A metal surface exposed to a corrosive environment may, under certain conditions experience attack at a number of isolated sites. If the total area of these sites is much smaller than the surface area then the metal is said to be experiencing localized corrosion. The rate of dissolution in this situation is often much greater than that associated with uniform corrosion and structural failure may occur after a very short period. Several different modes of localized corrosion may be identified. These are dependent on the type of metal undergoing corrosion and its environment at the time of attack. One of the most destructive forms is pitting corrosion which is characterized by the presence of a number of small pits on the exposed metal surface. The geometries of the pits depend on many factors such as the metal composition and the surface orientation. A similar mode of corrosion is crevice attack which occurs in situations where two or more surfaces in close proximity lead to the creation of a locally occluded region in which enhanced dissolution may occur. The rapidity with which localized corrosion can lead to the failure of a metal structure and the extreme unpredictability of the time and place of attack, has led to a great deal of study of this phenomenon. There are many difficulties associated with the experimental measurements necessary to understand the process and as a result a number of theoretical models of the various stages of localized corrosion have been developed. In this paper, a review of the literature on this modelling is presented with particular reference to crevice and pitting corrosion. The accuracy of the predictions of the models and the validity of the various approximations are discussed and both the achievements and the weak areas of the current state of corrosion modelling are demonstrated.
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