In this paper, we investigated vector equilibrium problems and gave the scalarization results for weakly efficient solutions, Henig efficient solutions, and globally efficient solutions to the vector equilibrium problems without the convexity assumption. Using nonsmooth analysis and the scalarization results, we provided the necessary conditions for weakly efficient solutions, Henig efficient solutions, globally efficient solutions, and superefficient solutions to vector equilibrium problems. By the assumption of convexity, we gave sufficient conditions for those solutions. As applications, we gave the necessary and sufficient conditions for corresponding solutions to vector variational inequalities and vector optimization problems.