This study employs a continuous scanning electron beam to deposit AlCoCrFeNi composite cladding on the surface of 253MA austenitic stainless steel to enhance its surface properties. The characteristics were examined through a scanning electron microscope (SEM), backscattered electron diffraction (EBSD), and white light interferometric three-dimensional surface profile instrument. This study investigated the effect of electron beam process parameters on the surface organization and mechanical properties of 253MA steel. The sample surface was divided into four zones: overlay, bonding, thermal influence, and substrate, according to the results. Coarse columnar and island-shaped crystals composed the overlay zone, while equiaxed austenite grains primarily constituted the substrate. With the increase of the beam current, the microstructure's grain size decreased, the substructures increased, and the BCC phase transformed into the FCC phase. The grain size slightly decreased, substructures changed marginally, and the BCC phase increased as the scanning speed increased. Additionally, the microhardness and mechanical properties of the overlay layer increased significantly, and wear volume and wear rate decreased progressively with the increase in beam current and scanning speed. At a beam current of 18 mA and a scanning speed of 200 mm/min, the surface hardness of 253MA steel reached the maximum value of 520 HV. When the beam current was 24 mA, and the scanning speed was 200 mm/min, the wear volume and wear rate of the overlay sample were minimal, accounting for 37.4% of the original sample's, and its wear resistance was 2.67 times more than that of the substrate.
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