Superfluid Droplets Research Articles

Quantized vortex nucleation in collisions of superfluid nanoscopic helium droplets at zero temperature.

We address the collision of two superfluid 4He droplets at non-zero initial relative velocities and impact parameters within the framework of liquid 4He time-dependent density functional theory at zero temperature. Despite the small size of these droplets (1000 He atoms in the merged droplet) imposed by computational limitations, we have found that quantized vortices may be readily nucleated for reasonable collision parameters. At variance with head-on collisions, where only vortex rings are produced, collisions with a non-zero impact parameter produce linear vortices that are nucleated at indentations appearing on the surface of the deformed merged droplet. Whereas for equal-size droplets, vortices are produced in pairs, an odd number of vortices can appear when the colliding droplet sizes are different. In all cases, vortices coexist with surface capillary waves. The possibility for collisions to be at the origin of vortex nucleation in experiments involving very large droplets is discussed. An additional surprising result is the observation of the drops coalescence even for grazing and distal collisions at relative velocities as high as 80 and 40m/s, respectively, induced by the long-range van der Waals attraction between the droplets.

Quantum dripping of superfluid 4He

Superfluid 4He droplets exhibit robustly quantized dripping periods despite gradually varying input flow rates owing to their high amplitude and undamped oscillation. Since “superfluid” is already placed at the beginning of the sentence, “as a result of superfluidity” may be removed here.

Self-interacting superfluid dark matter droplets

ABSTRACT We assume dark matter to be a cosmological self-gravitating Bose–Einstein condensate of non-relativistic ultralight scalar particles with competing gravitational and repulsive contact interactions and investigate the observational implications of such model. The system is unstable to the formation of stationary self-bound structures that minimize the energy functional. These cosmological superfluid droplets, which are the smallest possible gravitationally bound dark matter structures, exhibit a universal mass profile and a corresponding universal rotation curve. Assuming a hierarchical structure formation scenario where granular dark matter haloes grow around these primordial stationary droplets, the model predicts cored haloes with rotation curves that obey a single universal equation in the inner region ($r\, \lesssim \, 1$ kpc). A simultaneous fit to a selection of galaxies from the SPARC data base chosen with the sole criterion of being strongly dark matter dominated even within the innermost region, indicates that the observational data are consistent with the presence of a Bose–Einstein condensate of ultralight scalar particles of mass m ≃ 2.2 × 10−22 eV c−2 and repulsive self-interactions characterized by a scattering length as ≃ 7.8 × 10−77 m. Such small self-interactions have profound consequences on cosmological scales. They induce a natural minimum scale length for the size of dark matter structures that makes all cores similar in length (∼1 kpc) and contributes to lower their central densities.

Diffraction imaging of light induced dynamics in xenon-doped helium nanodroplets

We explore the light induced dynamics in superfluid helium nanodroplets with wide-angle scattering in a pump–probe measurement scheme. The droplets are doped with xenon atoms to facilitate the ignition of a nanoplasma through irradiation with near-infrared laser pulses. After a variable time delay of up to 800 ps, we image the subsequent dynamics using intense extreme ultraviolet pulses from the FERMI free-electron laser. The recorded scattering images exhibit complex intensity fluctuations that are categorized based on their characteristic features. Systematic simulations of wide-angle diffraction patterns are performed, which can qualitatively explain the observed features by employing model shapes with both randomly distributed as well as structured, symmetric distortions. This points to a connection between the dynamics and the positions of the dopants in the droplets. In particular, the structured fluctuations might be governed by an underlying array of quantized vortices in the superfluid droplet as has been observed in previous small-angle diffraction experiments. Our results provide a basis for further investigations of dopant–droplet interactions and associated heating mechanisms.

Equilibrium shapes of two- and three-dimensional two-phase rotating fluid drops with surface tension: Effects of inner drop displacement

The shapes of rotating fluid drops held together by surface tension are an important field of study in fluid mechanics. Recently, experiments with micrometer-scale droplets of liquid helium have been undertaken and it has proven useful to compare the shapes of the resultant superfluid droplets with classical analogs. If the helium is a mixture of He3 and He4, two phases are present. In a recent paper, the shapes of rotating two-phase fluid droplets were calculated where the inner drop was constrained to stay at the drop center. The outer shapes and dimensionless rotation rate–angular momentum relationships were shown to be similar to single-phase drops, providing that the density and surface tension scales were chosen appropriately. In the current paper, I investigate models in which the inner drop can displace from the center. In order to simplify the analyses, two-dimensional drops are first investigated. I show that the inner drop is unstable in the center position if its density is greater than the outer density and that the inner drop will move toward the outer boundary of the drop in these cases. When the inner drop has a higher density than the outer drop, the moment of inertia of displaced inner drops is increased relative to centered drops, and hence, the kinetic energy is decreased. Shapes of two- and three-dimensional drops, rotation rate–angular momentum, and kinetic and surface energy relationships are investigated for off-axis inner drops with parameters relevant to recent liquid He experiments.

4D-XY Superfluid Transition and Dissipation in 4He Confined in Nanoporous Media

4He confined in nanoporous Gelsil glass is a unique, strongly correlated Bose system exhibiting quantum phase transition (QPT) by controlling pressure. Previous studies revealed that the QPT occurs with four-dimensional (4D) XY criticality, which appears in the zero-temperature limit of the superfluid density. However, the P–T phase diagram also suggested that the 4D XY nature appears at finite temperatures. Here, we have determined the critical exponent of the superfluid density ρs of 4He in two Gelsil samples that have pore diameter to be about 3 nm, using a newly developed mechanical resonator technique. The critical exponent ζ in the powerlaw fitting ρs ∝ |1 − T/Tc|ζ, where Tc is the superfluid transition temperature, was found to be 1.0 ± 0.1 for all pressures realized in this experiment, 0.1 < P < 2.4 MPa. This value of ζ gives decisive evidence that the finite-temperature superfluid transition belongs to the 4D XY universality class. The emergence of the 4D XY criticality is explained by the existence of many nanoscale superfluid droplets, the so-called localized Bose–Einstein condensates (LBECs), above Tc. Due to the large energy cost for 4He atoms to move between the LBECs, the phase of the LBEC order parameters fluctuates not only in spatial (3D) but imaginary time (+1D) dimensions, resulting in the 4D XY criticality by a temperature near Tc. Since the finite size of the system in the imaginary time dimension Lτ is larger than the pore size, the 4D XY critical phenomenon is observed. In the very vicinity of Tc at which the correlation length exceeds Lτ, there may be a crossover from 4D to 3D XY criticality. Below Tc, macroscopic superfluidity grows in the nanopores of Gelsil by the alignment of the phases of the LBEC order parameters. An excess dissipation peak observed below Tc is well explained by this phase-matching process.

Aggregation of solutes in bosonic versus fermionic quantum fluids.

Quantum fluid droplets made of helium-3 (3He) or helium-4 (4He) isotopes have long been considered as ideal cryogenic nanolabs, enabling unique ultracold chemistry and spectroscopy applications. The droplets were believed to provide a homogeneous environment in which dopant atoms and molecules could move and react almost as in free space but at temperatures close to absolute zero. Here, we report ultrafast x-ray diffraction experiments on xenon-doped 3He and 4He nanodroplets, demonstrating that the unavoidable rotational excitation of isolated droplets leads to highly anisotropic and inhomogeneous interactions between the host matrix and enclosed dopants. Superfluid 4He droplets are laced with quantum vortices that trap the embedded particles, leading to the formation of filament-shaped clusters. In comparison, dopants in 3He droplets gather in diffuse, ring-shaped structures along the equator. The shapes of droplets carrying filaments or rings are direct evidence that rotational excitation is the root cause for the inhomogeneous dopant distributions.

Coexistence of vortex arrays and surface capillary waves in spinning prolate superfluid He4 nanodroplets

Within Density Functional Theory, we have studied the interplay between vortex arrays and capillary waves in spinning prolate He-4 droplets made of several thousands of helium atoms. Surface capillary waves are ubiquitous in prolate superfluid He-4 droplets and, depending on the size and angular momentum of the droplet, they may coexist with vortex arrays. We have found that the equilibrium configuration of small prolate droplets is vortex-free, evolving towards vortex-hosting as the droplet size increases. This result is in agreement with a recent experiment [S.M. O'Connell et al., Phys. Rev. Lett. 124, 215301 (2020)], where it has been disclosed that vortex arrays and capillary waves coexist in the equilibrium configuration of very large drops. Contrarily to viscous droplets executing rigid body rotation, the stability phase diagram of spinning He-4 droplets cannot be universally described in terms of dimensionless angular momentum and angular velocity variables: instead, the rotational properties of superfluid helium droplets display a clear dependence on the droplet size and the number of vortices they host.

Core fragmentation in simplest superfluid dark matter scenario

We study the structure of galactic halos within a scalar dark matter model, endowed with a repulsive quartic self-interaction, capable of undergoing the superfluid phase transition in high-density regions. We demonstrate that the thermalized cores are prone to fragmentation into superfluid droplets due to the Jeans instability. Furthermore, since cores of astrophysical size may be generated only when most of the particles comprising the halo reside in a highly degenerate phase-space, the well-known bound on the dark matter self-interaction cross section inferred from the collision of clusters needs to be revised, accounting for the enhancement of the interaction rate due to degeneracy. As a result, generation of kpc-size superfluid solitons, within the parameter subspace consistent with the Bullet Cluster bound, requires dark matter particles to be ultra-light.

Dynamical phase transition of photon condensate in an optical cavity

We demonstrate the existence of a dynamical phase transition in the quasi-one-dimensional photonic condensate system formed in an axially symmetric optical cavity filled with a suitable thermalizing medium. The dynamical transition is observed to occur between the periodically modulated superfluid phase and the superfluid droplets phase. The parameter domains and conditions leading to such a dynamical phase transition are identified. It is observed that such a transition in the system owes its origin to the collective photon dynamics rather than thermal or quantum effects.

Metal clusters synthesized in helium droplets: structure and dynamics from experiment and theory

Metal clusters have drawn continuous interest because of their high potential for the assembly of matter with special properties that may significantly differ from the corresponding bulk. Controlled combination of particular elements in one nanoparticle can increase the options for the creation of new materials for photonic, catalytic, or electronic applications. Superfluid helium droplets provide confinement and ultralow temperature, i.e. an ideal environment for the atom-by-atom aggregation of a new nanoparticle. This perspective presents a review of the current research progress on the synthesis of tailored metal and metal oxide clusters including core-shell designs, their characterization within the helium droplet beam, deposition on various solid substrates, and analysis via surface diagnostics. Special attention is given to the thermal properties of mixed metal clusters and questions about alloy formation on the nanoscale. Experimental results are accompanied by theoretical approaches employing computational chemistry, molecular dynamics simulations and He density functional theory.

Shapes of rotating normal fluid He3 versus superfluid He4 droplets in molecular beams

Previous single-pulse extreme ultraviolet and X-ray coherent diffraction studies revealed that superfluid 4He droplets obtained in free jet expansion acquire sizable angular momentum, resulting in significant centrifugal distortion. Similar experiments with normal fluid 3He droplets may help elucidating the origin of the of the large degree of rotational excitation and highlight similarities and differences of dynamics in normal and superfluid droplets. Here, we present the first comparison of the shapes of isolated 3He and 4He droplets following expansion of the corresponding fluids in vacuum at temperatures as low as ~ 2 K. Large 3He and 4He droplets with average radii of ~160 nm and ~350 nm, respectively, were produced. We find that the majority of the 3He droplets in the beam correspond to rotating oblate spheroids with reduced average angular momentum ($\Lambda$) and reduced angular velocities ($\Omega$) similar to that of 4He droplets. Given the different physical nature of 3He and 4He, this similarity in $\Lambda$ and $\Omega$ may be surprising and suggest that similar mechanisms induce rotation regardless of the isotope. We hypothesized that the observed distribution of droplet sizes and angular momenta stem from processes in the dense region close to the nozzle. In this region, the significant velocity spread and collisions between the droplets induce excessive rotation followed by droplet fission. The process may repeat itself several times before the droplets enter the collision-fee high vacuum region further downstream.

Angular Momentum in Rotating Superfluid Droplets.

The angular momentum of rotating superfluid droplets originates from quantized vortices and capillary waves, the interplay between which remains to be uncovered. Here, the rotation of isolated submicrometer superfluid ^{4}He droplets is studied by ultrafast x-ray diffraction using a free electron laser. The diffraction patterns provide simultaneous access to the morphology of the droplets and the vortex arrays they host. In capsule-shaped droplets, vortices form a distorted triangular lattice, whereas they arrange along elliptical contours in ellipsoidal droplets. The combined action of vortices and capillary waves results in droplet shapes close to those of classical droplets rotating with the same angular velocity. The findings are corroborated by density functional theory calculations describing the velocity fields and shape deformations of a rotating superfluid cylinder.

Quantum droplets of bosonic mixtures in a one-dimensional optical lattice

We demonstrate the existence of quantum droplets in two-component one-dimensional Bose-Hubbard chains. The droplets exist for any strength of repulsive intra-species interactions provided they are balanced by comparable attractive inter-species interactions. The ground-state phase diagram is presented and the different phases are characterized by examining the density profile and off-diagonal one- and two-body correlation functions. A rich variety of phases is found, including atomic superfluid gases, atomic superfluid droplets, pair superfluid droplets, pair superfluid gases and a Mott-insulator phase. A parameter region prone to be experimentally explored is identified, where the average population per site is lower than three atoms, thus avoiding three-body losses. Finally, the bipartite entanglement of the droplets is found to have a non-trivial dependence on the number of particles.

Disorderless Quasi-localization of Polar Gases in One-Dimensional Lattices.

One-dimensional polar gases in deep optical lattices present a severely constrained dynamics due to the interplay between dipolar interactions, energy conservation, and finite bandwidth. The appearance of dynamically bound nearest-neighbor dimers enhances the role of the 1/r^{3} dipolar tail, resulting in the absence of external disorder, in quasi-localization via dimer clustering for very low densities and moderate dipole strengths. Furthermore, even weak dipoles allow for the formation of self-bound superfluid lattice droplets with a finite doping of mobile, but confined, holons. Our results, which can be extrapolated to other power-law interactions, are directly relevant for current and future lattice experiments with magnetic atoms and polar molecules.

Spontaneous formation of polar superfluid droplets in a p -wave interacting Bose gas

We study the quantum fluctuations in the condensates of a mixture of bosonic atoms and molecules with interspecies p-wave interaction. Our analysis shows that the quantum phase of coexisting atomic and molecular condensates is unstable at the mean-field level. Unlike the mixture of s-wave interaction, the Lee-Huang-Yang correction of p-wave interaction is unexpectedly found here to exhibit an opposite sign with respect to its mean-field term above a critical particle density. This quantum correction to the mean-field energy provides a remarkable mechanism to self-stabilize the phase. The order parameter of this superfluid phase carries opposite finite momenta for the two atomic species while the molecular component is a polar condensate. Such a correlated order spontaneously breaks a rich set of global U(1) gauge, atomic spin, spatial rotation and translation, and time-reversal symmetries. For potential experimental observation, the phenomenon of anisotropic polar superfluid droplets is predicted to occur, when the particle number is kept finite.

Conservation of Hot Thermal Spin-Orbit Population of 2P Atoms in a Cold Quantum Fluid Environment.

The 0.4 K internal temperature of superfluid helium nanodroplets is believed to guarantee a corresponding ground-state population of dopant atoms and molecules inside this cryogenic matrix. We have recorded 6s ← 5p excitation spectra of indium atoms in helium droplets and found two absorption bands separated by about 2000 cm-1, a value close to the spin-orbit (SO) splitting of the In 2P ground state. The intensities of the bands agree with a thermal population of the 2P1/2 and 2P3/2 states at 870 K, the temperature of the In pick-up cell. Applying femtosecond pump-probe spectroscopy, we found the same dynamical response of the helium solvation shell after the photoexcitation of the two bands. He-density functional theory simulations of the excitation spectra are in agreement with the bimodal structure. Our findings show that the population of SO levels of hot dopants is conserved after pick-up inside the superfluid droplet. Implications for the interpretation of experiments on molecular aggregates are discussed.

Modelling electron beam induced dynamics in metallic nanoclusters

We present a computational scheme to simulate beam induced dynamics of atoms in surface dominated, metallic systems. Our approach is based on molecular dynamics and Monte Carlo techniques. The model is tested with clusters comprised of either Ni, Ag or Au. We vary their sizes and apply different electron energies and cluster temperatures to elucidate fundamental relations between these experimental parameters and beam induced displacement probabilities. Furthermore, we demonstrate the capability of our code to simulate beam driven dynamics by using Ag and Au clusters as demonstration systems. Simulations of beam induced displacement and sputtering effects are compared with experimental results obtained via scanning transmission electron microscopy. The clusters in question are synthesised with exceptional purity inside inert superfluid He droplets and deposited on amorphous carbon supports. The presented results may help to understand electron beam driven processes in metallic systems.

Spinning superfluidHe4nanodroplets

We have studied spinning superfluid $^4$He nanodroplets at zero temperature using Density Functional theory. Due to the irrotational character of the superfluid flow, the shapes of the spinning nanodroplets are very different from those of a viscous normal fluid drop in steady rotation. We show that when vortices are nucleated inside the superfluid droplets, their morphology, which evolves from axisymmetric oblate to triaxial prolate to two-lobed shapes, is in good agreement with experiments. The presence of vortex arrays confers to the superfluid droplets the rigid-body behavior of a normal fluid in steady rotation, and this is the ultimate reason of the surprising good agreement between recent experiments and the classical models used for their description.

Shapes of rotating superfluid helium nanodroplets

Author(s): Bernando, C; Tanyag, RMP; Jones, C; Bacellar, C; Bucher, M; Ferguson, KR; Rupp, D; Ziemkiewicz, MP; Gomez, LF; Chatterley, AS; Gorkhover, T; Muller, M; Bozek, J; Carron, S; Kwok, J; Butler, SL; Moller, T; Bostedt, C; Gessner, O; Vilesov, AF | Abstract: Rotating superfluid He droplets of approximately 1 μm in diameter were obtained in a free nozzle beam expansion of liquid He in vacuum and were studied by single-shot coherent diffractive imaging using an x-ray free electron laser. The formation of strongly deformed droplets is evidenced by large anisotropies and intensity anomalies (streaks) in the obtained diffraction images. The analysis of the images shows that in addition to previously described axially symmetric oblate shapes, some droplets exhibit prolate shapes. Forward modeling of the diffraction images indicates that the shapes of rotating superfluid droplets are very similar to their classical counterparts, giving direct access to the droplet angular momenta and angular velocities. The analyses of the radial intensity distribution and appearance statistics of the anisotropic images confirm the existence of oblate metastable superfluid droplets with large angular momenta beyond the classical bifurcation threshold.