Wood Surface Research Articles

Wood Surface-Embedding of Functional Monodisperse SiO2 Microspheres for Achieving Robust, Durable, Nature-Inspired, Programmable Superrepellent Interfaces.

Nature-inspired, robust, durable, liquid-repellent interfaces have attracted considerable interest in the field of wood biomimetic intelligence science and technology application. However, realizing green environmental protection and low maintenance and replacement cost wood surfaces constructed with micro/nanoarchitectures is not an easy task. Aiming at the problem of poor waterproof performance of wood, a silicon dioxide/polydimethylsiloxane (SiO2/PDMS) self-cleaning programmable superhydrophobic coating was biomimetically constructed on the wood substrate by surface-embedded dual-dipping design based on the "substrates + nanoparticles" hybrid principle of the lotus leaf effect. This robust, durable, nature-inspired, self-cleaning, programmable superhydrophobic coating was found to have no observable impact on the original color and texture of the natural wood. The SiO2/PDMS/wood prepared exhibited exceptional liquid repellency and a high static water contact angle (WCA) of 158.5° and a low slide angle (SA) of 10°, including everyday general-purpose droplets, indicating that the introduction of the monodisperse SiO2 microspheres can effectively enhance the superhydrophobic properties of the hydrophilic wood. We applied this strategy to a variety of substrates, including wood-cellulose aerogel and wood-cellulose paper, and demonstrated that the liquid-repellent nature of the self-cleaning superhydrophobic coating remained unchanged. Moreover, the superhydrophobic surface of SiO2/PDMS/wood was preserved even after harsh abrasion conditions, including mechanical damage (sandpaper, sharp steel blade, and tapes), thermal damage (UV irradiation and low/high-temperature exposure such as steaming and freezing), chemical damage, and solvent corrosion (immersion in acid, alkali), demonstrating robust stability of the superhydrophobic coating. Furthermore, the SiO2/PDMS programmable superhydrophobic coating exhibits exceptional exciting self-cleaning and stain-resistant properties, making it offer greater possibilities in terms of scientific challenges and real-world problem-solving at biomimetic smart superhydrophobic interfaces in wood.

The Weathering of the Beech and Spruce Wood Impregnated with Pigmented Linseed Oil

This research aimed to examine the effects of a deep impregnation technique (Royal process) and surface coating using a linseed oil-based product, enhanced with small amounts of brown and grey pigments, on the natural and artificial weathering of wood. The treated and reference samples underwent natural weathering for five years and artificial weathering for 1900 h. Changes in color and surface roughness were assessed during weathering. For the artificially weathered samples, liquid water absorption was measured both before and after exposure. The impregnated and coated samples gradually lost their brown color, turning grey over time. More pronounced differences were observed during natural weathering, with the coated samples showing greater structural changes on the wood surface. In contrast, impregnated samples slowed down structural alterations compared to the reference samples. Both treatments effectively reduced water absorption before weathering, although this effect diminished after exposure. The treatments did not significantly impact the fire resistance of spruce and beechwood.

Establishing fire protection patterns in wood using impregnation compositions from inorganic salts

An issue related to using inorganic salts for fire protection of wood is to ensure their flame-inhibiting ability and compatibility with wood and application technology. That is why the object of research was to establish the effectiveness of inhibitory properties of mixtures of inorganic salts during interaction with the flame and enabling interplay with wood. A synergistic increase in the inhibitory capacity of mixtures of aqueous solutions of salts of diammonium phosphate and ammonium sulfate at a ratio of 2:1, and for a mixture based on orthophosphoric acid, urea, and oxyethylidenediphosphonic acid in the concentration range of 20–25 % by mass, has been proven. During the interaction of the specified mixtures with the wood surface, it was found that after application to the wood surface, the dispersed component of the free energy of the wood surface decreased to zero; instead, the polar component increased 13 times, which indicates a change in the wood surface. During the tests of wood samples on the effect of the burner flame, it was found that the untreated sample ignited on second 53, and the flame spread throughout the sample for 102 s. On the other hand, the samples treated with a mixture of an aqueous solution of phosphate and ammonium sulfate, as well as a mixture of aqueous solutions based on orthophosphoric acid and urea and oxyethylidenediphosphonic acid, did not catch fire, the flame did not spread over the surface, and the flammability index was 0. The practical significance is that the results were taken into account when designing flame retardant compositions for wood. Thus, there are reasons to assert the possibility of targeted regulation of wood protection processes through the use of mixtures of inorganic salts capable of forming a protective layer on the surface of the material that inhibits the burning of wood

Field and laboratory perspectives on fentanyl and carfentanil decontamination

Abuse of the highly toxic compound fentanyl and its analogues is increasing, raising serious public health concerns due to their potency and availability. Therefore, there is a need for decontamination methodologies to safely remove fentanyl to avoid harmful exposure. In this study, the efficacy of commercial and in-house synthesized decontamination agents (Dahlgren Decon, RSDL (Reactive Skin Decontamination Lotion), FAST-ACT (First applied sorbent treatment against chemical threats), GDS2000, alldecont MED, bleach, Domestos Spray Bleach, Effekt Klor, MgO, TiO2-nanodiamond, and CeO2) were evaluated for the degradation of fentanyl and carfentanil under controlled laboratory conditions and on wooden floor surfaces. Liquid chromatography/mass spectrometry analysis showed that oxidative decontamination agents were the most effective, with N-oxides identified as major degradation products. The physiological effects of these N-oxides were also investigated regarding their ability to activate the µ-opioid receptor and their metabolism in human liver microsomes. The results provide empirical evidence that complements prior research findings on the degradation of fentanyl and carfentanil using a variety of decontamination agents.

Transparent Coating Systems Applied on Spruce Wood and Their Colour Stability on Exposure to an Accelerated Ageing Process

The objective of this study was to investigate the colour stability of spruce wood surfaces treated with coating systems (CS) and exposed to accelerated ageing. The tested CSs were transparent and three-layered; the top layer was modified with ultraviolet (UV) absorbers, while the base layer was modified with lignin stabiliser. Spruce wood surfaces treated with unmodified CSs were not colour-stable during the accelerated ageing process, with the surface exhibiting colour change after just 100 ageing hours. Adding specific UV absorbers into the top layer and lignin stabiliser into the base layer significantly improved the colour stability of the surface-treated wood. In all cases, however, the colour variation associated with ongoing ageing was significant. An additional study task was to determine whether the discolouration of surface-treated wood is caused by the discolouration of the wood substrate alone or also by the CS discolouration. Consequently, there was also the examination of discolouration of the individual coating materials or coating systems applied to glass slides. This testing proved that in the case of wood surface-treated with CS, without lignin stabiliser, the discolouration was the same as that of the substrate, and this was true throughout the whole ageing process. In the case of wood surface-treated with CS, but with lignin stabiliser, there were, in some cases, significant differences in discolouration between surface-treated wood and the wood substrate. These variations were especially evident during the initial 300 ageing hours.

Using plasma-activated water for decontamination of Salmonella spp. on common building surfaces in poultry houses

Plasma-activated water (PAW) has been shown to have antimicrobial properties, making it a promising tool for surface decontamination. This study evaluated the ability of PAW generated from high voltage atmospheric cold plasma to remove Salmonella from common surfaces (stainless steel (SS), polyvinyl chloride (PVC), concrete, and wood) found in poultry houses. PAW was generated by exposing distilled water to atmospheric cold plasma in 80% humid air at 90 kV and 60 Hz for 30 min. The resulting PAW contained 1120 ppm of nitrate and 1370 ppm of hydrogen peroxide, with a pH of 1.83. PAW was then applied to coupons of SS, PVC, wood, and concrete surfaces inoculated with 7–8 log10 CFU of cocktail of Salmonella spp. (S. Typhimurium, S. Newport, S. Montevideo, and S. Enteritidis). PAW effectively reduced Salmonella levels on SS and PVC surfaces to below the detection limit within 30 s. On wood surfaces, a longer treatment time of 7.5 min was required to achieve a maximum reduction of 2.63 log10 CFU, likely due to the porosity of the wood limiting PAW contact with the bacteria. On concrete surfaces, the reduction in Salmonella levels was only 0.98 log10 CFU. This was likely due to the greater surface roughness and high alkalinity, which neutralized the PAW species.

3D micromorphological reconstruction and roughness characterization of wood surface based on sequence images

A novel non-contact optical inspection technique is proposed to precisely reconstruct the three-dimensional surface structure of wood and evaluate its roughness. The feasibility of using image fusion techniques to characterize the 3D roughness of wood surfaces is explored by combining high-resolution serial image acquisition techniques with advanced data processing methods. The work focuses on examining various cut surfaces of three distinct wood species: Larch, Catalpa, and Toona sinensis. The proposed 3D roughness parameters are verified using 3D reconstruction and precise measurements. The experimental results demonstrate that the proposed method exhibits strong adaptability in measuring wood surface roughness and achieves a high degree of consistency with the results obtained from traditional digital microscope systems. This study not only validates the possible use of multilayer sequence image fusion technology in measuring wood roughness, but also establishes a solid basis for the creation of 3D assessment criteria for wood surface roughness and associated inspection systems.

A Review on the Effect of Wood Surface Modification on Paint Film Adhesion Properties

Wood surface treatment aims to improve or reduce the surface activity of wood by physical treatment, chemical treatment, biological activation treatment or other methods to achieve the purpose of surface modification. After wood surface modification, the paint film adhesion performance, gluing performance, surface wettability, surface free energy and surface visual properties would be affected. This article aims to explore the effects of different modification methods on the adhesion of wood coating films. Modification of the wood surface significantly improves the adhesion properties of the paint film, thereby extending the service life of the coating. Research showed that physical external force modification improved the hydrophilicity and wettability of wood by changing its surface structure and texture, thus enhancing the adhesion of the coating. Additionally, high-temperature heat treatment modification reduced the risk of coating cracking and peeling by eliminating stress and moisture within the wood. Chemical impregnation modification utilized the different properties of organic and inorganic substances to improve the stability and durability of wood. Organic impregnation effectively filled the wood cell wall and increased its density, while inorganic impregnation enhanced the adhesion of the coating by forming stable chemical bonds. Composite modification methods combined the advantages of the above technologies and significantly improved the comprehensive properties of wood through multiple modification treatments, showing superior adhesion and durability. Comprehensive analysis indicated that selecting the appropriate modification method was key for different wood types and application environments.

Effect of walnut tannin on wood surface hardness: A study on pine and walnut samples

The hardness of the wood surface determines its wear resistance and resistance to mechanical damage. This study aimed to determine the effect of walnut tannin used in wood preservation on the surface properties of wood. For this purpose, Scots pine (Pinus sylvestris L.) and walnut (Juglans regia L.) wood test specimens were treated with walnut tannin with a brush. The specimens then were coated with water-based and polyurethane varnishes. After drying, the surface hardness was measured. As a result of the research, it was determined that the highest surface hardness was in the control samples without tannin application and the highest value was in walnut wood.

Ultra-Pressurized Deposition of Hydrophobic Chitosan Surface Coating on Wood for Fungal Resistance.

Fungi (Neolentinus lepideus, Nl, and Trametes versicolor, Tv) impart wood rot, leading to economic and environmental issues. To overcome this issue, toxic chemicals are commonly employed for wood preservation, impacting the environment and human health. Surface coatings based on antimicrobial chitosan (CS) of high molar mass (145 × 105 Da) were tested as wood preservation agents using an innovative strategy involving ultra-pressurizing CS solutions to deposit organic coatings on wood samples. Before coating deposition, the antifungal activity of CS in diluted acetic acid (AcOOH) solutions was evaluated against the rot fungi models Neolentinus lepideus (Nl) and Trametes versicolor (Tv). CS effectively inhibited fungal growth, particularly in solutions with concentrations equal to or higher than 0.125 mg/mL. Wood samples (Eucalyptus sp. and Pinus sp.) were then coated with CS under ultra-pressurization at 70 bar. The polymeric coating deposition on wood was confirmed through X-ray photoelectron spectroscopy (XPS), energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM) images, and water contact angle measurements. Infrared spectroscopy (FTIR) spectra of the uncoated and coated samples suggested that CS does not penetrate the bulk of the wood samples due to its high molar mass but penetrates in the surface pores, leading to its impregnation in wood samples. Coated and uncoated wood samples were exposed to fungi (Tv and Nl) for 12 weeks. In vivo testing revealed that Tv and Nl fungi did not grow on wood samples coated with CS, whereas the fungi proliferated on uncoated samples. CS of high molar mass has film-forming properties, leading to a thin hydrophobic film on the wood surface (water contact angle of 118°). This effect is mainly attributed to the high molar mass of CS and the hydrogen bonding interactions established between CS chains and cellulose. This hydrophobic film prevents water interaction, resulting in a stable coating with insignificant leaching of CS after the stability test. The CS coating can offer a sustainable strategy to prevent wood degradation, overcoming the disadvantages of toxic chemicals often used as wood preservative agents.

Construction of structurally stable block electrodes with RuO2 distribution for supercapacitor based on TEMPO-treated wood loaded with Ru-TA complex

Block carbon is convenient for energy applications, however constructing composites for electronic energy storage by loading metal oxides on the surface of wood derived carbon is fraught with complications. The mild TEMPO method was employed to treat wood to expand carboxyl groups, followed by introducing tannic acid (TA) to produce Ru-TA complex (underdeveloped provider of RuO2) on wood. These composites were impregnated with H2SO4 and carbonized, transitioning into block electrodes with a clear-stable carbon skeleton and comprising uniformly diffused RuO2. The block electrodes exhibit an impressive specific surface area, with TPWTSC-7 among them completing 812.1406 m2/g. Electrochemical characteristics were investigated using KOH and H2SO4 solutions in three-electrode. Evaluation indicates that RuO2 and electrolyte have a comprehensive effect on performance, with a representative TPWTSC-4 demonstrating the Ct of 189.09 F/g (0.1 A g-1) in KOH solution, while achieving 289.99 F/g (0.1 A g-1) in H2SO4 solution, which is 8.82 times that of TPWSC. The storage mechanism of TPWTSC-0.83, TPWTSC-4 and TPWTSC-7 in H2SO4 solution are affected by diffusion control and capacitance, and TPWTSC-4 emerges a pseudo-capacitive contribution of 63.82 % (5 mV/s). For two-electrode, the easily operable TPWTSC-4//TPWTSC-4 achieves a CT of 34.17 F/g (0.05 A g-1), which also exhibits impressive power density.

A low-cost method for quantifying bouncing ball dynamics with smartphone video

Abstract This study employed a low-cost method for quantifying bouncing ball dynamics with smartphone video. High-speed video analysis was used to investigate the bouncing behaviour of different balls, including table tennis, rubber, and tennis balls, on a table tennis surface. To examine the effect of surface material on bouncing dynamics, the table tennis ball was also tested on wood and tile surfaces. Key parameters analysed included bounce height decay, the coefficient of restitution (COR), and the bounce half-life. Additionally, we measured the total bouncing time and analysed the relationship between changes in gravitational potential energy, kinetic energy, and total mechanical energy (ME). Our results revealed a significant correlation between the COR and the decay rate of bounce height. Balls with higher COR values, indicative of lower energy loss per bounce, exhibited slower decay rates, resulting in longer bounce half-lives and extended total bounce times. For instance, the table tennis ball on a tile surface demonstrated a high COR of 0.93, a bounce half-life of 4.65 bounces, and a total bounce time of 8.22 ± 0.34 s. This suggests that material properties such as stiffness and elasticity of both the ball and the surface significantly influence the COR and decay rate, beyond just surface smoothness. Furthermore, our analysis of ME changes in the bouncing balls aligns with theoretical predictions, providing insights into the energy transformations occurring during bouncing. This improved understanding can also be a valuable tool for educators, helping teachers and students bridge the gap between theory and real-world observations, leading to a deeper grasp of the concepts.

Evaluating the Effectiveness of Cellulose-Based Surfactants in Expandable Graphite Wood Coatings.

This study deals with the design of modern environmentally friendly and non-toxic flame retardants based on expandable graphite 25 K + 180 (EG) modified by cellulose ethers (Lovose TS 20, Tylose MH 300, Klucel H) and nanocellulose (CNC) that are biocompatible with wood and, therefore, are a prerequisite for an effective surfactant for connecting EG to wood. The effectiveness of the formulations and surfactants was verified using a radiant heat source test. The cohesion of the coating to the wood surface and the cohesion of the expanded graphite layer were also assessed. The fire efficiency of the surfactants varied greatly. Still, in combination with EG, they were all able to provide sufficient protection-the total relative mass loss was, in all cases, in the range of 7.38-7.83% (for untreated wood it was 88.67 ± 1.33%), and the maximum relative burning rate decreased tenfold compared to untreated wood, i.e., to 0.04-0.05%·s-1. Good results were achieved using Klucel H + EG and CNC + EG formulations. Compared to Klucel H, CNC provides significantly better cohesion of the expanded layer, but its high price increases the cost of the fireproof coating.

Superhydrophobic and antibacterial larch wood prepared by PEI controlled growth of conical ZnO nanopillar

The natural antibacterial performance of cicada wings inspired the morphology design and application of zinc oxide (ZnO) nanoparticles on wood surfaces to enhance combined antibacterial function. The commonly interior used larch wood was chosen as base material and firstly pre-treated with ultrasonic-hydrothermal method, the deposition of ZnO nanoparticles with different morphologies was controlled by polyethyleneimine (PEI) concentration during the crystal growth, and the analysis of surface characteristics and antibacterial efficacy was fully tested. Scanning Electron Microscopy (SEM) observations revealed that the addition of PEI altered the morphology of ZnO nanoparticles on the wood surface. ZnO structures without PEI exhibited hexagonal prismatic shapes. As the PEI concentration increased, the particle size of ZnO decreased. When 6 mmol/L of PEI was added, ZnO transformed into a conical structure. Contact angle measurements confirmed the preparation of superhydrophobic ZnO, which exhibited self-cleaning properties. The antibacterial circle method test results showed that superhydrophobic ZnO wood prepared with 6 mmol/L of PEI exhibited superior antibacterial properties, with higher activity against Staphylococcus aureus compared to Escherichia coli. Overall, the study demonstrates a promising approach to developing polyfunctional and effective antibacterial wood surfaces inspired by natural cicada wings nanostructures.

Synergetic integration of photothermal and self-cleaning features in a composite phase change material based on layered double hydroxides and polypyrrole

Composite phase change materials (PCMs) with photothermal functionality play a crucial role in efficiently storing and utilizing solar energy. However, the challenge of effectively removing of contaminants on photothermal conversion coatings has long puzzled researchers. In this study, we propose a novel approach to enhancing both photothermal conversion performance and self-cleaning properties of wood-based composite phase change materials, ultimately facilitating the sustainable and effective utilization of solar energy. The method utilized metal-organic frameworks (MOFs) as a precursor to form rough layered double hydroxides (LDH) on the wood surface through hydrolysis-induced exchange. Subsequently, polypyrrole (PPy) was deposited through vapor phase onto the LDH, and paraffin wax (PW) is utilized as the phase change material to prepare a novel composite phase change material. This modified wood structure facilitates leak-proof PW encapsulation and effective heat storage (167.6 J/g). PPy acts as a proficient photothermal converter and improves the composite material's heat transfer efficiency by establishing thermal conduction pathways, resulting in an 87.4 % enhancement in thermal conductivity compared to pure PW. The rough surface of LDH promotes multiple light reflections and scattering within the material, leading to increased light absorption by the PPy coating and achieving a photothermal conversion efficiency of up to 96.4 %. Furthermore, the high roughness of the LDH layer combined with the low surface energy of PW imparts superhydrophobic self-cleaning properties to the material, ensuring sustained effectiveness of the photothermal conversion coating over time. This research presents a viable approach for maintaining the cleanliness and efficiency of solar energy systems.

Cellulose nanofibers-based UV resistant and hydrophobic wood coatings

Wood and wood-based products are regarded as sustainable building materials, nonetheless, they frequently need the addition of protective coatings due to their susceptibility to abiotic and biotic degrading elements. Among the coating systems, water-borne coatings are a better choice since the majority of popular wood coatings are solvent-based and release volatile organic chemicals (VOCs). In this study, cellulose nanofibers (CNFs) were isolated from eucalyptus wood pulp using a chemo-mechanical method and used as the base substrate for wood coatings. The effect of CNF dispersion with varying concentrations (0.5 and 1 wt.%) of zinc oxide (ZnO) nanoparticles on UV-resistance of Pinus radiata and Hevea brasiliensis after 500 hrs of exposure was assessed. Wood surfaces without coating exhibited severe discolouration after 500 hrs of UV exposure. Only CNF-coating results in slight protection of wood surfaces from weathering but significantly increased water wettability of the surface. The incorporation of ZnO nanoparticles significantly reduced the colour change of the wood surfaces. As the concentration of ZnO increased, the colour stability and hydrophobicity of both the wood increased.

Analysis of wettability and contact angle of sodium bicarbonate impregnated wooden surfaces

Scots pine and spruce wood samples were vacuum impregnated with 3, 5, and 9% sodium bicarbonate solution. Contact angle measurements were made by dropping 0.05 mL of pure water and 3% saltwater solution onto the material’s surface. The surface roughness of each sample was measured, and that of Scots pine control samples was higher than that of spruce samples, but the surface roughness values of spruce wood were higher in the samples impregnated with sodium bicarbonate. When pure water or saltwater solution was dropped onto the samples, it was observed that as the waiting times increased, the contact angle value decreased, the droplet height decreased, and the droplet width increased. It was found that the contact angles were higher in the control samples of both tree species than in the samples of 5% and 7%. The contact angles of 9% impregnation solution, pure water, and salt water were higher than the control samples. As the solution ratio increased on the surfaces impregnated with sodium bicarbonate, the contact angle also increased, and the wettability behavior decreased accordingly. Sodium bicarbonate solution is effectively used in the impregnation process for pine and fir woods, making the materials more resistant to water under outdoor conditions. This solution significantly reduces the risk of deformation of wood by increasing the contact angle and reducing its water absorption properties.

A Study on the User Perception of CMF Design in South Korea, China, and Germany -Focused on Decorative Paper in Wooden Surface Material-

A Study on the User Perception of CMF Design in South Korea, China, and Germany -Focused on Decorative Paper in Wooden Surface Material-

Using Deep Learning Techniques for Anomaly Detection of Wood Surface

Using Deep Learning Techniques for Anomaly Detection of Wood Surface

Bioinspired all-day adaptive radiative cooler with high-power cooling and efficient suppressing overcooling

This research presents a design in the bionic on-off switch layer and thermal insulation layer, crucial for the cooling power adjustment of the radiative cooler. The design features a change in the upper surface area of the on-off switch layer, inspired by the unfolding and folding behaviors of pinto peanut leaves in day and night, which enables high-power cooling during the day and suppresses overcooling at night. The introduction of a bulge-pit structure in the thermal insulation layer reduces the heat exchange between the cooler and the outside. The novelty of this research lies in the integration of a bionic design, an innovative bulge-pit structure, and an optimized polyacrylonitrile spinning layer on the surface of green balsa wood. The study examines the cooling properties of the cooler under simulated day and night conditions. Key findings reveal that day subambient radiative cooling of 6.6 °C, which is slightly better than a passive radiative cooler. At night, it elevates the ambient temperature by 3.4 °C compared to a passive radiative cooler. The total energy savings applied in a specified area for all day are estimated to reach up to 770 kJ. This design marks a significant advancement in the radiative cooling field.