Surface Patterns Research Articles

Construction of anti-fouling ceramic tubular membranes with corrugated inner surfaces using DLP 3D printing

The challenge of membrane fouling persistently hinders the advancement of membrane technology. The construction of patterned membrane surfaces is anticipated to mitigate the effects of membrane fouling significantly. In this study, ceramic microfiltration membranes with corrugated patterns were fabricated by 3D printing combined with the dip-coating process. To assess the impact of surface patterning on ceramic membrane performance, we initially compared the pore size and pure water flux between straight and corrugated membrane tubes. Both configurations exhibited similar parameters: a support pore size of approximately 1 μm, a membrane layer pore size of about 110 nm, and a pure water permeance of around 950 L m−2 h−1·bar−1. The corrugated ceramic membranes demonstrated superior anti-fouling properties compared to their straight counterparts during the filtration of nanoparticle suspensions, oil-in-water emulsions, and bacterial suspensions. Specifically, under a nanoparticle suspension concentration of 2000 ppm, a transmembrane pressure of 0.2 MPa, and a flow rate of 1.0 m s−1, the corrugated membrane achieved a stable flux of approximately 1.7 times greater than that of the straight membrane. Furthermore, we explored the effects of surface patterning on fluid dynamics through numerical simulations. The enhanced turbulence dissipation rate in the patterned membrane tubes suggests increased surface turbulence and an improved capacity to remove contaminants. This research offers novel insights into the development of ceramic membranes with enhanced anti-fouling capabilities for water treatment.

Pattern‐Matched Polymer Ligpands Toward Near‐Perfect Synergistic Passivation for High‐Performance and Stable Br/Cl Mixed Perovskite Light‐Emitting Diodes

Mixed Br/Cl perovskite nanocrystals (PeNCs) exhibit bright pure‐blue emission benefiting for fulfilling the Rec. 2100 standard. However, phase segregation remains a significant challenge that severely affects the stability and emission spectrum of perovskite light‐emitting diodes (PeLEDs). Here, we demonstrate the optimization of the spacing between polydentate functional groups of polymer ligands to match the surface pattern of CsPbBr1.8Cl1.2 PeNCs, resulting in effective synergistic passivation effect and significant improvements in PeLED performances. The block and alternating copolymers with different inter‐functional group spacing are facilely synthesized as ligands for PeNCs. Surprisingly, block copolymers with a higher functional group density do not match PeNCs, while alternating copolymers enable efficient PeNCs with the high photoluminescence intensity, low non‐radiative recombination rate and high exciton binding energy. Density functional theory calculations clearly confirm the almost perfect match between alternating copolymers and PeNCs. Finally, pure‐blue PeLEDs are achieved with the emission at 467 nm and Commission Internationale de l'Eclairage (CIE) coordinates of (0.131, 0.071), high external quantum efficiency (9.1%) and record spectral and operational stabilities (~ 80 mins) in mixed‐halide PeLEDs. Overall, this study contributes to designing the polymer ligands and promoting the development of high‐performance and stable pure‐color PeLEDs towards display applications.

Pattern-Matched Polymer Ligands Toward Near-Perfect Synergistic Passivation for High-Performance and Stable Br/Cl Mixed Perovskite Light-Emitting Diodes.

Mixed Br/Cl perovskite nanocrystals (PeNCs) exhibit bright pure-blue emission benefiting for fulfilling the Rec. 2100 standard. However, phase segregation remains a significant challenge that severely affects the stability and emission spectrum of perovskite light-emitting diodes (PeLEDs). Here, we demonstrate the optimization of the spacing between polydentate functional groups of polymer ligands to match the surface pattern of CsPbBr1.8Cl1.2 PeNCs, resulting in effective synergistic passivation effect and significant improvements in PeLED performances. The block and alternating copolymers with different inter-functional group spacing are facilely synthesized as ligands for PeNCs. Surprisingly, block copolymers with a higher functional group density do not match PeNCs, while alternating copolymers enable efficient PeNCs with the high photoluminescence intensity, low non-radiative recombination rate and high exciton binding energy. Density functional theory calculations clearly confirm the almost perfect match between alternating copolymers and PeNCs. Finally, pure-blue PeLEDs are achieved with the emission at 467 nm and Commission Internationale de l'Eclairage (CIE) coordinates of (0.131, 0.071), high external quantum efficiency (9.1 %) and record spectral and operational stabilities (~80 mins) in mixed-halide PeLEDs. Overall, this study contributes to designing the polymer ligands and promoting the development of high-performance and stable pure-color PeLEDs towards display applications.

Development of laser structured three-dimensional patterns for improved wettability and performance of electrodes for lithium-ion batteries

The demand for improved performance and higher energy density of LIBs is growing due to their wide range of applications and advancement in the energy storage market for electric vehicles. Three-dimensional (3D) structured electrodes have recently been considered the best and most promising approach to improve battery performance as they exhibit high areal and specific capacity. In the work described here, a nanosecond pulsed fiber laser was used to generate four types of surface patterns named: line, grid, triangular end, and rectangular end patterns with an equal amount of ablated active material volume. A study on wettability was performed using the spread area, wetting time, wetting balance, and capillary rise measurements. Moreover, the Lucas Washburn and extended wettability models were used to quantitatively express the wetting behavior using the term wetting rate. In all approaches, line-patterned electrodes show better wettability along with a higher wetting rate, while poor behavior is seen with an unstructured electrode. Galvanostatic tests were used to examine how these electrode surface patterns influence the electrochemical performance of the battery. The capacity retentions, discharge capacity efficiencies, and cyclic stabilities were improved on cells with line, triangular end, and rectangular end patterned electrodes.

Perceptual dimensions of wood materials.

Materials exhibit an extraordinary range of visual appearances. Characterizing and quantifying appearance is important not only for basic research on perceptual mechanisms but also for computer graphics and a wide range of industrial applications. Although methods exist for capturing and representing the optical properties of materials and how they vary across surfaces (Haindl & Filip, 2013), the representations are typically very high-dimensional, and how these representations relate to subjective perceptual impressions of material appearance remains poorly understood. Here, we used a data-driven approach to characterizing the perceived appearance characteristics of 30 samples of wood veneer using a "visual fingerprint" that describes each sample as a multidimensional feature vector, with each dimension capturing a different aspect of the appearance. Fifty-six crowd-sourced participants viewed triplets of movies depicting different wood samples as the sample rotated. Their task was to report which of the two match samples was subjectively most similar to the test sample. In another online experiment, 45 participants rated 10 wood-related appearance characteristics for each of the samples. The results reveal a consistent embedding of the samples across both experiments and a set of nine perceptual dimensions capturing aspects including the roughness, directionality, and spatial scale of the surface patterns. We also showed that a weighted linear combination of 11 image statistics, inspired by the rating characteristics, predicts perceptual dimensions well.

Enhancing stability analysis of open-pit slopes via integrated 3D numerical modeling and data monitoring

The slope at Zhahanur open-pit mine (China) has experienced significant and prolonged deformation, posing a considerable risk to life and property within the mining area. To analyse the deformation and failure mechanism of the rock slope, geotechnical investigations, numerical simulations, and long-term movement monitoring were undertaken. In order to improve the efficiency of slope pretreatment, a point elimination method was proposed for the slope surface, and a 3D geological model of mining area was established. A systematic analysis was performed on monitoring data from surface slope radar and underground inclinometers, enabling the identification of the potential sliding surface and deformation pattern of northern slope in a rational manner. Additionally, through three-dimensional numerical simulation, the feasibility of the mining scheme that incorporates waste dump inside the pit was explored. These simulations accurately captured the varying deformation patterns at different levels and exhibited good agreement with available field monitoring data. The findings revealed a composite multi-stage slope failure pattern primarily controlled by weak layers. The safety factors associated to two competing slip surfaces were determined to be 1.20 and 1.15, respectively. To ensure the safe extraction of coal resources from the deformed slope, a combined mining scheme of in-pit dumping and mining is proposed in the study. The proposed scheme was shown to meet the production needs, with a minimum safety factor of 1.08 for rock slope under the mining scheme. By integrating various field monitoring techniques with numerical simulations, a collaborative monitoring scheme was devised to effectively and promptly identify potential sliding surface and implement necessary mining and control measures to ensure slope stability. This comprehensive approach provides valuable insights into the deformation behavior of the rock slope and facilitates the implementation of proactive measures to mitigate risks associated with slope instability.

Surface turbulence in film flow over periodic ripples

Turbulence in gravity-driven film flow is usually discussed in terms of three-dimensional solitary-wave pulses as they are frequently observed in flows along smooth walls. Here, we show that free-surface turbulence arises in films along rippled substrates, as they are commonly employed in process engineering applications, already at rather low Reynolds numbers from the irregular break-up of the solitary-wave fronts. Short waves in the capillary regime replace the broken solitary waves beyond a certain Reynolds number. The crossover coincides with the occurrence of steady three-dimensional surface patterns upstream, which suppress travelling waves. The waves show power spectral densities with power-law exponents typical for weak capillary-wave turbulence. With increasing Reynolds number, the steepness of the power law declines to lower levels.

Quantifying surface urban heat island variations and patterns: Comparison of two cities in three-stage dynamic rural–urban transition

Urban heat island (UHI) not only reflects the environmental thermal comfort and energy consumption, but also affects the urban meso‑scale climate. There are many researches related with UHI mainly focusing on urban and rural area, while neglecting dynamic rural–urban transition especially in a rapid urbanization in China. Beijing and Zhengzhou are studied by using city clustering algorithm (CCA) and boundary generation algorithm (BGA) to delineate the urban, peri‑urban and rural boundaries from 2000 to 2023 within three stages. Fourier transform model was used to identify the UHI patterns. Results show: 1) Two cities have undergone obvious expansions in 20 years, with a consistent mean LST decrease from urban to peri‑urban and rural areas in three stages. 2) The distribution of UHII was more consistent in Beijing, while it varied more in Zhengzhou across seasons. 3) The UHI patterns notably differ, with Zhengzhou experiencing variable patterns and Beijing consistently showing oblate patterns. 4) The profiles of UHII and NDVI in two cities varied seasonally and reflected urban expansions in terms of longitude and latitude. Understanding the long-term changes and patterns of urban heat islands in different cities will provide information for formulating adaptive policies for urban sustainability.

A feasibility study on femtosecond laser texturing of sprayed nanocellulose coatings

Nanocelluloses are emerging as natural materials with favourable properties for coating industry and can be applied by state-of-the-art spraying technology. While additional functionalities are commonly introduced through chemical modification, the surface microstructuring of nanocellulose coatings with high throughput methods remains unexplored. Here, a femtosecond laser is used for texturing spray-coated coatings made of cellulose nanofibrils (CNF) or cellulose nanocrystals (CNC). For coating thickness of 1.5 to 8 μm, processing limits were determined with maximum ablation energy linearly increasing with coating thickness and minimum ablation energy decreasing or increasing depending on the apparent coating density. Within applicable processing window of pulse rate and power setting, the operational ranges were determined for creating one-dimensional and two-dimensional surface patterns, requiring a higher laser energy for CNC compared to CNF coatings and yielding thinnest possible resolved patterns of 17 μm as determined by the laser spot diameter. The laser ablation under low energy corresponds to an increase in surface roughness and intensifies surface hydrophilicity, while the line patterns are able to pin water droplets with rising water contact angles up to 90°. Present feasibility study opens future possibilities for managing surface properties of nanocellulose coatings in applications where tuning of surface hydrophilicity is required.

Sem Studies on Coix Involucres

A SEM study on the involucral surface of Indian Coix have been undertaken. Five different involucral surface types have been established based on the surface pattern. Certain status changes have been proposed.

Automated assessment of hydrostatic pressure resistance in woven fabrics using the enhanced YOLOv8 network

Hydrostatic pressure resistance serves as a crucial metric in the assessment of water resistance in woven fabrics. The expeditious, precise, and efficient conduct of hydrostatic pressure tests holds paramount importance in advancing the progress and production of high-performance textiles. Addressing the challenges posed by intricate printed patterns on woven fabrics, and the presence of small, widely scattered water droplets, the study leverages the enhanced YOLOv8 model to develop a machine vision-based automated detection technique for assessing water resistance in woven fabric. The proposed method incorporates convolutional block attention module attention mechanisms into the backbone and neck network, replaces the path aggregation network structure of YOLOv8 with the bidirectional feature pyramid network structure, and introduces a dedicated detection head for small targets. These enhancements facilitate accurate identification of water outlet points on the woven fabric and precise recording of frame positions, enabling the precise measurement of hydrostatic pressure. Validation of the proposed model is conducted through a series of comparative experiments utilizing a self-collected dataset. The experimental results underscore the exemplary performance of the proposed model, evidenced by an AP0.5 score of 92.18%, showcasing superior overall efficacy in comparison with alternative models. Notably, the target localization time error is found to be less than 2 s when contrasted with manual detection. This method substantially enhances the accuracy of water droplet detection and localization in hydrostatic pressure resistance testing of woven fabric, characterized by complex surface patterns, thereby contributing to refinement of hydrostatic pressure testing methodologies in woven fabric analysis.

Fungal diversity in sediments of the eastern tropical Pacific oxygen minimum zone revealed by metabarcoding.

Oxygen minimum zones (OMZ) represent ~8% of the ocean, with the Pacific as the largest and top expanding area. These regions influence marine ecosystems, promoting anaerobic microbial communities. Nevertheless, only a fraction of microbial diversity has been studied, with fungi being the less explored component. So, herein we analyzed fungal diversity patterns in surface and subsurface sediments along a bathymetric transect using metabarcoding of the ITS1 region in the OMZ of the Mexican Pacific off Mazatlán. We identified 353 amplicon sequence variants (ASV), within the Ascomycota, Basidiomycota, and Rozellomycota. Spatial patterns evidenced higher alpha diversity in nearshore and subsurface subsamples, probably due to temporal fluctuations in organic matter inputs. Small-scale heterogeneity characterized the community with the majority of ASV (269 ASV) occurring in a single subsample, hinting at the influence of local biogeochemical conditions. This baseline data evidenced a remarkable fungal diversity presenting high variation along a bathymetric and vertical transects.

Effect of patterned condensation surface on the performance of a newly designed basin-type solar desalination unit

Evaporative solar desalination systems present a cost-effective solution for generating clean water from brine solutions or seawater. This study investigates the impact of condensation surface inclination, surface pattern, and wettability on the performance of a newly proposed basin-type solar desalination unit using computational fluid dynamics (CFD) based simulations. The proposed design of the system shows better performance in terms of water production compared to previously developed conventional units. It was observed that the wettability-based patterning with different arrangements on the condensation surface has a significant effect on the rate of water condensation. Five different cases of surface patterning on the condensation surface were considered. In one case, coatings of alternating hydrophobic and hydrophilic strips were considered (termed as Pattern-I, Pattern-II and Pattern-II for different cases based on the hydrophilic and hydrophobic coverages). In another case, small rectangular patches of hydrophilic (or hydrophobic) layers were coated on a hydrophobic (or hydrophilic) base substrate (termed as checkerboard Pattern-IV or V). The result shows 75.0% more efficiency for a checkerboard-based surface (Pattern-IV) and 150% more efficiency for a strip-based (Pattern-II) pattern than the pristine wettability surface of conventional design. Furthermore, the validation of the surface characteristics was performed based on available literature which implied satisfactory performance.

The influence of laser texturing on the tribological behavior of titanium alloy Ti6Al4V in medical applications

This paper analyzes the tribological behavior of the Ti6Al4V ELI alloy subjected to laser texturization for medical purposes. Laser texturing enables one to observe specific patterns of the material surface at established depths. Microtexturing of the samples was performed using a 355 nm picosecond laser. The influence of the microtexturing process (depending on the process parameters) on the geometric parameters of the proposed laser texturing pattern was evaluated. Selected samples were subjected to tribological testing using the ball-on-plate technique in dry and lubricant-sliding methods (in Ringer solution). The wear properties were evaluated by comparing the coefficient friction, wear volumes, and wear ratio. A scanning electron microscope characterized the morphologies of the wear scar and the wear mechanism. The experimental results show that the surface texturing and the changes in microgrooves can reduce wear. The results indicate, that samples after laser texturing were characterized by 15% higher microhardness, compared to those in the initial state. It was found, a 26% reduction in friction coefficient and 29% in the wear volume compared to the smooth, untextured surface samples under lubricated conditions. The decrease in value of the coefficient friction and wear volume for the samples after the laser texturing process is an effect of synergistic of entrapped wear debris in micro-grooves and increased hardness for samples after laser textured.

Scanning electron microscopic investigation on Chicory tribe (Compositae) botanical sources and their antimicrobial potential.

This study discusses the micro-level structural details of Cichorieae pollen sources elucidated by scanning electron microscopy (SEM) and explains their symmetry and morphometry. The in-depth knowledge from the electron ultrastructure of Asteraceae pollen has provided insights into enhanced pollen morphology, and the antimicrobial significance of species under study presents novel avenues for their natural defense mechanisms in the development of antimicrobial agents. In this research, both quantitative and qualitative features of pollen were examined. The pollen grains are prolate-spheroidal and oblate-spheroidal in shape, characterized by a maximum polar diameter of 55.6-61.0 μm and a maximum equatorial distance of 68.3-74.4 μm. SEM reveals various configurations such as echinate perforate-tectate, psilate, and echino-lophate perforate. The Cichorieae species have significant antimicrobial efficacy and are promising sources for the development of novel antimicrobial drugs with potential implications in pharmaceutical and healthcare industries. SEM analysis of Cichorieae pollens has provided remarkable insights into their unique structures, revealing diverse shapes and surface ornamentations, which can be used for accurate Asteraceae species identification. RESEARCH HIGHLIGHTS: SEM provides unique pollen surface structures and patterns of Chicory pollen grains. Chemical composition of Chicory botanical sources provides valuable information on their potential as antimicrobial agents. SEM imaging reveals specialized fenestrate grain structures of taxonomic importance.

Directional Pumpless Transport of Biomolecules through Self-Propelled Nanodroplets on Patterned Heterostructures.

The surface patterning in natural systems has exhibited appreciable functional advantages for life activities, which serve as inspiration for the design of artificial counterparts to achieve functions such as directional liquid transport at the nanoscale. Here, we propose a patterned two-dimensional (2D) in-plane heterostructure with a triangle-shaped hexagonal boron nitride (hBN) track embedded in graphene nanosheets, which can achieve unidirectional and self-propelled transport of nanodroplets carrying various biomolecules such as DNA, RNA, and peptides. Our extensive MD simulations show that the wettability gradient on the patterned heterostructure can drive the motion of nanodroplet with an instantaneous acceleration, which also permits long-distance transport (>100 nm) at the microsecond time scale. The different behaviors of various types of biomolecules have been further studied systematically within the transporting nanodroplets. These findings suggest that these specially designed, patterned heterostructures have the potential for spontaneous, directional transport of important biomolecules, which might be useful in biosensing, drug delivery, and biomedical nanodevices.

Implanted Carbon Nanotubes Harvest Electrical Energy from Heartbeat for Medical Implants.

Reliability of power supply for current implantable electronic devices is a critical issue for longevity and for reducing the risk of device failure. Energy harvesting is an emerging technology, representing a strategy for establishing autonomous power supply by utilizing biomechanical movements in human body. Here, a novel "Twistron energy cell harvester" (TECH), consisting of coiled carbon nanotube yarn that converts mechanical energy of the beating heart into electrical energy, is presented. The performance of TECH is evaluated in an in vitro artificial heartbeat system which simulates the deformation pattern of the cardiac surface, reaching a maximum peak power of 1.42W kg-1 and average power of 0.39W kg-1 at 60 beats per minute. In vivo implantation of TECH onto the left ventricular surface in a porcine model continuously generates electrical energy from cardiac contraction. The generated electrical energy is used for direct pacing of the heart as documented by extensive electrophysiology mapping. Implanted modified carbon nanotubes are applicable as a source for harvesting biomechanical energy from cardiac motion for power supply or cardiac pacing.

Machine learning-based prediction of polaron-vacancy patterns on the TiO2(110) surface

The multifaceted physics of oxides is shaped by their composition and the presence of defects, which are often accompanied by the formation of polarons. The simultaneous presence of polarons and defects, and their complex interactions, pose challenges for first-principles simulations and experimental techniques. In this study, we leverage machine learning and a first-principles database to analyze the distribution of surface oxygen vacancies (VO) and induced small polarons on rutile TiO2(110), effectively disentangling the interactions between polarons and defects. By combining neural-network supervised learning and simulated annealing, we elucidate the inhomogeneous VO distribution observed in scanning probe microscopy (SPM). Our approach allows us to understand and predict defective surface patterns at enhanced length scales, identifying the specific role of individual types of defects. Specifically, surface-polaron-stabilizing VO-configurations are identified, which could have consequences for surface reactivity.

Bandolier Bags and Indigenous Modernism

This is a material culture-based case study of two bandolier bags dated to the late nineteenth or early twentieth century in the Agnes Etherington Art Center collection in Kingston, Canada. The floral motifs that decorate these two bags are not made from porcupine quills, nor are all of them bilaterally symmetrical as in “traditional” Indigenous art. Instead, they are made from glass beads, and most of the floral designs are asymmetrical. The bags’ surface patterns and materials were made possible through international trade, which facilitated the merging of European and other global designs, materials, and forms with Indigenous visual and material culture. Contemporary Western anthropological discourse framed these Indigenous objects as “hybrids” and alleged that they distorted the original meaning of such styles in a European context while simultaneously “corrupting” traditional Indigenous art and culture. Such art forms were denied a place in modernity due to their supposed inauthenticity. Ironically, “authentic” Indigenous art and material culture was likewise barred from being considered “modern” due to its hand-made, “preindustrial” nature. Connecting North American historical developments with discourse on Indigenous modernisms, I argue that on the contrary, these bags evince their makers’ conscientious engagement with modernity and can be considered modern Indigenous art.

Boosting the performance of bolt-microtubular solid oxide fuel cells through surface pattern tuning

A number of bolt-microtubular anode supports (BMASs) are manufactured by winding the corresponding thin tapes on threaded rods of different thread pitches and depths, followed by co-lamination using isostatic press. Bolt-microtubular cells (BMCs) are also constructed on BMASs to investigate the effects of the created surface patterns on the cell performance and microstructure. The bolt-microtubular cell, whose anode support is patterned by using a threaded rod with 0.8 mm thread pitch and 0.4 mm thread depth, exhibits ∼92% higher maximum performance than that of the reference cell at 800 ºC under 0.3 NL/min hydrogen flow and stagnant air. The almost doubled performance is mainly due to the increase in anode-electrolyte and cathode-electrolyte interfacial areas by the surface patterns created. The cell is also subjected to a 200-h life test at 800 °C and 0.7 V and demonstrates a stable performance.