Channel Surface Research Articles

ANALYSIS OF PROPYLENE GLYCOL/ETHYLENE GLYCOL HEATING IN THE CYLINDRICAL CHANNEL OF THE SOLAR HEAT COLLECTOR

When designing solar thermal collectors, non-stationary operating conditions of the solar system are considered to determine the instantaneous heat output and temperature of the heat carriers during a given day or period. It is known that the amount of useful heat absorbed by a solar thermal collector is directly dependent on the temperature of the heat carrier at the inlet and outlet of the solar thermal collector. The calculation of the heat consumption and/or storage system also requires the temperature of the heat carrier at the outlet of the solar collector. The heating of the heat carrier in a solar collector can be divided into two stages: heating of the walls of the heat exchanger (cylindrical channel) in a solar thermal collector by solar energy and heating of propylene glycol/ethylene glycol in the heat exchanger (cylindrical channel) of a solar thermal collector. This paper presents seven methods for determining the temperature field of the walls of the heat exchanger (cylindrical channel) of a solar thermal collector, depending on the initial and boundary conditions. The most general case for calculating the temperature field of propylene glycol/ethylene glycol moving in the heat exchanger of a solar heat collector assumes the presence of heat exchange on the surfaces of its contact with the walls of the cylindrical channel and with the environment. The calculation takes into account the difficulties associated with the significant nonlinearity of boundary conditions of the "given surface radiation" type. That is, it is taken into account that one surface of the heat exchanger channel is turned to solar radiation, and the opposite is turned to the back wall of the solar heat collector. The solution is found analytically using the method of Green's functions.

Generalized extended (2+1)-dimensional Kadomtsev-Petviashvili equation in fluid dynamics: analytical solutions, sensitivity and stability analysis

This study discusses a new version of the (2+1)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$(2+1)$$\\end{document}-dimensional Kadomtsev-Petviashvili equation. This equation is used to model the behavior of nonlinear waves in various fields like ferromagnetic media, ion-acoustic waves in plasma physics, and fluid dynamics. It is instrumental in modeling surface and internal waves in straits or channels. The main goal of the research is to determine the exact solutions for this equation and analyze their physical characteristics. We obtain exact solutions using two improved techniques, namely the modified extended tanh-function and the modified generalized Kudryashov methods. These techniques investigate various exact solutions, such as exponential, rational, hyperbolic, and trigonometric. Besides, the sensitivity and the stability analysis of the model are presented. Additionally, three- and two-dimensional contour plots are created to present the physical behavior of the exact solutions.

A covalent organic framework nanosheet-nanochannel composite with signal amplification strategy for electrochemical enantioselective recognition

Recognition and separation of chiral isomers are of great importance in both industrial and biological applications. However, owing to identical molecular formulas and chemical properties of enantiomers, signal transduction and amplification are still two major challenges in chiral sensing. In this study, we developed an enantioselective device by integrating chiral covalent organic framework nanosheets (CONs) with nanochannels for sensitive identification and quantification of enantiomers. Using 3,4-dihydroxyphenylalanine (DOPA) as the model analyte, the as-prepared chiral nanofluidic device exhibits a remarkable chiral recognition ability to l-DOPA than d-DOPA. More importantly, due to the chelation of DOPA with Fe3+ ions, it can efficiently block the ion transport through channel and shield the channel surface charge, which will amplify the difference in the electrochemical response of l-DOPA and d-DOPA. Therefore, a sensitive chiral recognition can be achieved using the present nanofluidic device coupled using electrochemical amplification strategy. Notably, using this method, an ultra-low concentration of l-DOPA (as low as 0.21 pM) can be facilely and successfully detected with a linear range of 1 pM–10 μM. This study provides a reliable and sensitive approach for achieving highly selective detection of chiral molecules.

ON DEVELOPMENT OF OIL FIELDS

Using a literature review, the article concludes that the displacement of oil by surfactants affects interrelated factors: by affecting the surface tension at the oil-water-rock interface, SAM adsorption occurs on the surface of pore channels, rock surface water and oil wetting changes, the oil layer is broken up and washed from the rock surface, the dispersion of oil in water stabilizes, the phase permeability of the porous medium changes, and finally, the forced displacement of oil by the water phase occurs. Keywords: gravity, elastic, capillary forces, adhesion, adsorption.

Classification of sound speed fields in the Western Pacific Ocean based on tensor decomposition

The three-dimensional (3-D) sound speed structure of the ocean is a fundamental environmental element in studying underwater sound propagation modeling and forecasting. The accurate classification of the sound speed fields (SSFs) provides a comprehensive understanding and analysis of the sound propagation pattern. To take advantage of the 3-D structure of the ocean SSFs, this paper presents a quick method based on tensor decomposition for classifying the ocean 3-D SSFs. Utilizing the WOA18 dataset, High Order Iterative Orthogonal (HOOI) decomposition of the 3-D SSFs is executed so as to accurately extract the characteristic information of the SSFs. The Fuzzy C-Means clustering (FCM) method is applied to classify the feature tensors, partitioning of regional categories in different seasons and revealing the typical SSFs structures. By combining the BELLHOP model with analysis of the characteristics of the first convergence zone of each category, it is concluded that there are six categories of SSFs in the Western Pacific Ocean. The SSFs across all categories are primarily latitudinally distributed, featuring distinct sound channel axes and surface sound speed variations.

Biomimetic Superstructured Interphase for Aqueous Zinc-Ion Batteries.

The practical application of aqueous zinc-ion batteries (AZIBs) is greatly challenged by rampant dendrites and pestilent side reactions resulting from an unstable Zn-electrolyte interphase. Herein, we report the construction of a reliable superstructured solid electrolyte interphase for stable Zn anodes by using mesoporous polydopamine (2D-mPDA) platelets as building blocks. The interphase shows a biomimetic nacre's "brick-and-mortar" structure and artificial transmembrane channels of hexagonally ordered mesopores in the plane, overcoming the mechanical robustness and ionic conductivity trade-off. Experimental results and simulations reveal that the -OH and -NH groups on the surface of artificial ion channels can promote rapid desolvation kinetics and serve as an ion sieve to homogenize the Zn2+ flux, thus inhibiting side reactions and ensuring uniform Zn deposition without dendrites. The 2D-mPDA@Zn electrode achieves an ultralow nucleation potential of 35 mV and maintains a Coulombic efficiency of 99.8% over 1500 cycles at 5 mA cm-2. Moreover, the symmetric battery exhibits a prolonged lifespan of over 580 h at a high current density of 20 mA cm-2. This biomimetic superstructured interphase also demonstrates the high feasibility in Zn//VO2 full cells and paves a new route for rechargeable aqueous metal-ion batteries.

Validation of Fluid Flow Speed Behavior in Capillary Microchannels Using Additive Manufacturing (SLA Technology)

This research explores fluid flow speed behavior in capillary channels using additive manufacturing, focusing on stereolithography (SLA). It aims to validate microchannels fabricated through SLA for desired fluid flow characteristics, particularly capillary-driven flow. The methodology involves designing, fabricating, and characterizing microchannels via SLA, with improvements such as an air-cleaning step facilitating the production of microchannels ranging from 300 to 1000 µm. Experimental validation assesses fluid flow speed behavior across channels of varying dimensions, evaluating the impact of channel geometry, surface roughness, and manufacturing parameters. The findings affirm the feasibility and efficacy of SLA in producing microchannels with consistent and predictable fluid flow behavior between 300 to 800 µm. This study contributes insights into microfluidic device fabrication techniques and enhances the understanding of fluid dynamics in capillary-driven systems. Overall, it underscores the potential of additive manufacturing, specifically SLA, in offering cost-effective and scalable solutions for microfluidic applications. The validated fluid flow speed behavior in capillary channels suggests new avenues for developing innovative microfluidic devices with improved performance and functionality, marking a significant advancement in the field.

Correlation between CO2 Sensitivity and Channel-Layer Thickness in In2O3 Thin-Film Transistor Gas Sensors

CO2 monitoring is important for achieving net-zero emissions. Here, we report on a CO2 gas sensor based on an In2O3 thin-film transistor (TFT), which is expected to realize both low-temperature operation and high sensitivity. The effect of channel thickness on TFT performance is well known; however, its effect on CO2 sensitivity has not been fully investigated. We fabricated In2O3 TFTs of various thicknesses to evaluate the effect of channel thickness on CO2 sensitivity. Consequently, TFT gas sensors with thinner channels exhibited higher CO2 sensitivity. This is because the surface effect is more prominent for a thinner film, suggesting that charge transfer between gas molecules and the channel surface through gas adsorption has a significant impact on changes in the TFT parameters in the subthreshold region. The results showed that the In2O3 TFT in thin channels is a promising candidate for CO2-sensitive TFT gas sensors and is useful for understanding an effect of gas adsorption in oxide TFTs with a very thin channel as well.

Anti-bacterial PVA@Ag/PVDF NF membrane made by filtration-coating plus in-situ reduction of NPs for dye removal

In this study, a filtration-coating method was developed to create a PVA layer on a PVDF membrane, and then silver nanoparticles (Ag NPs) were introduced by in-situ reduction to form an antibacterial PVA@Ag/PVDF NF membrane. The relationship between the rejection of dye by the membrane, the morphology of the coated PVA layer and its coating process parameters, such as polymer concentration, crosslinking ratio, vacuum pressure, and time, was investigated. The filtration-coating method facilitated the infiltration of PVA molecules into the porous channel of PVDF membrane, thus improved the stability of coated PVA. Meanwhile, it was observed that high vacuum pressure (1 bar), high polymer concentration (2%), and short filtration time (5 min) have a similar effect to low polymer concentration (1%) and long filtration time (10 min), which results in the formation of a dense layer structure (2–5 μm) on the membrane surface and leads to a high rejection rate but low flux. While filtration at low vacuum pressure (0.1 bar) leads to a thin PVA layer (<0.2μm), and PVA turns to appear on the entrance and surface of pore channel of membrane. The coated membrane showed a stable performance during 72 hrs filtration. Furthermore, Ag NPs were incorporated into PVA layer by the in-situ reduction method, the obtained membrane showed an enhanced dye rejection (92% for methyl blue), and a low salt rejection (NaCl 18%) and moderate flux (17.2 L·m−2·h−1 at 1 bar). Moreover, the composite membrane demonstrated excellent antibacterial properties (Staphylococcus aureus and E. coli). Overall, this work may present a novel approach to prepare new NF membrane.

Stefan flow-inclusive mass transfer in a narrow cylindrical channel with a two-layer medium

The exploration and extraction of oil, coal, and gas reserves are closely tied to mass transfer phenomena within porous and fractured rock formations. Frequently, these processes involve the adsorption or desorption, dissolution, or evaporation of certain components on the surface of the pore channels. In these cases, Stefan hydrodynamic flows arise, and although they may be individually small, they can have a noticeable impact on mass transfer and flow structure considering particular length of the channel. The authors explore the issue of inert component diffusion from the surface of a capillary into a suspension flow. The analysis involves a two-layer flow, including a central two-phase (liquid and particles) component and a near-wall flow of the fluid carrier. A certain component from the channel’s surface permeates deep into the flow without interacting with the solid phase. In this research the authors solve a diffusion problem with boundary conditions that consider the presence of Stefan hydrodynamic flows. The calculations reveal that, depending on the magnitude of the Stefan flows and the length of the affected area, the porosity, and consequently, the viscosity of the two-phase flow zone can undergo significant variations.

Unconventional coke composition during high temperature anisole disproportionation on zeolites

Catalyst deactivation and shape selectivity in evolved products and retained coke are studied on medium, large and extra-large pore zeolites with varying Si/Al ratios in the disproportionation of anisole. Deactivation modelling as a function of time on stream highlights the key role of the catalyst pore volume. Changes in selectivity between the primary (methylanisole) and secondary (cresol) products are due to the overtaking of one path over a second for the production of cresol. The nature of the products (methyl phenols) inhibits the formation of “usual” polyaromatic and non-oxygenated coke via the Sullivan mechanism, leaving only adsorbed oxygenated monoaromatics, available for transalkylation reactions with the feed, having adsorbed and fouled most of the available surface in the catalyst channels.

Transient dispersion of reactive solute transport in electrokinetic microchannel flow

Motivated by emerging applications in bio-microfluidic devices, the present study rigorously examines the generalized Taylor–Gill hydrodynamic dispersion of a point source solute injected into a microchannel, influenced by a constant axial static electric field along the channel and charged surface with different wall potentials. The solute engages in a first-order irreversible chemical reaction at both the microchannel walls. By incorporating different wall potentials and absorptive coefficients at the lower and upper walls, the current transport model for electro-osmotic flows is extended to encompass a wider range of applications. The solute transport phenomenon is intricately modeled using the unsteady convective diffusion equation. Employing Gill's generalized dispersion model, a concentration decomposition technique, up to the third-order accuracy, we meticulously analyze the transport process. Furthermore, a comprehensive comparison between analytical outcomes and numerical simulations using the Brownian Dynamics method is undertaken, enhancing the robustness of the analytical approach. The scattering process is mainly analyzed with the help of exchange, convection, dispersion, and asymmetry coefficients, along with the mean concentration profile. The effect of initial solute release at various vertical locations in the microchannel is shown to exert a considerable impact on all the transport coefficients at initial times.

Engineering fully exposed edge-plane sites on carbon-based electrodes for efficient water oxidation

Endowing metal-free graphitic carbon electrodes with high electrocatalytic reactivity is a field of intense research, but remains elusive. Here, we introduce a prototypical edge-plane-site-specific engineering strategy on “herringbone” multi-walled carbon nanotubes by performing an intercalation-exfoliation and truncation process in molten inorganic salts. Controllable synthesis of the target H-MWCNTs-MS with fully exposed edge-plane sites on both the outer surface and inner channels was demonstrated. in-situ infrared spectroscopic study supports the theoretically energetic “edge-state” and identifies the reconstructed ketone/carboxyl-terminated edge sites under oxygen evolution reaction (OER) conditions. These oxygenated edge-plane sites boost charge redistribution and interlayer coupling, which essentially govern the synergistic catalysis, as evidenced by combined theoretical, electrokinetic, and H/D isotopic studies. Benefiting from the dense reactive sites and efficient electron tunneling, the H-MWCNTs-MS demonstrated impressive OER activity with an overpotential of 236 mV at a current density of 10 mA cm−2 in alkaline media, outperforming most state-of-the-art metal-free electrocatalysts reported to date. Furthermore, the catalyst displayed no noticeable degradation during 100 h of operation, indicating its potential for practical applications.

Optimization Design of Rocket Deflector Channel Surface Based on Kriging Surrogate Model

This study aims to optimize the gas flow environment of a rocket’s deflector channel. Numerical calculations and analysis were conducted on the influencing factors of a certain type of single-sided deflector channel, with the injection coefficient used as the evaluation index for the flow clearance. The study identified the deflector channel’s impact angle, curvature diameter of the bending section, and distance from the top of the deflector surface to the bottom as important structural parameters. There exists a complex nonlinear relationship between these parameters and the gas flow guiding effect of the deflector channel. The kriging surrogate model was employed for the optimization of the deflector channel’s surface. The results showed that, while meeting the basic requirements of the deflector channel, the optimized design improved the gas flow guiding effect by 27.58%, significantly enhancing the gas flow environment. The optimization error was within 1%, confirming the effectiveness and accuracy of the optimization. This study provides a reference for the future design and optimization of gas flow deflector channels, with the potential to improve the performance and efficiency of rocket deflector channels.

Design of dual-functional protic porous ionic liquids for boosting selective extractive desulfurization

Porous ionic liquids have demonstrated excellent performance in the field of separation, attributed to their high specific surface area and efficient mass transfer. Herein, task-specific protic porous ionic liquids (PPILs) were prepared by employing a novel one-step coupling neutralization reaction strategy for extractive desulfurization. The single-extraction efficiency of PPILs reached 75.0% for dibenzothiophene. Moreover, adding aromatic hydrocarbon interferents resulted in a slight decrease in the extraction efficiency of PPILs (from 45.2% to 37.3%, 37.9%, and 33.5%), indicating the excellent extraction selectivity of PPILs. The experimental measurements and density functional theory calculations reveal that the surface channels of porous structures can selectively capture dibenzothiophene by the stronger electrophilicity (Eint(HS surface channel/DBT) = −39.8 kcal mol−1), and the multiple extraction sites of ion pairs can effectively enrich and transport dibenzothiophene from the oil phase into PPILs through π···π, C–H···π and hydrogen bonds interactions. Furthermore, this straightforward synthetic strategy can be employed in preparing porous liquids, offering new possibilities for synthesizing PPILs with tailored functionalities.

Influence of heat flux profile on two-phase flow instability in parallel channels of helical coil once-through steam generator

To enhance the heat transfer capability, the helical coil once-through steam generator (HCOTSG) has been widely utilized in the small modular reactor (SMR). There are hundreds of parallel helical channels in the HCOTSG, and the coolant undergoes the phase change from subcooled liquid to superheated vapor in the helical tube. The flow oscillation between parallel channels may be triggered during the phase change. In present study, the two-phase flow instability is investigated with different heat flux profiles under many operating conditions. The thermal–hydraulic model for parallel channels of HCOTSG is established based on our previous work, while the local heat transfer phenomenon such as subcooled boiling, critical heat flux, and wall conduction are considered in detail. The heat flux profile along the tube is ascertained by the steady-state analysis of HCOTSG under different operating conditions and applied to the outside surface of the helical channel. The heat flux value is increased step by step to trigger the out-of-phase oscillation between parallel helical channels. The thermal–hydraulic model and analysis method are validated against experimental results. The characteristics of flow instability in the helical channel are also analyzed. It is observed that the delay effect causing the flow instability is more obvious if the void fraction exceeds 0.7 in the starting stage. Then the boundary of flow instability is compared under different heat flux profiles for various operating conditions of HCOTSG. The results suggest that the distribution of heat flux in the two-phase region plays a more significant role in the occurrence of flow instability in the parallel helical channel system. The thermal–hydraulic characteristics during flow instability are governed by the combined effects of void propagation and delayed feedback in the system. In conclusion, the thermal–hydraulic condition of HCOTSG undergoes the unstable region to achieve the normal operating point, which can be avoided by adjusting the operating parameters.

Oriented Interpenetrating Capillary Network with Surface Engineering by Porous ZnO from Wood for Membrane Emulsification.

Membrane emulsification technology has garnered increasing interest in emulsion preparation due to controllable droplet size, narrower droplet size distribution, low energy consumption, simple process design and excellent reproducibility. Nevertheless, the pore structure and surface engineering in membrane materials design play a crucial role in achieving high-quality emulsions with high throughput simultaneously. In this work, an oriented interpenetrating capillary network composed of highly aligned and interconnected wood cell lumens has been utilized to fabricate an emulsion membrane. A novel honeycomb porous ZnO layer obtained by a seed prefabrication-hydrothermal growth method was designed to reconstruct wood channel surfaces for enhanced microfluid mixing. The results show that through the unique capillary mesh microstructure of wood, the emulsion droplets were smaller in size, had narrower pore-size distribution, and were easy to obtain under high throughput conditions. Meanwhile, a well-designed ZnO layer could further improve the emulsion quality of a wood membrane, while the emulsifying throughput is still maintained at a higher level. This demonstrates that the convection process of the microfluid in these wood capillary channels was intensified markedly. This study not only develops advanced membrane materials in emulsion preparation, but also introduces a brand-new field for functional applications of wood.

Open-Top Patterned Hydrogel-Laden 3D Glioma Cell Cultures for Creation of Dynamic Chemotactic Gradients to Direct Cell Migration.

The laminar flow profiles in microfluidic systems coupled to rapid diffusion at flow streamlines have been widely utilized to create well-controlled chemical gradients in cell cultures for spatially directing cell migration. However, within hydrogel-based closed microfluidic systems of limited depth (≤0.1 mm), the biomechanical cues for the cell culture are dominated by cell interactions with channel surfaces rather than with the hydrogel microenvironment. Also, leaching of poly(dimethylsiloxane) (PDMS) constituents in closed systems and the adsorption of small molecules to PDMS alter chemotactic profiles. To address these limitations, we present the patterning and integration of a PDMS-free open fluidic system, wherein the cell-laden hydrogel directly adjoins longitudinal channels that are designed to create chemotactic gradients across the 3D culture width, while maintaining uniformity across its ∼1 mm depth to enhance cell-biomaterial interactions. This hydrogel-based open fluidic system is assessed for its ability to direct migration of U87 glioma cells using a hybrid hydrogel that includes hyaluronic acid (HA) to mimic the brain tumor microenvironment and gelatin methacrylate (GelMA) to offer the adhesion motifs for promoting cell migration. Chemotactic gradients to induce cell migration across the hydrogel width are assessed using the chemokine CXCL12, and its inhibition by AMD3100 is validated. This open-top hydrogel-based fluidic system to deliver chemoattractant cues over square-centimeter-scale areas and millimeter-scale depths can potentially serve as a robust screening platform to assess emerging glioma models and chemotherapeutic agents to eradicate them.

Inferring channel incision in gravel‐bed rivers: Integrating LiDAR data, historical aerial photographs and drone‐based SfM topo‐bathymetry

AbstractChannel incision is an evident trend for river evolution in many European rivers and notably the Western Carpathians, whose former braided and multichannel wandering river system is transforming into a single‐thread channel, but it is often difficult to separate drivers and determine if incision is finished or is still ongoing. To overpass these research gaps, this paper presents an innovative approach to assess the multidecadal incision of the Belá River in the Western Carpathians since 1949 by LiDAR‐based analyses of floodplain surfaces above the river channel dated from historical aerial images. Detailed analyses of ongoing incision were also calculated based on DEM of differences (DoD) using Structure‐from‐Motion (SfM) photogrammetry‐derived topo‐bathymetric models. The study applied the BACI (Before‐After‐Control‐Impact) approach that compared pre‐state (Before), post‐state (After) and reach (Control) that is not affected by potential external effects with degraded (impacted) reach to be able to distinguish the driver effects. Floodplain channel surface analyses indicate the maximum incision up to 4 m and incision rate of 5.7 cm/year that occurred in the most degraded reach. Moreover, cross‐section profiles point to accelerated incision of 24.5 cm/year in the last 10 years (2011–2021) by the propagation of incision upstream. Overall, the net changes from the UAV survey pointed to 22 759 m3 of gravel sediments, constituting outwash from the 1.6 km long channel system (2015–2022) by incision, whereas analyses of historical channel surfaces estimated erosion of 573 303 m3 from impacted reaches between 1949 and 2020. Incision evidence is only observed in the downstream part below the control section due to local drivers (channel regulation, comprising embankment and gravel mining that activated a backward erosion of the system with knickpoint migration upstream). This analysis shows the benefits of combining different sources of data to separate long‐term and ongoing channel responses and the BACI‐approach to better target cause–effect relationships in space and time.

Elucidating the effects of surface wettability on boiling heat transfer using hydrophilic and hydrophobic surfaces with laser-etched microchannels

This study explores the nuanced interplay between surface wettability and morphology in nucleate boiling heat transfer. Surfaces with identical microstructures but varying wettability are created on copper substrates using laser texturing and a hydrophobic agent. The spacing between laser-etched microchannels is adjusted to achieve different contact angles and percentages of laser-textured areas. Boiling performance is assessed with variations in channel spacing and surface coverage, revealing significant differences between hydrophilic and hydrophobic surfaces. The critical heat flux (CHF) enhancement mechanisms are identified, emphasizing either enhanced liquid replenishment or separate boiling and liquid-supply regions. A critical laser line spacing of 100 μm is determined, where hydrophobic and hydrophilic variants exhibit similar CHF. Interestingly, hydrophilic surfaces show a weak correlation between the heat transfer coefficient (HTC) and contact angle, while hydrophobic surfaces demonstrate a strong correlation. This separation of surface morphology and wettability confirms that lower wettability promotes early nucleate boiling and high HTC, whereas hydrophilic variants contribute to enhanced CHF with lower HTC. These distinctions are most prominent at high coverage with laser-textured areas and diminish as coverage decreases. The findings provide valuable insights into optimizing surface properties for efficient boiling heat transfer applications.