorption behavior of emulsified asphalt on aggregate surfaces with the internal interface strength of ECRM.

Techno-Economic-Environmental Analysis of Sustainable Anionic Biosurfactant Production from Palm Fatty Acid Distillate.

Currently, there is increased interest in biosurfactants as a substitute for surfactants synthesized from petroleum due to their superior properties and biodegradability. Palm oil derivatives, which can be converted to various products, were selected for biosurfactant synthesis. This paper simulated the biosurfactant production process from palm fatty acid distillate, that is, methyl ester sulfonate (MES), alkyl sulfate, alkyl phosphate, and alkyl carboxylate. Aspen Plus software was used to estimate the thermodynamic properties of intermediate aliphatic organic acids, e.g., methyl ester sulfonic acid, fatty alcohol sulfuric acid, and fatty alcohol phosphoric acid. The chemical process equipment was designed and evaluated to be used in techno-economic analysis, with comparison to petroleum source surfactant production, that is, sodium dodecylbenzenesulfonate (SDBS). The total production cost of each biosurfactant was expressed in terms of minimum selling price. The profitability of each project was determined and compared using three economic indicators: net present value (NPV), payback period, and internal rate of return (IRR). The life cycle assessment methodology was then used to evaluate the environmental impact of surfactant production. The results showed that all surfactant production processes, except for alkyl phosphate, were attractive alternatives as the project yielded a positive value of NPV. The highest NPV of 13.1 million USD was obtained from the MES production process, while the maximum IRR of 79.81% and payback period of 1.49 years were obtained from the alkyl carboxylate production process at a capacity of 1 ton/h. However, the sulfate production process caused more environmental impact than the other two surfactants (MES and carboxylate) due to more CO2 emission per product unit at the level of 2.88 tons CO2/ton surfactant, which is also more than the SDBS surfactant production process that released 2.46 tons CO2/ton surfactant.

The effect of anionic surfactant type and concentration on the development of waterborne nitrocellulose

To better understand the gel emulsification method as an efficient method for producing waterborne nitrocellulose coatings [1–3], the effect of anionic surfactant type (sodium dodecyl sulfate (SDS) and sodium dodecyl benzene sulfonate (SDBS)) and concentration on the emulsification process was investigated. In the case of using SDBS, it was not possible to produce nitrocellulose emulsion via the gel emulsification method while emulsions with submicron size were produced using SDS. Contrary to what might be thought, in the gel emulsification method, high surfactant concentrations did not contribute to better drop breakage and led to catastrophic phase inversion. In addition, increasing surfactant concentration increased the hydrophilicity of the final coatings and decreased their chemical and mechanical properties.

Molecular dynamics simulation of surfactant induced wettability alteration of shale reservoirs

Shale oil has recently received considerable attention as a promising energy source due to its substantial reserves. However, the recovery of shale oil presents numerous challenges due to the low-porosity and low-permeability characteristics of shale reservoirs. To tackle this challenge, the introduction of surfactants capable of modifying wettability has been employed to enhance shale oil recovery. In this study, we perform molecular dynamics simulations to investigate the influence of surfactants on the alteration of wettability in shale reservoirs. Firstly, surfaces of kaolinite, graphene, and kerogen are constructed to represent the inorganic and organic constituents of shale reservoirs. The impact and underlying mechanisms of two types of ionic surfactants, namely, the anionic surfactant sodium dodecylbenzene sulfonate (SDBS) and cationic surfactant dodecyltrimethylammonium bromide (DTAB), on the wettability between oil droplets and surfaces are investigated. The wettability are analyzed from different aspects, including contact angle, centroid ordinates, and self-diffusion coefficient. Simulation results show that the presence of surfactants can modify the wetting characteristics of crude oil within shale reservoirs. Notably, a reversal of wettability has been observed for oil-wet kaolinite surfaces. As for kerogen surfaces, it is found that an optimal surfactant concentration exists, beyond which the further addition of surfactant may not enhance the efficiency of wettability alteration.

Complexes of an Anionic Surfactant with Chitosan and Its Hydrophobic Derivatives As Disinfectants against SARS-CoV-2

This work is aimed at the preparation of complexes of chitosan and hydrophobically modified (HM) chitosan with an anionic surfactant sodium dodecylbenzene sulfonate (SDBS), and at the study of the virucidal activity of the complexes and their components against SARS-CoV-2. It is shown that the introduction of a sufficient amount (4 mol%) of hydrophobic n-dodecyl side groups provides the activity of HM chitosan against SARS-CoV-2 at moderate concentrations, at which unmodified chitosan and chitosan containing a lower amount of hydrophobic groups do not show any activity. Complexes of HM chitosan with SDBS are prepared, which is proven by fluorescence spectroscopy and isothermal titration calorimetry. It is discovered that HM chitosan/SDBS complex is more active than the polymer without surfactant, and an increase of the amount of hydrophobic groups enhances the activity

A novel PVA/MWCNTs hydrogel with high toughness and electromagnetic shielding properties

AbstractCarbon nanotubes (CNTs) are widely utilized as conductive fillers due to their high conductivity, lightweight, and ease of modification. However, their poor dispersion limits their otherwise excellent performance. In this study, we successfully prepared a high toughness, strong electromagnetic interference (EMI) shielding hydrogel by blending polyvinyl alcohol (PVA) hydrogel with multi‐walled carbon nanotubes (MWCNTs) modified by anionic surfactant sodium dodecylbenzene sulfonate (SDBS) and (3‐aminopropyl) triethoxysilane (KH550). We found that the modifiers can not only promote the uniform dispersion of MWCNTs but also improve the mechanical properties of the hydrogel. The results demonstrate that the stress (≈14.86 MPA), elongation at break (233.9%), and compressive strength (≈2.89 MPA) of PVA/MWCNTs composite hydrogel with 1 wt% MWCNTs and 5 wt% PVA were increased by 533.6%, 241.4%, and 206.5%, respectively. Encouragingly, the total electromagnetic shielding effectiveness (SET) is 123.6 dB at a thickness of 5 mm. In summary, this work provides a general approach to functionalizing MWCNTs, which has great potential for developing EMI shielding materials with high toughness.

Analysis of Surfactant and Polymer Behavior on Water/Oil Systems as Additives in Enhanced Oil Recovery (EOR) Technology through Molecular Dynamics Simulation: A Preliminary Study

The decline in oil production has led to the development of the Enhanced Oil Recovery (EOR) technology to increase oil production. Chemical injection is one of the methods in EOR by injecting surfactants or polymers into reservoir wells. To understand the properties and dynamics of surfactants and polymers at the nanoscale, computational studies using molecular dynamics simulation were carried out. In this study, surfactant Sodium Dodecyl Benzene Sulfonate (SDBS) and polymers such as Polyacrylamide (PAM) were used to investigate their effect on the oil-water interface system at the atomic level. Molecular dynamics simulation was carried out using Large-scale Atomic/Molecular Massively Parallel Simulator (LAMMPS) to calculate the diffusion coefficient and Interface Formation Energy (IFE) value for the addition of the surfactant and polymers. The simulation results show that the addition of the surfactant and polymers affects the water-oil interface system differently. The diffusion coefficient results indicates that there are strong interactions between SDBS and dodecane with D of 0.01358. While for PAM, the interactions with water are more significant with D of 0.059. The results of the IFE calculation value also show that the addition of SDBS and PAM makes the water-oil interface system more stable with the negative IFE value of -197.51 and -13.13 Kcal/mol respectively. The results of this study will be used as a reference and a basis for designing new surfactants or polymers that will led to more oil recovery.

Effects and mechanisms of different types of surfactants on sapphire ultrasonic polishing

The effects of three different types of surfactants, including cationic surfactant cetyltrimethylammonium bromide (CTAB), anionic surfactant sodium dodecyl benzene sulfonate (SDBS), and nonionic surfactant fatty alcohol polyoxyethylene ether (AEO), on sapphire ultrasonic polishing (UV-CMP) were studied. Through XPS, SEM, surface tension, zeta potential and particle size analysis, the implications of surfactants on the chemical products, abrasive adsorption, and material removal rate (MRR) of sapphire surface were investigated. The findings indicate that AEO and SDBS result in a certain degree of abrasive agglomeration and slight particle size increase due to hydrogen bonding and electrostatic repulsion respectively. The cationic surfactant CTAB exhibits significant agglomeration of abrasive particles due to electrostatic attraction, and causes the increase in particle size. The slurry’s surface tension is directly proportional to sapphire MRR within a certain range. The polishing effects are the best when 0.10% CTAB is added. Sapphire MRR is 80.50 nm/min, which is nearly twice as much as that of the slurry without surfactants. The surface roughness is 0.200 nm after polishing.

SDBS-Induced Dispersion Effect of High-Rank Coal Fines to Inhibit the Conductivity of Propping Fractures

Coal fines are commonly produced in the form of aggregates during the development of coalbed methane (CBM), which significantly restricts the well productivity. Specifically, the reunion state of coal fines plays a key role in impacting the conductivity of propping fractures after fracturing. In this work, the anionic surfactant sodium dodecyl benzene sulfonate (SDBS) was selected to control the reunion state of coal fines. Visualized simulations of coal fines’ transport behavior in proppants with different particle sizes were carried out under low constant pressure based on sand pack experiments. Moreover, the characteristics of coal fine filling and production in propping fractures were obtained. The results indicate that SDBS has a dispersion effect on coal fine aggregates in the KCl fracturing fluid, with an average reduction of 36% in particle size. There is a positive correlation between the proppant size and the permeability coefficient of propping fractures. Coal fines reduce the permeability coefficients obviously, which first rapidly decrease and then slowly reach a stable stage. In the first stage, the changes of permeability coefficients are affected by the relative particle sizes of the proppant and the coal fine, which is consistent with the classic 1/3 sealing mechanism. In the second stage, SDBS increases the amount of coal fines between the proppant pore throats, and the thickness of the filter cake formed from coal fines at the entrance of the propping fracture increases, resulting in the inhibition of fracture conductivity. Additionally, the output of coal fines is increased dramatically induced by SDBS. Finally, the inhibitory effect of SDBS on fluid production was verified by comparing the water production and coal fine content of two field wells CW # 1 and CW # 2. This study has guiding significance for the output and control of coal fines in low-pressure production of CBM wells.

Designing an Efficient Surfactant–Polymer–Oil–Electrolyte System: A Multi-Objective Optimization Study

This research aimed to study the effects of individual components on the physicochemical properties of systems composed of surfactants, polymers, oils, and electrolytes in order to maximize the recovery efficiency of kerosene while minimizing the impact on the environment and human health. Four independent factors, namely anionic surfactant sodium dodecylbenzene sulfonate (X1) (SDBS), oil (X2) (kerosene), water-soluble polymer poly(ethylene glycol) (X3) (PEG), and sodium chloride (X4) (NaCl), were studied using the full factorial design (FFD) model. Four output variables, namely conductivity (Y1), turbidity (Y2), viscosity (Y3), and interfacial tension (IFT) (Y4), were taken as the response variables. All four FFD models have high coefficients of determination and low errors. The developed models were used in a multi-objective optimization (MOO) framework to determine the optimal conditions. The obtained optimal conditions are X1 = 0.01, X2 = 50, X3 = 5, and X4 = 0.1, with an error of 0.9414 between the predicted and experimental objective function values. This result shows the efficiency of the model developed and the system used for the recovery of kerosene, while also having a positive effect on the protection of the environment.

Infrared spectroscopy: the key to elucidating the sorption mechanism of surfactants, dyes and pharmaceuticals on mineral composite material

There is a global problem with the effective purification of wastewater containing organic compounds, including dyes, pharmaceuticals and surfactants. Therefore, technologies for the removal of pollutants are still being explored. One of the promising methods could be the application of mineral sorbent composite based on lignite and bentonite. However, it is crucial to comprehensively recognize the mechanisms responsible for immobilizing organic compounds using mineral composite sorbents. The purpose of this work was to prepare and investigate the sorption mechanism of lignite-bentonite composite (BL) sorbents for the removal of dyes: Rhodamine B (RB), Remazol Brilliant Blue R (RBBR), pharmaceuticals: ibuprofen (IB), sulfamethoxazole (STX) and surfactant sodium dodecylbenzenesulfonate (SDBS). The quantitative sorption results have been performed using the high-performance liquid chromatography (HPLC) method. The application of infrared (IR) spectroscopy method was crucial to describe the sorption mechanism. After completing the sorption test, the spectra for the sorbents revealed bands associated with adsorbed RB, RBBR, IB, STX, and SDBS on the BL sorbent. Because lignite is predominated in BL composite, the sorption capacity and mechanism strictly correspond to its sorption properties rather than to bentonite ones. The spectra results indicate that the physical sorption process related to electrostatic forces, hydrogen bonding, and dispersion interactions are predominantly responsible for the immobilization of organic compounds tested on mineral sorbents. The X-ray diffraction (XRD) results indicate the ion exchange process involved in the case of RB adsorption on the bentonite sample. Nevertheless, the sorption mechanism was complex because of the extensive sorption properties of mineral composite and the different chemical properties of the tested organic compounds. The results of our spectroscopic studies help interpret the sorption mechanisms of organic compounds on mineral materials.

A novel method for the green utilization of waste fried oil

Waste fried oil was studied to prepare three different types of detergent such as soap, liquid soap and soap powder via saponification process. The preparation conditions of soap base were optimized by orthogonal experiment. The specific preparation processes included waste fried oil treatment, orange peel extract preparation, saponification, demoulding and drying. Results showed that the optimal conditions for saponification were as follows: ratio of pure waste fried oil to coconut oil = 6:4, alkali liquor (NaOH) mass fraction 30%, saponification temperature 70 °C, orange peel extract concentration 15%. The mature soap was then used to make liquid soap and soap powder by surfactant (sodium dodecylbenzene sulfonate, coconut diethanol amide) addition, followed by grinding. The prepared detergent conforms to the production standard of strong decontamination ability, possesses stable performance, is gentle to skin and non-toxic.

Surfactant-enhanced bioremediation of petroleum-contaminated soil and microbial community response: A field study

Surfactant-enhanced bioremediation (SEBR) is frequently employed to clean up soil polluted with petroleum hydrocarbons, but few studies have focused on how surfactants affect microbial communities and different fractions of petroleum hydrocarbons, particularly in the field. Here, the surfactants sodium dodecyl benzene sulfonate (SDBS), alpha olefin sulfonate (AOS), Triton X-100 (TX-100), Tween80, and rhamnolipid were combined with the oil-degrading bacterium Pseudomonas sp. SB to remediate oil-contaminated soil in the laboratory. AOS gave the highest removal efficiency (65.1%) of total petroleum hydrocarbons (TPHs). Therefore, AOS was used in a field experiment with Pseudomonas sp. SB and the removal efficiency of TPHs and long-chain hydrocarbons C21–C40 reached 57.4 and 53.0%, respectively, significantly higher than the other treatments. During bioremediation the addition of Pseudomonas sp. SB significantly stimulated the growth of bacterial genera such as Alcanivorax, Luteimonas, Parvibaculum, Stenotrophomonas, and Pseudomonas and AOS further stimulated the growth of Sphingobacterium, Pseudomonas and Alcanivorax. This study validates the feasibility of surfactant-enhanced bioremediation in the field and partly reveals the mechanism of surfactant-enhanced bioremediation from the perspective of changes in different fractions of petroleum and microbial community dynamics.