Surface Protrusions Research Articles

Gradient-Pattern Micro-Grooved Wicks Fabricated by the Ultraviolet Nanosecond Laser Method and Their Enhanced Capillary Performance.

Capillary-gradient wicks can achieve fast or directional liquid transport, but they face fabrication challenges by traditional methods in terms of precise patterns. Laser processing is a potential solution due to its high pattern accuracy, but there are a few studies on laser-processed capillary-gradient wicks. In this paper, capillary step-gradient micro-grooved wicks (CSMWs) were fabricated by an ultraviolet nanosecond pulsed laser, and their capillary performance was studied experimentally. The CSMWs could be divided into three regions with a decreasing capillary radius. The equilibrium rising height of the CSMWs was enhanced by 124% compared to the non-gradient parallel wick. Different from the classical Lucas-Washburn model describing a uniform non-gradient wick, secondary capillary acceleration was observed in the negative gradient direction of the CSMWs. With the increase in laser power and the decrease in scanning speed, the capillary performance was promoted, and the optimal laser processing parameters were 4 W-10 mm/s. The laser-enhanced capillary performance was attributed to the improved hydrophilicity and reduced capillary radius, which resulted from the increased surface roughness, protrusion morphology, and deep-narrow V-shaped grooves induced by the high energy density of the laser. Our study demonstrates that ultraviolet pulsed laser processing is a highly efficient and low-cost method for fabricating high-performance capillary gradient wicks.

A numerical study on thermal deformation of through silicon via with electroplating defect

PurposeBy investigating the thermal-mechanical interaction between the through silicon via (TSV) and the Cu pad, this study aimed to determine the effect of electroplating defects on the upper surface protrusion and internal stress distribution of the TSV at various temperatures and to provide guidelines for the positioning of TSVs and the optimization of the electroplating process.Design/methodology/approachA simplified model that consisted of a TSV (100 µm in diameter and 300 µm in height), a covering Cu pad (2 µm thick) and an internal drop-like electroplating defect (which had various dimensions and locations) was developed. The surface overall deformation and stress distribution of these models under various thermal conditions were analyzed and compared.FindingsThe Cu pad could barely suppress the upper surface protrusion of the TSV if the temperature was below 250 ?. Interfacial delamination started at the collar of the TSV at about 250 ? and became increasingly pronounced at higher temperatures. The electroplating defect constantly experienced the highest level of strain and stress during the temperature increase, despite its geometry or location. But as its radius expanded or its distance to the upper surface increased, the overall deformation of the upper surface and the stress concentration at the collar of the TSV showed a downward trend.Originality/valuePrevious studies have not examined the influence of the electroplating void on the thermal behavior of the TSV. However, with the proposed methodology, the strain and stress distribution of the TSV under different conditions in terms of temperature, dimension and location of the electroplating void were thoroughly investigated, which might be beneficial to the positioning of TSVs and the optimization of the electroplating process.

Machine learning algorithms to study the relative roles of jet convection and natural convection in the presence of surface roughness elements on enhancement of jet impingement heat transfer

Based on data-driven approaches, eight machine-learning algorithms have been proposed to characterize the heat transfer performance of turbulent jet impingement cooling. These algorithms are designed to cool high-heat-flux surfaces modified with single protrusions, multi-protrusions, or V-grooves. To train these algorithms, an experimental dataset was used, which included 184 experiments with Reynolds numbers ranging from 10,000 to 33,000, nozzle exit-to-plate distances ranging from 2 to 10 jet diameters, and two different heat inputs of 60 W and 90 W. Multiple linear regression algorithms in Python programming were used to model jet impingement cooling, showing that the proposed machine learning models provided more accurate predictions with a 20.4 % to 66.5 % relative residual improvement over the existing conventional regression model based on performance metrics like R2 and relative residual. This improvement was leveraged to quantify natural convection's impact on the effectiveness of heat transfer enhancement due to different types and sizes of roughness elements in high-temperature applications. The research found that as the protrusion surface area increased from 0.02 % to 0.188 % compared to the flat plate, the effectiveness of heat transfer enhancement decreased from 2.69 % to 8.37 % at similar operating conditions. These results revealed that natural convection, which opposes forced jet impingement, was strengthened with increased heat input values, roughness element surface area, and the local turbulence generated. The higher natural convection weakened the enhancement afforded by jet impingement on the modified plates relative to the flat plate. Additionally, the capabilities of machine learning algorithms were explored to unlock the full potential of the jet impingement technique and to overcome the associated complexity in jet impingement applications for next-generation electronics cooling. Finally, the Decision Tree Classifier algorithm was applied to classify the performance of the surface roughness element as either effective or ineffective.

Process and Design Challenges for Hybrid Bonding

Hybrid bonding is one of the key technology to enable solutions for high bandwidth with increasing power and signal integrity. Hybrid bonding involves, face-to-face interconnect formation between wafers and it acts as an extension of fusion bonding technology. Wherein, dielectric materials such as silicon dioxide bond at room temperature and the copper vias embedded in the dielectric expand to form the electrical connections, enabling the interconnect formation between the top and bottom wafer.Hybrid bonding provides advantages over traditional C4 flip-chip bonding involving solder-based micro-bumps, such as, interconnect pitch scaling to less than 10 µm thereby providing higher interconnect density and increased power and signal speed efficiency for memory and high-performance computing application along with better reliability. It is compatible with standard CMOS fabrication technology.In this work, we would like to present the design and process challenges which may lead to improved bonding yield. To enable hybrid bonding with high yield it is necessary that the bonding surfaces are flat with low roughness. The optimized chemical mechanical polishing (CMP) process is one of the key process technology which enables surface topography to be less than 10 nm and surface roughness to be less than 0.8 nm. The surface topography is dependent on the metal via layout, interconnect density and the surrounding dielectrics and hence, these design parameters act as a guiding principle for the application-oriented definition of the design to accommodate different pitch sizes of interconnecting vias (from 1 µm to 10 µm). The mechanical properties of the materials play a key role as well as this will define the removal rate of dielectric and the metals during the CMP process which will affect the dishing and the surface topography. To achieve high bonding yield the surface topography is key as this will affect the bond front propagation and hence the bonded and non-bonded region between the dielectrics. To further improve the bonding yield we have applied a tailored annealing recipe which improves the bonding yield significantly. This paper would focus our work on topography improvement and overall bonding yield in detail and a comparison of bonding yield with and without dummy vias. Dummy vias in this context refer to the copper via structures that are not intended for interconnect formation but are there for CMP process optimization to achieve better process control. Hence, the dummy vias are not connected to the underlying routing metal layer.Figure 1, shows an ideal surface that would result in W2W bonding with high yield. Figure 2 shows, the defects such as high copper dishing, copper protrusion, dielectric erosion and poor surface topography which will result in poor bonding yield. Figure 3 shows the bonding using SiON as the bonding dielectric with (a) without dummy copper vias (~98% bond yield) and (b) with dummy copper vias (~88% bond yield). Figure 1

Effect of Impregnation and Graphitization on EDM Performance of Graphite Blocks Using Recycled Graphite Scrap

In the present study, graphite scrap powder from machining of commercial graphite blocks for electrical discharge machining (EDM) applications was recycled as a filler material for manufacturing graphite blocks, and its suitability for use as EDM electrodes was thoroughly assessed. The effects of process parameters applied in EDM electrode manufacturing, including the number of impregnations and graphitization temperatures, on the physical properties of the resulting graphite blocks, were examined. Additionally, EDM performance was evaluated with respect to the above process parameters. In blocks subjected to three impregnation treatments, followed by graphitization at 2200 °C, surface protrusions formed during the EDM process, indicating that the EDM process did not proceed smoothly. On the other hand, in blocks that underwent three impregnation treatments, followed by graphitization at 2800 °C, no surface protrusions were observed, indicating successful EDM operation. This observation further confirms the suitability of these recycled materials for use in EDM electrodes. The graphite block electrodes fabricated using recycled graphite scrap exhibited inferior cyclic stability, with an electrode wear rate of 0.82%, higher than that of a commercial graphite block electrode (0.04%). Nevertheless, using recycled graphite scrap contributes to reducing product costs and CO2 emissions, making the developed graphite electrodes a favorable choice.

Reconstruction and analysis of surface topography of micro-indented surface texture by chi-square function

During surface texture micro-indentation processing, the texture around the contact area will form protrusions. The morphology of these protrusions can change the actual contact area of the contact surface and affect the functional surface. To accurately describe the morphology of surface texture protrusions during the micro-indentation process, scaled chi-square functions are proposed to fit and further analyze their morphology. By simulation, the surface protrusion curve is generated by the micro-indenter head in different materials and depths. The scaled chi-square function is used to fit the extracted curves, and the fitted n value is used as an important characteristic parameter of the protrusion morphology. The study shows that the morphology of the protrusions is related to the material’s elastic modulus, yield strength, power law hardening exponent, and forming depth. Based on our results, it is convenient to judge the highest position and maximum height of the protrusions. The research findings will aid in the holistic design of micro-indentation surface textures, predicting their morphology, and selecting appropriate processes, while also being relevant for evaluating material performance post-micro-indentation with broad application prospects.

Stability of mechanically exfoliated layered monochalcogenides under ambient conditions

Monochalcogenides of groups III (GaS, GaSe) and VI (GeS, GeSe, SnS, and SnSe) are materials with interesting thickness-dependent characteristics, which have been applied in many areas. However, the stability of layered monochalcogenides (LMs) is a real problem in semiconductor devices that contain these materials. Therefore, it is an important issue that needs to be explored. This article presents a comprehensive study of the degradation mechanism in mechanically exfoliated monochalcogenides in ambient conditions using Raman and photoluminescence spectroscopy supported by structural methods. A higher stability (up to three weeks) was observed for GaS. The most reactive were Se-containing monochalcogenides. Surface protrusions appeared after the ambient exposure of GeSe was detected by scanning electron microscopy. In addition, the degradation of GeS and GeSe flakes was observed in the operando experiment in transmission electron microscopy. Additionally, the amorphization of the material progressed from the flake edges. The reported results and conclusions on the degradation of LMs are useful to understand surface oxidation, air stability, and to fabricate stable devices with monochalcogenides. The results indicate that LMs are more challenging for exfoliation and optical studies than transition metal dichalcogenides such as MoS2, MoSe2, WS2, or WSe2.

Repeated local ellipsoid protrusion supplements HLA surface characterization.

Allorecognition of donor HLA is a major risk factor for long-term kidney graft survival. Although several molecular matching algorithms have been proposed that compare physiochemical and structural features of the donors' and recipients' HLA proteins in order to predict their compatibility, the exact underlying mechanisms are still not fully understood. We hypothesized that the ElliPro approach of single ellipsoid fitting and protrusion ranking lacks sensitivity for the characteristic shape of HLA molecules and developed a prediction pipeline named Snowball that is fitting smaller ellipsoids iteratively to substructures. Aggregated protrusion ranks of locally fitted ellipsoids were calculated for 712 publicly available HLA structures and 78 predicted structures using AlphaFold 2. Amino-acid sequence and protrusion ranks were used to train deep neural network predictors to infer protrusion ranks for all known HLA sequences. Snowball protrusion ranks appear to be more sensitive than ElliPro scores in fine parts of the HLA such as the helix structures forming the HLA binding groove in particular when the ellipsoids are fitted to substructures considering atoms within a 15 Å radius. A cloud-based web service was implemented based on amino-acid matching considering both protein- and position-specific surface area and protrusion ranks extending the previously presented Snowflake prediction pipeline.

Ozone and procaine increase secretion of platelet-derived factors in platelet-rich plasma

Platelet-rich plasma (PRP) is gaining more and more attention in regenerative medicine as an innovative and efficient therapeutic approach. The regenerative properties of PRP rely on the numerous bioactive molecules released by the platelets: growth factors are involved in proliferation and differentiation of endothelial cells and fibroblasts, angiogenesis and extracellular matrix formation, while cytokines are mainly involved in immune cell recruitment and inflammation modulation. Attempts are ongoing to improve the therapeutic potential of PRP by combining it with agents able to promote regenerative processes. Two interesting candidates are ozone, administered at low doses as gaseous oxygen-ozone mixtures, and procaine. In the present study, we investigated the effects induced on platelets by the in vitro treatment of PRP with ozone or procaine, or both. We combined transmission electron microscopy to obtain information on platelet modifications and bioanalytical assays to quantify the secreted factors. The results demonstrate that, although platelets were already activated by the procedure to prepare PRP, both ozone and procaine induced differential morpho-functional modifications in platelets resulting in an increased release of factors. In detail, ozone induced an increase in surface protrusions and open canalicular system dilation suggestive of a marked α-granule release, while procaine caused a decrease in surface protrusions and open canalicular system dilation but a remarkable increase in microvesicle release suggestive of high secretory activity. Consistently, nine of the thirteen platelet-derived factors analysed in the PRP serum significantly increased after treatment with ozone and/or procaine. Therefore, ozone and procaine proved to have a remarkable stimulating potential without causing any damage to platelets, probably because they act through physiological, although different, secretory pathways.

Blebs and former blebs: From surface protrusions to extracellular vesicles in cancer signalling, anoikis resistance and beyond.

Associations between plasma membrane blebbing and metastatic progression have been widely reported. There are also reports of increased extracellular vesicle release from cancer cells. Yet the ties between these closely related phenomena are incompletely understood. In this commentary, we remark on a recent finding on cellular membrane blebs in melanoma signaling. We discuss possible implications for cancer biology and draw parallels to knowns and unknowns in the relationships of extracellular vesicles and cancer progression.

Investigating the coupled effect of different aspect ratios and leeward protrusion lengths on vortex-induced vibration (VIV)-galloping energy harvesting: Modelling and experimental validation

Flow-induced vibration energy harvesting is one of the promising approaches for realizing self-powered wireless sensor networks. Incorporation of metasurfaces or surface protrusions on the bluff bodies is an emerging way of enhancing energy harvesting performance. This paper experimentally and numerically investigates the coupled effect of implementing different aspect ratios and leeward protrusion lengths on the performance of vortex-induced vibration (VIV)-galloping energy harvesters. A total of sixteen protruded bluff bodies with four different aspect ratios and four protrusion lengths are proposed for comparative studies. A comprehensive mathematical model is established based on the extended Hamilton’s principle and Tamura’s aerodynamic force model. Both the wind tunnel experiments and numerical simulations manifest a different development trend for the bluff bodies with aspect ratios greater or lower than the unity. For most of the bluff bodies, increasing the protrusion length can lead to an increase in both the VIV-galloping cut-in speed and output power at higher wind speeds. Wind tunnel computational fluid dynamics (CFD) simulations are also performed to investigate the underlying aerodynamic reasons for the observed phenomena. Based on the classic Den Hartog’s criterion and Hu’s findings, it can be found that there is a consistency among the wind tunnel CFD simulation results and the experimental and numerical findings. Furthermore, the wind speed ratio of quasi-steady galloping to Kármán-vortex resonance is selected as an index to evaluate the interaction extent of VIV and galloping oscillations. It is revealed that strongly conjoint VIV-galloping oscillations can be more easily observed when the ratio approaches unity, while no interaction can be detected when the ratio is higher than a value between 11.91 to 23.27 in this study. Further, impedance matching tests and forward wind sweep experiments show that the maximum output power measured among all the studied cases is 0.992 mW, which occurs at the test speed of 5.1 m/s and an optimal load resistance of 200 kΩ, for the bluff body with an aspect ratio of 3:2 and a leeward protrusion length of 10 mm. This outperforms the optimal case of our previous study by 31.04%. Moreover, using the optimization theory, this bluff body is proved to be the global optimal solution of this study, which can well balance the cut-in speed and output power for the applications in the natural gentle breeze.

Research on the thermo-electrochemical behavior during the electrodeposition process of lithium metal battery

Lithium metal batteries (LMBs) are promising renewable energy storage device with higher energy density. During charging/discharging, the electrodeposition or dendrite growth on surface of Li electrode and temperature influence thermo-electrochemical behaviors in LMBs greatly. Coupling electrochemical reaction kinetic equations and thermal relations in electrode, as well as diffusion migrating equations of Li+ ion in electrolyte is employed to investigate the effects of temperature, charging current density, volume fraction of active solid and Li concentration in positive electrode, as well as salt concentration in electrolyte on the entropy production relating to power consumption and Joule heat, as well as cell voltage and overpotential in positive electrode and negative electrode with protrusion surface during charging. More polarization reactions together with larger heat generation take place, and cause more entropy generation in area of protrusion. The voltage efficiency is defined to evaluate thermo-electrochemical behaviors in LMBs, and the higher voltage efficiency occurs with the decrease in charging current density. The 93.6% voltage efficiency can be obtained in the case with solid-phase volume fraction of 0.518 in positive electrode under charging current density of 43.608A/m2. All results from investigation will be beneficial to obtain better thermo-electrochemical behavior in Li metal batteries.

Computational Study of Supersonic Flow Over a Flat Plate With Protrusion

Motivated by a developmental approach of using micro-actuated surface protrusions to control/maneuver slender bodies in supersonic flight, this paper presents a detailed study of a two dimensional laminar supersonic flow over a flat plate with a surface protrusion. The flow field is computed by solving the Navier-Stokes equations using the finite difference method with the particle velocity upwinding scheme (PVUS) for spatial discretization, and the explicit Mac Cormack scheme for temporal integration. A range of free stream Mach numbers (2.0 - 4.5), Reynolds numbers (1000 - 100000) and protrusion heights (0.866% to 8.66% of the characteristic length) has been considered for a thorough parametric study. The parametric study indicates that the oblique shock structure and strength are influenced by all the variables to varying extents. However, the shock location is substantially altered by the protrusion height, Reynolds number, and protrusion shape, while the influence of Mach number is only marginal. An increase in the protrusion height results in an increased wall pressure as well as increased separation lengths on both sides of the protrusion. In contrast, an increase in Mach number increases the wall pressure, but moves the separation point marginally towards the protrusion. Increase in Reynolds number and protrusion bluffness (triangular → trapezoidal → rectangular) increases separation lengths on both sides of the protrusion. In addition to taking a close look at the flow physics, particularly in the protrusion vicinity, considerable attention has also been devoted to important design parameters such as wall pressure, skin friction and the overall normal and tangential force coefficients.

Actin-mediated endocytosis in the E-YSL helps drive epiboly in zebrafish.

In zebrafish, a punctate band of F-actin is reported to develop in the external yolk syncytial layer (E-YSL) during the latter part of epiboly in zebrafish embryos. Here, electron microscopy (EM) and fluorescence confocal microscopy were conducted to investigate dynamic changes in the E-YSL membrane during epiboly. Using scanning EM, we report that the surface of the E-YSL is highly convoluted, consisting of a complex interwoven network of branching membrane surface microvilli-like protrusions. The region of membrane surface protrusions was relatively wide at 30% epiboly but narrowed as epiboly progressed. This narrowing was coincident with the formation of the punctate actin band. We also demonstrated using immunogold transmission EM that actin clusters were localized at the membrane surface mainly within the protrusions as well as in deeper locations of the E-YSL. Furthermore, during the latter part of epiboly, the punctate actin band was coincident with a region of highly dynamic endocytosis. Treatment with cytochalasin B led to the disruption of the punctate actin band and the membrane surface protrusions, as well as the attenuation of endocytosis. Together, our data suggest that, in the E-YSL, the region encompassing the membrane surface protrusions and its associated punctate actin band are likely to be an integral part of the localized endocytosis, which is important for the progression of epiboly in zebrafish embryos.

Effect of temperature on pure mode Ⅲ fracture behavior and fracture morphology of granite after thermal shock

To investigate the effect of temperature on the pure mode III fracture behavior and fracture morphology of granite after thermal shock, edge-notched disc bend granite specimens are selected for heat treatment and a series of fracture tests. Firstly, the effect of temperature on the macroscopic fracture behavior of the rock is analyzed regarding the physical and mechanical properties and fracture toughness. Then, the impact of temperature on the microscopic fracture morphology of the rocks is discussed based on a fractal theory using 3D laser scanning techniques. The results show that temperature affects the fracture behavior of rock by changing its physical parameters and mechanical properties. High temperatures can change the fracture mode of rocks and have a softening effect on rocks. The heat treatment temperature of 325 °C above can convert rocks from brittle to ductile failure. When the heat treatment temperature is above 525 °C can evolve rocks from pure mode III fracture to mixed mode I/III fracture. The fracture toughness of the rock and the joint roughness coefficient are highly linearly correlated with temperature. The fracture toughness of the rock decreases by 0.5 MPa∙m0.5, and the joint roughness coefficient increases by 1.7 for every 100 °C increase in temperature in the range of 25 °C to 625 °C. The asperity height and slope angle of the rock obey a normal distribution. The higher the temperature, the larger the fracture surface area, the larger the fractal dimension, the stronger the anisotropy of the surface protrusions, and the rougher the rock surface.

Filopodia In Vitro and In Vivo.

Filopodia are dynamic cell surface protrusions used for cell motility, pathogen infection, and tissue development. The molecular mechanisms determining how and where filopodia grow and retract need to integrate mechanical forces and membrane curvature with extracellular signaling and the broader state of the cytoskeleton. The involved actin regulatory machinery nucleates, elongates, and bundles actin filaments separately from the underlying actin cortex. The refined membrane and actin geometry of filopodia, importance of tissue context, high spatiotemporal resolution required, and high degree of redundancy all limit current models. New technologies are improving opportunities for functional insight, with reconstitution of filopodia in vitro from purified components, endogenous genetic modification, inducible perturbation systems, and the study of filopodia in multicellular environments. In this review, we explore recent advances in conceptual models of how filopodia form, the molecules involved in this process, and our latest understanding of filopodia in vitro and in vivo.

Durability of Slippery Liquid-Infused Surfaces: Challenges and Advances

Slippery liquid-infused porous surfaces (SLIPS) have emerged as a unique approach to creating surfaces that can resist fouling when placed in contact with aqueous media, organic fluids, or biological organisms. These surfaces are composed of essentially two components: a liquid lubricant that is locked within the protrusions of a textured solid due to capillarity. Drops, immiscible to the lubricant, exhibit high mobility and very-low-contact-angle hysteresis when placed on such surfaces. Moreover, these surfaces are shown to resist adhesion to a wide range of fluids, can withstand high pressure, and are able to self-clean. Due to these remarkable properties, SLIPS are considered a promising candidate for applications such as designing anti-fouling and anti-corrosion surfaces, drag reduction, and fluid manipulation. These collective properties, however, are only available as long as the lubricant remains infused within the surface protrusions. A number of mechanisms can drive the depletion of the lubricant from the interior of the texture, leading to the loss of functionality of SLIPS. Lubricant depletion is one challenge that is hindering the real-world application of these surfaces. This review mainly focuses on the studies conducted in the context of enhancing the lubricant retention abilities of SLIPS. In addition, a concise introduction of wetting transitions on structured as well as liquid-infused surfaces is given. We also discuss, briefly, the mechanisms that are responsible for lubricant depletion.

Genomic and ultrastructural analysis of monkeypox virus in skin lesions and in human/animal infected cells reveals further morphofunctional insights into viral pathogenicity.

Monkeypox (MPOX) is a zoonotic disease that affects humans and other primates, resulting in a smallpox-like illness. It is caused by monkeypox virus (MPXV), which belongs to the Poxviridae family. Clinically manifested by a range of cutaneous and systemic findings, as well as variable disease severity phenotypes based on the genetic makeup of the virus, the cutaneous niche and respiratory mucosa are the epicenters of MPXV pathogenicity. Herein, we describe the ultrastructural features of MPXV infection in both human cultured cells and cutaneous clinical specimens collected during the 2022-2023 MPOX outbreak in New York City that were revealed through electron microscopy. We observed typical enveloped virions with brick-shaped morphologies that contained surface protrusions, consistent with the classic ultrastructural features of MPXV. In addition, we describe morpho-functional evidence that point to roles of distinct cellular organelles in viral assembly during clinical MPXV infection. Interestingly, in skin lesions, we found abundant melanosomes near viral assembly sites, particularly in the vicinity of mature virions, which provides further insight into virus-host interactions at the subcellular level that contribute to MPXV pathogenesis. These findings not only highlight the importance of electron microscopic studies for further investigation of this emerging pathogen but also in characterizing MPXV pathogenesis during human infection.

Field synergy and thermodynamic evaluation of a mini-duct with several protrusions utilizing the cross-flow method: A numerical exercise

The field synergy and entropy generation analysis of turbulent flow in a mini rectangular duct featuring surface protrusions has been numerically explored in a finite volume approach. The governing differential is solved iteratively using adequate numerical boundary conditions and a second-order upwind technique. In the post-processing, entropy generation, and irreversibilities are measured. The duct Reynolds number (ReDh, duct) has been varied from 17,831 to 53,492 at a fixed nozzle Reynolds number (ReDh, nz) of 5104. The effects of the duct Reynolds number on the thermal and frictional irreversibility have been quantified. Thermal, frictional, and total irreversibilities have been reported to rise with ReDh, duct. Furthermore, it is discovered that thermal irreversibility dominates over frictional irreversibility. It has been found that conducting triangular protrusions creates more entropy than conducting rectangular protrusions. Filed synergy analysis has also been carried out by integrating the energy equation. Heat transfer rate has been seen to increase with synergy angle (α). Triangular protrusions have a greater field synergy angle (α) than rectangular protrusions.

Ordered Electronic Reconstruction of the (112¯0$11\bar{2}0$) ZnO Single Crystal

AbstractThree‐dimensional (3D) charge‐written periodic peak and valley nanoarray surfaces are fabricated on a () ZnO single crystal grown via chemical vapor transport. Because the grown ZnO crystals exhibit uniform n‐type conduction, 3D periodic nanoarray patterns are formed via oxygen annealing. These periodically decorated structures show that the peak arrays are conducting at the nanoampere level, whereas the valley arrays are less conductive. Energy dispersive spectroscopy indicates that the valley arrays are deficient in zinc by ≈4–6 at%, and that the peak arrays are deficient in oxygen, respectively. Kelvin probe force microscopy reveals the presence of periodic wiggles featuring variations of ≈70–140‐meV between the peak and valley arrays. A significant decrease in the Fermi level of the valley region is observed (≈190 meV), which corresponds to a high zinc vacancy doping density of 2 × 1018 cm−3. This result indicates the periodic generation of an extremely large electric field (≈11 000 V cm−1) in the vicinity of the peak–valley arrays. Computational analysis corroborates the experimentally observed generation of VZn and the preferential formation of surface protrusions on ZnO () rather than on (0001), based on surface effects, along with the generation of peak and valley features.